• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.84-91
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• 2020

The efficiency of the synthetic magnesium silicate used in basic polyols and edible oil purification is evaluated by its purification ability and filtration rate and is affected by the particle size and surface area of magnesium silicate. In this study, it was investigated the change on the particle size of magnesium silicate was influenced by the reaction temperature, injection rate, injection order (Si, Mg) and Mg/Si reaction mole ratio. The synthesized magnesium silicate was compared and analyzed for the synthesis, grinding, and refining processes. In the synthesis process, the reaction temperature and feed rate did not affect the average particle size change of magnesium silicate, while the reaction molar ratio of Mg / Si and the order of injection acted as main factors for the change of average particle size. The average particle size of magnesium silicate increased by 8.7 ㎛ from 54.4 ㎛ to 63.1 ㎛ at Mg injection when Mg molar ratio increased from 0.125 to 0.500, and increased by about 4.8 ㎛ from 47.3 ㎛ to 52.1 ㎛ at Si injection. The average particle size according to the order of injection was 59.1 ㎛ for Mg injection and 48.4 ㎛ for Si injection and the difference was shown 10.7 ㎛, therefore the filtration rate was about 2 times faster under the condition of Mg injection. That is, as the particle size increases, the filtration time is shortened and washing filtration rate can be increased to improve the productivity of magnesium silicate. The cake form of separated magnesium silicate after filtration becomes a solid through drying process and is used as powdery adsorbent through the grinding process. As the physical strength of the dried magnesium silicate increased, the average particle size of the powder increased and it was confirmed that this strength was affected by the reaction molar ratio. As the reaction molar ratio of Mg / Si increased, the physical strength of magnesium silicate decreased and the average particle size after grinding decreased by about 40% compared to the average particle size after synthesis. This reduction of strength resulted in an improvement of the refining ability due to the decrease of the average particle size and the increase of the amount of fine particle after the pulverization, but it resulted in the decrease of the purification filtration rate. While the molar ratio of Mg/Si was increased from 0.125 to 0.5 at Mg injection, the refining ability increased about 1.3 times, but the purification filtration rate decreased about 1.5 times. Therefore, in order to improve the productivity of magnesium silicate, the reaction molar ratio of Mg / Si should be increased, but in order to increase the purification filtration rate of the polyol, the reaction molar ratio should be decreased. In the synthesis parameters of magnesium silicate, the order of injection and the reaction molar ratio of Mg / Si are important factors affecting the changes in average particle size after synthesis and the changes of particle size after grinding due to the changes of compressive strength, therefore the synthetic parameter is an important thing that determines productivity and refining capacity.

• The Korean Journal of Pesticide Science
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• v.4 no.2
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• pp.37-43
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• 2000

Effects of silicon application on development of colonies of Sphaerotheca fuliginea were examined. Cucumber plants were applied with nutrient solutions amended with different concentrations of soluble silicon and selected leaves were inoculated with known concentrations of conidia of the pathogen. Colony number per leaf, colony area per leaf, and germination rate of conidia of S. fuliginea collected from the inoculated leaves were reduced as silicate concentrations in the nutrient solutions increased from 0.05 to 4.10 mM. The increase in resistance of plants to mildew infection was apparently due to silicate accumulation in leaves, and there was no correlation between cation or ionic strength effects and the silicate treatments. Silicate treatment in growth medium remarkably suppressed powdery mildew development on cucumber. Colonies of mildew fungus were visible with over approx. 38.3% of the mature leaf surface, while that of the leaves in high Si plants was 2.3% observed at 51 days after transplanting. No significant differences were observed between 1.7 mM and 3.4mM silicate treatments. Conidial germination rates were significantly reduced by increasing Si amendments. Conidial germination ranged from 14.7 to 20.3% for plants grown in low Si solution(<1.40 mM), and from 9.0 to 12.4% for plants grown in high Si solution(>1.8 mM). Foliar applications of Si with ${\geq}$ 17.0 mM decreased the number of powdery mildew colonies. Persistence of Si foliar sprays effects on cucumber demonstrated that the 17 mM Si spray applied 4 days before inoculation with S. fuliginea reduced mildew colony formation. The relationship was positive and linear.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.31 no.3
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• pp.326-335
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• 1986

In cold water irrigation, some growth and yield were decreased by heavy application of nitrogen but in-creased by heavy application of phosphate, potassium and silicate. Among growth characters, number of spikelets per panicle and grain filling ratio were affected significantly. Cold damage in number of spikelets, spikelet sterility and degeneration of spikelet and branch could be reduced by increasing application amount of phosphate, potassium and in particular silicate. Number of spikelets per branch was closely related with number of spikelets per secondary branches. Number of abortive grains and immature grains had negative correlations with yield and could be reduced by heavy application of phosphate, potassium and silicate. Heavy nitrogen application led to high total nitrogen content and restrained the uptake of phosphate, potassium and silicate. However, adverse results were showed by heavy application of phosphate, potassium and silicate. Inorganic element contents in branches were lower than those in leaf blades, but higher than those in chaff. Branches showed little differences in inorganic element contents between heading stage and maturing stage. Inorganic element contents in branches were considered to be influenced by those in leaf blades and to affect those in chaff. Some growth characters related to source and sink, such as degeneration of branches and spike-lets, sterility ratio, ripening ratio, and yield had closer relationship with nutrient contents in branches than those in leaf blades and chaff. The results demonstrated that the rachis branch not only was a transport pathway of nutrient but also would play an important role in accumulating substances in panicles.

