• Title/Summary/Keyword: 그라이트

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Characteristics of Sedimented Sandy in Nackdong River Delta (낙동강 델타지역 퇴적사질토의 특성)

  • Kim, Byeong-Jun;Kim, Jae-Hong;Jung, Jin-Yeong;Kwon, Jeong-Keun;Kim, Tae-Hyung
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.2
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    • pp.25-33
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    • 2016
  • This study was a basic research to obtain the knowledge of physical properties of the upper sedimented sandy soil in the Nakdong river delta area. The characteristics of shear strength and permeability with fine content and relative density were also investigated. The upper sedimented sandy soil near paddy and lower soft clay layers showed high percentage of fine content, and the rest parts had about 5% of fine content. The specific gravity regardless of depth and location was almost constant. The upper sedimented sandy soil mostly had particle size about 0.1 ~ 0.4mm regardless of sedimentation environment and has illite, a clay mineral, in the entire soil samples. The results of direct shear tests on remolded specimens of the upper sedimented sandy soil revealed that the friction angle and cohesion increased with relative density, but its effect was not significant. The fine content was significant, that as increasing it, the friction angle decreased and cohesion increased linearly. The permeability decreased with relative density and fine content, and the permeability of soil containing more than 15% of fine content was independent on the relative density.

Clay Mineralogy and Geochemistry of a Sediment Core from the Seamount to the South of Antarctic Polar Front, Drake Passage (남극 드레이크해협 극전선 남부 해산 퇴적물 코어의 점토광물 및 지구화학적 특성)

  • Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.3 s.49
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    • pp.163-169
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    • 2006
  • Mineralogy and geochemistry of the sediment core from the seamount (2710 m below the sea level) just south of the Antarctic Polar Front were examined to draw paleoceanographic information in glacial-interglacial cycles. Smectite was most abundant clay mineral associated with illite and chlorite. Its content was slightly higher below 170 cm, suggesting a boundary between isotope stage 4 and 5. Si, Zr, Cs, Th, REE, $K_{2}O$, and $Al_{2}O_{3}$ show complete antithetical distribution with respect to $CaCO_{3}$ through the core. $SiO_{2}$ maxima and $CaCO_{3}$ minima at depths of 24, 136, and 176 cm are probably correlated with massive influx of ice-rafted debris during the advance of Antarctic ice shelves. Ni, Cu, and Ba show rather little correlation with $SiO_{2}$, suggesting their relation to biogenic debris, precipitation from seawater, or hydrothermal input. Particularly, Ba maxima tend to lag $10{\sim}20cm$ after $SiO_{2}$ maxima, probably due to rapid increase of productivity following deglaciation.

Presence of Leucocratic Granites of the Taebaegsan Region and Its Vicinities (태백산지역과 인근에 분포하는 우백질 화강암체의 존재)

  • Yoo, Jang Han;Koh, Sang Mo;Moon, Dong Hyeok
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.263-272
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    • 2013
  • The Taebaegsan region and its vicinities mainly consist of Precambrian granitic gneisses and Cambrian meta-sedimentary rocks. And lots of leucocratic(alkali) granites smaller than the stocks are found here and there. Therefore the presence of leuco-granites is not properly described yet in the former studies. For the effective distinction of several granitic rocks, outcrop characteristics, mineral identification, and petro-chemical properties were studied. Some part of granitc gneisses could be classified into typical metamorphic rocks such as migmatites and banded gneisses. And some shows rather dark appearance with gray quartz and feldspars, and others two mica granites, leucocratic ones etc. But all of leucocratic granites of the region usually show bright milky white to beige color. Since they mainly consist of quartz, feldspars, muscovite, and small amounts of sericites, amphiboles, tourmaline and lepidolite. And all of alkali granites belong to the calc-alkalic, peraluminous and S-type in character. During magmatic differentiation of leucocratic granites, CaO and total Fe contents are clearly decreased than those of the older granitic rocks. On the other hand, magmatic evolution also had induced the greisenization and albitization which enriched the relative amounts of alkali elements such as $K_2O$ and $Na_2O$.

