• 제목/요약/키워드: 기름오염

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Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

Discussion on the Criterion for the Determination of On-Water Oil Removal Resource Requirement in Korea (우리나라 기름오염 방제능력 확보기준의 타당성)

  • Kang Seong-Gil;Sung Hong-Gun;Lee Moonjin;Choi Hyuek-Jin;Yu Jeong-Seok;Kang Chang-Gu
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.4
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    • pp.3-18
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    • 2002
  • The present study was carried out to discuss the suitability of the criterion for the determination of the on-water oil removal resource requirement in Korea by comparison with the US criterion. According to the present criterion in Korea, the on-water response operation against the worst case discharge assuming the oil spillage of 60,000 ton from the accident of DWT 300,000 tanker requires the oil recovery capacity of 19,425 kl/hr (on-water recovery volume 20,000 ton). Under the US criterion, the recovery capacity of 16,667 kl/hr is required to respond to oil spill accident of the worst case discharge from the DWT 300,000 tanker. The result shows that resource requirement from the Korean criterion is 16% higher than US criterion, indicating that thc Korean criterion is reasonable.

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Strategies for Advancement of response management system on marine pollution (해양오염 방제체제의 선진화 방안)

  • Kim Dae Won
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.1
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    • pp.3-24
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    • 2000
  • The provability of major oil spill acidents around Korean coast is very high due to increase of sea traffic and decrease of quality of ships crews and increase of the old-ship. The Strategies of establishment of a advanced response management system against this mass pollution incident are as follows;. 1. Development of Regional Contingency Plan, which is scientifically illuminated, in order to implement the National Contingency Plan efficiently. 2. Early completion of a national response capability twenty thousand tons. 3. To strengthen training and exorcise specialized in the field of marine pollution response. 4. Establishment of a system of response cooperation among neighbor countries by promoting the NOWPAP tasks etc. The response policy in the 21th century should be concentrated to promote a practicle response capability through response operation scientifically specialized and internationalized by establishing the advanced response system early.

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Response Activities for Tar Ball Pollution from the 'Hebei Spirit' Oil Spill in the Southwestern Sea of Korea (서남해역에서 허베이스피리트호 원유유출 사고에 의해 생성된 타르볼 방제작업)

  • Cho, Hyun-Jin;Kim, Jeong-Yeop;Yang, Mun-Chul;Seo, Kang-Ryul;Min, Nam-Gi;Im, Sung-Huk;Jeon, Sung-Gun;Kim, Hee-Sik;Kim, Young-Hwa;Kim, Gi-Hun;Chang, Sun-Hee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.4
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    • pp.279-283
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    • 2009
  • Approximately 12,547 kL of oil from the tanker 'Hebei Spirit' released into the western sea of Korea, which subsequently reached and covered extensive areas of the western coastlines of Korea. In the following days great numbers of tar balls hit the southwestern coast. Three different cleanup methods were used to mediate the southwestern coastline tar ball pollution by Korea Coast Guard (KCG) net setting, manual pick up, and sweeping them up. Net setting was useful in protecting coastlines from being hit by tar balls. The cold weather in winter conditions helped the tar ball response efforts because it caused them to harden, allowing them to be swept up from beaches and to be gathered up by hand.

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A CFD Study of Oil Spill Velocity from Hole in the Hull of Oil Tanker (유조선 선체 파공에 따른 원유 유출 유속의 CFD 연구)

  • Choi, Dooyoung;Lee, Jungseop;Paik, Joongcheol
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.71-71
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    • 2018
  • Sea pollution accidents have been occurred due to the increase of marine ship traffic. Oil spill from the hull hole induced by tanker collision results in the huge sea pollution. Proper and prompt reaction on such oil spill disaster is needed to minimize the damage. Thru-hull emergency wood plug is typically used to manually close small holes, while it is required to develop some mechanical devices for closing large holes in the hull due to huge fluid pressure. Accurate estimation of oil discharge and velocity from such holes are important to develop proper device to control hull hole damage. High resolution CFD modeling investigation on the configurations of hull hole of 7.5 m initial depth and 30 cm diameter, which was observed in the oil spill accident of the Hebei Sprit off the west coast of Korea in 2007, has been carried out to compute the oil spill velocity distribution in terms of flow depth. Friction loss due to the viscous flow and the discharge coefficient of crude oil with specific gravity SG = 0.85 and viscosity of $4-12cP(mPa{\cdot}s)$ at the temperature of $20^{\circ}C-100^{\circ}C$ are presented in terms of Reynolds number based on the results of high-resolution CFD modeling.

