• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.5
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• pp.1486-1494
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• 1991

본 연구에서는 분말단조 공정의 유한요소 컴퓨터 시뮬레이션을 위한 기초연구 로 다공질예비성형체의 기지(matrix)인 합금강의 변형률 속도와 온도에 따른 일축 압 축하의 열-점소성 거동을 조사하였다. 변형률 속도와 온도의 영향을 동시에 고려하 기 위하여 변형률 속도 .epsilon.=$10^{-4}$, $10^{-2}$ 및 $10^{-1S-1}$과 온도범위 800~ 1200.deg. C에 대하여 실험하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.164-164
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• 2015

Al과 Al합금은 경량금속으로 가공성과 내식성이 우수하여 철강제품의 부식방지, 고효율 반사체 등의 산업 분야에 널리 이용된다. 본 연구에서는 Al과 Al-3wt%Si, Al-10wt%Si의 Al 합금을 마그네트론 스퍼터링으로 코팅하였고 외부 자기장 변화와 빗각 증착에 따른 반사율과 조직 변화 등의 물성을 비교 분석하였다.

• Journal of the KSME
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• v.23 no.3
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• pp.186-190
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• 1983

파괴역학 연구를 대상재료에 의해 구분하면 선형파괴와 탄소성재료의 파괴로 나눌 수 있다. 취 성파괴(brittle fracture)를 다루는 선형타성 파괴역학연구는 주로 여러가지 크랙의 모양, 시편모양, 부하형태에 따른 탄성응력분포 혹은 은력확대계수를 구하거나 에너지방법에 의해 안정비안정 크랙전파를 연구한다. 대개의 경우 취성파괴는 전체 구조물에 치명적이 되기 쉽다. 따라서 구조물 설계시에 취성파괴의 가능성을 배제하기 위해 재료의 적절한 선택과 같은 대책을 강구하는 것이 바람직하다. 다시 말해, 구조물 재료는 강도와 연성의 상황에 따른 적절한 조합을 필요로 한다. 오늘날 특수합금과 같은 고강도 금속에서의 취성화 경향이 증가하나 합금설계시 강도와 아울러 연성을 증가시키기 위한 여러 대책이 파괴역학 연구의 중요한 부분을 차지한다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.160-160
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• 2012

Al과 Al합금은 경량금속으로 가공성과 내식성이 우수하여 철강제품의 부식방지, 고효율 반사체 등의 산업 분야에 널리 이용된다. 본 연구에서는 Al과 Al-3wt%Si, Al-10wt%Si의 Al 합금을 마그네트론 스퍼터링으로 코팅하였고 외부 자기장 변화와 빗각 증착에 따른 반사율과 조직 변화 등의 물성을 비교 분석하였다.

• Korean Journal of Materials Research
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• v.10 no.6
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• pp.403-408
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• 2000

The Al-Cr-Zr composite metal powders were prepared by mechanical alloying and consolidated by vacuum hot pressing. The microstructural characteristics and the thermal stability of the MA Al-Cr-Zr alloys were evaluated by means of microhardness measurement, XRD and TEM in order to develop high temperature, high strength aluminum alloys. The mechanical alloying was conducted in attritor with 300rpm for 20 hours. The density of the vacuum hot pressed Al-Cr-Zr alloy reached at 97% of theoretical one. After exposing at $300^{\circ}C$ for 100 hours, there is almost no variation in hardness change of the MA alloys. Even after exposing at $ 500^{\circ}C$ for 100 hours, the hardness of the alloy was decreased within 6% of the initial value. The fine stable $Al_3Zr\;and\; Al_{13}Cr_2$ intermetallics were formed at the stage of consolidation and heat treatment in aluminum matrix. The good thermal stability of the MA Al-Cr-Zr alloy can ab attributed to the role of the dispersoids, inhibiting grain growth of nanocrystalline, and the final grain size after heat treatment was less than 150nm.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.81-89
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• 1994

A study on Mm type electrode which is relatively high in electrode capacity and low in material cost was performed to develope high performance nickel-metal hydride battery. The electrode characteristics were investigated by P-C-T, charge-discharge and microencapsulation treatment experiments. The plateau pressure and hydrogen absorption capacity obtained from the P-C-T experiment were 0.4 atm and 310 mAh/g, respectively. The electrode capacity and stability of microencapsulated electrode were improved than those of conductor mixed electrode and the microencapsulation was possible without pretreatment. The electrode capacity of microencapsulated Mm type alloy was 240~250 mAh/g(0.2 C).

