• Title/Summary/Keyword: 나노필러

Search Result 58, Processing Time 0.05 seconds

Preparation of Lignocellulose Nanofibers from Korean White Pine and Its Application to Polyurethane Nanocomposite (국산 잣나무 유래 리그노셀룰로오스 나노섬유 제조 및 이를 이용한 강화 폴리우레탄 나노복합재료)

  • Jang, Jae-Hyuk;Lee, Seung-Hwan;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
    • /
    • v.42 no.6
    • /
    • pp.700-707
    • /
    • 2014
  • The effect of steam and ozone pretreatments on fibrillation efficiency by wet disk-milling was investigated. Hemicellulose (40%) and lignin (42%) of Korean white pine were partially removed by steam and ozone pretreatments, respectively. With increasing wet disk-milling time, the diameter of fibers was significantly decreased and its size distribution became narrow. Especially, the average diameters of lignocellulose nanofibers after steam and ozone pretreatments were 19 nm and 12 nm, respectively. Thus-obtained lignocellulose nanofibers-reinforced polyurethane composite was prepared. Tensile strength and elastic modulus were drastically improved with increasing wet disk-milling time and lignocellulose nanofiber content. Nanocomposite reinforced by lignocellulose nanofibers after two pretreatments showed higher tensile properties, compared to that reinforced by lignocellulose nanofiber without pretreatment, at the similar wet disk-milling time.

Influence of Hydrophobic Silica on Physical Properties of Epoxy Nanocomposites for Epoxy Molding Compounds (에폭시 몰딩 컴파운드를 위한 에폭시 나노복합재료의 소수성 실리카의 영향)

  • Kim, Ki-Seok;Oh, Sang-Yeob;Kim, Eun-Sung;Shin, Hun-Choong;Park, Soo-Jin
    • Elastomers and Composites
    • /
    • v.45 no.1
    • /
    • pp.12-16
    • /
    • 2010
  • In this work, the effect of hydrophobic treated silica on the water absorption, thermal stabilities, and mechanical properties of the epoxy nanocomposites were investigated as a function of the silica content. As filler, fumed silica treated by dimethyldichlorosilane was used. It was found that the silica was well dispersed in the epoxy resins by the melt-mixing method with the addition of a silane coupling agent. The water absorption of the nanocomposites decreased with an increase of the silica content due to the effect of hydrophobic treated silica. The thermal properties, such as thermal degradation temperature, glass transition temperature ($T_g$), and coefficient of thermal expansion (CTE), of the nanocomposites were improved by the addition of silica. Furthermore, the mechanical properties of the nanocomposites, that is, the tensile strength and modulus, were enhanced with increasing silica content. This was attributed to the physically strong interaction between silica and epoxy resins.

Effects of Morphologies of Carbon Nanomaterials on Conductivity of Composites Containing Copper/Carbon Nanomaterial Hybrid Fillers (탄소 나노 물질의 형상에 따른 구리/탄소나노물질 하이브리드 필러의 전도성 향상 거동 분석)

  • Lee, Yeonjoo;Hong, Sung-uk;Choi, Hyunjoo
    • Journal of Powder Materials
    • /
    • v.25 no.5
    • /
    • pp.435-440
    • /
    • 2018
  • In the present study, we develop a conductive copper/carbon nanomaterial additive and investigate the effects of the morphologies of the carbon nanomaterials on the conductivities of composites containing the additive. The conductive additive is prepared by mechanically milling copper powder with carbon nanomaterials, namely, multi-walled carbon nanotubes (MWCNTs) and/or few-layer graphene (FLG). During the milling process, the carbon nanomaterials are partially embedded in the surfaces of the copper powder, such that electrically conductive pathways are formed when the powder is used in an epoxy-based composite. The conductivities of the composites increase with the volume of the carbon nanomaterial. For a constant volume of carbon nanomaterial, the FLG is observed to provide more conducting pathways than the MWCNTs, although the optimum conductivity is obtained when a mixture of FLG and MWCNTs is used.

