• Title/Summary/Keyword: 나노 복합재

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Improvement of Electrical Conductivity of Carbon-Fiber Reinforced Plastics by Nano-particles Coating (나노입자 코팅 탄소섬유 강화 복합재료의 전기전도도 향상)

  • Seo, Seong-Wook;Ha, Min-Seok;Kwon, Oh-Yang;Cho, Heung-Soap
    • Composites Research
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    • v.23 no.6
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    • pp.1-6
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    • 2010
  • The electrical conductivity of carbon-fiber reinforced plastics (CFRP's) has been improved by indium-tin oxide (ITO) nano-particle coating on carbon fibers for the purpose of lightning strike protection of composite fuselage skins. ITO nano-particles were coated on the surface of carbon fibers by spraying the colloidal suspension with 10~40% ITO content. The electrical conductivity of the CFRP has been increased more than three times after ITO coating, comparable to or higher than that of B-787 composite fuselage skins with metal wire-meshes on the outer surface, without sacrificing the tensile property due to the existence of nano-particles at fiber-matrix interface. The damage area by the simulated lightning strike was also verified for different materials and conditions by using ultrasonic C-scan image. As the electrical conductivity of 40% nano-ITO coated sample surpass that of the B-787 sample, the damage area by lightning strike also appeared comparable to that of the materials currently employed for composite fuselage construction.

A Study on the Fabrication and Mechanical Properties Evaluation of Natural Fiber Composites added Eco-friendly Materials (친환경 소재를 첨가한 천연섬유 복합재의 제조 및 기계적 물성 평가 연구)

  • Kim, Jae-Cheol;Lee, Dong-Woo;Prabhakar, M.N.;Song, Jung-Il
    • Composites Research
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    • v.33 no.4
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    • pp.213-219
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    • 2020
  • Recently, global facing environmental issues have been raised caused by plastic waste. Hence, increasing the demand for interest in environmentally friendly materials. In this row, research on engineering composite materials also replacing the synthetic reinforcement by introducing natural fibers. However, focus on the strength and interfacial adhesion between matrix and reinforcement is very essential in natural fiber composite, which is insufficient in the literature. There are number of approaches for improving the mechanical strength of the composites, one of the common methods is to reinforce additive nanoparticles. The present investigation, bio-additives were synthesized utilizing bio-waste, cheap, bio-degradable sea-weed powder that could replace expensive nanomaterials and reinforced into the CFRP composite through Hand lay-up followed by a vacuum process. Mechanical properties were evaluated and analyzed through microanalysis. The results concluded that synthesized additives are effective for improving mechanical properties such as tensile, flexural, impact, and shear strength. Overall, the results confirmed that the fabricated composites have potential applications in the field of engineering applications.

Investigation of Interfacial Adhesion of Different Shapes of Nano Carbon Fillers Reinforced Glass Fiber/Epoxy Composites by Spray Coating (형상이 다른 나노입자 스프레이 코팅에 따른 탄소계 강화 유리섬유와 에폭시 수지간 계면강도 관찰)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Choi, Jin-Young;Shin, Pyeong-Su;Lee, En-Seon;Park, Joung-Man
    • Composites Research
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    • v.27 no.3
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    • pp.109-114
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    • 2014
  • Manufacture of nancomposites has simple process for developing nanocomposites due to the increasing applications using nanofillers. This work studied nanofiller coated glass fiber for reinforcing material with good wetting and conductivity and the morphology of nanofiller coated glass fiber was analyzed by FE-SEM. The durability of reinforced glass fiber was investigated with different shapes of nanofillers using sonication rinsing method. Fatigue test was performed to evaluate the adhesion of reinforcing interface and stability of nanofiller coating layer for single fiber reinforced composites. Apparent modulus and conductivity of nanofiller coating layer were evaluated to realize multifunctional of nanocomposites. Fiber type of nanofiller was better than plate type due to better cohesion between fiber and nanofillers. At last, the stability of fiber type nanofiller of coating layer has better durability and conductivity than plate type case.

