• Title/Summary/Keyword: 나일론66

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폴리아미드(나일론)

  • 한국골판지포장공업협동조합
    • Corrugated packaging logistics
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    • no.48 s.11
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    • pp.67-68
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    • 2003
  • 폴리아미드는 산 아미드결합(-CO-NH-)에 의해 구성되는 고분자화합물로 나일론으로 알려져 있다. 나일론은 미국 듀퐁사의 상품명인데 폴리아미드대신 사용되고 있다. 나일론6, 나일론66, 나일론610, 나일론11, 나일론12, 나일론46, 나일론MXD6등이 제조되고 있다. 이들 가운데 가장 많이 사용되고 있는 것이 나일론6, 나일론66이다.

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Study on the Physical and Rheological Properties of Nylon66/MWCNT Composites (나일론66/MWCNT 복합체 물성 및 유변학적 특성 연구)

  • Kim, Do Eui;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.214-218
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    • 2013
  • Nylon66/multi-walled carbon nano tube (MWCNT) composites were fabricated by twin screw extruder. The contents of MWCNT were 1, 3, 5, and 7 wt%. Thermal properties, dispersion, rheological and impact properties were measured by DSC, TGA, X-ray diffraction (XRD), SEM, Dynamic rheometer, and Izod impact tester. The effect of MWCNT on the non-isothermal crystallization of Nylon66 was confirmed by DSC. The complex viscosity at low frequency and the shear thinning tendency of the composites increased with MWCNT content. An increase in the elasticity was confirmed from the decrease in the slop of G'-G" plot. Izod impact strengths of the composites were analyzed as a measure of mechanical properties, which indicated that the composites exhibit a 60% enhancement for the impact strength when 3 wt% MWCNT was added. The dispersion of MWCNT within Nylon66/MWCNT composites was also checked by SEM.

Improvement research for impact strength of nylon66/silicate composites (나일론66/실리케이트 복합체의 충격특성 개선 연구)

  • Lee, Bom Yi;Kim, Youn Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4653-4658
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    • 2014
  • A study of the improvement in the impact strength is required to apply Nylon 66/silicate composites as an automobile material. Nylon 66/silicate composites were prepared using a twin screw extruder in case of a silicate treatment by ${\gamma}$-APS (S-silicate) and the addition of an octene ${\alpha}$ olefin grafted by maleic anhydride (PE-g-MAH). The chemical structure of the silane treated silicate was measured by Fourier transform infra-red (FT-IR) spectroscopy. The chemical reaction was confirmed by the decrease in the FT-IR intensity of the OH stretching vibration. The thermal properties, intercalation structure, and Izod impact strength were measured by DSC, TGA, XRD, and Izod impact tester. There was no significant effect on the degradation temperature of the Nylon66/silicate composite, but the crystallization temperature and crystallinity increased slightly in the case of the Nylon66/silicate composites. This suggests that the additives act as heterogeneous nuclei on the Nylon 66 matrix. The Izod impact test indicated that S-silicate enhanced the impact performance by up to 24%.

화학의 세계-나일론 66의 뒷 이야기

  • Jin, Jeong-Il
    • The Science & Technology
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    • v.31 no.7 s.350
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    • pp.74-74
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    • 1998
  • 1939년 미국에서 첫 선을 보인 나일론이 선풍적인 인기를 끌면서 일본의 대미 실크 수출이 큰 타격을 입게 되었다. 이에 따라 태평양전쟁을 일으킨 일본은 전쟁비용조달에 어려움을 겪게 되었고 대미감정이 더욱 악화됐다. 언론에서는 나일론이란 이름이 일본을 조소하기 위해 만든 것이라고 보도 했다.

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Study on the physical properties of nylon66/glass fiber composites as a function of extrusion number (나일론66/유리섬유 복합체의 압출횟수에 따른 특성 연구)

  • Lee, Bom Yi;Kim, Youn Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3990-3996
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    • 2014
  • Because the physical properties can be decreased when a Nylon 66/glass fiber composite is injected into a mold over $300^{\circ}C$, a systematic study of the thermal history in the case of re-use is needed. Nylon 66/glass fiber extrudates as a function of the extrusion number were prepared using a twin screw extruder at 305/290/273/268/265/$260^{\circ}C$. The chemical structure, thermal properties, melt index, crystal structure, Izod impact strength, and rheological properties were measured by Fourier transform infra-red (FT-IR), melt indexer, DSC, TGA, XRD, Izod impact tester, and dynamic rheometer. The FT-IR spectra indicated that the number of extrusions did not affect the chemical structure. The decrease in molecular weight with increasing extrusion number was confirmed by the melt index and the complex viscosity of extrudates. Based on the DSC and TGA results, the thermal history had no effect on the melting temperature, regardless of the number of extrusions, but the degradation temperature decreased up to $20^{\circ}C$ with increasing extrusion number. The Izod impact strengths of the extrudates were found to decrease with increasing extrusion number. No structural change after extrusion was also confirmed because there was no change in the slope and shape of the G'-G" plot.

Bonding Behavior of Carbon Black/Nylon 66 Hybrid Nanofiber Webs via Microwave Heating (카본블랙/나일론 66 혼합 나노섬유웹의 마이크로파에 의한 접착거동)

  • Shin, Dong-Ho;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.114-117
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    • 2003
  • Conventional heating the heat source cause the molecules to react from the surface toward the center so that successive layers of molecules heat in turn. The product surfaces may be in danger of over heating by the time heat penetrates the material. Microwave, however, produce a volume heating effect. All molecules are set in action at the same time. It also evens temperature gradients and offers other important benefits such as selective heating. (omitted)

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives- (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성-)

  • Chun, Young-Sik;Hong, Young-Keun;Chung, Kyung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.194-202
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    • 1996
  • Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

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