• Title/Summary/Keyword: 기구합성

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EMC Compatibility Analysis of CEU EMC test results in the Optical Satellite System (광학위성 카메라전자부 EMC 시험결과의 시스템 양립성 검토)

  • Jang, Jae-Woong;Kim, Tae-Yoon;Lim, Seong-Bin;Moon, Guee-Won
    • Aerospace Engineering and Technology
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    • v.9 no.2
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    • pp.161-167
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    • 2010
  • CEU(Camera Electronic Unit) loaded in optical satellite for a high resolution image acquisition is composited with CC(Camera Controlloer), FPA(Focal Plane Assembly) and CEUP(CEU Power supply). EMC test and analysis results are explained in this paper. CE, CS, RE and RS test is performed in the 1st EMC test, RE, RS test which is not complied and influence considerably after shielding structure is performed in the 2nd EMC test. An effect due to the noise of CEU in the GPS/S-band receiving band is analyzed based on 2nd EMC test results. Margin more than 6dB is guaranteed when CEU is shielded.

Preparation of Nylon Elastomer and Its Application in the Electrospinning Process (나이론탄성체 제조와 전기방사응용)

  • Park, Jun-Seo;Ketpang, Kriangsak
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.274-281
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    • 2009
  • Nylon 6 and nylon elastomer were prepared by anionic polymerization route. Nylon elastomers, composed of hard segment of polyamide(PA) and soft segment of polyether(PE), were synthesized by use of TDI terminated polyol with caprolactam. The morphology of the electrospun webs of nylon and nylon elastomers, observed by FE-SEM, showed that the porous electrospun web was composed of nanofibers, whose diameter were in the range of 100 to 180 nm. Their behavior of melting and crystallization and the chemical structure of nylon elastomers were investigated by DSC and ATR FT-IR. Result of tensile testing indicated that nylon has higher tensile strength and lower elongation than nylon elastomers. Atmospheric plasma(APP) with $O_2$ and $N_2$ as reactive gas modified the surface of electrospun nylon and electrospun nylon elastomers allowing them higher hydrophilicity, while APP with $CH_4$ as reactive gas modified the surface of polymers allowing higher hydrophobicity.

Preparation of $BaTiO_3$ powder in solid reaction and basic study on dielectrics of $CeAIO_3-BaTiO_3$system ($BaTiO_3$ 분말합성조건 및 $CeAIO_3-BaTiO_3$계 유전체의 기초적 연구)

  • Lim, Dae-Young;Kim, Jong-Ock;Lee, Chae-hyun;Park, Won-Kyu
    • The Journal of Natural Sciences
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    • v.8 no.1
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    • pp.61-69
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    • 1995
  • It is hard to synthesize pure $BaTiO_3$ from $BaCO_3$ and $TiO_2$ in solid reaction for the activity of BaO and secondary phase. For this reason, the wet chemical techniques have been studied. Starting material which was used in these methods were expensive and the properties of powder which was synthesized in same defined. So, some process have been studying again to improve soild reaction method. This study which was one of those was to defin the forming mechanism of $Ba_2TiO_4$ and to control some condition of $Ba_2TiO_4$. The synthesis temperature of $BaTiO_3$ in solid reaction was near $1120^{\circ}C$. The quantity and forming temperature of $Ba_2TiO_4$ could be controlled by atmosphere heat treatment. $Ba_2TiO_4$ was related to expansion in Ba-rich region of $BaTiO_3$. $BaTiO_2O_5$ and $BaTiO_3O_7$ was reason to expand in Ti-rich region. The dielectrics of $CeAIO_3$ which was synthesized and sintered in reduction atmosphere and $BaTiO_3$ system were affected by $CeO_2$ which was formed for the decomposition of $CeAIO_3$ heat treatment in air.

