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金刻本 "素問" 楬秘 (금각본(金刻本) "소문(素問)"에 대하여)

  • 전초진
    • Journal of Korean Medical classics
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    • v.17 no.4
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    • pp.81-88
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    • 2004
  • "황제내경 소문(黃帝內經 素問)" 24권에서 1권이 망실(亡失)되었다. 금각본(金刻本)은 지금 권3에서 권5, 권11에서 권20이 현존하고 있고 1권이 망실(亡失)되고 모두 13권으로 되어 있다. 이 책의 권3앞 페이지의 "황제내경 소문(黃帝內經 素問)" 제목밑에 "국립북평도서관수장(國立北平圖書館收藏)"이라는 도장이 찍혀 있는데, 이는 바로 1949년전에 원래 국립북평도서관(國立北平圖書館)(지금은 북경도서관(北京圖書館)으로 이름을 바꾸었음)에 수장(收藏)되어 있었음을 알 수 있다. 도서관(圖書館)에서는 이 책의 갈피에 다음과 같은 감정(勘定)문자를 적어 놓았다. "황제내경 소문(黃帝內經 素問)24권에서 l권이 망실(亡失)되고 13권이 보존되어 있는데 권3에서 권5까지, 권11에서 권18까지, 권20이다. 망실(亡失)된 편장(篇章)이 있다. 당대(唐代)의 왕빙(王冰)이 주석을 달았다. 금각본(金刻本) 5책(冊)이 있다." 왕빙(王冰)이 편차(編次)하고 주역(註譯)을 단 "소문(素問)"(즉 왕빙본(王冰本))은 모두 24권인데 그 당시에 이미 권7인 "자법론(刺法論)", "본병론(本病論)"이 망실(亡失)된 상태이다. 현존(現存)하고 있는 "소문(素問)" 금각본(金刻本)은 그 분량이 비록 왕빙본(王冰本)의 1/2정도밖에 되지 않지만 양(量)으로 판정할 수 없을 정도로 큰 가치를 가지고 있다. 이 책은 "소문(素問)" 판본학(版本學), 교감학(校勘學) 및 "소문(素問)"석음(釋音)의 연구에 있어서 모두 엄청난 가치를 지닌다. 현존(現存)하고 있는 금각본(金刻本)13권은 "소문(素問)"판본 중에서 가장 오래 된 각본(刻本)이다. 이 책은 비록 중국의서목록(中國醫書目錄)에 기재되어 있지만 중국에서 간행(刊行)된 적이 없고 의서문헌(醫書文獻)을 연구하는 사람들도 이 책에 대하여 알고 있는 사람이 드물다. 금각본(金刻本)과 "중광보주황제내경소문(重廣補注黃帝內經素問)의 가장 다른 곳은 석음(釋音)부분이다. 금각본(金刻本)은 석음(釋音)이 비교적 많고 글자 밑에 훈고(訓詁) 또한 많다. "중광보주(重廣補註)"본(本)은 석음(釋音)이 비교적 적고 글자 밑에 훈고(訓詁)가 거의 없다.

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A Study on the Leaching of Gold and Silver from Concentrate by Acidothiouration (산성치오요소법에 의한 금정광으로부터 금, 은의 침출에 관한 연구)

  • 김성규;이화영;오종기
    • Resources Recycling
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    • v.3 no.2
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    • pp.17-23
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    • 1994
  • The dissolution of gold and silver from concentrate was studied with acidic thiourea solution. The results showed that the gold and silver extraction was severely affected by concentration of thiourea and oxidant, pulp density, etc. Especially, oxidant such as ferric ions enhanced the leching rate of gold and silver. High concentration of ferric ions, however, dissolved the sulfide ore to form electrochemically passive layer on the surface of ore particles, which caused the precious metal not to be leached out from the ore. The use of $SO_2$could not effectively enhance the recovery of precious metal but reduce to some extent the consumption of thiourea. The leaching of gold and silver was achieved with recovery more than 90% and 80%, respectively, under the following conditions; Thiourea conc. :0.4M Oxidant : None $H_2SO_4$ conc. : 0.5M Pulp density : <10% Leaching time :4 Hrs Potential :250mV The Thiourea was consumed about 10% in comparison with its initial concentration.

