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http://dx.doi.org/10.9713/kcer.2012.50.3.421

Preparation of UV-curable Ozone Resistance Coating Solutions using Fluoromonomer  

Lee, Chang Ho (Department of Chemical Engineering)
Lee, Sang Goo (Division of Green Chemistry, Korea Research Institute of Chemical Technology)
Kim, Sung Rae (Korea Conformity Laboratories)
Lee, Jong Dae (Department of Chemical Engineering)
Publication Information
Korean Chemical Engineering Research / v.50, no.3, 2012 , pp. 421-426 More about this Journal
Abstract
The effect of synthesis conditions such as various organic material and composition of organic-inorganic material in ozone resistance and surface characteristic of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Organic-inorganic hybrid coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 2,2,2-trifluoroethylmethacrylate, and various organic materials with acrylate group, bar-coated on substrates using applicator and densified by UV-curing. It was found that ozone resistance and surface hardness of the coating film was increased with contents of TEOS. It was also found that ozone resistance of coating film was increased with contents of 2,2,2-trifluoroethylmethacrylate. On the other hand, surface hardness was decreased with increase of 2,2,2-trifluoroethylmethacrylate. In addition, Surface hardness of coating film was increased with the addition of aliphatic urethane acrylate. It was also found that the transmittance of coating films was not influenced by content of TEOS and 2,2,2-trifluoroethylmethacrylate. In addition, the coating film exhibited high transmittance of above 90%.
Keywords
Fluoropolymer; Ozone Resistance; Sol-gel; UV-curable; Hybrid Coating;
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Times Cited By KSCI : 6  (Citation Analysis)
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1 Do, Y. W., Yu, D. S., Lee, J. H., Park, S. A. and Ha, J. W., "Thermally Curable Organic-inorganic Hybrid Coatings on Ophthalmic lenses," Appl. Chem., 11, 9(2007).
2 Jaworek, T., Bankowsky, H., Koniger, R., Reich, W., Schrof, W. and Schwalm, R., "UV-radiation Curing of Waterbased Urethaneacrylate Coatings," Macromol Symp., 159, 197(2000).   DOI
3 Karatas, S., Kizilkaya, C., Kayaman-Apohan, N. and Gungor, A., "Preparation and Characterization of Sol-Gel Derived UV-Curable Organo-Silica-Titania Hybrid Coatings," Prog. Org. Coat., 60, 140(2007).   DOI   ScienceOn
4 Gurol, M. D. and Singer, P. C., "Kinetics of Ozone Decomposition: a Dynamic Approach," Environ. Sci. Technol., 16, 377(1982).   DOI   ScienceOn
5 Cho, M., Kim, H., Cho, S. H. and Woon, J., "Investigation of Ozone Reaction in River Waters Causing Instantaneous Ozone Demand," Ozone-Sci. Eng., 25, 251(2003).   DOI   ScienceOn
6 Shin, Y. J., Yang, D. H., Oh, M. H., Yoon, Y. S. and Shin, J. S., "Hard Coatings on Polycarbonate Plate by Sol-gel Reactions of Melamine Derivative, Poly(vinyl alcohol), and Silicates," J. Ind. Eng. Chem., 15, 238(2009).   과학기술학회마을   DOI   ScienceOn
7 Decker, C., T. Nguyen Thi Viet, Decker, D. and Weber-Koehl, E., "UV Radiation Curing of Acrylate/epoxide Systems," Polym., 42, 5531(2001).   DOI   ScienceOn
8 Gururaj, T., Subasri, R., Soma Raju, K. R. C. and Padmanabham, G., "Effect of Plasma Pretreatment on Adhesion and Mechanical Properties of UV-Curable Coatings on Plastics," Appl. Surf. Sci, 257, 15(2011).
9 Chang, C. H., Lee, S. G. and Lee, J. D., "Preparation and Characterization of Photochromic Organic-inorganic Hybrid Coating Using 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene," Polymer(Korea), 36, 16(2012).   과학기술학회마을   DOI   ScienceOn
10 Kang, D. P., Park, H. Y., Ahn, M. S., Myung, I. H., Lee, T. J., Choi, J. H. and Kim, H. J., "Properties of Sol-gel Materials Synthesized from Colloidal Silica and Alkoxy Silanes," Polymer(Korea), 29, 242 (2005).   과학기술학회마을
11 Choia, M. C., Kim, Y. K. and Ha, C. S., "Polymers for Flexible Displays: From Material Selection to Device Applications," Prog. Polym. Sci., 33, 581(2008).   DOI   ScienceOn
12 Jung, J. M., Kwon, S. W. and Oh, S. K., "A Study on the Evaluation of Field Application for the Waterproofing or Corrosion Proof Construction Method as Coating High Quality Filtration Plant with Ozone Resistance Paint of Phenol Degeneration Polyamine," Journal of the Korea Institue of Building Construction, 5, 33(2005).   과학기술학회마을
13 Sepeur, S., Kunze, N., Werner, B. and Schmidt, H., "UV Curable Hard Coatings on Plastics," Thin Solid Films, 351, 1793(1999).
14 Park, H. S., Yeom, C. M. and Yoon, J. Y., "Current Features of Ozonation Facilities in Domestic Water Treatment Plants," Journal of K.W.W.A., 15, 279(2001).   과학기술학회마을
15 Oh, S. K., Kwak, G. S. and Yang, S. D., "A Study on the Surface Deterioration Evaluation of Epoxy Resin Coating as Anticorrosive Material of Concrete Water Tank Using Ozone," Journal of the Architectural Institute of Korea, 19, 87(2003).   과학기술학회마을
16 Kwak, K. S., Seo, H. J., Miyauchi, H., Kim, G. Y. and Oh, S. K., "A Study on Suggestion of the Evaluation Method of $O_3$ Deterioration of Waterproofing and Corrosion Prevention Materials in Concrete Facility for Advanced Water Treatment Using Ozone($O_3$) Sterilization," Journal of the Architectural Institute of Korea, 26, 79(2010).   과학기술학회마을
17 Kim, S. H., "A Study to Prove the Performance of the Ozone Resistant Paint for the Standards Establishment of the Ozone Contact Facility Waterproof and Anti-corrosion," University of Seoul Master of Engineering Thesis(2010).
18 Lee, S. B., "Technology Trends of Fluoride Materials," Chemical Materials Information Bank Report(2010).
19 Won, J. U., Joen, J. P. and Lee, B. J., "Recent Development of Fluoropolymers," Polym. Sci. Tech., 14, 206(2003).
20 Hong, Y. T., Lee, J. H. and Kim, Y. S., "Fluoropolymer Films," Polym. Sci. Tech., 13, 724(2002).
21 Qu, A., Wen, X., Pi, P., Cheng, J. and Yang, Z., "Gradient Distribution of Fluorine on the Film Surface of the Oranic-inoganic Hybrid Fluoropolymer," Colloids Surf., A: Physicochem. Eng. Aspects, 345, 18(2009).   DOI   ScienceOn
22 Samson, F., "Ophthalmic Lens Coating," Surf. Coat. Technol., 81, 79(1996).   DOI   ScienceOn