• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.1
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• pp.39-45
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• 2016

Thermal management of a fuel cell is important to satisfy the requirements of durability and efficiency under varying load conditions. In this study, a linear state feedback controller was designed to maintain the temperature within operating conditions. Due to the nonlinearity of automotive fuel cell system, the state feedback controller results in marginal stable under load condition from $0.5A/cm^2$ to $0.7A/cm^2$. A PWM (Pulse Width Modulation) and the modified state feedback controller are applied to control the temperature under the load condition from $0.5A/cm^2$ to $0.7A/cm^2$. The cooling system model is composed of a reservoir, radiator, bypass valve, fan, and a water pump. The performance of the control algorithm was evaluated in terms of the integral time weighted absolute error (ITAE). Additionally, MATLAB/SIMULINK$^{(R)}$ was used for the development of the system models and controllers. The modified state feedback controller was found to be more effective for controlling temperature than other algorithms when tested under low load conditions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.6
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• pp.585-592
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• 2011

The enhancement of the cold-start capability of polymer electrolyte fuel cells is of great importance in terms of the durability and reliability of fuel-cell vehicles. In this study, vanadium oxide films deposited onto the flat surface of metallic bipolar plates were synthesized to investigate the feasibility of their use as an efficient self-heating source to expedite the temperature rise during startup at subzero temperatures. Samples were prepared through the dip-coating technique using the hydrolytic sol-gel route, and the chemical compositions and microstructures of the films were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and field-emission scanning electron microscopy. In addition, the electrical resistance hysteresis loop of the films was measured over a temperature range from -20 to $80^{\circ}C$ using a four-terminal technique. Experimentally, it was found that the thermal energy (Joule heating) resulting from self-heating of the films was sufficient to provide the substantial amount of energy required for thawing at subzero temperatures.

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.382-387
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• 2018

In this study, the reaction characteristics of combined steam and carbon dioxide reforming of methane (CSCRM) reaction using Pd-Ni-YSZ catalyst were investigated according to types of catalysts and gas compositions. Catalysts were prepared in the form of powder and porous disk. The injected gases were supplied at different ratios of $CH_4/CO_2/H_2O$. As a result, the conversion of $CH_4$ and $CO_2$ was improved as a result of using the porous disc type catalyst as compared with that of the powder type catalyst. When the $CH_4/CO_2/H_2O$ ratio of the feed gas was 1 : 0.5 : 0.5, the $H_2/CO$ ratio was adjusted close to 2. However, after 6 hours of the reaction, $CH_4$ conversion was partially reduced by the carbon deposition and the pressure drop increased from 0.1 to 0.8. This issue was then solved by optimizing the water content. As a result, it was confirmed that the durability was secured by preventing the carbon deposition when the gas was supplied at a $CH_4/CO_2/H_2O$ ratio of 1 : 0.5 : 1, and the conversion rate was maintained at a relatively high level.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.687-693
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• 2019

As the hydrogen fuel cell market is expanded starting from hydrogen electric vehicle and power generation field, the demand for fuel cells and hydrogen increases recently. Therefore, research works on fuel cell durability and fuel efficiency are required in order to activate the fuel cell market and commercialization. A dead-ended anode system was used in this study to optimize the fuel cell performance and fuel efficiency. The effect of purge condition according to the applied current and hydrogen supply pressure on the fuel cell performance were evaluated. In addition, the influence of water back diffusion on the different electrolyte membrane thickness was analyzed. The accumulated water was purged with a solenoid valve in the case of 3% voltage decrease in the dead-ended anode system. The experiment was performed with the hydrogen supply pressure of 0.1~0.5 bar and purge duration of 0.1~1 second. A maximum fuel efficiency of 98.9% was achieved under the purge duration of 0.1 s and hydrogen supply pressure of 0.1 bar with a NR 211 (25.4 um) membrane. However, the fuel cell performance decreased in a long-term operation due to some frequent flooding. The fuel efficiency and purge interval increased due to decreased back diffusion rates of the water and nitrogen with a NR 212 (50.8 um) membrane.