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The Study of Surface Plasmonic Bands Using Block Copolymer Nanopatterns (블록공중합체 나노패턴을 이용한 표면 플라즈몬 연구)

  • Yoo, Seung Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.88-93
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    • 2017
  • It is important to develop a simple method oftuning localized surface plasmon resonance(LSPR) properties, due to their numerous applications. In addition, the careful examination of the shape, size and combination of metal nanoparticles is useful for understanding the relation between the LSPR properties and metal nanostructures. This article describes the dependence of theLSPR properties on the arrays of metal nanoparticles obtained from a block copolymer(BCP) micellar thin film. Firstly, two different Au nanostructures, having a dot and ring shape, were fabricated using conventional block copolymer micelle lithography. Then, Ag was plated on the Au nanostructures through the silver mirror reaction technique to obtain Au/Ag bimetallic nanostructures. During the production of these metallic nanostructures, the processing factors, such as the pre-treatment by ethanol, silver mirror reaction time and removal or not of the BCP, were varied. Once the Au nanoparticles were synthesized, Ag was properly plated on the Au, providing two distinguishable characteristic plasmonic bands at around 525nm for Au and around 420nm for Ag, as confirmed bythe UV-vis measurements. However, when a small amount of Au seed nanoparticles, which accelerate the Ag plating speed,was formed by usinga block copolymer with a relatively highmolecular weight, all of the Au surfaces were fully covered by Ag during the silver mirror reaction, showing only the characteristic peak for Ag at around 420nm. The Ag plating technique on Au nanoparticles pre-synthesized from a block copolymer is useful to study the LSPR properties carefully.

Genetic Environments of Dongwon Au-Ag-bearing Hydrothermal Vein Deposit (동원 함 금-은 열수 맥상광상의 생성환경)

  • Lee, Sunjin;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.54 no.6
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    • pp.753-765
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    • 2021
  • The Dongwon Au-Ag deposit is located within the Paleozoic Taebaeksan province, Okcheon belt. Mineral paragenesis can be divided into two stages (stage I, ore-bearing quartz veins; stage II, barren carbonate veins) by major tectonic fracturing. Stage I, at which the precipitation of major ore minerals occurred, is further divided into three substages(early, middle and late) with paragenetic time based on minor fractures and discernible mineral assemblages: early, marked by deposition of pyrite with minor magnetite, pyrrhotite and arsenopyrite; middle, characterized by introduction of electrum and base-metal sulfides with minor sulfosalts; late, marked by argentite, Cu-As (and/or Sb) and Ag-Sb sulfosalts with base-metal sulfides. Fluid inclusion data show that stage I ore mineralization was deposited between initial high temperatures (≥430℃) and later lower temperatures (≤230℃) from fluids with salinities between 6.0 to 0.4 wt. percent equiv. NaCl. The relationship of salinity and homogenization temperature suggest that ore mineralization at Dongwon was deposited mainly due to fluid boiling, cooling and dilution via influx of cooler, more dilute meteoric waters. Changes in stage I vein mineralogy reflect decreasing temperature and fugacity of sulfur by evolution of the Dongwon hydrothermal system with increasing paragenetic time. The Dongwon deposit may represents a Korean-type and/or Au-Ag type mesothermal/epithermal gold-silver deposit.

Discrete Dipole Approximation Calculation of the Extinction Spectra of Gold-Silver Alloy Nanoparticles (이산 쌍극자 근사를 이용한 금-은 합금 나노입자의 소광 스펙트럼 계산)

  • Lee, Hee-Mi;Chandra, Saha Leton;Jang, Joon-Kyung
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.136-140
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    • 2007
  • By using the discrete-dipole approximation, we computed the extinction spectrum of a gold-silver alloy nanoparticle. We have examined how the surface plasmon resonance changes with respect to the variation in the composition of the alloy particle. As the fraction of silver increases for a 10nm particle, the peak position of the extinction spectrum blue-shifts linearly. The intensity of the peak however increases exponentially with increasing the silver fraction. These results are in accord with the previous experimental results.