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Establishment of $F_0$-value Criterion for Canned Tuna in Cottonseed Oil (참치 기름담금 통조림의 $F_0$-값 설정에 관한 연구)

  • HAN Bong-Ho;CHO Hyun-Duck;YU Hong-Sik;KIM Sang-Ho;CHUNG Youn-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.6
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    • pp.675-681
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    • 1994
  • [ $F_0$ ]-values of the canned tuna in cottonseed oil (CTCO) were investigated under different sterilizing conditions to optimize the energy consumption and microbiological safety. The $F_0$-values were measured using a microcomputer based technique. The exact cold point was not the volumetric center of the cans, and it was located in the center of meat mass in can which had ca. $6\%$ of head space. Location of the test cans in retort showed no remarkable influence on the $F_0$-values when the cans were jumble loaded. The process time before sterilization should be shortened as much as possible to prevent the contamination of microorganisms. Thermophilic spore forming bacteria found from raw and precooked tuna were Bacillus subtilis, Bacillus cereus and Bacillus pasteurii, and the most heat resistant was Bacillus subtilis. The rational $F_0$-value for the CTCO obtained from the preservation test was regarded as 6min.

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A Study on the Improvement of Compensation Regime for Oil Pollution Accident in Korea (유류오염사고 피해보상제도 개선방향에 관한 연구)

  • Na, Eun-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.2
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    • pp.104-110
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    • 2009
  • This study tries to give improvement directions of the law of oil spill focusing on the view that satisfying remuneration for victims should be considered. And it looks through the existing remuneration system provided by P&I Club and IOPC Fund. It also covers with issues related to remuneration in order to find the best for victims. The major contents of this study are as follows. First, the present law of compensation security to Marine oil pollution accident should be revised. Maximum value of remuneration needs to be raised and subjects liable to pay reparation need to be expanded. Second, in case the damage is widely different comparing to similar cases in foreign countries, it's hard to get complete remuneration from international corporations responsible for reparation. That's the reason the national emergency system for oil pollution must be established. Third, this study says the law that certainly defines a liability subject and that the liability is not necessarily caused by fault should be enacted. Last, it suggest that victims should have their object income data to facilitate establishment of the law of compensation for damages from marine oil pollution. To calculate proper remuneration, government should consider to choose one of public organizations as an investigator to damages and should collect accurate statistics relating to fishery. Furthermore, compensation system which can provide rapid reparation to victims needs to established by founding professional maritime organization of arbitration.

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Biodegradation of petroleum hydrocarbons by bacteria with surfactant producing capability and cell surface hydrophobicity (계면활성제 생성능과 세포 표면 소수성을 가진 세균 균주들에 의한 석유탄화수소의 생분해)

  • Kwon, Sun-Lul;Song, Hong-Gyu
    • Korean Journal of Microbiology
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    • v.53 no.4
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    • pp.265-272
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    • 2017
  • Some bacteria with different mechanisms for hydrocarbon degradation were isolated from oil-contaminated soils in Korea. Isolate Acinetobacter calcoaceticus SL1 showed biosurfactant- producing activity in oil-spreading test, and it exhibited a good emulsifying activity of 43.6 and 54.5% for diesel oil and n-hexane, respectively. It also has high cell surface hydrophobicity which can make it easily attaches to hydrocarbons and degrade them. It degraded 100% of 1,000 mg/L of n-octadecane and naphthalene, respectively in 3 days, 72.3% of 1,000 mg/L diesel oil in 7 days and 78.0% of 10,000 mg/L diesel oil in oil-contaminated soil during 28 days. Isolated strains Bacillus amyloliquefaciens S10 and B. subtilis GO9 can produce biosurfactant and formed 6.34 and 2.5 cm diameter of clear zones, respectively in oil-spreading test. Surface tension of their culture supernatant reduced from 74.6 to 34.4 and 33.3 mN/m, respectively during incubation, and critical micelle concentrations of culture supernatants were 2.0 and 5.9%, respectively. Consortium of A. calcoaceticus SL1 and B. amyloliquefaciens S10 degraded 77.8% of 10,000 mg/L diesel oil in 3 days, which indicated more efficient oil degradation than that by A. calcoaceticus SL1 alone. If these bacteria were applied together as a consortium to oil-contaminated sites, they may show a high removal rate of petroleum hydrocarbons.

