• 제목/요약/키워드: 금속화

Search Result 2,191, Processing Time 0.036 seconds

Environment-friendly Trivalent Chromate Treatment for Zn Electroplating (아연도금용 친환경 3가 크로메이트 표면처리기술)

  • Kim, Soo Won;Lee, Chul Tae
    • Applied Chemistry for Engineering
    • /
    • v.17 no.5
    • /
    • pp.433-442
    • /
    • 2006
  • Hexavalent chromium passivation, as very effective anti-corrosion method, can not be used in the field of surface treatment for metal, any more. Throughout the world, this regulations which was applied to automotive industries will be extended to all industries including electronics industries in the near future. Therefore a new anti-corrosion method should be established without delay, and trivalent chromium passivation as an alternatives replace the hexavalent chromium passivation for the time being. This paper gives an overview of the currently available trivalent chromium passivation processes, and then it attempts to give an insight to develop a more effective trivalent chromium conversion coating process for possible substitution of the hexavalent chromium passivation process.

Synthesis of Pd-Ag on Charcoal Catalyst for Aerobic Benzyl Alcohol Oxidation Using [Hmim][PF6] ([Hmim][PF6]를 사용한 벤질 알코올의 호기성 산화반응용 팔라듐-은 차콜 촉매 제조)

  • Choo, Yunjun;Yoo, Kye Sang
    • Applied Chemistry for Engineering
    • /
    • v.25 no.4
    • /
    • pp.425-429
    • /
    • 2014
  • Pd on charcoal particles were prepared by wet impregnation to develop commercial catalyst for aerobic benzyl alcohol oxidation. Especially, one of room temperature ionic liquids, [Hmim][$PF_6$], was used as an effective solvent in the synthesis to improve the metal dispersion of the catalysts. Among the Pd/Charcoal with various Pd concentrations, 7.5 wt% catalyst showed the higher catalytic activity and stability. Moreover, Ag was used as a promoter with various ratios in catalyst preparation. Under identical reaction conditions, the catalyst with 9 : 1 of Pd and Ag weight ratios was most active due to higher metal dispersion.

Development of Lightweight DMFC System for Charging Secondary Battery in Military Operational Environment (군 운용환경에서 이차전지 충전을 위한 경량화 DMFC 시스템 개발)

  • LEE, SUWON;GWAK, GEONHUI;RO, JUNGHO;CHO, YOUNGRAE;KIM, DOYOUN;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.28 no.5
    • /
    • pp.481-491
    • /
    • 2017
  • In this study, we developed 300 W lightweight DMFC system for charging secondary battery in small unit military operation. In order to reduce the volumetric shape and weight of the system considering the environment of the individual soldier's, the arranging of system components has been optimized. A metal bipolar plates made of STS-470FC have been implemented to the DMFC stack to meet the weight demand of the system. As a result of the performance test of the stack, the target value was satisfied by outputting 561 W exceeding 24% of the stack output 450 W required to output 300 W required for the entire system. Moreover, 2,655 hours exceeding 1,000 hours also has been satisfied. To ensure good robustness of the metallic bipolar plate based DMFC stack, finite element method based simulations are conducted using a commercial ANSYS Fluent software.

Recent Trend of Lithium Secondary Batteries for Cellular Phones (최근 휴대폰용 배터리의 기술개발 동향)

  • Lee, H.G.;Kim, Y.J.;Cho, W.I.
    • Journal of the Korean Electrochemical Society
    • /
    • v.10 no.1
    • /
    • pp.31-35
    • /
    • 2007
  • In this review article, we are going to explain the recent development of lithium secondary batteries for a cellular phone. There are three kinds of rechargeable batteries for cellular phones such as nickel-cadmium, nickel-metal hydride, and lithium ion or lithium ion polymer. The lithium secondary battery is one of the most excellent battery in the point of view of energy density. It means very small and light one among same capacity batteries is the lithium secondary battery. The market volume of lithium secondary batteries increases steeply about 15% annually. The trend of R&D is focused on novel cathode materials including $LiFePO_4$, novel anode materials such as lithium titanate, silicon, and tin, elecrolytes, and safety insurance.

$K_3Li_2(Nb_xTa_{1-x})_5O_{15}$ 세라믹스의 Nb/Ta비에 따른 전기적 특성 변화

  • Kim, Yeong-Seop;Lee, Jun-Hyeong;Kim, Jeong-Ju;Lee, Hui-Yeong;Jo, Sang-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.08a
    • /
    • pp.39-39
    • /
    • 2003
  • 텅스텐브론즈 세라믹스의 결정구조는 산소 팔면체를 뼈대로 각각 다른 형태의 A, C, B 양이온 자리로 이루어져 있다. A, C의 양이온 자리는 알카리 이온 또는 알카리 토금속 이온으로 채워지며, B 자리는 Nb 또는 Ta 이온으로 채워지게 된다. 이 중 A와 C 자리가 채워지는 정도로 unfilled, filled, completely filled 텅스텐브론즈로 나누어지게 된다. completely filled 텅스텐브론즈의 대표적인 물질인 $K_3Li_2Nb_5O_{15}$(KLN)는 전광특성, 비선형 광학특성으로 인하여 다양한 광소자로의 응용과 압전 특성, 초전 특성을 이용한 압전 소자로의 응용이 가능한 재료로 보고되고 있다. 하지만 이러한 꽉 찬 결정구조로 인하여 KLN의 경우 한정된 고용영역을 가지고 있어 물리적 성질의 변화가 제한되어 있는데, 이를 극복하기 위한 여러 가지 시도가 있었다. 이 중 A 자리와 C 자리를 치환하는 연구는 많이 알려져 있으나 치환시 빈 자리를 수반하는 경우가 대부분이다. 반면, B 자리를 치환하는 연구는 Nb를 Ta로 치환하는 경우가 알려져 있는데 이 경우 결정내에 빈자리가 생성되지 않는다. 이들 연구는 모두 단결정의 경우에 국한되어 있으며 단결정 제조시에는 조성을 정확히 조정하기 어렵고, 냉각시 crack이 발생하는 등의 문제를 가지고 있어 그 응용이 제한되고 있다. 따라서 본 연구에서는 KLN 다결정 세라믹스에서 Nb를 Ta으로 치환하여 치환에 따른 상변화와 치밀화 거동, 그리고 이에 따른 전기적 특성을 조사하여 이들 간의 상관관계를 조사하였다.

