• Title/Summary/Keyword: 근적외선 분광학

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Comparative Study of NIR-based Prediction Methods for Biomass Weight Loss Profiles

  • Cho, Hyun-Woo;Liu, J. Jay
    • Clean Technology
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    • v.18 no.1
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    • pp.31-37
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    • 2012
  • Biomass has become a major feedstock for bioenergy and other bio-based products because of its renewability and environmental benefits. Various researches have been done in the prediction of crucial characteristics of biomass, including the active utilization of spectroscopy data. Near infrared (NIR) spectroscopy has been widely used because of its attractive features: it's non-destructive and cost-effective producing fast and reliable analysis results. This work developed the multivariate statistical scheme for predicting weight loss profiles based on the utilization of NIR spectra data measured for six lignocellulosic biomass types. Wavelet analysis was used as a compression tool to suppress irrelevant noise and to select features or wavelengths that better explain NIR data. The developed scheme was demonstrated using real NIR data sets, in which different prediction models were evaluated in terms of prediction performance. In addition, the benefits of using right pretreatment of NIR spectra were also given. In our case, it turned out that compression of high-dimensional NIR spectra by wavelet and then PLS modeling yielded more reliable prediction results without handling full set of noisy data. This work showed that the developed scheme can be easily applied for rapid analysis of biomass.

Effects of Chemical Contents Variation in Covered Barley Seed on Near Infrared Reflectance Spectroscopy (겉보리 종실 성분 변이가 근적외 분광분석치에 미치는 영향)

  • 김병주;박의호;정찬식
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.3
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    • pp.354-361
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    • 1996
  • Near Infrared Reflectance Spectroscopy(NIRS) is accepted as today's most versatile method for rapid chemical analysis. The technique offers rapid multicomponent analysis. This study was conducted to improve the efficiency of quality analysis in covered barley grain, and to search for the effects of chemical components variation in covered barley grain on NIRS. Among the three groups with different range in the contents, each equation for starch contents increased standard error of prediction(SEP) and increased correlation coefficient from 0.872 to 0.883. According as, $\beta$-glucan and protein contents decreased SEP and increased correlation coefficient by expanded chemical components variation. Effective equation for ash contents analysis was obtained from group 3. Among the covered barley chemical components, starch and ash contents were required to conduct futher studies in term of accuracy and variation of contents. It was concluded that NIRS method would be applicable for the rapid determination of $\beta$-glucan and protein contents in covered barley grains.

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Analysis Methods of Visible and Near-Infrared (VNIR) Spectrum Data in Space Exploration (우주탐사에서의 가시광-근적외선 분광 자료 분석 기법)

  • Eung Seok Yi;Kyeong Ja Kim;Ik-Seon Hong;Suyeon Kim
    • Journal of Space Technology and Applications
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    • v.3 no.2
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    • pp.154-164
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    • 2023
  • In space exploration, spectroscopic observation is useful for understanding objects' composition and physical properties. There are various methods for analyzing spectral data, and there are differences depending on the object and the wavelength. This paper introduces a method for analyzing visible & nearinfrared (VNIR) spectral data, which is mainly applied in lunar exploration. The main analysis methods include false color ratio image processing, reflectance pattern analysis, integrated band depth (IBD) processing, and continuum removal as preprocessing before analysis. These spectroscopic analysis methods help to understand the mineral properties of the lunar surface in the VNIR region and can be applied to other celestial bodies such as Mars.

Structural Analysis of Petroleum Fractions by Near-Infrared and $^{13}C$-NMR Spectroscopy (근적외선과 $^{13}C$-핵자기 공명 분광학에 의한 석유유분 구조분석)

  • Choi, Ju-Hwan;Kim, Hai-Dong;Choi, Young-Sang
    • Analytical Science and Technology
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    • v.9 no.2
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    • pp.168-178
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    • 1996
  • Molecular structures of petroleum fractions(diesel fuel, bunker-C oil, lubricant base stocks) have been analyzed and compared in terms of the compositions (aromatics, naphtherucs, paraffinics), aromatics(benzene-nuclear and bonded alkyl groups), C2(methylene) carbon atoms % $C_{\alpha}$ and $C_{\beta}$ carbon stom % in alkyl groups and paraffins(branched and normal) by near-infrared and $^{13}C$-NMR spectroscopy.

