• Title/Summary/Keyword: 냉각재시료

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경수로 원자로 냉각재 CRUD 대표시료 채취 기술에 관한 고찰

  • Kim, Min-Jae;Kim, Jong-Bin;Gang, Deok-Won;Park, Jong-Seok
    • 대한방사선방어학회:학술대회논문집
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    • 2009.04a
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    • pp.254-255
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    • 2009
  • 국내 경수로 원전의 경우, 원전의 효율적, 경제적 운영차원에서 장주기 운전으로 패턴을 바뀌면서 핵연료봉 표면상에 크러드(crud)의 침적량은 점점 증가하는 경향을 나타내고 있다. 이러한 경향은 원자로의 출력 제어와 직결되면서 이에 대한 문제 해결을 위한 대표성이 있는 시료의 채취와 재현성이 있는 부식 생성물의 측정이 요구되어져 왔다. 원자로 계통 내에서 부식생성물의 농도변화에 대한 평가, 특히 입자농도가 증가되어지면 축방향 출력편차(Axial Offset Anomaly, AOA)가 발생될 수 있는 위험에 노출되거나, 핵연료 교체를 위해 발전소 정지시(shut down) 부식생성물의 방출이 급격히 증가되는 것으로 나타났다. 특히 입자성을 띤 물질은 존재의 특성상 이들 물질에 대한 대표시료의 채취가 어려울 뿐 아니라 grab 채취로 인해, 분석결과에 대한 재현성이 낮으며 계통 선량율의 제어와 작업자 피폭관리에 많은 어려움이 뒤따르고 있어 선진 원전 운영국에서는 앞 다투어 대표시료를 채취 할 수 있는 capillary sampling 법이나 integrated sampling법을 적용해 오고 있다. 본 논문에서는 국내 경수로 원전에서 일반적으로 사용하고 있는 grab sampling 법에 대한 문제점 파악과 해외 원전에서 사용 중인 capillary sampling 법의 국내 적용 가능성에 대해 살펴보았다.

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원자력발전소 1차계통 탈염기 제염계수 특성 분석

  • 성기방;강덕원
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.387-391
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    • 1997
  • 냉각재중의 방사능을 띤 성분 중에는 이온교환기에서 제거가 가능한 이온성분과 함께 필터에 의해서 주로 제거되는 입자성 물질로 존재한다. 운전중의 냉각재내 방사성 부식생성물의 물리적 조성 분포 측정 결과에 따르면 90%이상이 0.45$mu extrm{m}$필터에 의해 제거되는 입자성 물질로 구성되어 있다. 이로 인해 새수지 충전후 얼마 사용하지 않은 탈염기의 제염계수가 탈염기에서 완벽한 제거가 어려운 입자성 부식생성물로 인해 10이하를 나타낼 수 있다. 1차계통에 쓰이는 수지의 성능검사를 위해 사용하고 있는 현재의 제염계수 측정법은 다음과 같은 두가지 이유로 완벽하지 않음을 알 수 있다. 첫째, 냉각재중의 방사능을 띤 성분중에는 이온교환기에서 제거가 가능한 이온성분과 함께 필터에 의해 제거되는 입자성 물질도 함께 존재하므로 탈염기의 제염계수 측정 절차는 입자성 물질을 배제한 후 측정해야 하며, 특히 수치 교체를 결정하기 위한 제염계수 측정시에는 여과된 여액으로 방사능 농도를 측정하는 것이 바람직하다. 둘째 운전중인 냉각재의 시료중에는 핵분열 수율이 높고 핵연료봉 손상부위로 유출이 용이한 불활성 기체핵종들이 많이 존재하며, 탈염기 후단에서 채취한 시료중에도 많이 존재하고, 시료 이송과 방사능 측정동안의 짧은 시간동안에도 계속 붕괴반응함으로서 새로 생긴 핵종으로 인해 마치 탈염기의 제거능이 낮은 것으로 오판될 수 있다. 이러한 측정 오차인자를 고려하여야 1차계통 탈염기의 교환능력을 정확히 판정할 수 있다.