• Proceedings of the KWS Conference
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• 2010.05a
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• pp.23-23
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• 2010

마찰교반접합(Friction Stir Welding)은 1991년 영국 TWI에서 개발된 접합 법으로서 일정한 속도로 회전하는 툴이 재료내부에 삽입 되면서 툴과 재료사이에서 마찰열이 발생하여 연화된 재료와 접합 툴 사이에서의 기계적 교반에 의해 소성변형이 일어남과 동시에 접합이 이루어진다. 마찰교반접합은 동적 재결정에 의한 접합부의 미세한 결정립 형성으로 인하여 기계적 특성이 향상되며 보호 가스가 필요 없어 친환경적임과 동시에 용융 용접 법에 비해 접합 시 에너지 소모가 적다는 장점이 있다. 마찰교반접합은 기존의 저융점 재료에 관한 접합을 넘어서 최근에는 철계 합금, 타이타늄 합금, 니켈계 합금 등 고융점 재료에서의 적용에 관한 연구가 이루어지고 있다. 하지만 마찰교반접합을 이용하여 위와 같은 강한 재료를 접합하기 위해서는 내구성이 갖추어진 툴이 반드시 수반된다. 슈퍼 오스테나이트계 스테인리스강은 염화물의 농도가 높은 부식 환경에 적용되는 소재로서, 공식(pitting corrosion) 및 틈부식 (crevice corrosion)에 대한 내식성을 높이기 위하여 Mo의 함량을 6%로 낮추고 20~25% Cr과 Ni을 첨가하여 사용된다. 이러한 고합금의 슈퍼 오스테나이트계 스테인리스강은 여타 내식성 합금에 비하여 내식성이 매우 우수한 것으로 알려져 있다. 최근 SO2 배출에 대하여 규제가 강화되면서 화력 발전소용 탈황 설비 중 일부 장비에서 6% Mo가 첨가된 슈퍼 오스테나이트계 스테인리스강의 사용이 늘어나고 있다. 본 연구에서는 $Si_3N_4$ 툴을 사용하여 Mo이 6% 첨가된 슈퍼 오스테나이트계 스테인리스강인 1925hMo강을 마찰교반접합하였다. 툴 회전속도 (200rpm, 300rpm, 460rpm, 700rpm)를 변수로 하여 접합을 실시하였다. 접합 후 외관상태를 점검하였으며 광학현미경 (optical microscope)과 주사전자현미경 (scanning electron microscope)을 사용하여 미세조직 관찰을 하였으며 경도 및 인장강도 측정 등의 실험을 통하여 접합부의 기계적 특성을 평가하였다. 그 후 이러한 결과를 통하여 미세조직과 기계적 특성과의 관련성을 조사하였다.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.197-208
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• 2003

This paper is to determine the possibility of re-using waste concrete from Incheon city area. The strength test was conducted with five aggregate compounds which was replaced a natural aggregate with recycled aggregate. After checking the physical characteristics of recycled aggregate compounds, the mix design of recycled concrete was conducted. For the relatively comparison between natural and recycled compounds, while the unit aggregate weight was changed, other conditions were fixed. The freezing and thawing test which included fly-ash and super-plastezer were performed to check the durability and workability when recycling waste concrete. In the physical characteristics of recycled aggregate, it was found that the specific gravity of recycled coarse aggregate and recycled fine aggregate satisfied the first grade of recycle specification(KS), and all compounds of recycled aggregate also satisfied the second grade of absorption specification, Especially up to the 50% substitution of recycled aggregate is equal to or a bit lower than that of convention aggregate. In comparison with conventional concrete, the recycled concrete is lower than maximum by 7% in compressive strength decreasing rate after freezing-thawing test. From now, although most of recycled concrete was used to the building lot, subgrade, asphalt admixture, through the result. It was proved that possibility of re-using recycled aggregate as the substructure of bridge, retaining wall, tunnel lining and concrete structure which is not attacked the drying shrinkage severely.