Effects of Heat-Treatments on Transformation Behavior of Matrix Structures in High Alloyed White Cast Iron (고합급백주철에 있어서 열처리가 기지조직의 변태에 미치는 영향)

  • Shin, Sang-Woo;Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.409-414
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    • 2000
  • Three different white cast irons alloyed with Cr, V, Mo and W were prepared in order to study their transformation behavior of matrix structures in heat-treated conditions. The specimens were produced using a 15kg-capacity high frequency induction furnace. Melts were super-heated to $1600^{\circ}C$, and poured at $1550^{\circ}C$ into Y-block pepset molds. Three combinations of the alloying elements were selected so as to obtain the different types of carbides and matrix structures : 3%C-10%Cr-5%Mo-5%W(alloy No. 1), 3%C-10%V-5%Mo-5%W(alloy No. 2) and 3%C-17%Cr-3%V(alloy No. 3). The heat-treatments were conducted as follows: frist of all, as-cast specimens were homogenized at $950^{\circ}C$ for 5h under the vacuum atmosphere. Then, they were austenitized at $1050^{\circ}C$ for 2h and followed by air-hardening in air. The air-hardened specimens were tempered at $300^{\circ}C$ for 3h. The observation of morphology of the matrix structures was carried out in the states of as-cast(AS), air-hardened(AHF) and tempered(AHFT). The matrix structures of each alloy were almost fully pearlitic in the as-cast state but it was transformed to martensite, tempered martensite and retained austenite by the heat-treatments such as air-hardening and tempering.

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Experimental Study on the Mitigation of Harmful Algal Blooms by Mono-Minerals (환경친화성 단일 광물질에 의한 적조구제 실험)

  • 장영남;채수천;배인국;박맹언;김필근;김선옥
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.557-561
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    • 2003
  • It is important to find out a new material having high removal efficiency for the harmful algal blooms because the dispersion of Hwangto in a large amount to the sea water may bring some ecologically unfavorable problems. For this purpose, the efficiency of several natural and synthetic mineral species for the mitigation of algal blooms was measured. The mixing ratio of monominerals and the sea water with 3,000∼5,000 cells/$m\ell$ of Cochlodinium polykrikoides was 10 g/${\ell}$ and the removal ratio was measured by counting the living cells after the dispersion time of 10, 30 and 60 min., respectively. According to the experimental results, the removal ratio by illite, kaolinite, montmonmorillonite, red mud, Na-A type of zeolite ranged 84-92% after 1hr of contact time, which is comparable to that of Hwangto. The size of above monominerals ranged 3∼50${\mu}m$. Meanwhile, the amorphose material and hematite with the size of 50∼100 nm showed excellent removal ratio of more than 99% after 30min. of dispersion. The results of the study showed that the removal ratio was not related to the chemical composition and pH of the minerals applied but to the grain size. The experimental results strongly suggest that the main mitigation mechanism would be the contact and coagulation.

Improvement of Insulation System for LNG Storage Tank Base Slab (LNG 저장탱크 바닥판 단열 시스템 개선)

  • Lee, Yong-Jin;Lho, Byeong-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.4
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    • pp.141-147
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    • 2010
  • Liquefied natural gas(LNG) is natural gas that has been converted temporarily to liquid form for ease of storage and transport it. Natural gas is the worlds cleanest burning fossil fuel and it has emerged as the environmentally preferred fuel of choice. In Korea, the demand of this has been increased since the first import from the Indonesia in 1986. LNG takes up about 1/600th the volume of natural gas in the gaseous state by cooling it to approximately $-162^{\circ}C(-260^{\circ}F)$. The reduction in volume therefore makes it much more cost efficient to transport and store it. Modern LNG storage tanks are typically the full containment type, which is a double-wall construction with reinforced concrete outer wall and a high-nickel steel inner tank, with extremely efficient insulation between the walls. The insulation will be installed to LNG outer tank for the isolation of cryogenic temperature. The insulation will be installed in the base slab, wall and at the roof. According to the insulation's arrangement, the different aspects of temperature transmission is shown around the outer tank. As the result of the thermal & stress analysis, by the installing cellular glass underneath the perlite concrete, the temperature difference is greatly reduced between the ambient temperature and inside of concrete wall, also reducing section force according to temperature load.