• Journal of the Korean Ceramic Society
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• v.40 no.2
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• pp.139-145
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• 2003

We studied oxidation behaviors of anti-oxidative Y-Cr oxide coated sol on ferritic steel for application of the Fe-Cr alloys as interconnectors of planar-type Solid Oxide Fuel Cells(SOFCs). In coated$YCrO_3$on the ferritic steel, the phases of $YCrO_3$,$Cr_2O_3$and $Mn_{1.5}Cr_{1.5}O_4$on the coated surface were detected, but iron base scales were not observed after oxidation at 80$0^{\circ}C$ for 40 h. The Mn-Cr oxide scales were grown with oxidation by diffusing components in the ferritic steel from inner. The Log(ASR/T) value that expresses electrical resistance of coated$YCrO_3$on the ferritic steel was -4.57~$-4.70{omega}cm^2K^{-1}$, lower in comparison with the one of the uncoated ferritic steel,$-3.99{omega}cm^2K^{-1}$. This indicates the applicability of Fe-l6Cr alloy as interconnector materials for SOFCs.

• Analytical Science and Technology
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• v.16 no.6
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• pp.431-437
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• 2003

Metalization yield of uranium oxide to uranium metal from lithium reduction process of spent pressurized water reactor (PWR) fuels was measured using thermogravimetric analyzer. A reduced metal produced in the process was divided into a solid and a powder part, and each metalization yield was measured. Metalization yield of the solid part was 90.7~95.9 wt%, and the powder being 77.8~71.5 wt% individually. Oxidation behaviour of the quartemary alloy was investigated to take data on the thermal oxidation stability necessary for the study on dry storage of the reduced metal. At $600{\sim}700^{\circ}C$, weight increments of alloy of Mo, Ru, Rh and Pd was 0.40~0.55 wt%. Phase change on the surface of the alloy was started at $750^{\circ}C$. In particular, Mo was rapidly oxidized and then the alloy lost 0.76~25.22 wt% in weight.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.552-556
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• 2007

In this study, noble metals (Pd, Ru, Ir) were supported to $TiO_2$ catalyst. In order to distribute metals uniformly, $H_2O-H_2$ pretreatment technique was used. Xylene, toluene, and MEK were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and were characterized by XRD, and XPS analysis. Pd-Ru, Pd-Ir bimetallic catalysts had multipoint active sites which improved the range of Pd metal state. Bimetallic catalysts had a higher conversion of VOCs than that of monometallic one. The effect of $H_2O-H_2$ pretreatment technique was the enhancement of uniform distribution of Pd particles and promotion of catalytic efficiency. In this study, addition of Ru and Ir metals to Pd promoted oxidation conversion of VOCs. In addition, $H_2O-H_2$ pretreatment promoted removal efficiency of VOCs on the $TiO_2$ support.

• 연구논문집
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• s.27
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• pp.201-208
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• 1997

To improve the joining characteristics of metallic converter substrate for exhaust gas cleaning, high temperature brazing process has been studied. In this study, the effect of chemical composition of brazing filler metal on the oxidation behavior of brazed joints was investigated closely. Brazing was carried out at $1200^\circC$ in vacuum furnace using nickel-based filler metals : BNi-5 powder(Ni-Cr-Si base alloy) and MBF-50 foil(Ni-Cr-Si-B). The MBF-50 containing 1-1.5 wt%B showed relatively poor oxidation resistance of the brazed joints compared to BNi-5, because of the faster invasion of oxygen through the Kirkendal voids along the interface of mother alloy/filler metal.