• Title/Summary/Keyword: 금속합금

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Improvement of Surface Properties of CP-Titanium by Thermo-Chemical Treatment (TCT) Process (열확산처리 공정에 의한 순수 타이타늄의 표면특성 향상 연구)

  • Jeong, Hyeon-Gyeong;Lee, Dong-Geun;Yaskiv, O.;Lee, Yong-Tai;Hur, Bo-Young
    • Korean Journal of Metals and Materials
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    • v.49 no.9
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    • pp.692-698
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    • 2011
  • The thermo-chemical treatment (TCT) process was applied to achieve surface hardening of CP titanium. The following three different surface modification conditions were tested so that the best surface hardening process could be selected:(a) PVD, (b) TCT+PVD, and (c) TCT+Aging+PVD. These specimens were tested and analyzed in terms of surface roughness, wear, friction coefficient, and the gradient of hardening from the surface of the matrix. The three test conditions were all beneficial to improve the surface hardness of CP titanium. Moreover, the TCT treated specimens, that is, (b) and (c), showed significantly improved surface hardness and low friction coefficients through the thickness up to $100{\mu}m$. This is due to the functionally gradient hardened surface improvement by the diffused interstitial elements. The hardened surface also showed improvement in bonding between the PVD and TCT surface, and this leads to improvement in wear resistance. However, TCT after aging treatment did not show much improvement in surface properties compared to TCT only. For the best surface hardening on CP titanium, TCT+PVD has advantages in surface durability and economics.

Effect of Precipitates on Hot Ductility Behavior of Steel Containing Ti and Nb (Ti-Nb 합금강에서 합금성분의 변화에 따른 석출물거동이 고온연성에 미치는 영향)

  • Han, Won Bae;Lee, Jong Ho;Kim, Hee-Soo;An, Hyeun Hwan;Lee, Seung Jae;Kim, Seong Woo;Seo, Seok Jong;Yoon, Chong Seung
    • Korean Journal of Metals and Materials
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    • v.50 no.4
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    • pp.285-292
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    • 2012
  • Hot ductility behavior of precipitation-hardened low-carbon iron alloys containing 0.02 wt% Ti and 0.05 wt% Nb was characterized by a hot tensile stress test. Carbon (0.05, 0.1, 0.25 wt%) and boron (0.002 wt%) contents were varied to study the effect of precipitates on the high-temperature embrittlement of the alloys in the temperature range of $600{\sim}800^{\circ}C$. Ductility loss was observed at $700^{\circ}C$ for the tested alloys. The cause of the ductility loss was mainly attributed to the carbides and ferrite films formed at the grain boundaries during deformation. Although the carbon content tended to raise the total fraction of Nb (C, N), the precipitates were formed mostly in the grain interior as the precipitation temperature was raised above the deformation temperature by the high carbon content. Hence, carbon in excess suppressed the hot ductility loss. Meanwhile, boron addition improved the hot ductility of the alloys. The improvement is likely due to the boron atoms capturing carbon atoms and thus retarding the carbide formation.

Improvement of Mechanical and Corrosion Properties of Mg-Ca-Zn Alloy by Grain Refinement (Grain Refinement를 통한 Mg-Ca-Zn합금의 기계적 특성 및 부식 특성 향상)

  • Kim, Dae-Han;Choi, Jong-Min;Lim, Hyun-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.9
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    • pp.418-424
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    • 2017
  • Magnesium has a higher specific strength than other metals and is widely used industry wide due to its excellent vibration absorption ability and electromagnetic wave shielding property.For example, it is used for automobile parts such as car seat frames and cylinder heads, and is widely used in electronic products such as notebook cases and mobile phone cases. In addition, it is in the spotlight as a bone-implant material used to assist in the treatment of damaged bones when the bones are cracked or broken. Currently, Ti alloy, stainless steel and Co-Cr-Mo alloy are used as the implant material, and the Mg alloy remains in research stage. The current problem with bone implant implants is that the patients must undergo reoperation to remove the implants after joint surgery. Magnesium, however, can achieve sufficient strength compared to current materials. In addition, since it is self-decomposed after the recovery, reoperation is not necessary. In this paper, Mg alloys were designed by adding harmless Ca and Zn to the human body. In order to improve the strength and corrosion resistance, the final alloy was designed by adding a small amount of Sr as a grain refiner. The radioactive elements of Sr are harmful to the human body, but other naturally occurring Sr elements are harmless. Microstructure analysis of the alloys was performed by optical microscopy and scanning electron microscopy. The mechanical properties and corrosion characteristics were evaluated by tensile test, potentiodynamic test and immersion test.