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Synthesis of $Cp^*Ru(CO)(PR_3)H$ Type Complexes and Photo-Induced H/D Exchange Reaction ($Cp^*Ru(CO)(PR_3)H$형 착물의 합성과 광반응에 의한 H/D 교환반응)

  • Lee, Dong Hwan;Kim, Sng Il;Kim, Jang Il;Oh, Yung Hee;Kam, Sang Kyu
    • Journal of the Korean Chemical Society
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    • v.41 no.12
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    • pp.645-652
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    • 1997
  • Hydride complexes Cp*Ru(CO)(PR3)H (Cp*=η5-C5Me5, PR3=PMe3, PEt3, PMePh2, PPh3, PCy3)(4a-4f) were synthesized by the reaction of the corresponding chloro complex Cp*Ru(CO)(PR3)Cl (3a-3f) with various hydridic reagent (NaBH4, LiAlH4, LiBEt3H) or NaOMe. Irradiation of Cp*Ru(CO)(PCy3)H (5e) in C6D6 solution with UV light caused H/D exchange reaction between coordinated Cp*, PCy3 and/or Ru-H ligand proton and a deuterium of the deuterated aromatic solvent through a series of inter- and intramolecular C-H activation. The proposed mechanism was described.

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Preparation and Characterization of Conducting Composites Impregnated with Thick Polyheterocyclic Polymers (전도성 복합소재의 합성과 특성연구)

  • Park, Jun-Seo
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.342-347
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    • 1998
  • Light-weight conductive polymer composites were prepared by incorporating polyheterocycles such as polypyrrole and polythiophene into pores of a highly porous cross-linked polystyrene, host polymer, to form a conductive network. The highly hydrophobic and porous host polymer was synthesized by concentrated emulsion polymerization method. Polypyrrole-based composites, prepared by employing ferric chloride-methanol system, showed a conductivity as high as 0.82 S/cm. Conductivity of polythiophene-based composites, prepared from ferric chloride-acetonitrile system, was 6.05 S/cm. Conductivity of compositivity was influenced by the initial molar ratio of oxidant to monomer as well. SEM micrographs of the composites showed that conducting polymer coated uniformly the inside wall of the porous host polymer. Shielding effectiveness of the polypyrrole-based composites and of the polythiophene-based composites were 15.2 dB and 22.5 dB at 2.0 GHz, respectively. In the temperature range from 20 to 300K, a polypyrrole impregnated composite exhibited seimiconducting behavior and followed the variable range hopping(VRH) model for charge transport.

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Active Transport of Anions through Synthesized Polymer Membrane with Pyridine as Fixed Carrier (피리딘 고정전달자를 함유한 합성 고분자막을 통한 음이온의 능동전달)

  • 이용현;한정우박돈희조영일
    • KSBB Journal
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    • v.6 no.3
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    • pp.241-247
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    • 1991
  • The Poly (4-vinyipyridine-co-styrene) membrane containing Pyridine as fixed carrier was synthesized and characterized. And the active transport mechanism of Cl- and $CCl_3COO^-$ with changing concentration of $H^+$ and $OH^-$ was investigated. $CCl_3COO^-$ was transported not only by a symport mechanism with $H^+$ transfer but also by an antiport mechanism with $OH^-$transfer, while $Cl^-$ was transported only by a symport mechanism with $H^+$ transfer. Observing the initial flux of anions, salt formation constant between ions and membrane (K), and diffusion coefficient in membrane (D) were calculated as follows: for $Cl^-, \;K=4.60{\times}10^2\;mol^{-1}{\cdot}\textrm{cm}^3, \;D=1.57{\times}10^{-3}{\textrm{cm}^2/h$ and for $CCl_3COO^-, \;K=1.l0{\times}10^4\;mol^{-1}{\cdot}\textrm{cm}^3, \;D=1.14{\times}10^{-4}{\textrm{cm}^2}/h$.

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Design and Fabrication of X-band Wideband Array Antenna for SAR Applications (SAR를 위한 X-band 광대역 배열 안테나의 설계 및 제작)

  • Won Young-Jin;Lee Young-Ju;Kong Young-Kyun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.2 s.105
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    • pp.184-192
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    • 2006
  • Synthetic Aperture Radars(SAR) are used mainly for high-resolution imaging of the terrain. This paper describes the $16{\times}16$ array antenna designed for an X-band, automobile-based SAR(AutoSAR) system. This antenna has the structure of several layers such as radome, radiators, slots, feed network, and honeycomb cores. Each layer is adhesively bonded to meet different combination of structural and electrical design requirements. Using the Strip-Slot-Foam-Inverted-Patch(SSFIP) structure and honeycomb cores, a wide bandwidth and a structural hardness were achieved. Measurement results were compared with simulation results. It was observed that this antenna had a bandwidth of 1.7 GHz, side-lobe levels of less than -20 dB, half-power beamwidth of $5^{\circ}$ and $5^{\circ}$, and gains of 25.0 dBi. The observed results show that the designed array antenna will be applicable to the wideband SAR system.

