• Title/Summary/Keyword: 내화재

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Technology Development of Domestic Chrome Castable Refractory Application for Slagging Type High Temperature/Pressure Gasifier (슬래깅 방식 고온/고압 가스화기의 국산 크롬 내화재 적용 기술 개발)

  • Chung, Seok-Woo;Jung, Woo-Hyun;Seo, Seok-Jung;Hwang, Sang-Yeon;Choi, Young-Chan;Jung, Hun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.867-870
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    • 2009
  • 일반적으로 내화재의 내침식성은 크롬 함량이 증가함에 따라 향상되는 특성을 가지는데, 본 연구에서는 이러한 크롬 내화재의 물성을 보다 향상시키기 위하여 인산염 화합물인 $AlPO_4$를 첨가하는 실험을 진행하였으며, 이러한 실험 결과 선정된 $AlPO_4$ 1% 첨가 크롬 내화재를 대상으로 캐스타블 및 브릭 형태로 각각 제작하였을 때 내침식 특성에 대해 회전 침식 시험장치를 이용한 실험을 실시하였는데, 실험 결과 캐스타블에 비해 브릭 내화재가 내침식성이 우수하지만 일부 spalling이 발생하는 것으로 파악되었다. 그리고, 가스화기로의 석탄 공급 방식에 따라 내화재 벽면에서 발생하는 석탄입자에 의한 내화재 침식 정도에 대한 전산해석을 수행한 결과 top feeding에 비해 side feeding 방식이 내화재 전면에 걸쳐 침식 현상이 크게 발생할 것으로 예측되어 보다 크롬 함량이 많은 내화재를 선정해야 할 것으로 평가되었다.

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Basic Study on the Recycling of a Waste MgO-C Refractory Material as a Flux for EAF Steelmaking (전기로 폐 MgO-C계 내화재의 제강원료 활용 가능성 연구)

  • Wang, Jei-Pil;Kim, Hang-Goo;Go, Min-Seok;Lee, Dong-Hun
    • Resources Recycling
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    • v.30 no.6
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    • pp.53-60
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    • 2021
  • In EAF steelmaking industries, MgO content in slag increases due to the addition of dolomite flux to protect refractory lines of furnaces and improve the desulfurization capability of slag. In addition, coal powder is injected in the molten steel bath to increase the energy efficiency of the process. In this regard, the utilization of waste MgO-C refractory material as a flux was examined because it has high amounts of MgO (>70%) and graphite carbon (>10%). A series of experiments were carried out using industrial EAF slag with added light burnt dolomite and waste MgO refractory material from a Korean steel company. The results for the addition of the two fluxes were similar in terms of slag basicity; therefore, it is expected that waste MgO-C refractory material can successfully replace dolomite flux. In addition, when the waste MgO-C refractory material was added as flux, slag foaming phenomenon was demonstrated because of the reaction between the graphite from the refractory material and iron oxides in the slag.

Fire resistance assessment of precast fireproof duct slab (프리캐스트 방식 내화풍도슬래브의 화재저항성 평가)

  • Choi, Soon-Wook;Kang, Tae-Ho;Lee, Chulho;Kim, Se Kwon;Kim, Tae Kyun;Chang, Soo-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.6
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    • pp.669-680
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    • 2020
  • In Korea, fireproof performance is evaluated through a series of fire-resistance tests for important structures, and the performance standard follows the guidelines suggested by ITA. The fireproof duct slab manufactured by combining the slab and the fireproof material with a precast method is effective in that it can eliminate the construction time of the fireproof material. In this study, a series of fire resistance tests was performed on the fire test specimens under the RWS fire scenario in order to secure the fire resistance performance of the precast fireproof duct slab. As a result of the test, it was found that the fireproof performance was secured when the thickness of the fireproof material was 30 mm or more. In both fireproof materials and concrete, the rate of temperature change initially increased, then decreased, and then increased again, and the temperature at the inflection point was measured as 110℃ for all fireproof materials and concrete. It is judged that this occurs when the C-S-H (CaO-SiO2-H2O) generated by the hydration reaction in both the fireproof material and concrete is dehydrated.