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Correlation of $^{137}Cs/^{60}Co$ Activity Ratio in Radwaste with Primary Coolant (원자로 냉각재와 방사성폐기물 내 $^{137}Cs/^{60}Co$ 핵종비)

  • Jee, Kwang-Yong;Park, Yeong-Jae;Pyo, Hyung-Yeol;Ahn, Hong-Joo;Kim, Won-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.9-17
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    • 2007
  • In order to compare the correlation of radioactivity ratio between the radwaste streams and the primary coolant of PWR NPPs, A RCS sampling kit was installed to primary coolant system for the collection of the radionuclides during the normal operation of NPPs. RCS samples were collected from PWR type of domestic NPPs through 2004 to 2005, and pretreated with acid microwave digestion or leaching method to assay quantitatively of several interesting radionuclides. The radioactivity ratios of $^{137}Cs\;to\;^{60}Co$ in a filter cartridge and a resin cartridge were 2.3E-2 and 7.3E-1, respectively. At a same period of the reactor operating cycle, the radioactivity ratios of $^{137}Cs\;to\;^{60}Co$ were 6.3E-1 for a evaporator bottom, 6.7E-1 for a spent resin, and 5.6E-2 for a dry active waste, so that these radwaste streams were identified as having similar characteristics with the corresponding RCS samples.

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Hotcell Examination of TMI-2 Debris (1)

  • 이기순;김은가;정양홍;유병옥;서항석;박대규;안상복;주용선;정경환
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.267-272
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    • 1998
  • TMI-2 사고는 2차 냉각계통의 이상을 발단으로 해서 노심이 용융되는 중대사고로 진행하였는데, 노심의 손상이 실제 예상한 것보다 심하게 나타났다. 따라서 이 사고를 계기로 하여 원자로 안전성에 대해 큰 문제점이 제기되어 안전성의 재평가의 필요성이 크게 대두되었다. 이와 같은 필요성에 따라 TMI-2 원자로에서 채취한 노심재 시료에 대한 광범위한 핫셀시험이 수행되었는데, 이 연구에서는 노심 상부에서 채취한 데브리스 시료에 대한 핫셀시험을 수행하여 그 결과를 검토 분석하였다.

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Effect of Cooling-rate Dependence on the Magnitude of Thermoremanent Magnetization (냉각률이 자화에 미치는 영향)

  • Yu, Yong-Jae
    • 한국지구물리탐사학회:학술대회논문집
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    • 2010.10a
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    • pp.43-45
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    • 2010
  • Acquisition of thermoremanent magnetization follows a Boltzman statistics, as such long reaction time in a slowly cooled environment allows more chance to align individual magnetic particles parallel to the external magnetic field. Hence it has been proposed that the slowly cooled rocks often acquire stronger magnetization than the rapidly cooled ones. Such a proposition has been experimentally validated to be true for the fine-grained magnetite- or titanomagnetite bearing basaltic rocks collected from the mid-ocean ridges. However, the effect of cooling-rate on the remanence intensity appears to be insignificant for nominal grain ranges.

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Changes in Quality of Lettuce During Storage by Immersion-Type Hydrocooling (침지식 냉수냉각에 의한 상치의 저장중 품질변화)

  • Jeong, Jin-Woong;Kim, Byeong-Sam;Kim, Oni-Woung;Nahmgung, Bae;Park, Kee-Jai
    • Korean Journal of Food Science and Technology
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    • v.27 no.4
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    • pp.537-545
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    • 1995
  • Quality changes of lettuce were studied during storage to investigate the efficiency, cooling properties and the washing and storage effects of immersion-type hydrocooling. As a result of plotting the nondimensionalized lettuce temperature versus cooling time, its cooling rate coefficient was shown to be $-0.365\;min^{-1}{\sim}-0.255\;min^{-1}\;(R^2=0.99{\sim}0.88)$. Rate of weight loss was not significantly (p>0.05) different between lettuces with various treatment conditions during storage at $5^{\circ}C$. However, during storage at $15^{\circ}C$, weight loss of hydrocooled lettuce was lower than that of non-treated lettuce after from 10 to 15 days. Especially, The lettuce packed with PE was more effective than that packed with try in terms of packing condition after hydrocooling. Lettuce pretreated with sterilizing agent, packed with PE vinyl film, removed residual water after hydrocooling had lower decaying rate than any other lettuces. Changes of L and b values in hydrocooled lettuce were slower than those of non-treated one. During changes of chlorophyll content, the initial value, $115.7{\sim}147.3\;mg%$ was decreased to $50{\sim}60%$ after 25 days of storage at $5^{\circ}C$ and within 15 days of storage at $15^{\circ}C$. It could be presumed that the addition of sterilizing agent reduced the initial level of overall total and coliform count and its growth rate during storage. The respiration rate of hydrocooled lettuce at $5^{\circ}C$ was $23.95\;mg{\cdot}CO_2/kg\;hr$, which is 10% of those of non-treated lettuce.

