• Journal of the Korean Chemical Society
• /
• v.18 no.3
• /
• pp.194-201
• /
• 1974

The tetradentate schiff base ligand, N,N'-bis(salicylaldehyde)-m-phenylenediimine has been prepared from salicylaldehyde and m-phenylenediamine by Duff-reaction. The schiff base ligand has been reacted with Cu(II), Ni(II), Co(II), and Zn(II) to form new complexes; Cu(II)$[C_{20}H_{14}O_2N_2]{\cdot}2H_2O, Ni(II)[C_{20}H_{14}O_2N_2]{\cdot}2H_2O, Co(III)[C_{20}H_{14}O_2N_2]{\cdot}2H_2O and Zn(II)2[C_{20}H_{14}O_2N_2]{\cdot}4H_2O$. It seems to be that the Cu(II), Ni(II) and Co(II) complexes have hexacoordinated configuration with the schiff base and two molecules of water, while Zn(II) complex has tetracoordinated configuration with the schiff base and four molecules of water. The mole ratio of tetradentate schiff base ligand to Cu(II), Ni(II) and Co(II) are 1:1 but to Zn(II) is 1:2. These complexes have been identified by visible spectra, infrared spectra, T.G.A. and elemental analysis.

• Journal of the Korean Chemical Society
• /
• v.41 no.11
• /
• pp.581-585
• /
• 1997

The luminescence spectra of Tb(Ⅲ) complexes have been investigated as a function of molar metal-to-ligand ratio and pH. The ligands used in this study are iminodiacetate (IDA) and methyliminodiacetate (MIDA). The 549 nm emission band, most sensitive to the coordination environment among the observed bands, is monitored to reveal the optimum condition for $TbL^{3-}_3$ complex formation in aqueous state.

• Korean Chemical Engineering Research
• /
• v.43 no.1
• /
• pp.33-38
• /
• 2005

The distribution of vanadium and iron ionic species in the presence of picolinate ligand has been simulated at various conditions with different pH values and compositions in the decontamination waste solution. In spite of variations of metal concentration in the decontamination solution, the shape of distribution diagrams were not changed greatly at both high (the molar ratio of picolinate to vanadium is 6) and low (the molar ratio is 3) LOMI decontamination conditions. However, in the solution of low-picolinate condition the shape of the distribution diagram of iron(II)-picolinate complexes was changed significantly. This phenomenon is attributed to the shortage of relative amount of picolinate ligand to iron existed in the solution, and originated from the difference in stability constants for complexes formed between vanadium(III) and iron(II) species with picolinate ligand. The distribution diagrams obtained in this study can be applied very usefully to the prediction or understanding the reaction phenomena occurred at various conditions in the course of the LOMI waste treatments such as an ion exchange operation.

• Electrical & Electronic Materials
• /
• v.4 no.4
• /
• pp.330-337
• /
• 1991

y의 크기가 0.02에서부터 2.0까지의 두 차수만큼 변하게 불소가 첨가된 YBa$_{2}$Cu$_{3}$$O_{7-x}$F$_{y}$ 초전도물질을 금속질산염과 수산화나트륨 및 불화나트륨을 써서 졸-겔법으로 제조하였다. 불소함유양들을 이온-선택 전극을 사용하여 측정하였다. 반응물질로 첨가된 불소전부가 최종시료속에 존재한다는 것을 알았다. XRD 관측으로부터 y.leq.0.2인 시료들은 단지 단상 페로브스카이트 구조로 되었고 반면 y.geq.0.5인 것들은 최종시료속에 BaF$_{2}$ YF$_{3}$및 CuO와 같은 화합물들과 함께 생성되어져 있다고 결론지을 수가 있다. 더구나 고체 $^{19}$ F 핵자기공명관측이 불소가 정말로 격자위치들 속에 혼입되어 있는지 여부를 확인하기 위하여 행해졌는데 실험결과로부터 YBa$_{2}$Cu$_{3}$$O_{7-x}$ 격자위치속에 혼입된 불소의 몰비는 화합물 1몰당 약 0.2라는 것을 보여주었다. 또한 전기저항률의 측정은 개시감계온도가 y.leq.0.2와 같이, 지정된 첨가율이 적은 영역에서는 y의 증가에 따라 약간씩 증가하는 경향이 있음을 보여주고 있다.

• The Korean Journal of Ecology
• /
• v.28 no.6
• /
• pp.389-393
• /
• 2005

This study was carried out to investigate the effects of soil acidification on the growth of 3-year-old Pinus densiflora seedlings grown for 21 weeks in brown forest soils acidified with $H_2SO_4$ solution. The concentrations of Al in the acidified soils were increased with increasing amount of $H^+$ added to the soil. The total dry weight of the seedlings was reduced by the addition of the $H_2SO_4$ solution. In addition, there was a strong positive correlation (r=0.97, p<0.01) between the dry weight of the seedlings and the molar (Ca+Mg+K)/Al ratio of the soil. The seedlings with the molar (Ca+Mg+K)/Al ratio of 1.0 resulted from approximately 50% growth reduction compared with the control value. The results suggest that the molar (Ca+Mg+K)/Al ratio of the soil may be a useful indicator for assessing the critical load of acid deposition.