Thermal Property and Fire Resistance of Cellulose Insulation (섬유질 단열재의 열적 특성 및 내화성능)

  • Kwon, Young-Cheol;Seo, Seong Yeon;Kim, Sung Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.3
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    • pp.203-212
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    • 2005
  • Cellulose insulation is primarily manufactured from recycled newsprint and treated with fire retardants for the fire resistance. Thanks to the fire retardants, it is not combustible and flammable. In addition to that, Its thermal resistance is much better than that of fiberglass or rock wool. It is made from waste paper and easily decayed when it is demolished, and it has small embodied energy. So it is very environment-friendly building material. For broader use of cellulose insulation in buildings in Korea, it is necessary to test its physical performance to compare the results with the requirements on the Korean Building Code. To this end, apparent thermal conductivity (ka) measurements of Korean-made loose-fill cellulose insulations were recently completed using equipment that was built and operated in accordance with ASTM C 518 and the fire resistance was tested in accordance with ASTM C 1485. Korean loose-fill cellulose has thermal conductivity about 5% greater than the corresponding U.S. product at the same density. This is likely due to differences in the recycled material being used. Both spray-applied and loose-fill cellulose insulation lose about 1.5% of their thermal resistivity for $5.5^{\circ}C$ increase in temperature. The fire resistance of cellulose insulation is increased in linear proportion to the increase of the rate of fire retardant. Thanks to the high fire resistance, cellulose insulation can be used as a substitution of Styrofoam or Urethane foam which is combustible. The thermal conductivity of cellulose insulation was $0.037-0.043W/m{\cdot}K$ at the mean specimen temperature from $4-43^{\circ}C$. It corresponds to the thermal resistance of "Na Grade" according to the Korean Building Code. The effect of chemical content on thermal conductivity was negligible for all but the chemical-free specimen which had the highest value for the thermal conductivity over the temperature range tested. The thermal resistance of cellulose insulation is better than that of fiberglass or rock wool, and its fire resistance is higher than that of Styrofoam or Urethane foam. Therefore it can be substituted for those above considering its physical performance. Cellulose insulation is no more expensive than Styrofoam or rock wool, so it is recommended to use it more widely in Korea.

Experimental evaluation of fire protection measures for the segment joint of an immersed tunnel (침매터널 세그먼트조인트의 내화 대책에 대한 실험적 평가)

  • Choi, Soon-Wook;Chang, Soo-Ho;Kim, Heung-Youl;Jo, Bong-Hyun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.3
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    • pp.177-197
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    • 2011
  • In this study, a series of fire experiments under $HC_{inc}$ and ISO834 (duration of 4 hour) fire scenarios were carried out for three different types of fire protection measures for the segment joint to evaluate their applicabilities to an immersed tunnel. The experimental results revealed that an expansion joint installed to allow relative movements between concrete element ends in an segment joint is the most vulnerable to a severe fire. For the fire protection measure where the originally designed steel plates at an expansion joint arc replaced by fire-resistant boards, the experiments showed that they cannot achieve good fireproofing performance under both $HC_{inc}$ fire scenario and ISO834 (4 hour) fire scenarios since the installation of fire-resistant boards results in the reduction of the sprayed fire insulation thickness. On the other hand, the application of modified bent steel plates replacing the original steel plates was proved to be very successful in fireproofing of the expansion joint due to more sprayed materials filled in bent steel plate than in the original design concept as well as higher adhesion between the steel plate and the sprayed fire insulation layer.

