• Title/Summary/Keyword: 금속 부식

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A Study on Corrosion of the HFC-125 fire extinguishing agent for Metal and Non-Ferrous Metal (HFC-125 소화약제의 금속 및 비철금속 부식성 평가에 관한 연구)

  • Lee, Chang-Woo;Ham, Eun-Gu;Yoo, Ju-Yeol;Seo, Sang-Hun;Kim, Gin-Sung;Cho, Yong-Sun
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2016.11a
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    • pp.271-274
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    • 2016
  • 본 논문에서는 오존층 파괴 및 지구 온난화에 악영향을 미치는 할로겐화합물 소화약제를 대체하여 개발된 청정소화약제인 할로겐화합물 청정소화약제(Halocarbon clean agent)의 열분해 생성물(thermal decomposition products)의 영향에 평가하고자 한다. 이를 위해 할로겐화합물 청정소화약제인 HFC-125가 화원 크기의 변화에 따른 열분해 생성물의 미치는 영향을 측정하기 위해 소화시험을 실시하였고 금속(철), 비철금속(구리), 유리 시편의 부식성과 전자부품(SD-Card) 작동여부를 평가 하였다. 금속 및 비철금속 시편의 부식성을 측정하기 위해 디지털 카메라를 통해 이미지를 촬영하고 그래픽 편집 소프트웨어를 이용하여 채도(saturation)를 측정하여 부식성의 정도를 분석하였다. 금속, 비철금소, 유리 시편의 부식성 분석 결과, 화원의 크기가 증가할수록 금속 및 비철금속의 부식성이 증가하였다. 즉, 화원의 크기(fire size)에 따라 열분해 생성물질도 증가하여 금속 및 비철금속의 부식을 증가시키는 것으로 사료된다.

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A Study on the metals corrosion in Air (대기 중 금속부식영향에 관한 연구)

  • 김윤신;박태술;문정숙;이상복;이용현
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.279-280
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    • 2000
  • 대기 중 금속부식은 SO$_2$와 부유먼지, $O_3$, 산성비 등의 대기오염물질 및 농도와 그 밖의 이술, 빗물, 해수입자, 온도, 습도, 강우빈도 및 산도 등의 여러 가지 요인에 의해서 영향을 받지만, 특히 SO$_2$와 습도와 관련하여 금속부식에 영향을 미치고 있다. 금속 부식이란 금속의 산화상태 즉 산화ㆍ환원 반응으로 대기오염물질의 금속부식에 미치는 영향은 오염물질 자체가 부식에 직접관여 하는 것 외에 촉매 역할로써의 간접적 요인이 더욱 중요시되고 있으며, 오염물질의종류 및 농도와 지역적 특성에 의한 영향이 크다. (중략)

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Corrosive Characteristics of Metal Materials by a Sulfate-reducing Bacterium (황산염환원미생물에 의한 금속재료의 부식 특성)

  • Lee, Seung Yeop;Jeong, Jongtae
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.219-228
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    • 2013
  • To understand characteristics of biogeochemical corrosion for the metal canisters that usually contain the radioactive wastes for a long-term period below the ground, some metal materials consisting of cast iron and copper were reacted for 3 months with D. desulfuricans, a sulfate-reducing bacterium, under a reducing condition. During the experiment, concentrations of dissolved metal ions were periodically measured, and then metal specimen and surface secondary products were examined using the electron microscopy to know the chemical and mineralogical changes of the original metal samples. The metal corrosion was not noticeable at the absence of D. desulfuricans, but it was relatively greater at the presence of the bacterium. In our experiment, darkish metal sulfides such as mackinawite and copper sulfide were the final products of biogeochemical metal corrosion, and they were easily scaled off the original specimen and suspended as colloids. For the copper specimen, in particular, there appeared an accelerated corrosion of copper in the presence of dissolved iron and bacteria in solution, probably due to a weakening of copper-copper binding caused by a growth of other phase, iron sulfide, on the copper surface.