DEVELOPMENT OF ANTICARIOGENIC COMPOSITE RESIN (항우식성 복합레진의 가능성)

  • Park, Jeong-Won
    • Restorative Dentistry and Endodontics
    • /
    • v.35 no.2
    • /
    • pp.65-68
    • /
    • 2010
  • Due to the improvement of the composite resin and esthetic desire of the patient, amalgam restoration has been replaced by composite resin. However, still there are many unsolved problems, for example, technique sensitivity, polymerization shrinkage stress and limited mechanical properties. These factors results in fracture of the restoration and secondary caries of the tooth. Also the use of the dental bonding system should be used for the retention of the restoration. In this paper, I want to talk about the present and the future of the remineralizing component released from dental composite resin to overcome the secondary caries and there possibility in the clinical use.

Preparation and Characterization of High Density Polyethylene (HDPE)/Exfoliated Graphite (EFG) Nanocomposite Films (High Density Polyethylene (HDPE) / Exfoliated Graphite (EFG) 나노복합필름 제조와 특성에 관한 연구)

  • Kwon, Hyok;Kim, Dowan;Seo, Jongchul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
    • /
    • v.19 no.2
    • /
    • pp.95-102
    • /
    • 2013
  • Exfoliated graphite (EFG) with high aspect ratio was incorporated with high density polyethylene (HDPE) for use as high barrier packaging material such as water-sensitivity electric product and pharmaceutical packaging. Also HDPE/EFG nanocomposite films were prepared by adding the compatibilizer for effective dispersion and compatibility. Their chemical properties, crystal structure properties, thermal properties and water barrier properties of as-prepared HDPE/EFG nanocomposite films were investigated as a function of EFG contents. It showed that there is a weak interfacial interaction between HDPE and EFG, however, the water vapor permeations were decreased from 127 to 78 (70 ${\mu}m{\cdot}g/m^2$, $day{\cdot}atm$) by addition of EFG. Especially, the physical properties of HDPE/EFG nanocomposite films were effectively increased up to 0.5 wt%, however, there were no significant improvement of properties in nanocomposite films at the additional EFG loading. To maximize their performance of the nanocomposite films, further research is required to enhance the dispersion of EFG and compatibility of EFG in HDPE matrix.

  • PDF

Fabrication and Microstructure of Metal-Coated Carbon Nanofibers using Electroless Plating (무전해 도금을 이용한 금속 코팅된 탄소나노섬유의 제조 및 미세조직)

  • Park, Ki-Yeon;Yi, Sang-Bok;Kim, Jin-Bong;Lee, Jin-Woo;Lee, Sang-Kwan;Han, Jae-Hung
    • Composites Research
    • /
    • v.20 no.5
    • /
    • pp.43-48
    • /
    • 2007
  • The absorption and the interference shielding of electromagnetic wave have been very important issues for commercial and military purposes. The stealth technique is one of the most typical applications of electromagnetic wave absorption technology. This study has started for the development of composite fillers containing dielectric and magnetic lossy materials. To improve the electromagnetic characteristics of conductive nano fillers, carbon nanofibers (CNFs) with nickel-phosphorous (Ni-P) or nickel-iron (Ni-Fe) have been fabricated by the electroless plating process. Observations by the electron microscopy (SEM/TEM) and element analyzer (EDS/ELLS) showed the uniform Ni-P and Ni-Fe coated CNFs. The compositions of the plating layers were about Ni-6wt%P and Ni-70wt%Fe, respectively. The average thicknesses of the plating layers were about $50\;{\sim}\;100\;nm$.

THE EFFECTS OF DRYING AGENTS AND BONDING AGENTS ON THE SHEAR BOND STRENGTH OF SEALANTS TO ENAMEL (치면건조제와 접착제의 사용에 따른 치면열구전색재의 전단결합강도에 관한 연구)

