• Membrane Journal
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• v.26 no.3
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• pp.212-219
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• 2016

The alumina hollow fiber membranes were prepared by spinning and sintering a polymer solution containing suspended alumina powders. For determine pore structure of hollow fiber membranes formed by different solvent-nonsolvent interaction rate, dimethylsulfoxide (DMSO), dimethylacetamide (DMAc), triethylphosphite (TEP) were prepared in dope solution by solvent, polyethersulfone (PESf) and polyvinylpyrrolidone (PVP) were used as a polymer binder and additive. The pore structure of hollow fiber membranes was characterized using scanning electron microscope (SEM). The alumina hollow fiber membranes prepared by DMSO, DMAc were had the asymmetric structure mixed sponge-like and finger-like morphology, while TEP solvent were had single sponge-like structure. The prepared hollow fiber membranes were analyzed gas permeation and mechanical strength experiment also. The hollow fiber membrane having single sponge-like structure was had high gas permeation performance. On the contrary to this, more finger-like morphology was less gas permeation performance.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.11a
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• pp.133-136
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• 2005

원자현미경을 이용하여 나노허니컴 구조물의 굽힘 탄성계수를 측정하였다. 나노허니컴 구조물의 단면적은 기공들의 배열 때문에 위치마다 다르게 되고, 이로 인해 관성 영역 모멘트는 상수값으로 계산되지 않는다. 본 연구에서는 나노허니컴 구조물의 단위 면적 내 관성 영역 모멘트 평값을 벌크 구조의 나노허니컴 구조물의 영률로 가정하였다. 단위 면적 내 광성 영역 모멘트 평균값과 나노허니컴 구조물의 기공률 사이에 관계식이 유도되었다. 기공의 직경이 31 nm 인 양극 산화 알루미늄 필름이 나노허니컴 구조물로 제작되었다. 양극 산화 알루미늄의 영률이원자현미경을 이용한 굽힘 실험으로 측정되었으며, 나노 인장시험기의 인장 실험 결과와 비교되었다.

• Composites Research
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• v.33 no.3
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• pp.147-152
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• 2020

In this study, void behavior of composite laminate by local internal pressure gradient due to structural geometry and surface film application condition was experimentally evaluated through fabrication of spar/skin integrated structure specimens. Viscosity comparison and thermal analysis for both carbon fiber prepreg and surface film were conducted and cure characteristic and rate difference were analyzed. 2 types of spar/skin integrated structural specimens were prepared based on different application condition of surface film. Subsequently, those specimens were evaluated through visual surface inspection, non-destructive and destructive inspection. In a specimen #1 with full application of surface film, low pressurized area of composite laminate created by pressure gradient of structural geometry had voids. It exhibited that voids could not be evacuated and were locked in cured laminate by the influence of pre-cured surface film with relatively faster cure rate. In a specimen #2 without surface film, it revealed that all internal voids disappeared in the cured laminate. Therefore, it is verified that surface film acts as barrier film preventing void movement and evacuation during autoclave cure.

• Journal of the Korean Electrochemical Society
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• v.6 no.1
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• pp.53-58
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• 2003

It is well known that the anode substrate of anode-supported type SOFC should have high electrical conductivity and high gas permeability to minimize the polarization loss of the cell performance during operation. In this study, we made anode substrates of SOFC with two different methods, which gave different anode microstructures, especially different pore structures with each other. We performed electrical and microstructural characterization of Ni/YSZ cermet anode via extensive measurements of its electrical conductivity and gas permeability combined with adequate image analysis based on quantitative stereological theory

• Journal of the Microelectronics and Packaging Society
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• v.22 no.2
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• pp.21-26
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• 2015

Mesoporous ceramic materials were applied in various fields such as adsorbent and gas sensor because of low thermal conductivity and high specific surface area properties. This structure could be divided into open-pore structure and closed-pore structure. Although closed-pore structure mesoporous ceramic materials have higher mechanical property than open-pore structure, it has a restriction on the application because the increase of specific surface area is limited. So, in this work, specific surface area of closed-pore structure $TiO_2$ was increased by anneal time. As increased annealing time, crystallization and grain growth of $TiO_2$ skeleton structured material in mesoporous structure induced a collapse and agglomeration of pores. Through this pore structural change, pore connectivity and specific surface area could be enhanced. After anneal for 24 hrs, porosity was decreased from 36.3% to 34.1%, but specific surface area was increased from $48m^2/g$ to $156m^2/g$. CO gas sensitivity was also increased by about 7.4 times due to an increase of specific surface area.