Assessment of structural fire resistance of a fire-proofed immersed tunnel under tunnel fire scenarios (화재시나리오별 침매터널 구조물의 화재저항성 평가)

  • Choi, Soon-Wook;Chang, Soo-Ho;Kim, Heung-Yon;Jo, Bong-Hyun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.12 no.6
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    • pp.429-441
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    • 2010
  • In this study, fire resistance of a fireproof material sprayed upon an immersed tunnel was experimentally evaluated under $HC_{inc}$ and IS0834(duration of 4 hours) fire scenarios. Under $HC_{inc}$ fire scenario, the maximum inner temperatures of a concrete specimen at the depth of 0, 25 and 50 mm from the interface between the structure and the fire-proofing layer were $311^{\circ}C$, $194^{\circ}C$ and $142^{\circ}C$ respectively. Similarly, the corresponding maximum temperatures under IS0834 fire scenario were $332^{\circ}C$, $222^{\circ}C$ and $179^{\circ}C$ respectively. From the results, it was revealed that the two different fire scenarios assumed in this study have almost the same fire capacity as each other in the maximum temperature concept. In addition, a structural analysis of the immersed tunnel under $HC_{inc}$ fire scenario was carried out to verify the effects of the fireproof material on its structural stability. Material loss and deterioration of a concrete specimen without any fire-proofing measure was also experimentally evaluated to obtain input parameters for the structural analysis under such a severe fire scenario. From the results, it was confirmed that the application of fireproof measures to the immersed tunnel is essential for its structural stability even under a severe fire scenario.

Analyses for Temperature Profile and Heat Loss Calculation in the Refractory of Coal Gasifier (석탄가스화기 내화재 온도분포 및 열손실 해석)

  • 이진욱;윤용승;안달홍
    • Journal of Energy Engineering
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    • v.8 no.1
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    • pp.67-75
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    • 1999
  • 여러 종류의 내화재로 구성된 석탄가스화기에서의 온도분포 및 열손실량을 구하기 위한 전산해석을 수행하였다. 석탄가스화기 내화재 설계를 위한 적절한 방법론을 제안하기 위하여 1차원 이론적 해석, 2차원 전도열전달 해석 및 3차원 대류-전도 복합열전달 해석 등 세가지 방법론으로 해석을 각각 수행하였다. 해석 결과들은 석탄가스화기 실험 결과와 정상적 정량적으로 잘 일치하는 것으로 나타났다. 결과의 정확성, 수치해석 상의 수렴성 및 계산시간 등을 종합적으로 고려해 볼 때, 전산해석에 핵심 경계조건인 가스화기 내벽의 온도를 적절히 설정할 수 있는 경우에는 2차원 전도열전달 해석이 공학적 설계에 적용하기 알맞은 방법론으로 판단되었다. 전산해석 결과에 의하면, 현재 실험이 진행중인 하루 3톤 처리 용량급의 석탄가스화기에서의 총 열손실량은 설계치 운전 기준으로 약 1% 정도인 것으로 판별되었다.

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Comparative Analysis of Fire Resistance in Glued Laminated Timber: The Impact of Adhesives and Surface Direction (구조용 집성재의 접착제 종류 및 접착면 방향성에 따른 내화성능 비교 분석)

  • Choi, Yun-Jeong;An, Jae-Hong;Baik, Kwon-hyuk
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.761-772
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    • 2023
  • The fire resistance design of timber structures involves calculating the residual section based on charring depth, which is then utilized in structural design. Charring depth is determined from fire-resistance test results in Korea, which currently do not account for the charring properties of the adhesive used in Glued Laminated Timber(GLT) production. This study fabricated GLT using various adhesives employed in domestic GLT production, comparing the charring properties by adhesive type and the fire resistance performance relative to the directionality of the laminated surface. Melamine demonstrated the most advantageous fire resistance performance, followed by resorcinol and polyurethane. Furthermore, it was established that the laminated section exhibited a higher charring rate, influenced by the adhesive, compared to the laminated surface, which significantly impacts the fire resistance performance.