Adsorption Properties of U, Th, Ce and Eu by Myogi Bentonite Occurring in Japan (일본 묘기광산 벤토나이트의 물리화학적 성질 및 U, Th, Ce 및 Eu 흡착특성)

  • Song Min-Sub;Koh Sang-Mo;Kim Won-Sa
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.183-194
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    • 2005
  • The mineralogical, physicochemical and thermal properties of the Myogi bentonite occurring in Japan were measured. A adsorption properties of U, Th, Ce and Eu ions on the Myogi bentonite were also investigated in different solution concentrations and pH conditions. The Myogi bentonite showed a strong alkaline character (pH 10.4), very high swelling, viscosity property and CEC, and a slow flocculation behavior due to the strong hydrophilic property. By the thermal analysis, the dehydroxylation of crystal water in bulk and clay fractions of the Myogi bentonite occur at $591^{\circ}C$ and $658^{\circ}C$, respectively, The adsorption experiments of ions such as U, Th, Ce and Eu were conducted for 0.2 g bentonites with 20mL solutions of various concentrations and different pH conditions with pH 3, 5, 7, 9, and 11. As a result, the Myogi bentonite showed excellent adsorption capacities for Ce, Th and Eu ions, whereas U ion showed very low adsorption capacity. Generally, Ce, Th and Eu ions showed the similar adsorption properties for the different concentrated solutions and pH conditions. These adsorption properties seem to be affected by the formation of various forms of chemical species and precipitation as well as ionic exchange reaction and surface adsorptions on smectite. Some associated zeolite minerals perhaps have some effects on the adsorption of U, Th, Ce and Eu on Myogi bentonite.

Effect of Pinching Time and Plant Growth Retardants on Growth Control of Ardisia pusilla in an Ebb and Flow System (Ebb and Flow 시스템에서 적심시기와 생장조절제 처리에 의한 산호수의 생장조절)

  • Won, Eun-Jeong;Park, Ji-Eun;Park, Yoo-Gyeong;Jeong, Byoung-Ryong
    • Journal of Bio-Environment Control
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    • v.20 no.4
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    • pp.333-340
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    • 2011
  • This study was conducted on the effect of plant growth retardants (PGRs) on growth of potted Ardisia pusilla and Ardisia pusilla var. variegata grown for a short term in an ebb and flow system. Plants were planted in 10 cm plastic pots, containing a mixture of peat moss and perlite (1 : 1, v/v) on 30 June 2005 and were grown until 23 Sep. 2005. The PGRs used were 50, 200, 350, 500 $mg{\cdot}L^{-1}$ daminozide (B- 9), 10, 40, 70, 100 $mg{\cdot}L^{-1}$ paclobutrazol (Boundy), and 5, 15, 25, 35 $mg{\cdot}L^{-1}$ ethephon (Florel). On every irrigation, the nutrient solution containing PGRs was supplied at a 2 cm depth and was kept for 15~20 minutes. The surplus nutrient solution was drained back into the tank for next irrigations. In both cultivars, paclobutrazol gave the most pronounced effect in inhibition of stretchiness. Ardisia pusilla, which was pinched just before initiation of paclobutrazol treatment, resulted in the greatest inhibition of shoot elongation. Daminozide treatments above 200 $mg{\cdot}L^{-1}$ also gave reduction of shoot length. However, ethephon treatments gave no dwarfing effect in Ardisia pusilla. Inhibition of stretchiness was observed even in the lowest concentration treatments. Among the PGRs, paclobutrazol was the most effective in suppressing plant stretchiness.

Petrology and Geochemistry of Peridotite Xenoliths from Miocene Alkaline Basalt Near the Mt. Baekdu Area (백두산 지역의 마이오세 알칼리 현무암에 포획된 페리도타이트의 암석학적/지화학적 특성)

  • Kim, Eunju;Park, Geunyeong;Kim, Sunwoong;Kil, Youngwoo;Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.311-325
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    • 2017
  • Peridotite xenoliths in middle Miocene alkaline basalt from the Mt. Baekdu area are mainly anhydrous spinel lherzolites, displaying coarse-grained protogranular texture. These xenoliths have late-stage secondary orthopyroxene replacing olivine as the metasomatic mineral and glass formed along the grain boundaries. The studied xenoliths are characterized by the high $Mg{\sharp}[=100{\times}Mg/(Mg+Fe_{total})$ atomic ratio] of olivine, orthopyroxene and clinopyroxene (89~92) and the $Cr{\sharp}[=100{\times}Cr/(Cr+Al)$ atomic ratio] of spinel (10~29). Based on major-element data, the studied xenoliths are similar to those from the abyssal peridotites. Clinopyroxenes of the xenoliths are mostly enriched in incompatible trace elements, exhibiting two types of REE patterns: (1) LREE-depleted with $(La/Yb)_N$ of 0.1~0.2 and $(La/Ce)_N$ of 0.4~0.8. (2) LREE enriched with $(La/Yb)_N$ of 2.2~3.8 and $(La/Ce)_N$ of 1.2~1.6. The calculated equilibrium temperatures and oxygen fugacities resulted in $920{\sim}1050^{\circ}C$ and ${\Delta}fO_2(QFM)=-0.8{\sim}0.2$, respectively. It is suggested that the Mt. Baekdu peridotite xenoliths represent residues left after variable degrees of melt extraction(less than 15 vol%), which was subsequently subjected to different degrees of modal/cryptic metasomatism by silica- and LREE-enriched fluids (or melts).

