• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.4
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• pp.68-75
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• 2018

The introduction of advanced water treatment facilities has increased as the conventional purification method cannot remove the substance clearly. However, the internal waterproofing and Anticorrosion materials of the advanced water treatment facility using ozone deteriorate due to the oxidation power of ozone and affects the concrete, which causes a decrease in durability. This study is to evaluate the ozone resistance according to the type of spray metal and the surface treatment method of the coating, and the bond strength after ozone treatment in order to develope a finishing method to prevent deterioration of concrete structure of water treatment facility using metal spraying method as a way to construct metal panel with excellent ozone resistance and chemical resistance by an easier way than the previous. The Experimental results show that spray metal Ti has superior ozone resistance even after spraying. It is considered to be the most suitable method for ozone resistance and bond performance by finishing using Teflon sealing as surface treatment method.

• Polymer(Korea)
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• v.38 no.5
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• pp.573-579
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• 2014

The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.4
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• pp.61-68
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• 2019

As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

• Journal of Adhesion and Interface
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• v.2 no.4
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• pp.32-38
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• 2001

Effects of the ratio of rubber composition on covulcanization and ozone resistance were studied in this study. Specimens used in this study were rubber compounds(specimen-A) blended with various ratio of NR, SBR, BR, IIR, and EPDM, unsaturated rubber compounds(specimen-B) with NR/BR/SBR, and saturated rubber compounds(specimen-C) with NR/IIR/EPDM. PAD adhesion specimen was prepared from vulcanizing specimen-A and B, and specimen-A and C, respectively. Using same adhesion specimen, peel strength was measured and tested ozone resistance. In specimen-A, peel strength was higher with increasing NR ratio for NR and BR contained blends. In other specimen-A containing NR and SBR, the peel strength was also increased with increasing SBR ratio. NR/BR/IIR/EPDM rubber compounds had also better adhesion property than NR/SBR/IIR/EPDM compounds. As more unsaturated rubber was blended, the peel strength was higher but ozone resistance was worse. Optimum ratio of unsaturated and saturated rubbers for the peel strength and ozone resistance was 60/40.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.421-426
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• 2012

The effect of synthesis conditions such as various organic material and composition of organic-inorganic material in ozone resistance and surface characteristic of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Organic-inorganic hybrid coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 2,2,2-trifluoroethylmethacrylate, and various organic materials with acrylate group, bar-coated on substrates using applicator and densified by UV-curing. It was found that ozone resistance and surface hardness of the coating film was increased with contents of TEOS. It was also found that ozone resistance of coating film was increased with contents of 2,2,2-trifluoroethylmethacrylate. On the other hand, surface hardness was decreased with increase of 2,2,2-trifluoroethylmethacrylate. In addition, Surface hardness of coating film was increased with the addition of aliphatic urethane acrylate. It was also found that the transmittance of coating films was not influenced by content of TEOS and 2,2,2-trifluoroethylmethacrylate. In addition, the coating film exhibited high transmittance of above 90%.

• Elastomers and Composites
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• v.46 no.4
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• pp.329-334
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• 2011

In general, butyl rubber(IIR : isobutylene isoprene rubber) has excellent gas permeability resistance and impact absorbance property as low resilience elastomer. In this experiment butyl rubber blends with EPDM(ethylene propylene diene monomer) were prepared by mechanical mixing method. Curing behavior, physical properties and ozone resistance etc. were subsequently examined. Measurement results of gas transmission rate test shows that butyl rubber contents above 50 wt% showed significant decrease in gas permeability resistant property. However, in butyl rubber/EPDM blend, EPDM contents above 25 wt% indicates no surface change due to improvement of ozone resistance under the condition of 50 pphm, $50^{\circ}C$, 120 hrs.

• Elastomers and Composites
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• v.43 no.2
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• pp.104-112
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• 2008

The ethylene propylene diene terpolymer (EPDM) blends with styrene butadiene rubber (SBR) were prepared from an open 2-roll mill following the conventional rubber blend method, and then cure characteristics, mechanical properties and ozone resistance were subsequently examined. With incorporation of SBR the torque value of the EPDM and SBR blends showed a gradual increase in the cure curve. The maximum torque value was obtained with lowest level at 25wt% of SBR and it was increased linearly with more than 25wt%. As the SBR loading increased scorch time and optimum cure time decreased. Hardness represented a maximum at 50wt% of SBR. However upper and lower than that value it decreased. It was found that the unfavorable characteristics of ozone resistance of pure SBR was significantly improved through the blending of SBR with EPDM.