A Study on Increased Properties of Cellulose-Based Biodegradable Polymer Composites (셀룰로오스 기반 생분해성 고분자 복합재의 물성 증가에 관한 연구)

  • Sangjun Hong;Ajeong Lee;Sanghyeon Ju;Youngeun Shin;Teahoon Park
    • Composites Research
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    • v.36 no.2
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    • pp.126-131
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    • 2023
  • Growing environmental concerns regarding pollution caused by conventional plastics have increased interest in biodegradable polymers as alternative materials. The purpose of this study is to develop a 100% biodegradable nanocomposite material by introducing organic nucleating agents into the biodegradable and thermoplastic resin, poly(lactic acid), to improve its properties. Accordingly, cellulose nanofibers, an eco-friendly material, were adopted as a substitute for inorganic nucleating agents. To achieve a uniform dispersion of cellulose nanofibers (CNFs) within PLA, the aqueous solution of nanofibers was lyophilized to maintain their fibrous shape. Then, they were subjected to primary mixing using a twin-screw extruder. Test specimens with double mixing were then produced by injection molding. Differential scanning calorimetry was employed to confirm the reinforced physical properties, and it was found that the addition of 1 wt% CNFs acted as a reinforcing material and nucleating agent, reducing the cold crystallization temperature by approximately 14℃ and increasing the degree of crystallization. This study provides an environmentally friendly alternative for developing plastic materials with enhanced properties, which can contribute to a sustainable future without consuming inorganic nucleating agents. It serves as a basis for developing 100% biodegradable green nanocomposites.

Molecular Dynamics and Micromechanics Study on Mechanical Behavior and Interfacial Properties of BNNT/Polymer Nanocomposites (분자동역학 전산모사와 미시역학 모델을 이용한 질화붕소 나노튜브/고분자 복합재의 역학적 물성 및 계면특성 예측)

  • Choi, Seoyeon;Yang, Seunghwa
    • Composites Research
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    • v.30 no.4
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    • pp.247-253
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    • 2017
  • In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

The Role of Nano-particles on the Material Properties of Epoxy/Fe2O3 Nano-composites (Epoxy/Fe2O3 나노 복합재의 물성치에 미치는 나노 입자의 역할)

  • Park, Joo-Hyuk;Kim, Jung-Yub
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.5
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    • pp.88-93
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    • 2002
  • The objective of this study is to obtain fundamental understandings involving the manufacturing process of nano-composite via resin transfer molding and explore the role of nano sized $Fe_2O_3$ particles in the epoxy/$Fe_2O_3$ nano-composites. To achieve this goal, following investigations have been conducted: Define the optimum dispersion technique of nano-particles, identify the effect of the nano-particles to the resin viscosity, characterize the key mechanical properties versus particle loading amounts, and explore the usefulness and quality improvement in nano-composites. These efforts will be useful for designers to quantify application payoffs and define a technology development roadmap for manufacturing nano-composites, and will help an engineering design and manufacturing nano-composites more efficiently by providing the design methodology.

Organically Modified Vermiculite-Poly(Ethylene Terephthalate) Nanocomposites (유기물로 개질한 나노점토-폴리(에틸렌 테레프탈레이트) 복합재료의 기계적 특성)

  • Hai Anh Thi Le;Yong Tae Park
    • Composites Research
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    • v.36 no.4
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    • pp.275-280
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    • 2023
  • Because polymer-based composites are lightweight and have excellent properties, their demand is growing rapidly as a way to fulfill properties that are difficult to achieve with a single material. As a result, there has been a lot of research on polymer nanocomposites, which are made by dispersing particles with a size of 1-100 nm in a polymer matrix. In addition, many nanocomposites using thermoplastic resins as matrix materials are being studied. In this study, poly(ethylene terephthalate) (PET)-based nanocomposites containing organic nanoclays modified with cetyltrimethylammonium bromide (CTAB) as interlayer materials were prepared. Among various nanoclays, vermiculite (VMT) has been studied to increase the mechanical and thermal properties of polymeric materials due to its low cost, abundant reserves and unique properties. However, the strong interlayer bonding of VMT has limited its utilization due to its poor exfoliation and dispersion performance within polymer matrices. In this study, the mechanical properties of the VMT content were confirmed by tensile tests, the dispersion of VMT particles in the PET matrix was evaluated by TEM cross-sectional images, and the nitrogen gas barrier properties were evaluated.