C2H5OH-CH2OHCH2OH-Ca(OH)2-CO2계에서의 비정질탄산칼슘의 결정화 연구

  • Kim, Hwan;Ahn, Ji-Whan
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.3-27
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    • 1996
  • 분체의 입자 배열이 불규칙한 경우뿐만 아니라 입자 크기가 극미세하여 X선회절분석이 불가능한 경우에도 비정질물질이라 한다. 수용액 속에서 이런 비정질 물질을 합성하기 위해서는 합성용액의 과포화도를 높여 계속 유지시킴에 따라 극미세 1차핵 생성의 지속적인 유도에 따른 입자 성장을 최대한 억제시켜야만 한다. 본 연구에서는 흡습제, 칼슘제 및 식품 첨가제 등으로 이용되는 비정질 탄산칼슘을 계에서 합성하고, 이때 생성된 비정질 상태의 겔을 수용액 환경을 변화시켜가면서 따라 결정화를 유도하고 탄산칼슘의 동질이상을 관찰하였다. CO2의 유속을 11/min, 교반속도를 600rpm으로 고정시키고, Ca(OH)2의 양을 10g에서 50g까지 변화시켜가면서 겔 상태의 비정질 탄산칼슘을 합성하였다. 이때 전기전도도는 CO2의 용해와 더불어 Ca(OH)2의 용해도가 증가함에 따라 변화하였으며, 반응종반부에는 겔화가 시작될 때까지 거의 일정하였다. 따라서, 이러한 사실들로부터 현탁액 내에서의 전기전도도의 변화는 Ca이온의 영향을 받는 것으로 사료된다. 비정질 탄산칼슘은 수용액에서 불안정하여 CO2 가스를 방출하면서 급격히 결정화되는데, 본 연구에서는 Ca(OH)2의 양을 20g으로 하여 위의 방법에 의해 얻어진 겔을 수용액의 종류와 농도 및 결정화 온도, 교반속도를 달리하면서 결정화시켰다. 교반속도를 100rpm으로 하여 물의 온도변화에 다라 결정화시킨 경우 전 온도범위에서 칼사이트상이었으며, 물의 온도가 5$^{\circ}C$일 경우에는 미세한 입자들이 응집된 형태였으나, 그 외의 온도변화조건에서는 모두 평균입경 0.4$\mu\textrm{m}$정도의 비교적 균일하 능면체 형태였다. 또한 교반속도를 500rpm으로 증가시켰을 경우에는 8$0^{\circ}C$에서 침상의 아라코나이트가 소량생성되었음을 SEM사진으로 관찰할 수 있었으며, 소량의 바테라이트도 혼재되어 결정화되었음을 XRD결과로 알 수 있었다. 교반속도를 100rpm으로 한 NH4Cl 0.5mol/l 수용액에서는 입자의 형태와 크기가 불규칙한 칼사이트로 결정화되었으며, MgCl2 0.05mol/l 수용액의 경우에는 순수한 H2O의 경우에서와는 달리 2$0^{\circ}C$에서는 모서리가 무딘 매우 균일한 크기의 칼사이트 입자가 관찰되었으며, 6$0^{\circ}C$부터는 아라고나이트가 생성됨을 관찰할 수 있었다. 따라서, 고온(8$0^{\circ}C$)의 농도 MgCl2 수용액(0.1, 0.2 mol/l)에서 교반속도를 높여(800rpm) 겔을 결정화시킨 결과 아라고나이트의 생성수율이 증가되는 것을 확인할 수 있었다.

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