The Effect of a Au Based Bonding Agent Coating on Non-Precious Metals-Ceramic Bond Strength (비귀금속 합금에 적용한 Au Based Bonding Agent가 금속-도재 결합에 미치는 영향)

  • Lee, Jung-Hwan;Ahn, Jae-Seok
    • Journal of dental hygiene science
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    • v.9 no.4
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    • pp.405-412
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    • 2009
  • The purpose of this study investigated the effect of Au coating on adhesion between porcelain matrix and metal substructure interface. Titanium, Ni-Cr alloy and Co-Cr alloy are well known as proper metal for the dental restorations. The success of a porcelain fused to metal (PFM) restoration depends upon the quality of the porcelain-metal bond. However, adhesion between dental alloys and porcelain is related to diffusion of oxygen during ceramic firing. The excessive oxidized layers make hard adhesion between dental alloy and ceramic. Ni-Cr and Co-Cr specimens were divided into test and a control group and Titanium specimens were divided into three test groups and a control group. Each group had 20 specimens. The adhesion characteristics of porcelain and metal with Au coating layer and without Au coating layer were observed with scanning electron microscopy(SEM). The adhesion was evaluated by a biaxial flexure test and volume fraction of adherent porcelain was determined by SEM/EDS analysis. Result of this study suggest that Au coating layer is effective barrier to diffuse oxide layer completely protect non-precious alloys from oxidation during the porcelain firing. The SEM photomicrographs of cross-section specimens showed a smooth interface between Au coating layer and metals and porcelain which suggested proper chemical bonding, and no gap, porosity were observed. The mode of failure was mainly adhesive for Ti tested specimens, but mixed failures with adhesive and cohesive were observed in Ni-Cr and Co-Cr specimens. The adhesion between non-precious metals and porcelain would not be improved by Au coating agent. However, It is suggested that the continuous study is required further investigation and development.

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The Effect of Au Addition on the Hardening Mechanism in Ag-30wt%Pd-10wt%Cu Alloy (Ag-30wt% Pd-10wt% Cu 3원합금(元合金) 및 Au 첨가합금(添加合金)의 시효경화특성(時效硬化特性))

  • Lee, K.D.;Nam, S.Y.
    • Journal of Technologic Dentistry
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    • v.21 no.1
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    • pp.27-41
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    • 1999
  • The Ag-Pd-Cu alloys containing a small amount of Au is commonly used for dental purposes, because this alloy cheaper than Au-base alloys for clinical use. However, the most important characteristic of this alloy is age-hardenability, which is not exhibited by other Ag-base dental alloys. The specimens used were Ag-30Pd-10Cu ternary alloy and Au addition alloy. These alloys were melted and casted by induction electric furnace and centrifugal casting machine in Ar atmosphere. These specimens were solution treated for 2hr at $800^{\circ}C$ and were then quenched into iced water, and aged at 350-$550^{\circ}C$ Age-hardening characteristic of the small Au-containing Ag-Pd-Cu dental alloys were investigated by means of hardness testing, X-ray diffraction and electron microscope observations, electrical resistance, differential scanning calorimetric, energy dispersed spectra and electron probe microanalysis. Principal results are as follows ; Maximum hardening occured in two co-phases of ${\alpha}_2$ + PdCu In stage II, decomposition of the $\alpha$ solid solution to a PdCu ordered phase($L1_o$ type) and an Ag-rich ${\alpha}_2$ phase occurred and a discontinuous precipitation occurred at the grain boundary. From the electron microscope study, it was concluded that the cause of age-hardening in this alloy is the precipitation of the PdCu redered phase, which has AuCu I type face-centered tetragonal structure. Precipitation procedure was ${\alpha}{\to}{\alpha}_1+PdCu{\to}{\alpha}_2+PdCu$ at Pd/Cu = 3 Pd element of Ag-Pd-Cu alloy is more effective dental alloy on anti-corrosion and is suitable to isothermal ageing at $450^{\circ}C$.

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Development of Liquid Metal Passive Cooling Flow Simulation System (액체금속 피동냉각유동모사 실증설비의 개발)

  • Ryu, Kyung-Ha;Kim, Jae-Hyoung;Lee, Tae-Hyun;Lee, Sang-Hyuk;Bahn, Byoung-Min
    • Transactions of the KSME C: Technology and Education
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    • v.3 no.4
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    • pp.257-264
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    • 2015
  • To maintain sustainability of nuclear energy as an important energy source, both safety problem and Spent Nuclear Fuels(SNFs) problem should be solved. In case of Gen-IV reactors such as fast reactor, SNFs can be used as fuels by using fast neutrons. It can be a suitable treatment method of high-level waste in near future. Liquid metals such as Sodium or Lead-Bismuth Eutectic (LBE) can be possibly used as a coolant to use fast neutrons. In this paper, it was described that natural circulation parameter studies, design analyses, material selections and a completion of facilities. To develop a natural circulation facility, thermal hydraulic analyses were performed. Installation technique of liquid metal natural circulation were secured.