Biodiesel Production from Waste Frying Oil by the Chemical Catalysts (폐유지로부터 화학촉매에 의한 바이오디젤 생산 연구)

  • Kim Deog-Keun;Lee Jin-Suk
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.487-490
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    • 2005
  • 재생 가능한 자원인 동식물성 기름으로부터 만들어지는 수송용 연료 바이오디젤은 낮은 대기오염물질 배출과 $CO_2$ Neutral 특성으로 환경친화적인 연료로 인정올 받으며 전세계적으로 그 생산량이 급격히 증가하고 있다 한국에서는 년간 20만톤의 폐식용유가 배출되며 이중 약 10만톤이 회수 가능한 것으로 추산된다. 폐식용유의 무단 폐기로 인한 수질오염과 폐기물의 자원 재활용 및 에너지 생산 관점에서 폐식용유를 바이오디젤 원료로 사용하는 연구가 많이 진행되었다. 높은 함량의 유리지방산을 함유한 폐식용유를 효율적으로 전이에스테르화(methanolysis) 하기 위해서는 먼저 산 촉매를 이용한 유리지방산의 전환 제거가 필요하다 본 연구에서는 다양한 종류의 강산성 이온교환 수지를 폐식용유의 전처리(pre-esterification)용 고체 산 촉매로 회분식 반응기에서 테스트하였으며 그 결과 Amberlyst-15가 유리지방산의 에스테르화 반응에 가장 적합한 것으로 나타났다. 회분식 반응기에서 도출된 최적 전처리 반응조건을 적용한 200시간 이상의 연속 전처리 운전결과 폐식용유에 함유된 $5\%$의 유리지방산이 $90\%$이상 전환제거 되었다 전처리 반응 후의 폐식용유를 균질계 염기촉매(KOH) 존재하에 메탄올과 전이에스테르화 반응을 시킨 결과 바이오디젤로 불리는 지방산메틸에스테르(Fatty Acid Methyl Ester, FAME)의 생산 수율은 $85\%$로 얻어졌으며 국내 바이오디젤 표준 규격에 따른 연료특성 분석 결과 FAME의 농도 규격을 제외한 모든 항목이 국내 규격을 만족하였다 폐식용유 바이오디젤의 FAME 농도가 $94.3\%$로 국내 규격$96.5\%$에 미달하는 문제는 식물성 원료유로 제조한 고순도 바이오디젤과 혼합 사용하거나 감압 증류 공정을 통해 고농도의 폐식용유 바이오디젤을 제조하여 해결 가능하다. 대전시 신성동 소재의 음식점에서 수거한 폐식용유를 원료로 하여 생산한 바이오디젤의 차량 배출가스 실증 테스트 결과 경유 차량의 주 오염물질인 PM과 Soot 및 기타 오염물질의 배출량은 감소하였으나 NOx의 배출량은 약간 증가하는 것으로 나타났다

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Case Study of Oil Spill Monitoring Caused by Maritime Casualties Using Satellite Data in 2014 (해양사고에 의한 유출유 모니터링 사례 소개와 향후 방향)

  • Yang, Chan-Su
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2014.06a
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    • pp.79-80
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    • 2014
  • Most of marine pollution have been occurred by oil spill accidents resulted from ship accidents in South Korea. This year there were two large oil spill accidents: the Yeosu Oil Spill Accident (2014.01.31.(Fri.) 09:35 LT) and the Captain Vangelis L. Oil Spill Accident (2014.02.15.(Sat.) 14:00 LT). In general, Synthetic Aperture Radar (SAR) is used in monitoring and detection of oil dumping and spilled oils by accident at sea. Therefore it is expected that KOMPSAT-5, launched successfully last year, will take part in that mission during a normal operation mode. After the two accidents, high spatial resolution optical satellite data including KOMPSAT-3 were acquired February 2 and 14, 2014. In this presentation, we analyzed optical properties of spilled oils from optical satellite imagery to estimate the spilled area and the volume at each region. Finally, a satellite application planning for ocean surveillance in South Korea will be presented.

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