• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.49-56
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• 2020

In this study, surface modification of CaCO₃ nanoparticles by a silane coupling agent propyltrimethoxysilane (PTMS) was conducted and the effect of surface hydrophobicity on the stability of foam and emulsion was studied in order to test the potential applicability as a foam stabilizer or an emulsifier. The surface modification of CaCO₃ nanoparticles by PTMS was confirmed by FT-IR, DSC and TGA analysis. The atomic concentration of CaCO₃ particle surface treated by PTMS has been also identified by using XRD and XPS analyses. Both floating tests and contact angle measurements were also performed to examine the effect of PTMS concentration on the surface modification of CaCO₃ nanoparticles.

• Water for future
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• v.13 no.4
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• pp.51-59
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• 1980

본 논문에 있어서 오염물질의 분산현상에 관한 해석은 활류의 전단효과에만 의존해온 과거의 연구와는 달리, fingering 현상과 2차류의 특성과의 관계로 고찰하는 것이 본 연구의 목적이다. finering 현상의 발달과정과 일반적인 제인자들을 결정하기 위해서, 횡방향속도분포와 속도변동은 taft법과 수색기포법에 의해서 측정하였고, 특히 농도의 유하상태는 laser-beam System을 사용해서 명확하게 측정하였다. 이 현상은 유동모델에 의한 2차류를 고려하므로써 명백하게 설명 할 수 있었다. 그 결과, 분산계수는 활류구조와 함께 단면내 2차류에 의해서도 강한 영향을 받는 것이 구명되었다. 또, 분산계수와 2차류와의 관계는 시행적으로 (5)식을 제시하였고, 한편 실용적으로는 유속, 수색, 수로폭, 조도등의 제수리량을 고려한 실험식 (8)을 제안하였다.

• Journal of Environmental Impact Assessment
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• v.28 no.3
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• pp.332-345
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• 2019

The purpose of the study is to evaluate the treatability of contaminated groundwater with TPH and (or) $Cr^{6+}$. Laboratory scale tests were performed for oil/water separation, dissolved air flotation (DAF), coagulation and precipitation, and filtration with sand and activated carbon respectively. Two times of oil/water separation tests for total 40 minutes of separation or separating time shows 90.2 % of TPH removal rate. In case of DAF test for high TPH sample, the TPH removal rates were not varied significantly by the variation of microbubble size. However, tests for low TPH samples show that TPH removal rate increases as microbubbles are smaller. When coagulant was added to sample for DAF test, TPH removal rate was increased 12.3 %. SS removal rate by DAF was 97.9 % at $16-40{\mu}m$ and it was increased as the size of microbubble is reduced. Tests for coagulation and precipitation were performed to evaluate the removal of $Cr^{6+}$ in groundwater. The increase of $FeSO_4$ dosage increased $Cr^{6+}$ removal rate in the coagulation and precipitation process. As the amount of activated carbon in the filter media increased TPH removal rate in the filtration process. SS removal rate by the filtration was 96.7 % similar to the results of DAF process tests. The filtration process treats TPH and SS. Best design parameters are determined as the size of sand is $425-850{\mu}m$ and the ratio of activated carbon and sand is 50:50.

• Magazine of the Korean Society of Agricultural Engineers
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• v.30 no.3
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• pp.106-113
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• 1988

This study was performed to obtain the basic data which can be applied to use of foamihg mortars. 1. At the mixing ratio 1:1, the highest strengths were showed by foaming mortam, respec - tively. But, it. gradually was decreased in poorer mixing ratio and more addition of foam- ing agent. The decreasing rates of strengths were incresed in poorer mixing ratio and more addition of foaming agent. 2. The strengths were decreased up to 77.0-92.8% by mix-foaming type and 36.7-74.4% by pre-foamed type than cement mortar. 3. At the mixing ratio of 1:1, the lowest air contents were showed by foaming mortars, respectively. But, it gradually was increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of air contents were increased in richer mixing ratio and more addition of foaming agent. 4. Air contents were showed up to 26.0-63.8 times by mix-foaming type and 5.8-17.7 times by pre-foamed type than cement mortar, respectively. 5. The correlations between compressive strength and air content were highly significant, respectively. The multiple regression equations of strengths and air content were computed depending on a fuction of mixing ratio and addition of foarning agent. It was highly significant, respectively.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.107.2-107.2
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• 2010