Effects of the Brazing Bonding between Al2O3 and STS304 with an Ion Beams (이온빔을 이용한 STS304와 알루미나 브레이징 접합효과)

  • Park, Il-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.12
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    • pp.8679-8683
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    • 2015
  • Using a surface modification technique, ion beam assisted deposition (IBAD) of Ti thin film it becomes possible to prepare an active ceramic surface to braze $Al_2O_3$-STS304 with conventional Ag-Cu eutectic composition filler metal. Researches on bonding formations at interfaces of ceramic joints were mainly related on the development of filler metals to ceramic, the process parameters, and clarifications of reaction products. From the results, the reactive brazing is a very convenient technique compared to the conventional Mn-Mo method. However melting point of reactive filler is still higher than that of Ag-Cu eutectic and it forms the brittle inter metallic compound. Recently several new approaches are introduced to overcome the main shortcomings of the reactive metal brazing in ceramic-metal, metal vapor vacuum arc ion source was introduced to implant the reactive element directly into the ceramics surface, and sputter deposition with sputter etching for the deposition of active material.

A Novel Process for Extracting Valuable Metals from Waste Electric and Electronic Scrap Using Waste Copper Slag by a High temperature Melting Method (폐동(廢銅)슬래그를 활용(活用)한 폐전기전자(廢電氣電子) 스크랩으로부터 유가금속(有價金屬) 고온용융추출(高溫鎔融抽出) 공정(工程) 개발(開發))

  • Kim, Byung-Su;Lee, Jae-Chun;Lee, Kwang-Ho
    • Resources Recycling
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    • v.16 no.3 s.77
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    • pp.27-33
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    • 2007
  • It is very important in the view point of resource recycling to recover valuable metals such as copper and tin from waste electric and electronic scrap. The waste electric and electronic scrap contains significant amounts of copper, tin, and so on. In this study, a new process for extracting copper and tin contained in the waste electric and electronic scrap using waste copper slag which is generated from the melting furnace of copper smelter was presented. Advantage of the proposed process is to reuse waste copper slag instead of new fluxes as slag formatives. In each experiment, the waste electric and electronic scrap and waste copper slag were melted inputting suitable amount of CaO as an additional flux. Up to 95% of copper and 85% of tin in the raw material were extracted in a Cu-Fe-Sn alloy phase.

Silver Alloying Process for Mokumegane-like Effect for Jewelry Design (장신구 디자인을 위한 모꾸메가네 효과 은 합금 공정)

  • Song Oh-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.3
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    • pp.506-511
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    • 2006
  • Silver is one of the most appropriate Jewelry materials for Jewelry casting and bench working. The technique known as 'Mokumegane' is good for making silver jewelry with natural patterns, such as wood grain patterns, but the process is not easy for silversmithing because it requires complicated and heavy labour. Instead of using conventional Mokumegane technique, we propose a new modified silver-copper casting process that enables a similar surface effect with good metal bonding strength between silver and copper. Simply pouring the molten silver into pre-aligned copper granules or 0.5 mm to 1.5 mm-thick copper sheets leads to well embedded copper silver ingots. The rolled silver plates from those ingots show excellent bonding interface even after the silver plate rolled ten times. We successfully fabricated prototype rings with copper embedded silver plates. Our result implies that our newly proposed process nay be a simpler way to fabricate silver jewelry with a pseudo-Mokumegane effect.

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A Study on RFID Tag Recognition for Metal Pipe in Fish Cultivating Industry (양식용 철제 가두리에 대한 RFID 태그 인식률 개선에 관한 연구)

  • Park, Sung-Mee;Kim, Chae-Soo
    • Journal of Korea Society of Industrial Information Systems
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    • v.17 no.7
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    • pp.209-214
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    • 2012
  • RFID(Radio Frequency IDentification) is an emerging technology which brings enormous productivity benefits in applications where objects have to be identified automatically. But despite of RFID's advantage, it is not easy to realize the RFID technology in business world. The failure to read RFID tags is the most urgent problem that should be solved for RFID application. Specially, in metal and liquid material, recognition rate of RFID tag is lower than others. Though some special tags for metal and liquid have been invented, it has not prevalent in business world on account of high price. In this paper, styrofoam pad is suggested to improve recognition rate of RFID tag for metal pipe which is used in fish cultivating industry. We makes experiment using Taguchi method and analyze the effects on styrofoam thickness, attachment location of tag, and angle of antenna.