Leaching of Gold and Silver from Anode Slime with Inorganic Reagents (양극슬라임으로부터 무기침출제에 의한 금과 은의 침출)

  • Xing, Wei Dong;Lee, Ki Woog;Lee, Man Seung
    • Resources Recycling
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    • v.26 no.1
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    • pp.30-36
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    • 2017
  • Leaching experiments of anode slime were performed with several inorganic acids (HCl, $HNO_3$ and $H_2SO_4$) together with thiourea and thiosulfate solution to recover gold and silver. Gold was not dissolved at all into these inorganic acids in the absence of any oxidizing agents. At the same concentration of inorganic acid, the leaching of percentage of Ag was the highest in the sulfuric acid solution. The leaching percentage of silver increased with the increase of HCl concentration owing to the formation of $AgCl_2{^-}$. Copper, nickel and zinc except tin was almost dissolved in these inorganic acids but no tin was dissolved in nitric acid solution. Most of Au and Ag were dissolved into the mixture of sulfuric acid and thiourea solution. Thiosulfate could dissolve some silver from the anode slime but no gold was dissolved by this agent.

Type Classification and Material Properties by the Composition of Components in Gold Earrings Excavated from the Yeongnam Region (영남지역 출토 금제 귀걸이의 성분 조성에 따른 유형 분류와 금속 재료 특성)

  • Jeon, Ikhwan;Kang, Jungmoo;Lee, Jaesung
    • Korean Journal of Heritage: History & Science
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    • v.52 no.1
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    • pp.4-21
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    • 2019
  • In this paper, 23 Silla gold earrings from the sixth and seventhand centuries, excavated from the Yeongnam region, were analyzed. Based on the silver content of the gold plate, they were classified into three types. The classifications included type I(20-50wt%), type II(10-20wt%) and type III (less than 10wt%). In the analysis process, the composition and morphological differences were identified on the surface of the gold plate. In the case of type I and II earrings, it was observed that the fine holes were concentrated in a relatively higher part of the gold content. The causes of the difference in the surface composition of the gold plate were divided into four categories: 1) surface treatment, 2) thermal diffusivity in the manufacturing process, 3) differences in composition of alluvial gold, and 4) the refining method of gold. It is possible that depletion gilding was attempted to increase the gold content while intentionally removing the other metals from the surface of the gold alloy in the portion where the gold deposit is relatively concentrated on the surface of the gold plating. The highest copper content was detected in the earring with the highest gold content of the analyzed earrings, and it was assumed that thermal diffusion had occurred between the gold plate and the metal rod during the manufacturing process rather than intentional addition. Copper was detected only in the thin ring earring type, and copper was not detected in the thick ring earring type or pendant type. It also proves that this earring has a high degree of tightness at higher temperatures, as there was an invisible edge finish on other earrings and horizontal wrinkles on the gold plate surface. In terms of the material of the gold plate, we examined whether the silver content of the gold plate was natural gold or added by alloy through analyzing the alluvial gold collected in the region. As a result of the analysis, it was found that on average about 13wt% of silver is included. This suggests that type II is natural gold, type III is refined gold, and type I seems to have been alloyed with natural gold. Here, we investigated the refining method introduced in the ancient literature, both at home and abroad, about the possibility of alloying silver after the refining process of type III earrings and then making pure gold. It was found that from ancient refining methods, silver which had been present in the natural gold was removed by reacting and combining with silver chloride or silver sulfide, and long-term efforts and techniques were required to obtain pure gold through this method. Therefore, it was concluded that the possibility of adding a small amount of silver in order to increase strength after making pure gold through a refining process is low.