The metal corrosion caused by museum indoor air pollutants (박물관 실내 대기오염물질에 의한 금속 부식 영향)

  • Kang, Dai-Ill
    • Journal of Conservation Science
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    • v.22
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    • pp.5-14
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    • 2008
  • The effect of air pollutants coming from internal museum materials such as wood-based products and cements on metal corrosion have been investigated. The Oddy test and the Chamber test was employed as a corrosion test. The metal pieces after the Oddy test had different corrosion types caused by the internal museum materials. The most effective wood based product was 18T HS(E0) and 9mm plywood(F0,E0). Iron(Fe) and copper(Cu) also bronze of the Chamber test had corrosion caused by Formic acid, Acetic acid, and Acetaldehyde. The packing materials in high humidity had caused more corrosion on the surface of the metal pieces than in low humidity.

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A Study on the Process Conditions Optimization for Al-Cu Metal Line Corrosion Improvement (Al-Cu 금속 배선 부식 개선을 위한 공정조건 최적화에 관한 연구)

  • Mun, Seong Yeol;Kang, Seong Jun;Joung, Yang Hee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.11
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    • pp.2525-2531
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    • 2012
  • Al-Cu alloy has been used as a circuit material for its low resistance and ease to process for long years at CMOS technology. However, basically metal is very susceptible to corrosion and which has been a long pending trouble in various fields using metal. The defect causes the reliability concerns, so improved methods are necessary to reduce the defect. In the various corrosion parameters, PR strip process conditions after metal etch and optimal cleaning solutions are controllable and increase the process margin to prevent the metal corrosion. This study proposes that chlorine residue after metal etch as the source of metal corrosion, and charges should be removed by optimizing PR strip process condition and cleaning condition.

Development of surface treatment materials for improving durability of metallic bipolar plates in PEMFC (연료전지용 금속분리판 내구성 향상을 위한 표면처리기술 개발)

  • Kim, Myong-Hwan;Goo, Young-Mo;Yoo, Seung-Eul
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.41-44
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    • 2008
  • 본 연구에서는 고분자 전해질 연료전지용 금속분리판의 전기화학적 부식을 방지하기 위한 금속 첨가 DLC(Diamond-like-carbon) 표면처리 방법을 개발하였으며, stainless steel 304를 모재로 하여 텅스텐 첨가 DLC, 티타늄 첨가 DLC, 몰리브덴 첨가 DLC 금속분리판을 제작하였다. 제작된 금속분리판을 이용하여 내구성 평가,전기화학적 부식 특성, 성능평가 및 접촉저항 특성 등을 평가하였다. 전기화학적 부식특성의 경우 각각의 분리판에 대해 6.69, 1.2, 1.0 ${\mu}A/cm^2$로 모재인 STS 304의 25 ${\mu}A/cm^2$의 부식전류밀도에 비해 우수한 부식특성을 보였다. 또한 초기 성능에서 몰리브덴 첨가 DLC 분리판의 경우 300 mA/$cm^2$에서 0.757 V로 측정되었으며, 이는 graphite 분리판 측정 결과인 0.758 V와 유사한 성능을 보였다. 또한 내구성 평가에서 초기 성능 대비 성능 감소율이 10% 감소하는데 소요된 시간은 graphite 분리판의 경우 2,000시간으로 나타났으며, 몰리브덴 첨가 DLC 분리판의 경우 1,700시간으로 측정되었다. 1,500시간 까지의 성능 감소율은 grphite,텅스텐 첨가DLC,티타늄 첨가DLC, 몰리브덴 첨가 DLC 분리판 순으로 각각에 대해 37.7, 60.3, 92.8, 45.7 ${\mu}V$/hr로 나타났다.

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Metal Corrosion Mechanism by Sulfate-reducing and Iron-oxidizing Bacteria in Saline System and its Optimal Inactivation (염수계 철산화균 및 황환원균에 의한 금속 부식 및 최적 제어 방안)