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근적외선 분광분석법 (Near Infra Red Spectroscopy)의 농업 분야 적용

  • 조규채
    • Journal of Biosystems Engineering
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    • v.23 no.2
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    • pp.195-205
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    • 1998
  • 급속한 산업의 발전은 우리의 생활을 여러모로 바꾸어 왔다. 그 중에서 특히 자연에 의존하는 농업분야는 이러한 산업의 발달에 힘입어 날로 기계화 및 정보화되고 있는 실정이다. 따라서 현대사회에서는 과거와 달리 다양한 형태의 도구들이 등장하여 이것을 이용함으로써 발전 속도가 더욱 가속화되고 있는 추세이며, 그 활용 여부가 우리 모두의 중요한 경쟁력으로 자리하고 있다 농업분야에서의 도구들은 생산성 향상에 기여하는 농업관련 기계에 초점을 맞추어 왔으나, 이제는 농산물의 품질에도 상당히 중요성이 인식되어 그것을 측정 및 분석하는 다양한 방법과 도구들이 등장하고 있는 실정이다. 그 중에서도 특히 농산물의 품질을 신속하게 판별하려는 여러 가지 시도는 괄목할만한 발전을 해왔으며, 그 응용분야도 날로 확산되고 있는 추세이다. 농산물은 공산품과 달리 상당히 불균일한 산물이며, 때문에 가급적 다수의 시료를 측정하여 결과를 사용하지 않으면 신뢰도가 떨어져 측정 가치를 잃게 된다. 그래서 시료를 파괴하지 않고 짧은 시간 내에 전수검사를 수행할 수 있는 분석 및 측정방법을 연구 발전시켜 왔다. 이 중에서 빛을 이용하여 분석을 행하는 분광학(Spectroscopy) 중에서 근적외선(Near Infra Red)을 이용한 형태에 대해 알아보기로 한다.(중략)

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Relationship between Near Infrared Reflectance Spectra and Mechanical Sensory Score of Commercial Brand Rice Produced in Jeonbuk (전북산 브랜드 쌀의 근적외선 분광스펙트럼과 기계적 식미치간의 상호관계)

  • Song, Young-Ju;Song, Young-Eun;Oh, Nam-Ki;Choi, Yeong-Geun;Cho, Kyu-Cha
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.spc1
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    • pp.42-46
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    • 2006
  • The purpose of this study was to assess whether mechanical sensory score by Toyo Midometer can be substituted by near-infrared spectroscopy (NIRS) method in whole-grain milled rice samples. Toyo values of collected commercial brand rice (n=127) had comparatively wide ranges from 62.9 to 84.2 (Mean=70.5; S.D.=4.0). Calibration equation was developed using 73 samples. Standard error of calibration (SEC) for sensory score equation and $R^2$ were 0.95, and 0.94, respectively, however, percentage of variation in the reference method values (1-VR) which give a true indication of equation performance was slightly lower (1-VR=0.81) than calibration equation. It was demonstrated that, even though NIRS has potential as a rapid tools to predict rice sensory score, the prediction of sensory score in rice by NIRS needs to be further investigation on a large number of sample with different varieties and growing locations.

Cure Kinetics for the Acid Anhydride-cured Epoxy System Using a Near-infrared Reflection Spectroscopy (근적외선 분광분석을 통한 산무수물경화 에폭시 시스템의 경화 동력학)

  • 곽근호;박수진;이재락
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.65-71
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    • 2000
  • The latent properties and cure kinetics of an acid anhydride-cured epoxy resin have been investigated by a near-infrared (NIR) reflection spectroscopy. The assignments of the latent properties and cure behaviors were performed by the measurements of the NIR reflectance for epoxide and hydroxyl groups at different temperatures. A comprehensive analysis of the origin, location, and shifts during reaction of all major NIR absorption peaks in the spectral range from 4000 to 7100 $cm^{-1}$ / was provided. The extent of reaction was determined from NIR absorption band at the 4530 $cm^{-1}$ / depending on epoxide concentration and cure temperature.

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Non-destructive Analysis of Compost by Near Infrared Spectroscopy (근적외선 분광법을 이용한 퇴비의 비파괴 분석)

  • Nam, Jae Jak;Lee, Sang Hak
    • Journal of the Korean Chemical Society
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    • v.44 no.5
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    • pp.410-414
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    • 2000
  • The feasibility of near infrared spectroscopy (NIRS) for the evaluation of the compost pro-duced by composting swine excreta has been investigated. The analytes determined were total nitrogen, total phosphorus, organic matter,total carbon,moisture, Cu, $K_2O$ and $Na_2O$. The ranges of concentration of the cal-ibration samples obtained by the conventional chemical method for each component were 1.30-2.75%, 1.45-4.86%, 7.36-81.5%, 23.0-41.1%, 4.2 the coefficient of variation was 4.38, 5.5, 3.2, 1.5, 10.9, 10.6 and 11.9% for total nitrogen, total phosphorus, organic matter, total carbon, moisture, Cu, $K_2O$ and $Na_2O$,respectively. The overall results showed that NlRS can be used for a non-destructive and rapid determination of the analytes to evaluate the quality of compost samples.

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