A Study of Mode of Action of Alachlor - II. Effect of Alachlor on Peroxidase Synthesis in Oat(Avena sativa L.) (Alachlor의 제초기구(除草機構)에 관한 연구(硏究) - II. Alachlor가 귀리의 Peroxidase합성(合成)에 미치는 영향(影響))

  • Kwon, S.W.;Kim, J.C.
    • Korean Journal of Weed Science
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    • v.10 no.3
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    • pp.233-239
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    • 1990
  • The effect of alachlor treatment on peroxidase synthesis in oat root tips was studied. Alachlor caused increase in the amount of soluble peroxidase in oat root tips, peroxidase activity increase as the rate of alachlor application increased, Alachlor treatment of oats with $1{\times}10^{-6}M$, peroxidase activity increased 0.20 unit higher than that of nontreatment. After 12hr, 65mM of peroxide treatment of oats inhibited 16% root growth, and 130 mM peroxide treatment caused 59% inhibition. With PAGE of peroxidase extracted from normal root tips, PAGE give 4 species($P_2$, $P_3$, $P_4$, and $P_5$ band) of peroxidase. Alachlor significantly activated isoperoxidase. Three isoperoxidase($P_1$, $P_6$, and $P_7$) are synthesized at a increased concentration of alachlor, SDS-PAGE analysis of proteins extracted from oat root tips showed that they were made up of subunits blow 100 kD polypeptide.

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Luminescent Characteristics of $MgZnSiN_2$ Phosphors Doped with Tb or Eu ($MgZnSiN_2$ 모체에 Tb 또는 Eu이 첨가된 형광체의 발광 특성)

  • Lee, Soon-Seok;Lim, Sung-Kyoo
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.12
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    • pp.31-36
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    • 1999
  • The $Mg._5Zn._5SiN_2:Tb$ and $Mg._5Zn._5SiN_2:Eu$ materials were synthesized and studied to develop new phosphors for thin-film electroluminescent device application. Photoluminescence and cathodoluminescence characteristics of the synthesized phosphors were similar to general emission spectra of Eu, Tb ion, respectively. The CIE color coordinates, threshold voltage and luminance of the $Mg._8Zn._2SiN_2:Eu$ thin-film electroluminescent device fabricated by electron-beam deposition system were x=0.47, y=0.46, 47V, and 23.5 cd/$cm^2$ at 80V, respectively. The capacitance-voltage and charge-voltage characteristics of the thin film electroluminescent devices were also measured.

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Characteristics of Cu(II) Extraction by β-ketohexanal (β-ketohexanal에 의한 Cu(II)의 추출 특성)

  • Shin, Jeong-Ho;Lee, Sang-Hoon;Jeong, Kap-Seop;Park, Kyung-Kee;Jun, Sang-Woo
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1053-1060
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    • 1996
  • $\beta$-ketohexanal as a chelating extractant was synthesized from the reaction of ethyl formate and methyl propyl ketone in the presence of sodium amide, and the equilibrium characteristics in the extraction of copper by $\beta$-ketohexanal-chloroform were investigated. The equilibrium constants such as the dissociation constant and the partition coefficients of $\beta$-ketohexanal, the stability constant and the partition coefficient of copper chelating complex, and the overall equilibrium constant in the extraction of copper were determined by spectrophotometric measurements, and the mechanism of extraction was proposed. The percent of extracted copper by $\beta$-ketohexanal-chloroform was near 100%, and the selective extraction of copper from Cu-Zn-Cd mixture was possible. Copper was found to be extracted as $CuR_2$ and the equilibrium reaction was expressed as $Cu^{2+}+2{\overline{HR}}{\rightleftarrows}{\overline{CuR{_2}}}+2H^+$.

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