  • Lim, Hyun-Hwa;Jang, Ki-Taek;Kim, Chong-Chul;Hahn, Se-Hyun
    • Journal of the korean academy of Pediatric Dentistry
    • /
    • v.30 no.2
    • /
    • pp.196-203
    • /
    • 2003
  • The application of sealants is a highly technique-sensitive procedure, requiring an extremely dry field prior to placement. Moisture contamination of the etched enamel surface before sealant placement is cited as the main reason for sealant failure. The purpose of this study was to evaluate the effects of different methods of sealant application on the shear bond strength of sealants to enamel. In groups 1, 2, 3, 4 Teethmate(unfilled sealant) was used, while Ultraseal XTplus(filled sealant) was used in groups 5, 6, 7, 8. Groups 1 and 5(control) were acid etched for 15 seconds using 35% phosphoric acid, washed and then dried. In groups 2, 6 drying agents were applied, and in groups 3, 7 bonding agents were applied and light cured. In groups 4 and 8 both drying agent and bonding agent were applied. Then sealant was cured to the specimen using molds 3mm in diameter and 2mm in height. Thermocycling was performed and shear bond strength was finally measured. The following results were obtained : 1. Groups using filled sealant(groups 5, 6, 7, 8) showed higher shear bond strengths compared to groups using unfilled sealant(groups 1, 2, 3, 4). 2. Among groups using unfilled sealant(groups 1, 2, 3, 4), groups 2, 3, 4 showed significantly higher shear bond strength compared to group 1(p<0.05). There were no significant differences among groups 2, 3 and 4. 3. There were no significant differences(p>0.05) among groups using filled sealant(groups 5, 6, 7, 8). 4. When modes of fracture were examined, cohesive failure was observed in groups 2, 3 and 4.

  • PDF

Investigation on DC Breakdown Characteristic of Nano/Micro Epoxy (에폭시의 마이크로 나노 필러 함량에 따른 DC절연파괴특성 평가)

  • Kwon, Jung-Hun;Cho, Sung-Hoon;Kim, Yu-Min;Lim, Kee-Joe
    • Proceedings of the KIEE Conference
    • /
    • 2011.07a
    • /
    • pp.1599-1600
    • /
    • 2011
  • 현재 사용되는 전력기기와 전기에너지로 구동되는 기기등은 환경 조화와 에너지 절약을 목표로 고전압 대용량화, 축소 소형화 및 고효율화가 진행되는 과정에 있다. 이런 기기들은 전위를 유지하기 위해서 전기절연기술이 필수적이다. 특히 전기절연재료의 역할이 중요해서 재료의 특성이 기기전체의 종합성능을 지배하기도 한다. 본 연구에서는 몰드 변압기의 절연수지로 사용되는 에폭시 복합체와 마이크로 $SiO_2$와 Ag 각 시편의 열팽창률과 유전 특성 및 온도에 따른 절연파괴강도를 측정하여 열적 특성 및 전기적 특성을 검토하고 분석한다.

  • PDF

Development of electro-spray micro-thruster and measurement of nano-scale thrust (Electro-spray 마이크로 추진 장치 개발 및 나노 크기의 힘 측정)

  • Lee Young-Jong;Si Bui Quang Tran;Byun Do-Young
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2007.04a
    • /
    • pp.45-48
    • /
    • 2007
  • Conventional force sensors such as piezoelectric sensor has limitations for measuring micro/nano-scale thrust. In this study we developed nano-scale measurement system using laser displacement sensor and cantilever. And electrospray microthruster was fabricated by using stainless capillary and extraction electrode, to generate nano-scale thrust. The measurement system can measure the around 90 nN thrust from this thruster. In addition, we designed and fabricated electrospray micro thruster based on PMMA(Polymethyl methacrylate), which has a nozzle protruded from the substrate.

  • PDF

Recent Advances on Ionic Liquid based Mixed Matrix Membrane for CO2 Separation (CO2 분리를 위한 이온성 액체 기반 혼합 매트릭스 멤브레인의 최근 발전)

  • Wang, Chaerim;Patel, Rajkumar
    • Membrane Journal
    • /
    • v.31 no.1
    • /
    • pp.1-15
    • /
    • 2021
  • The membrane-based CO2 capture is a fast-growing branch in gas separating field. Ionic liquid assisted mixed matrix membrane (MMM), which consists of organic fillers with dispersed ionic liquid, shows high potentiality as a candidate for CO2 separation medium. In MMM, various kinds of ionic liquid and inorganic filler are incorporated into polymer to enhance gas separating performance. Especially, the strong interaction between ionic liquid and organic filler gives huge influence on enhancing the separating performance by increasing affinity, selectivity and adsorption of CO2 into the framework. Also the mechanical properties of metal organic framework are positively tuned by input of ionic liquid to improve CO2 permeability and selectivity. In this review, study of various combinations of ionic liquid and metal organic framework (MOF) in the polymeric membrane for carbon dioxide separation is discussed.