• Elastomers and Composites
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• v.43 no.1
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• pp.8-17
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• 2008

Styrene-butadiene rubber(SBR) has good abrasion resistance, miscibility, and anti-vibration property. however, it is easily damaged by ozone and swelled by hydrocarbon fluids because of unsaturation part in main chain, that causes loss of visco-elasticity and reduction of product's life cycle. Therefore, object of this study is to cope with this problem. SBR is blended with various proportion of ethylene-propylene-diene terpolymer(EPDM), which has excellent ozone and oxygen resistance, to improve physical properties and ozone resistance, and diverse analytical techniques are used to measure morphology, glass transition temperature$(T_g)$, ozone-resistance, degradation temperature, static spring constant, hardness for considering a suitability for anti-vibration industrial product. We found that the blend consisting of SBR 70% and EPDM 30% showed no crack after ozone test and good miscibility between SBR and EPDM from this study.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2004.05a
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• pp.32-36
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• 2004

본 연구는 최근 인구와 산업체가 급증하고 있는 김해시를 대상으로 김해시.군을 통합한 1996년 이후부터 2002년까지 김해시 지상오존농도의 변화경향과 고농도 오존일에 대한 사례 연구결과 다음과 같다. 김해시 대기오염농도의 시계열변화는 증가추세가 뚜렷하였으며, 최근 대기환경기준이 강화되면서 환경지정기준을 초과하기도 하였다. 계절별 오존농도의 일변화는 사계절 가운데 봄철이 가장 농도가 높게 나타났으며 매년 증가하는 농도폭도 가장 크게 나타났다. 이는 여름철의 경우 태양고도가 높고 단위시간당 일사량은 많으나, 장마와 같은 운량 증가로 인한 일사량의 감소되거나, 기온이 상승할 경우 해안으로부터 해풍이 증가하여 여름보다는 봄철에 더 높은 농도를 나타낸 것으로 생각되며, 인구와 자동차 등의 증가로 인한 배출량이 증가한 것도 크게 영향을 미친 것으로 생각된다. 연구기간동안 60 ppb 이상의 고농도 오존일의 총 발생빈도는 237일로 나타났으며, 매년 발생빈도가 증가하고 있으며, 대기환경기준 100 ppb/hr를 초과한 날도 8일이나 되었는데, 1999년이 4일 발생하여 오존에 의한 대기오염규제지역으로 선정되었는데, 고농도 오존일은 지난 1997년 이후 매년 증가하고 있으며 겨울을 제외한 전 월에 발생하는 특징을 나타내어 오존의 저감을 위한 실천 계획 수립뿐 아니라 고농도 오존일에 대한 집중적인 연구와 빠른 시간 내에 오존의 예.경보제를 도입 운영하는 것이 김해시민의 건강과 복지에 도움이 될 것으로 생각된다. 고농도 오존일에 대한 사례일 첫 번째인 5월 1일은 일 최고 기온은 그리 높은 상태는 아니었지만 광범위한 이동성 고기압에 의해 대기가 정체하고 바람이 약한 시점에 광화학반응에 의한 오존생성이 용이하였고 해안가의 높은 농도의 오존이 수송되어 고농도 오존이 발생하였으며, 사례 2의 경우 대륙에서 이동해 오는 이동성 고기압의 영향으로 대기는 안정하고 바람이 약하여 기온이 급상승하였으며, 광화학반응에 의한 오존 생성이 용이하였다. 사례 3의 경우는 남북으로 놓여 있는 대규모 기압계 사이에 안상부 형태의 대상고기압이 놓여 대기는 매우 안정하고 바람이 약하며 때때로 기압계에 의한 바람이 불 경우 다소 강한 바람이 불어 일사량이 많은 기압계에서 광화학반응과 수소에 의한 오존생성이 용이하여 고농도 오존을 발생하였다.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.4
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• pp.419-424
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• 2007

According to increase of consumer's desire for clean tap water, advanced treatment processes include with membrane, ozone, and granular activated carbon(GAC) were introduced. In order to evaluate the effect of advanced treatment processes for residual chlorine decay and trihalomethane(THM) formation in water distribution system, dissolved organic matter(DOC) removal of each advanced treatment process was investigated. The residual chlorine decay and THM formation using bottle tests were also evaluated. $UV_{254}$ removal in all advanced treatment was better than DOC removal. Especially, DOC by ozone treated was removed as 4% in contrast with sand filtered water, but $UV_{254}$ was removed about 17%. This result might be due to convert from hydrophobic DOC to hydrophilic DOC by ozonation. Ozone/GAC process was most effective process for DOC removal. The residual chlorine decay constants in treated water by sand filtration, ozonation, GAC adsorption, and ozone/GAC processes were 0.0230, 0.0307, 0.0117 and 0.0098 $hr^{-1}$, respectively. The sand filtered water was produced 81.8 ${\mu}g/L$ of THM after 190 hours of reaction time, as the treated water by ozone, GAC, and Ozone/GAC was less produced 6.0, 26.2, 30.3% in contrast with sand filtered water, respectively. Consequently, the durability of residual chlorine and reduction of THM formation were improved by advanced treatment processes.