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Campylobacter spp., Salmonella spp. and Escherichia coli of Broiler Viscera Silage added with Table Sugar (설탕 첨가에 따른 육계 내장 사일리지의 Campylobacter와 Salmonella spp. 및 Escherichia coli 성장 변화)

  • 조상훈;이영현
    • Food Science of Animal Resources
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    • v.24 no.1
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    • pp.92-96
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    • 2004
  • pH, Campylobacter spp., Salmonella spp. and Escherichia coli of under-utilized broiler viscera silage added with table sugar during storage at 25$^{\circ}C$ were investigated. pH of silage with 0 and 1 %(w/w) table sugar increased continuously after day 2, but that of 3, 4 and 5% remained 4.0∼4.2 after decrease from 5.2 at day 0. The Campylobacter spp. count of 0% was 8.21 at day 4, however that of 3 and 5% showed 7.56 and 7.38 logCFU/mL, respectively. The Salmonella spp. of 0% maintained 5.8∼6.8 logCFU/mL during fermentation, but that of 3 and 5% was not detected after day 4. The initial E. coli count of silage without table sugar was 5.8 log CFU/mL, but reduced to 4.1 log CFU/mL at day 2, and maintained at the level between 4.0 and 5.0 log CFU/mL, thereafter. However, E. coli was not detected in the silage with 3 and 5% table sugar after day 2. The counts of Campylobacter spp., Salmonella spp. and Escherichia coli of under-utilized broiler viscera silage reduced markedly by adding table sugar. It was proved that the possibility of microbiologically safe broiler offal silage as a potential resource for animal feed materials was improved.

Property Change of Heat-reservoir Refractory Brick With Varying Compositions and Sintering Conditions Utilizing Mill-scale and Red-firing Clay As Raw Materials (밀스케일과 적점토를 원료로한 축열재에서 원료성분과 소성조선에 따른 특성 변화)

  • Kim, Jeong-Seog;Kim, Hong
    • Resources Recycling
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    • v.8 no.1
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    • pp.23-28
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    • 1999
  • Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

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Evaluation of $^{14}C$ Behavior Characteristic in Reactor Coolant from Korean PWR NPP's (국내 경수로형 원자로 냉각재 중의 $^{14}C$ 거동 특성 평가)

  • Kang, Duk-Won;Yang, Yang-Hee;Park, Kyong-Rok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.1
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    • pp.1-7
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    • 2009
  • This study has been focused on determining the chemical composition of $^{14}C$ - in terms of both organic and inorganic $^{14}C$ contents - in reactor coolant from 3 different PWR's reactor type. The purpose was to evaluate the characteristic of $^{14}C$ that can serve as a basis for reliable estimation of the environmental release at domestic PWR sites. $^{14}C$ is the most important nuclide in the inventory, since it contributes one of the main dose contributors in future release scenarios. The reason for this is its high mobility in the environment, biological availability and long half-life(5730yr). More recent studies - where a more detailed investigation of organic $^{14}C$ species believed to be formed in the coolant under reducing conditions have been made - show that the organic compounds not only are limited to hydrocarbons and CO. Possible organic compounds formed including formaldehyde, formic acid and acetic acid, etc. Under oxidizing conditions shows the oxidized carbon forms, possibly mainly carbon dioxide and bicarbonate forms. Measurements of organic and inorganic $^{14}C$ in various water systems were also performed. The $^{14}C$ inventory in the reactor water was found to be 3.1 GBq/kg in PWR of which less than 10% was in inorganic form. Generally, the $^{14}C$ activity in the water was divided equally between the gas- and water- phase. Even though organic $^{14}C$ compound shows that dominant species during the reactor operation, But during the releasing of $^{14}C$ from the plant stack, chemical forms of $^{14}C$ shows the different composition due to the operation conditions such as temperature, pH, volume control tank venting and shut down chemistry.

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