• Economic and Environmental Geology
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• v.39 no.5 s.180
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• pp.597-605
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• 2006

In this study, we examined the applicability of 3-D electrical resistivity survey to detect underground cavities within ground subsidence area at the field test site, located at Yongweol-ri, Muan-gun in Korea. Underground cavities are widely present within the limesilicate bedrock overlain by the alluvial deposits in the area of the test site where the ground subsidences have occurred in the past. The limesilicate cavities are mostly filled with groundwater and clays in the test site. Thus, cavities have low electrical resistivity compared to the surrounding host bedrock. The results of the study have shown that the zones of low resistivity correspond to the zones of the cavities identified in the boreholes at the test site, and that the 3-D electrical resistivity survey is very effective to detect underground cavities.

• Applied Biological Chemistry
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• v.14 no.3
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• pp.183-189
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• 1971

The studies reported herein were conducted to inquire the effect of fused siliceous materials which mixed with sand and quartz added calcium fertilzer on rice grown on low available silica content soil. The applied nitrogen level were examined for the two plots, nitrogen 10kg and 20kg per 10 a., and the siliceous materials(Wollastonite, Fused sand and Fused quartz) were applied as levels to 100kg, 300kg and 500kg per 10a. in the pots. The results are summerized as follows; 1. The available silica content solved in N/2 HCl solution of fused sand was more than of fused quartz but the silica solubility in 2% citric acid of fused quartz were higher than other. 2. The absorbed silica content by plant grown on the fused quartz plot was the highest among other siliceous materials and of fused sand and natural wollastonite were at almost equal. The ratio of absorbed silica of natural wollastonite was highest among them and in fused materials, the quartz was higher than sand. 3. The productivity of rice was increased by percentage of filled grain, weights of 1000 grains, and number of spikelets on account of the large quantity of the silica absorbed by plant Especially fused quartz showed the highest productive effect among siliceous materials and natural wollastonite and fused sand were similar effect. 4. From the above results. the fused quartz was selected as expelled siliceous fertilizer on rice plant among them and the fused sand was equal effect to natural wollastonite.

• Korean Journal of Food Science and Technology
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• v.47 no.2
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• pp.145-148
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• 2015

According to the Korea Food Additives Code, sodium metasilicate is permitted for use as a filtering agent for edible oils and fats. Sodium metasilicate is currently used as a food additives to increase the weight of shark fins. In this study, we developed an analytical method to quantify sodium metasilicate in food. Sodium metasilicate content was estimated by measuring the moisture content, pH and silicon content of shark fins. Silicon content was analyzed using inductively coupled plasma-optical emission spectrometry (ICP-OES) following microwave-assisted digestion with $HNO_3$ (65%) and $H_2O_2$ (30%). Shark fin total silicon content was $7.17{\pm}8.92mg/kg$, while the soluble silicon content was $2.34{\pm}3.80mg/kg$. After soaking raw shark fin in an aqueous solution of sodium metasilicate, fin weight, pH and silicon content were measured. These results would be used as the basic information for shark fins safety management.

• Korean Journal of Environmental Agriculture
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• v.22 no.4
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• pp.255-260
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• 2003

Silicon is known to accumulate in plants and results in greater resistance to diseases and insect pests. In this study, we investigated the effect of silicate fertilizer applied in soil on the development of powdery mildew of oriental melon. Oriental melon seedlings of four-leaf stage were transplanted and grown in a plastic film house. Silicate fertilizer was applied to maintain soil available $SiO_2$ level of 200 mg/kg one week before transplanting. Fungicide triflumizol was sprayed three times; one, two, and three weeks after transplanting. Sphaerotheca fuliginea was inoculated 2 weeks after transplanting. The number of infected leaf and the number of fungal colony in leaves were measured one, two, and three weeks after the inoculation. Three weeks after the fungal inoculation, in the treatment of fungicide triflumizol. infected leaf numbers and number of colony per leaf were reduced by 10 and 58%, respectively. In the silicate fertilizer treatment, infected leaf numbers and numbers of colony per infected leaf were suppressed only by 6 and 16%, respectively, and the efficacy was lower than that of the fungicide triflumizol. The combined treatment of silicate fertilizer and the fungicide suppressed powdery mildew more effectively, and infected leaf numbers and numbers of colony per leaf were reduced by 31 and 80%, respectively. These results indicate that although silicate fertilizer itself is not much effective in the suppression of powdery mildew, it can significantly enhance the efficacy of the fungicide.