  • PDF

Thin Micro-Porous Scaffold Layer on Metallic Substrate (금속기질에 앓은 마이크로 다공질 스케폴드 코팅에 관한 연구)

  • Sin, D.C.;Miao, X.;Kim, W.C.
    • Journal of Power System Engineering
    • /
    • v.14 no.5
    • /
    • pp.41-47
    • /
    • 2010
  • 티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.

Wear and Oxidation Charateristics of Two Phase Intermetallic Compounds (다상 금속간 화합물의 내마모 및 내산화 특성)

  • Lee, Jong-Hun;Bae, Jong-Uk;Lee, Sang-Yul
    • 연구논문집
    • /
    • s.28
    • /
    • pp.183-192
    • /
    • 1998
  • The wear and oxidation resistance of two phase nickel aluminides was investigated. Wear tests of various heat-treated specimens at room temperature and at $500^{\circ}C$ were performed under no lubricant condition in air by using a ball-on-disk type tribotester. Isothermal oxidation tests were made at $1100^{\circ}C$ in air flowing at the rate of 70cc/min and at $1000^{\circ}C$ in air by using TGA. Experimental results from wear tests showed that nickel aluminide with a higher content of Al had an improved wear resistance at both temperatures. Also the examination of the wear tracks after wear test at both room temperature and $500^{\circ}C$ indicated that regardless of the alloy compositions the wear tracks of the two phase nickel aluminides showed an abrasive type wear The improved oxidation resistance observed in the Ni-34at%Al alloy could to be attributed to the microstructural difference between the aluminides. An accelerated oxidation along the thin layer of $Ni_3AL$ along the grain boundary observed in the microstructure of the Ni-32at%Al aluminide could be attributed to the poor oxidation resistance.

  • PDF

Verification of Quantitative Evaluation Method for Ferritic Weld Metal Microstructure (철강 용착금속 미세조직의 정량화 기법 검증)

  • Kim Ka-Hee;Kim Hee-Jin;Ryoo Hoi-Soo
    • Journal of Welding and Joining
    • /
    • v.23 no.4
    • /
    • pp.27-33
    • /
    • 2005
  • Quantitative evaluation was performed on the microstructure of flux-cored arc(FCA) weld metal using a method blown as IIW scheme. It was mainly intended to figure out any practical difficulties in applying this method and also to provide the consumable makers with basic guide line in developing FCA welding consumables far better properties. Assessment of the experimental results showed IIW scheme was quite reliable in the low heat input range where the acicular ferrite was a major constituent. However, in the high heat input range, some scatter was noticed as the other phases like grain boundary ferrite and Widmansttaten ferrite become dominant. It implies that the accuracy of IIW scheme depends on the faction of microstructural constituents and it become worse as the fraction of latter two phases increases. This tendency was discussed in terms of the characteristics of those two phases. In addition, base line microstructure of rutile type FCA weld metal was addressed for developing new FCA welding consumables intended for higher heat input welding.

The Color Analysis and The Optical Absorption Properties of Yellow(x)-Blue(1-x) Color Lens (Yellow(x)-Blue(1-x) 칼라렌즈의 광흡수 특성과 color 분석)

  • Park, Sang An;Kim, Yong Geun
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.5 no.2
    • /
    • pp.201-205
    • /
    • 2000
  • The colors of a tinted lens for a mixed color could be applied to a subtractive mixture's law, and the estimation of a tinted lens used the properties of optical absorptions and the color analysis. The optical absorption properties of Yellow(x)-Blue(1-x) depended on the yellow color in short wavelength below 500 nm, the absorption in the 550~650 nm wavelength regions depended on the blue color. The absorption band in the 550~650 nm wavelength regions was a peak for an ion of transition metal. The color properties of Yellow(x)-Blue(1-x) analysing by the $L^*a^*b^*$ of CIE system shifted to toward $+a^*$ decreasing x, it was formed of a pure color because of a low saturation existing in +0.6.

  • PDF

Examination of Organizational Communication and Culture as a Moderator of the Relationship between Job Satisfaction and Organizational Performance (직무 만족과 조직 성과의 관계 탐색 : 조직 커뮤니케이션과 조직 문화의 조절 효과)

  • Lee, Gunhyuk
    • The Journal of the Korea Contents Association
    • /
    • v.13 no.4
    • /
    • pp.376-388
    • /
    • 2013
  • This study investigated the role of organizational communication, culture and trust as a moderator of the organizational performance(the growth of production and quality improvement) and job satisfaction. Using data collected from 248 workers at 128 establishments in Changwon industrial complex, morderated regression analyses explored the proposed model. As a result, communication activity and organizational trust was found negatively to moderate the relationship between job satisfaction and quality improvement/the growth of production. And organizational culture was found positively to moderate the relationship between satisfaction and quality improvement. Implications of these findings were discussed.