  • Sung, Eun-Hae;Han, Ji-Sun;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.798-807
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    • 2008
  • Due to economic impairment derived from metal corrosion of pumping station installed around coastal area, it was needed for related cause-effect to be investigated for understanding practical corrosion behavior and providing proper control. This research was thus carried out to determine whether the microbe can influence on metal corrosion along with its control in the laboratory. For this study, groundwater was sampled from the underground pump station(i.e. I Gas Station) where corrosion was observed. Microbial diversity on the samples were then obtained by 16S rDNA methods. From this, microbial populations showing corrosion behaviors against metals were reported as Leptothrix sp.(Iron oxidizing) and Desulfovibrio sp.(Sulfur reducing) Iron oxidizing bacteria were dominantly participating in the corrosion of iron, while sulfate reducing bacteria were more preferably producing precipitate of iron. In case of galvanized steel and stainless steel, iron oxidizing bacteria not only enhanced the corrosion, but also generated its scale of precipitate. Sulfate reducing bacteria had zinc steel corroded greater extent than that of iron oxidizing bacteria. In the inactivation test, chlorine or UV exposure could efficiently control bacterial growth. However as the inactivation intensity being increased beyond a threshold level, corrosion rate was unlikely escalated due to augmented chemical effect. It is decided that microbial corrosion could be differently taken place depending upon type of microbes or materials, although they were highly correlated. It could be efficiently retarded by given disinfection practices.

An Experimental Investigation of the Effect of Corrosion on Dry Friction Noise (건성마찰 소음에 대한 부식 영향도 실험연구)

  • Baek, Jongsu;Kang, Jaeyoung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1251-1256
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    • 2015
  • This study investigates the friction noise characteristic in relation to the corrosion of metal by using the frictional reciprocating and pin-on-disk system. From the experiments, it is found that the corrosion of metal advances the onset time and increases the magnitude of friction noise. Further, it is observed that the effect of corrosion on friction noise stems from the alteration of tribo-surface during repetitive frictional motion. The alteration of the corrosive contact surface induces a negative friction-velocity slope, by which the corrosion of metal can generate dynamic instability faster than non-corrosion of metal.

부식환경에서의 파괴 및 피로

  • 이동영
    • Journal of the KSME
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    • v.28 no.4
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    • pp.313-321
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    • 1988
  • 어떤 구조물이 반복하중을 받으면 피로파괴를 일으킨다. 만일 이 구조물이 부식환경 속에 앗 으면 불활성 분위기나 공기 중에서 보다 빨리 파괴에 이르게 된다. 이러한 현상을 흔히 부식 피로라고 한다. 부식피로에 크게 영향을 미치는 변수들을 대략 기계적 변수, 금속학적 변수, 환경 변수로서, 기계적 변수에는 최대응력 확대계수, 응력확대계수범위, 응력비, 반복하중 주파수, 반복하중파형, 응력상태, 잔류응력, 균열의 크기 및 모양 등이 있으며 금속학적 변수로는 합금 조성, 합금원소와 불순물의 분포, 미세조직과 결정구조, 열처리, 소성가공, 집합조직 등이며 환 경변수에는 온도, 환경의 형태(기체, 액체), 부식성분의 분압 또는 농도, 전기화학적 전위, pH, 수용성 환경의 점성, 피복, 부식억제제 등이 있다. 이와 같이 부식환경 속에 있는 구조물의 파 손을 이해하기 위하여는 응력부식과 부식피로를 공부하여야 한다. 이 현상은 매우 복잡한 문 제이기 때문에 아직도 완전히 이해되지 않은 상태이고 따라서 중요한 연구대상이 되고 있다. 여기서는 응력부식과 부식피로의 파괴역학적인 측면을 소개하고자 한다.

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Experimental Study on the Corrosion Characteristics of Zn and Zn-15Al Coatings Deposited by Plasma Arc Thermal Spray Process in Saline Solution (플라즈마 아크 용사 공법에 의해 도포된 Zn 및 Zn-15Al 금속 코팅의 해수 환경에서 부식 특성에 관한 실험적 연구)

  • Jeong, Hwa-Rang;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.6
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    • pp.539-550
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    • 2021
  • In this study, Zn and Zn-15Al were coated on general carbon steel by plasma arc metal spraying and then immersed in a 3.5wt.% NaCl solution similar to the seawater environment to evaluate the corrosion resistance properties. Through the surface shape analysis test by SEM and XRD, it was found that the Zn coating was porous and needle-shaped, so the penetration of the electrolyte was easy, and thus the corrosion rate was rapid. On the other hand, the Zn-15Al coating had a uniform and dense shape and was shown to suppress corrosion.