• Journal of the Korean GEO-environmental Society
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• v.15 no.4
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• pp.61-67
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• 2014

With a view to resolving environmental problems of hazardous cement, this study seeks to identify the unconfined compressive strength and bending strength of the vegetation block designed herein by utilizing high-strength natural soil stabilizer instead of cement. Soil stabilizer is mainly made of mixture of short fiber extracted from natural fiber and lime, etc. Soil stabilizer reinforces the shearing strength of soil to improve block supportive power and durability while preventing flood and frost damages. For the unconfined compressive strength test, test pieces were prepared by mixing soil stabilizer and weathered soil in different ratios of 6 %, 12 % and 18 %. Experiments were carried out according to curing periods of 5th, 7th, 14th and 28th of the day. For bending strength test, blocks were made in the same mixture ratios as for the unconfined compressive test and tested for each stage. Also, to evaluate for the field applicability, proposed optimum water content considering the characteristics of the soil stabilizer. Permeability test result for the vegetation block, satisfied by the KS F 4419 quality standards.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.12
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• pp.1427-1430
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• 2014

A thermal barrier coating (TBC) prevents heat directly transferring from a high-temperature flame to a substrate. The TBC system comprises a top coating and bond coating. TBC technology reduces the substrate surface temperature by about $100{\sim}170^{\circ}C$. In the TBC system, internal stress is generated by the difference in thermal expansion coefficients of the substrate and coating. The internal stress also differs according to the shape and position of the blade. In this study, finite element analysis was performed for different curvatures of coin-shaped specimens, which are commonly used for thermal fatigue tests, and the changes in internal stress of the TBC system were compared. Based on the results, the curvature at which the minimum stress occurs was derived, and the thermal stress was confirmed to increase with the difference between a given curvature and the curvature with the minimum stress.

• Journal of Conservation Science
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• v.29 no.3
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• pp.249-259
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• 2013

This study was experimented on accelerated weathering test using salt and freeze-thaw to prove effects of consolidants and consolidation for stone cultural heritage. The samples used four kinds of stones (Gyeongju Namsan Granite, Iksan Granite, Yeongyang Sandstone and Jeongseon Marble) which to distributed by three type of weathering grade (Fresh, Weathered Stone and Highly Weathered Stone) added for thermal treatment. The samples were treated with three consolidants (Wacker OH 100, Remmers KSE 300 and 1T1G), and tested by 500 cycles with freezing-thawing and 50 cycles of salt weathering test. As a results of freezing-thawing test, the crack and destruction occurred from some samples. And total immersed samples maintained effect of consolidation to 200 cycles. Also, The rock particle was fall off and gradually destructed by salts weathering test. The consolidated sample relatively had fewer changes by the weathering than not treated sample. The sprayed sample had not continuous effect on weathering.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.38 no.2
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• pp.193-202
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• 2018

This paper proposed a crack spacing calculation formulation which is an important parameter for calculating the crack width, that is the main factor for verification of serviceability limit states and durability performance evaluation of reinforced concrete members. The basic equation of average crack spacing is derived by considering the bond characteristics which is the governing equation for the analysis of cracking behavior in reinforced concrete members. In order to consider the effect of the cover thickness and concrete compressive strength, the crack spacing measured in 124 direct tensile tests performed by several researchers was analyzed and each coefficient was proposed. And, correlation analysis was performed from 80 specimen data where the maximum and average crack spacing were simultaneously measured, and a correlation coefficient that can easily predict the maximum crack spacing from the average crack spacing was proposed. The results of the proposed average crack spacing equation and maximum crack spacing correlation were compared with those current design code specification. The comparisons of proposed equations and the Korean design codes show that the proposed formulation for the average crack spacing and the maximum crack spacing improves the accuracy and reliability of prediction compared to the corresponding provisions of the Korean Concrete Structural Design Code and Korean Highway Bridge Design Code (Limit States Design).