• Korean Journal of Soil Science and Fertilizer
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• v.18 no.4
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• pp.319-324
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• 1985

This study was designed to evaluate the feasibility of direct application of quenched slag, as a silicate fertilizer byproduct of iron and steel industry. A field experiment was conducted on a low silica content paddy soil and its effect was compared to over corresponding air-cooled slag of milled commercial silicate fertilizer on rice plant growth and yields. The yields of rice were slightly higher in the commercial air-cooled slag than in the quenched slag, however, there was no significant statistical difference. The silica content of rice plants at harvest was higher in commercial silicate fertilizer than that of quenched slag. The available soil silica was high in quenched slag at the early growing stage, however, at harvest higher in air-cooled slag, which meant that the quenched slag might release silica quickly in soil. This results indicated that the slag could be considered resource as a silicate fertilizer.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.3
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• pp.175-181
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• 2000

This study was carried out to investigate the change of soil physical properties in long-term fertilized paddy soils with a Fine silty family of Typic Halpaqueps (Pyeongtaeg series). Treatments fertilized consisted of no fertilizer, compost, NPK, NPK+compost for thirty one years and of NPK+silicate for seventeen years. Water stable aggregate and degree of aggregate stability, which were higher in surface-soil than sub-soil, were high in order of NPK + compost > NPK + silicate > compost > NPK > no fertilizer plot. The ratio of aggregate larger than 0.5mm was high at compost and silicate plots but that smaller than 0.5mm was high at no fertilizer and NPK plots. And this aggregate stability showed negative correlation with soil hardness and bulk density ; positive correlation with sedimentation volume of soils in water. Sedimentation volume of soils in water was a little higher in surface-soil than sub-soil and in wet soil than dry soil, respectively. Pore space ratio and water retention capacity of soils were the most increased by the application of compost and not affected by silicate as in cases of liquid limit and plastic limit. Ignition loss of soils was high in order of NPK + compost > compost > NPK + silicate > NPK > no fertilizer plot. And field shattering ratio of soil mass smaller than 25.4mm was relatively high in NPK + compost, compost, and silicate plots.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.51 no.5
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• pp.408-419
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• 2006

A pot experiment was conducted for two years to evaluate the effects of purified Si fertilization combined with $^{15}N$ on the nutrient uptake, plant growth characteristics, and photosynthetic characteristics of rice in water melon cultivated soil. In 2002, plant height was positively affected at 25 DAT (Day After Transplanting) by Si fertilization in 100%N treatment. However, in 2003, plant height at 25 DAT was negatively affected by Si fertilization in low N level but it was reversed in high N level with initial increase of plant height. Tiller number per pot was positively affected by N and Si fertilization level, especially for high N fertilized treatment. Leaf color was positively affected by Si fertilizatlon in no N fertilized pots, however, Si was not effected in 50%N and 100%N fertilized treatments. N harvest index (NHI) increased with increased Si fertilization in no N plots, however it decreased with increasing of N fertilization level. Nitrogen use efficiency (NUE) decreased with increasing of fertilized N but Si fertilization increased NUE in 50%N plots, however, it was not different by the Si fertilization level in 100%N plots. In 50%N+200%Si plots, NUE was greatest with 130 and shoot N content was $16.2g-N/m^{2}$. N content ($g/m^{2}$) in rice plant increased with increasing Si fertilization in no N plots at panicle initiation stage, 50 and 100%N plots at heading stage and all N treatment at harvesting time. This was mostly more efficient in late growth stage than early growth stage. The concentration (%) of P and K increased with increasing N fertilization level at heading and harvesting but it was not significantly different by the Si fertilization treatment except a little decreasing with increasing Si fertilization level at heading. Potassium content was also not significantly related with N fertilization level except increasing with Si fertilization level at panicle initiation stage. Plant Ca content (%) decreased with increasing of Si fertilization at heading stage and Si fertilization increased Ca content at panicle initiation stage and heading stage and it increased with increasing of Si fertilization level. Photosynthetic activity was not directly related with Si fertilization amount, however, Fluorescent factors, Fv'/Fm' and PsII, were positively affected by Si fertilization level. In conclusion, N fertilization in Si 200% fertilized condition should be reduced by about 50% level of recommended N fertilization for rice cropping in green-house water-melon cultivated paddy field. However, improvement of Ps by Si fertilization could not be attributed to Ps activity in the same leaf area but because of increased total leaf area per pot improved fluorescent characteristics.