Characteristics of Silane Treated Graphene Filled Nanocomposites Exposed to Low Earth Orbit Space Environment (저궤도 우주환경하의 실란처리된 그래핀 첨가 나노 복합재료의 물성특성)

  • Noh, Jae-Young;Jin, Seung-Bo;Kim, Chun-Gon
    • Composites Research
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    • v.28 no.3
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    • pp.130-135
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    • 2015
  • This study investigates the property of graphene filled polymer nanocomposites in LEO(Low Earth orbit) environment conditions. In order to improve compatibility with polymer matrices and resistance of carbon material against AO(Atomic oxygen) attack, silanization of graphene oxide with organosilane was carried out. The corresponding moieties were characterized through X-ray photoelectron spectroscopy (XPS). Graphene oxide filled nanocomposites were prepared using solution based processing methods. The sets of specimen series were tested in an accelerated LEO simulated space environment facility. Graphene oxide and silane treated graphene oxide reinforced nanocomposites were compared with neat epoxy. The comparison revealed that the silane treated graphene filled polymer composite shows inherent resistance against atomic oxygen attack while the lack of silane treatment resulted in a reduction in performance.

차세대 나노 박막 다원계 모물질 설계, 합성 기술

  • Mun, Gyeong-Il;Sin, Seung-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.121-121
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    • 2012
  • 산업이 고도화, 다원화, 세계화되고 있는 현대사회는 다기능성, 고물성, 극한 내구성을 가지며 환경 친화적이면서 에너지 효율을 극대화시킬 수 있는 다기능 소재의 개발을 요구하고 있다. 이러한 시점에서 다양한 물성을 동시에 발현이 가능한 코팅 소재는 향후 미래에 중요한 원천 소재로서 주목되고 있다. 특히, 환경에 의해 쉽게 물성 및 구조의 변화가 쉬운 종래의 코팅소재와는 달리, 다양한 외부환경에서도 미세 구조 및 물성을 안정적으로 유지할 수 있는 신개념의 코팅 소재의 개발이 절실히 요구되고 있다. 이를 위해서는 코팅소재의 다 성분화가 필수적이다. 최근의 코팅 기술은 2가지 이상의 물성, 특히 서로 상반되는 물성을 동시에 구현할 수 있는 소재의 개발을 요구하고 있다. 이러한 물성의 구현을 위하여 더 많은 성분으로 구성되며 더욱 복잡한 조직으로 구성된 코팅층에 대한 개발이 진행이 필요하다. 본 연구에서 목표로 하는 신 개념의 원천소재기술은 4성분계 이상의 원료 물질을 단일 타겟으로 제조하여, 단순한 공정으로서 단일 코팅층 내에 다양한 성분과 10 nm 미만 크기의 나노 결정립/나노 비정질로 구성된 나노 복합 구조의 형성이 가능하도록 하는 기술을 개발하고자 한다. 이를 통해 복합기능 3 이상의 다기능성 부여는 물론, 그림 1에 정리된 기존 코팅재에서 결여된 특성을 포함한 극한 기능성(광대역 윤활성, 전자 이동 제어에 의한 온도 저항 계수 및 전기 저항 조절, 고온 열적 안정성, 내산화성, 고열전도율, 초저마찰/내구성/초고경도성 등)의 구현이 가능한 복잡한 형태의 나노 복합 코팅층 소재 개발이 가능하도록 하는 기술이다. 또한 기존 코팅재의 구조적 결함을 통해 발생하는 내식성 문제를 방지할 수 있는 기술이다. 다성분계 모물질의 개발이 중요한 이유는 다수의 성분 원소를 합금 상태로 형성시킴으로서, 단일 소스에 의해 다양한 원소를 동시에 스퍼터링 및 증착이 가능하도록 할 수 있다는 장점을 가지기 때문이다. 특히, 타겟의 미세구조를 나노구조화 하는것을 통해, 스퍼터링 yield의 차이가 큰 원소일지라도 균일하게 증착시킬 수 있는 방법을 개발하고자한다. 또한 다수의 타겟을 이용하여 균일한 다성분 코팅층 형성하는 기존의 PVD 코팅방법으로는 다수의 성분타겟을 사용함으로서 장비의 복잡성, 코팅의 재현성, 대형화 등의 문제점을 본질적으로 갖고 있다. 이를 위한 해결방법으로 본 발표에서는 3가지 이상의 다기능성 구현을 위한 가장 중요한 원천기술이라 할 수 있는 다성분계 타겟 모물질 제조 기술의 개발 진행 사항에 대해 소개하고자 한다.

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