• Electrical & Electronic Materials
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• v.5 no.4
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• pp.406-410
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• 1992

본 논문에서는 MgFe$_{2}$O$_{4}$ 세라믹스의 구조적 특성을 개선하기 위하여 TiO$_{2}$를 0-10[wt%] 첨가하여 세라믹스를 만들고 TiO$_{2}$가 습도센서용 MgFe$_{2}$O$_{4}$ 세라믹스의 구조적 특성에 미치는 영향을 조사하였다. 각 시편은 TiO$_{2}$가 첨가되는 양이 증대함에 따라 NgTi$_{2}$O$_{5}$의 이상이 나타났다. TiO$_{2}$의 첨가량이 6[wt%]일 때 까지는 시편의 밀도가 증가하여 기공율의 저하를 가져왔고 기공의 크기가 최소가 되는 조성은 5[wt%]의 TiO$_{2}$가 첨가되었을 때이며 이때의 평균 기공의 크기는 1615[.angs.]이었다. 따라서 5[wt%]의 TiO$_{2}$를 첨가했을 때가 기공의 크기 조절에 최적이라고 생각되며 센서용 기판으로 응용하기 적합하다고 생각된다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.405-406
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• 2003

분진여과시 형성되는 분진 케이크는 궁극적인 여과 성능을 좌우하며, 필터의 구조, 분진 입자의 형태나 크기, 분진농도, 여과속도 등에 의해 영향을 받는다 특히 필터의 표면 구조나 기공 크기는 여과 초기 단계의 케이크 층의 구조를 결정하며, 연속적인 여과시 초기 케이크 층은 다음에 쌓이는 케이크 형성과 비저항에 영향을 주므로 필터 medium 구조 또한 분진여과 과정에서 중요한 영향 요인이 된다. 본 연구에서는 필터 medium의 구조가 서로 다른 고온가스정화용 복합 세라믹 필터, metal fiber mat, 스테인레스 필터를 이용하여 분진농도와 여과속도를 변수로 하여 분진 여과 실험을 함으로써 각각의 필터에 대한 케이크 비저항과 기공율을 실험과 이론식으로부터 추정하였다. (중략)

• Polymer(Korea)
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• v.39 no.1
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• pp.151-156
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• 2015

Herein, novel porous structures were fabricated from monomer solutions of dimethylsiloxane and benzene by directional crystallization in twice. First, a honeycomb-like structure was fabricated by $1^{st}$ directional crystallization of solvent. By infiltration of the solution and subsequent $2^{nd}$ directional crystallization, novel structures of different pores in the honeycomb-like structure were fabricated. The porous materials prepared by the repeated directional crystallization have higher indentation modulus and hardness than those of the samples prepared by single directional crystallization. When a higher solution concentration was used in $2^{nd}$ directional crystallization, the maximum increase (indentation modulus: 2140% increase, indentation hardness: 2330% increase) was obtained. On the other hand, porosity and contact angle were lower in the samples from $2^{nd}$ directional crystallization than those from $1^{st}$ directional crystallization. A large decreases was observed, when a relatively high concentration was used in $2^{nd}$ directional crystallization (porosity: 21% decrease, contact angle: 36% decrease).

• Journal of Korea Foundry Society
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• v.32 no.3
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• pp.150-156
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• 2012

발포금속은 초경량 재료로서 폐기공과 개기공의 두 가지 형태의 구조를 지니고 있으며 폐기공은 내충격성, 흡음성, 단열성의 기능을 지니고 있고, 개기공은 필터, 생체지지대, 촉매재, 열방출재 등으로 사용되고 있다. 개기공발포재는 삼차원 구조모양으로 프리커서를 이용한 압력정밀주조나 기공입자용출법으로 제조하고 있으나 기공의 크기나 셀의 형상, 두께 등을 조절하기에 어려움이 있다. 이를 해결하기 위하여 환경친화적인 펄라이트를 사용하여 목적하는 크기의 그래뉼을 제조한 후, 용융마그네슘합금을 감압주조법으로 주조하여 그래뉼의 크기로 기공율을 조절하고, 주형의 온도와 압력에 따른 유동의 길이를 측정하였다. 그래뉼 직경이 2.3 $mm{\O}$ 일때에 주형의 온도 $300^{\circ}C$ 이상, 압력이 5000 Pa 이상에서 유동길이 6.5 cm 이상을 얻었다.

• Membrane Journal
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• v.21 no.3
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• pp.229-235
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• 2011

In this study, mesoporous titania/alumina membranes were prepared by sol-gel method. Pore structure and phase composition of titania/alumina membranes could be changed by calcination temperature. The addition of alumina into titania membranes retarded anatase-to-rutile phase transformation, resulting in stabilization of pore structures. The 5 time dip-coated membrane calcined at $450^{\circ}C$ is about $10.3{\mu}m$ in thickness with an average pore size of 5 nm. Hydrogen and nitrogen permeances through the membrane were $17.1{\times}10^{-7}mol/m^2{\cdot}s{\cdot}Pa$ and $4.7{\times}10^{-7}mol/m^2{\cdot}s{\cdot}Pa$, respectively. These data were explained by the Knudsen diffusion mechanism.