고온건식탈황기술은 고온고압에서 석탄가스에 함유된 황화합물을 제거하는 기술로 석탄가스화에 의해 생성된 고온의 석탄가스의 열손실을 최소화하여 열효율이 높은 기술이다. 본 연구에서는 석탄으로부터 합성원유를 생산하는 0.3 배럴/일 규모 석탄액화(CTL)공정의 연계운전을 통하여 건식탈황공정의 성능을 평가하였다. 0.3 배럴/일 규모 석탄액화공정은 석탄가스화기, 건식탈황공정, 액화공정으로 구성되어 있으며 30 atm의 고압에서 운전된다. 건식탈황공정은 석탄가스화기와 액화공정 사이에 위치하여 석탄가스화로부터 생성된 석탄가스에 함유된 황화합물을 아연계 건식탈황제에 의해 제거한 후 액화반응기로 공급하여 황화합물에 의한 촉매의 피독을 막아주는 역할을 수행한다. 본 연구에서는 기존에 개발된 두 개의 기포유동층 반응기로 구성된 탈황장치를 30 atm에서 운전이 가능하도록 수정/보완하여 실제 운전압력인 30 atm의 고압에서 연속운전을 수행하였다. 실험 결과 탈황효율은 99% 이상이며 탈황반응기 출구 황화합물의 농도는 1 ppmv 이하로 유지하였다.

• Magazine of the Korean Society of Agricultural Engineers
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• v.30 no.1
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• pp.73-80
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• 1988

This study was performed to obtain the basic data which can be applied to use of foaming mortars. The results obtained were Summarized as follows; 1.At the mixing ratio of 1:1, the highest bulk densities were showed by foaming mortars, respectively. But, it gradually was decreased in poorer mixing ratio and more addition of foaming agent. The decreasing rates of bulk densities were increased in richer mixing ratio and more addition of foaming agent. 2.The bulk densities were decreased up to 38.8-55.9% by mix-foaming type and 9.7-23.6% by pre-foamed type than cement mortar. 3.At the mixing ratio of 1:1, the lowest absorption rates were showed by foaming mortars, respectively. But, it gradually was increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of absorption rates were increased in richer mixing ratio and more addition of foaming agent. 4.Absorption rates when immersed in 72hours were showed up tp 3.41-5.85 times by mix-foaming type and 1.05- 1.S5times by pre -foamed type than cement mortar, it was significantly higher at the early stage of immersed time than cement mortar. 5.The correlations between bulk density and absorption rate were highly singnificant, respectively. The multiple regression equations of bulk density and absorption rate were computed depending on a fuction of mixing ratio and addition of foaming agent. it was highly significant respectively.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.264-271
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• 2023

In this study, ASCO^Ⓡ SLES-430 surfactant was synthesized by adducting 3 moles of ethylene oxide and 1 mole of propylene oxide to lauryl alcohol followed by a sulfation process, and the structure of the synthesized ASCO^Ⓡ SLES-430 was elucidated by performing FT-IR, ¹H-NMR and ¹³C-NMR analyses. Interfacial properties such as critical micelle concentration, static surface tension, emulsification index, and contact angle were measured, and environmental compatibility indices such as oral toxicity and skin irritation were also estimated for ASCO^Ⓡ SLES-430. Both results were compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328 SLES surfactants possessing 2 moles and 3 moles of ethylene oxide, respectively. In particular, both foaming ability and foam stability were evaluated for ASCO^Ⓡ SLES-430 and compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328, which have been widely used in detergent products, in order to test the potential applicability of ASCO^Ⓡ SLES-430 in detergent product formulation for a small capacity built-in washing machine.