• Journal of Korean Society of Environmental Engineers
• /
• v.31 no.7
• /
• pp.473-482
• /
• 2009

In this study, iron and manganese coated sand (IMCS) was prepared by mixing Joomoonjin sand with solutions having different molar ratio of manganese ($Mn^{2+}$) and iron ($Fe^{3+}$). Mineral type of IMCS was analyzed by X-ray diffraction spectroscopy. Removal efficiency of arsenic through As(III) oxidation and As(V) adsorption by IMCS having different ratio of Mn/Fe was evaluated. The coated amount of total Mn and Fe on all IMCS samples was less than that on sand coated with iron-oxide alone (ICS) or manganese-oxide alone (MCS). The mineral type of the manganese oxide on MCS and iron oxides on ICS were identified as ${\gamma}-MnO_2$ and mixture of goethite and magnetite, respectively. The same mineral type was appeared on IMCS. Removed amount As(V) by IMCS was greatly affected by the content of Fe rather than by the content of Mn. Adsorption of As(V) by IMCS was little affected by the presence of monovalent and divalent electrolytes. However a greatly reduced As(V) adsorption as observed in the presence of trivalent electrolyte such as $PO_4\;^{3-}$. As(III) oxidation efficiency by MCS in the presence of NaCl or $NaNO_3$ was two times greater than that in the presence of $PO_4\;^{3-}$. Meanwhile a greater As(III) oxidation efficiency was observed by IMCS in the presence of $PO_4\;^{3-}$. This was explained by the competitive adsorption between phosphate and arsenate on the surface of IMCS.

• Journal of the Korean Chemical Society
• /
• v.37 no.7
• /
• pp.635-641
• /
• 1993

Electrochemical cell, $Pt|air(PO_2=5.3{\times}10^{-3}atm)|Zr_{0.85}Ca_{0.15}O_{1.85}|air(PO_2= 0.21atm)|Pt$, has been designed to characterize the solid electrolyte and the temperature dependence of the electromotive force (EMF) has been measured in a temperature range of 600∼1000${\circ}$C. Solid electrolyte shows pure ionic conduction of the oxygen anion. The Fe-FexO, Co-CoO, Ni-NiO, and Cu2O-CuO electrodes have been prepared by mixing the 1 : 1 mole ratio of each metal and metal oxide and then by heating at 800${\circ}$C for 6 hours. Electrochemical cells, Pt│M(s), $MO(s)|Zr_{0.85}Ca_{0.15}O_{1.85}|air(PO_2=0.21atm)|Pt$, have been designed and the temperature dependence of the EMF has also been measured in the same temperature range. The changes of the thermodynamic state functions for the formation of the metal oxides are calculated from the electromotive forces and their temperature dependences. The material properties of the oxide systems are also discussed with the function changes.

• Journal of the Korean Magnetics Society
• /
• v.19 no.6
• /
• pp.209-215
• /
• 2009

M-type barium ferrite (BaFe12O19) powders were synthesized through the co-precipitation method. Starting material composition $Fe^{3+}:\;Ba^{2+}$ mole ratio was fixed as 8 and the relative amount of $Fe^{3+}$ and $Ba^{2+}$ was controlled. Structure and magnetic properties and powder morphology were investigated using XRD, SEM, VSM. Powder showing high coercivity and small magnetization was obtained at pH8 and $Fe_{3+}:\;Ba_{2+}$ of 12 : 1.5. Small magnetization value was originated from the existence of ${\alpha}-Fe_2O_3$. Single-phase Mtype barium ferrite were obtained regardless of the heat treatment condition and the amount of $Fe_{3+}\;and\;Ba_{2+}$ at pH$\approx$10. The largest value of magnetization (55.7 emu/g) under investigation were obtained when $Fe_{3+}:\;Ba_{2+}$ of 13.6 : 1.7 and furnace cooled powder in $O_2$. Particle size of powder was in the range of 50~200 nm.

• Journal of the Korean Chemical Society
• /
• v.18 no.3
• /
• pp.189-193
• /
• 1974

The tridentate schiff base, salicylidene imino-o-thiolbenzene, has been synthetized from salicylaldehyde and o-amino thiolbenzene by Duff reaction. The schiff base has been reacted with Cu(II), Ni(II), and Zn(II), to form new complexes; Cu(II)$[C_{13}H_9ONS]{\cdot}3H_2O$, Ni(II)$[C_{13}H_9ONS]{\cdot}3H_2O,\;Zn(II)[C_{13}H_9ONS]{\cdot}3H_2O$ It appears that the Cu(II)-complex has tetra-coordinated configuration with the schiff base and one molecule of water, while the Ni(II) and Zn(II)-complexes have hexacoordinated configuration with the schiff base and three molecules of water. The mole ratio of tridentate schiff base ligand to metals was 1:1. These complexes have been identified by infrared spectra, visible spectra, TGA, DTA and elemental analysis.

• Journal of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.304-308
• /
• 1989

The spectrophotometric determination of $Lu^{3+},\;Eu^{3+}$ and some other rare earths have been investigated using Methyl Thymol Blue(MTB) as spectrophotometric reagent. Rare earth elements form a stable complex with MTB abount pH 6.5 and the ratio of its complex is 1 to 1. MTB has a absorption maxima at 440nm and rare earth MTB complex has absorption maxima 610nm at pH 6.5, respectively. The absorbance of the rare earth MTB complex is stable in 7 hours after color developing and obey the Beer law in the range of $0{\sim}110{\mu}g/50ml$. The ligand such as phosphate, citrate and EDTA decrease the absorbance of its complex considerably, and this method has a poor selectivity of each rare earth element and the molar absorptivity is $1.2{\sim}2.0{\times}10^4mol^{-1}{\cdot}l{\cdot}cm^{-1}$. In methyl alcohol, ethyl alcohol and acetone medium we did not find out any absorption change of the rare earth MTB complex.