Electroplating of Precious Metal Accessory parts (귀금속 액세서리 도금기술)

  • Kim, Yu-Sang;Jeong, Gwang-Mi
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.167.1-167.1
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    • 2016
  • 금도금은 장식용 핸드백이나 가방 등에 주로 사용하고 있으며, 이러한 금을 도금하면 장식성이 최대로 되어 고객을 만족시킬 수 있다. 금도금은 초기에는 주로 외관의 장식용에 사용 되었으나, 이후 디자인과 기능성부품으로 이용이 확대되었다. 현재 국내의 금 사용량과 수요량은 매년 급증하고는 있지만 희소성, 지역편중성, 공급불안정과 이에 따른 가격불안정성과 같은 자원적 문제를 갖고 있을 뿐만 아니라 전량 수입에 의존하고 있다. 유럽, 특히 이탈리아의 금도금의 기술동향을 제공함으로써 매출증대를 향상시킬 수 있다. 이러한 금도금기술은 수출용 액세서리 등의 분야로 적용이 확대되고 있다.

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The related record about 'Daejanggeum' and its modern acceptance (대장금(大長今)' 관련 기록의 현대적 수용 - 문화콘텐츠로의 생성과 전개 양상 분석 -)

  • Nam, Eunkyung
    • (The)Study of the Eastern Classic
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    • no.43
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    • pp.33-64
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    • 2011
  • The historical drama played on TV in 2003, Daejanggeum is originally based on the short historical record of lady doctor of the palace from the [Jungjong record] of Josun. The drama mixed fiction and historic record well together draw enormous interest and became a novel, musical and animation for children. Also the location of shooting drama became a theme park to attract travelers and the name 'Daejanggeum' was used for products to create great additional value. Most of all, the drama then was exported to overseas and became the representing drama of Korea. Therefore, drama is the representing piece that proved the success of historic data with its application as various modern cultural contents. The analysis of success reason of showed the creation of new modern woman character, fresh selection of the item that suits well in the time of desiring wellbeing, the strong drama scenario with different story development compared to previous historic drama. Also, it used 'one source multi use' method prior to the broadcasting and prepared production of various cultural contents. This success of Daejanggeum means a lot from the point of 'modern acceptance of tradition' to tradition researchers.

Metallogeny on Gold-Silver in South Korea (남한(南韓)의 금(金)·은광화작용(銀鑛化作用)에 대(對)한 고찰(考察))

  • Kim, Won Jo
    • Economic and Environmental Geology
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    • v.19 no.4
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    • pp.243-264
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    • 1986
  • This work is a metallogeny on gold-silver deposits in South Korea based on the close examination of the author's own data and a broad review of existing literature available. The metallogenic epochs in Korea are temporarily connected with the history of tectonism and igneous activities, and are identified as the Precambrian, Paleozoic, Jurassic to early Cretaceous, late Cretaceous to early Tertiary, and Quaternary epochs, whereas the metallogenic provinces are spatially associated with some of the felsic to intermediate igneous rocks, lacking mineralization related to basic and ultrabasic rocks. The metallogeny on the gold-silver deposits is mostly related to the granitic rocks intrusives. Epigenetic gold-silver mineralization in South Korea ranges in metallogenic epochs from Precambrian through Triassic, Jurassic and Cretaceous to Eocene (?), in genetic types from hypothermal through mesothermal and epithermal quartz-sulfide veins to volcanogenic stockworks, with some disseminated types. Reporting on metallic association from gold without silver, gold-silver, silver-gold, silver without gold, and gold or silver as a by-product from other metallic ores. The most representative genetic types and metal associations of gold-silver deposits are hydrothermal quartz veins associated with the Daebo and Bulgugsa granitic magmatism. The most closely associated paragenetic metallic minerals in gold-silver hydrothermal quartz-sulfide vein type deposits are: copper, lead, zinc, pyrite and arsenopyrite. More than 560 gold-silver mines are plotted in the distribution map grouped within the 10 different metallogenic provinces of South Korea. Specific mineralizations with related mineral association in both sulfides and gangues observed selected from 18 Korean and 8 Japanese Au-Ag deposits. The 7 selected individual gold-silver mines representing specific mineralization types are described in this report.

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