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.530-536
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• 1993

Acidic degreasing agent(ADA) was prepared by blending n-octanoic acid, MJU-100A, Tetronix T-701, POE(6)-2-ethylhexyl ether, Newpol PE-68, sorbitol, and phosphoric acid. The physical properties of ADA tested with aluminum specimen showed the following results; when 3wt% ADA-5 was performed at $70^{\circ}C$, the degreasing rate was 98% which is comparitively good, and the percentage of etching was 0.277% which was found to be less than that of commercialized product. When 20wt% of ADA-5 was added at $65^{\circ}C$, the percentage of derusting was 93% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

• Korean Journal of Heritage: History & Science
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• v.41 no.1
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• pp.5-19
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• 2008

Thirty six samples of Western asia glass vessel shards which were excavated from South Mound of Hwangnamdaechong were each measured for thickness, pore size and specific gravity and analyzed for ten major compositions and thirteen trace elements. The glass samples with colorless, greenish blue and dark purple blue were well classified by principal component analysis(PCA). All glass shards of Hwangnamdaechong belonged to Soda glass system ($Na_2O-CaO-SiO_2$) which have the range of 14~17% $Na_2O$ and 5~6% CaO. The corelation coefficients of (MgO, $K_2O$) and (MnO, CuO) showed above 0.90. The concentrations of thirteen trace elements apparently differentiated from colorless, greenish blue and dark blue glasses. We found that thirteen trace elements were very important indices for studying raw material of glass and the origin of glass making. Colorless glass : The specific gravity is $1.50{\pm}0.04$. Circle or oval circle pores are observed with regular direction in internal zone and the longest one is about 0.35 mm. The raw material of sodium must be the plant ash because sodium glasses contain HCLA(High CaO, Low $Al_2O_3$) and HMK(high MgO, high $K_2O$) and suggested to Sasanian glass. The total amount of coloring agent of colorless glass is below 1 % which is too small to attribute to the color. Greenish blue glass : The specific gravity is $1.58{\pm}0.04$. The fine pores which are 0.1~0.2mm are dispersed in internal zone. Sodium glasses are distributed to HCLA and HMK. Therefore the greenish blue glass also have used plant ash for raw material of sodium with the same as colorless glass. It was also suggested to the glass of Sasanian. The total amount of coloring agent of greenish blue glass is about 4% under the influence of working MnO, $Fe_2O_3$ and CuO. Dark purple blue glass : The specific gravity is $1.48{\pm}0.19$. There are rarely pores in internal zone. They are distributed to HCLA and LMK(Low MgO, Low $K_2O$) and suggested to Roman glass. The raw material of sodium is estimated to natron. The total amount of coloring agents of greenish blue is about 3% by $Fe_2O_3$ and CuO. These studies for western asia glass shards from South Mound of Hwangnamdaechong could be used in the future as the standard data which could be compared with those of other several graves in Korea and dispersed in foreign areas.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.9
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• pp.743-748
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• 2009

Chemical sludge conditioning is widely used to improve the dewatering efficiency. It is treated with commonly used conditioners, and then thickened and dewatered with a mechanical device. This paper aims to examine the flotation and thickening efficiencies of sewage sludge for conditioning conditions, such as unaerobic storage time, kinds of coagulant and dosages, and flotation conditions, such as sludge concentration and A/S ratio, using an dissolved air flotation apparatus. Experimental results showed that the specific surface area and specific resistance to filtration (SRF) were significantly increased and the flotation and thickening efficiencies were decreased with anaerobic storage time. However, the flotation and thickening efficiencies faintly decreased in sewage sludges conditioned as $Al_2(SO_4)_3$, $Fe_2(SO_4)_3$, and PSO-M. Flotation and thickening efficiencies in conditioned sewage sludge could be sustained up to 96% at A/S ratio of 0.01 mL/mg or over.