• Resources Recycling
• /
• v.22 no.1
• /
• pp.64-71
• /
• 2013

Mineral carbonation has been proposed as a possible way for $CO_2$ sequestration. The electric arc furnace slags consist of calcium, magnesium and aluminum silicates in various combinations. If they could be used instead of natural mineral silicates for carbonation, considerable energy savings and $CO_2$ emissions reductions could be achieved. Indirect aqueous carbonation of the slags consists of two steps, extraction of calcium and carbonation. Acetic acid leaching of electric arc furnace slags had been already studied to extract Ca in them, but it was reported that the carbonation of the extracted $Ca^{2+}$ in the leached solution would suffer from too slow kinetics, even at high pressure of $CO_2$. In this work, to develop more efficient extraction of the electric arc furnace slags, hydrochloric acid leaching to separate calcium from them was studied, and the results were compared with the acetic acid ones. The phase boundary between $Ca^{2+}$ and $CaCO_3$ in the solution with pH was determined by thermodynamic calculations. Hydrochloric acid was more effective than acetic acid for the extraction of Ca in electric arc furnace slag, and there is a possibility to recycle an unreacted hydrochloric acid in the leached solution by electrolysis or evaporation.

• Economic and Environmental Geology
• /
• v.36 no.6
• /
• pp.415-429
• /
• 2003

This study was objected to identify the difference of water quality and the characteristics of water contamination in adjacent bed-rock areas of Upper Hwajeonni and Guryongsan Formations in Miwon, Choongchungbuk-do, Korea. Water samples showed mainly (Ca, Mg)-$HCO_3$ type in Upper Hawjeonni Formation and (Ca, Mg)-$SO_4$ and (Ca, Mg)-$HCO_3$ types in Guryongsan Formation indicating the enrichment of $SO_4$ in major compositions. Groundwater quality could be divided into two groups based on the major weathering processes, implied by the ratio of bicarbonate to silica. Carbonate-silicate weathering predominates in Upper Hwajeonni Formation, and silicate weathering in Guryongsan Formation. Stream-water quality also appeared to be controlled by water-rock interaction. Cluster analysis identified three groups of groundwater and four groups of stream-water with distinctive geochemical characteristics. The results of factor analysis indicated that the levels of each chemical constituent in water samples derived from both natural weathering reactions and anthropogenic contamination sources. To delineate the pollution potential of water resources, Modified Pollution Index(M.P.I.) was developed. M.P.I. scores of water samples ranged from -0.08 to 0.18, with mostly positive along the rock quarry in Guryongsan Formation areas. M.P.I. scores appeared to be a useful predictor of metal contamination of water resources.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.15 no.4
• /
• pp.255-262
• /
• 1982

The data of 37 oceanographic stations in the coastal sea of Jeju island are compiled in terms of temperature, salinity, dissolved oxygen, silicate, nitrate and phosphate to analyge the chelnical characteristics in this region. This work was carried out during June, 1951. The concentrations of nutrients in the layer more than 50 m are generally 0.5-3 times larger than the surface layer. Each constituents in this layer are as follows: temperature ranged 11.8 to $15.4^{\circ}C$ and salinity, 33.8 to $34.8\%_{\circ}$; and also dissolved oxygen and slicate are 5.2 to 5.6ml/l and 5.6 to $9.0{\mu}g-at/l$, respectively. And nitrate and phosphate ranged 1.0 to $6.0{\mu}g-at/l$ and 0.1 to $0.5{\mu}g-at/l$, respectively. The coastal sea of Jeju island is divided into two parts in chemical view point : one is the southeastern sea of Jeju island under the influence of the Tsushima Current, md the other is the northeastern sea of Jejo island under the influence of the Yellow Sea Bottom Cold Water and the south coastal water of Korea. The north-western sea of Jeju island had relatively a cold (about $13^{\circ}C$) and low saline water (about $34\%_{\circ}$), and dissolved oxygen was higher than in the neibouring waters. It seems that in the southern area between Moseulpo and Seogwipo of Jeju island, two different Ivater masses are complicately intermixed and a tidal front is formed.

• 한국해양학회지
• /
• v.26 no.3
• /
• pp.278-290
• /
• 1991

A synoptic survey of chemical properties was carried out at 21 stations in the Ulleung Basin in May 1988 on board T/V HANBADA. Vertical structures of typical profiles are: surface mixedlayer waters in the upper 30∼40 m with depleted nutrients concentrations, thermocline waters with rapid variations in all physical and chemical properties. and deep Waters below 200 m which are nearly homogeneous. Along the northern section at 37$^{\circ}$12'N. The salinity minimum layer was observed at about 190m. which characterize the East Sea Intermediate Water (ESIW). The dissolved oxygen concentration in this layer was about 230∼ 275uM, lower than 290uM (6.5ml/l) which is the previously known characteristics of the ESIW. However, apparent oxygen utilization (AOU), nitrate, phosphate and silicate show systematically low concentration in the salinity-minimum layer. The low values of AOU and all the nutrients associated with the salinity-minimum, may be useful to identify the ESIW and serve as a new tracer in the East Sea.

• Proceedings of KOSOMES biannual meeting
• /
• 2009.06a
• /
• pp.137-143
• /
• 2009

진해만과 가덕도 주변 해역에서 2007년 2회(하계와 추계)에 걸쳐 표층 및 저층수 조사를 실시하여 수질 환경 특성을 파악하였다. 수온은 표층이 저층보다 높았는데 여름이 가을보다 표 저층간의 차이가 컸으며, 염분은 가덕도 남쪽에서 낙동강 물의 유입 영향으로 저염분을 나타내었다. 부유물질은 표층수의 경우 진해만 및 연안에서 높고 외해에서 낮았으며, 과거의 조사 농도 범위에 속하였다. POC는 계절별로 분포 차이가 있지만 유기물 유입원에 대한 근접성과 기초 생산아 영향을 받는 것으로 나타났다. COD는 표층에서 오염원의 영향이 많은 진해만에서 높고 외해로 가면서 낮아졌다. 여름에 진해만 일부 정점은 해역별 수질기준 III등급이었다. DO는 저층이 표층보다 낮았는데 특히 진해만 내완 외해의 깊을 수심 정점에서 차이가 크고, 하계에 성층에 의하여 수증간에 큰 자이를 나타내었다. 인산염-인과 규산염-규소는 저층수에서 용존산소가 낮아짐에 따라 높은 농도를 나타내는 경향이 강하였으며, 암모니아-질소도 내만의 저산소층에서 높은 농도를 보였다. 표층수의 용존 무기질소는 신항과 가덕도 주변에서 높고 진해만 서쪽 및 외해로 갈수록 낮아졌으며, 과거 조사 농도보다 낮고 좁은 변동 범위를 보였다. 총 질소와 총인도 외해역에서 낮은 농도였으며, 표층보다 저층이 높은 추세였고 여름에 더욱 뚜렷하였다. 총질소 평균 농도로는 해역별 수질기준과 I등급을 만족하였으나 정점별로는 $I{\sim}III$등급까지 변화가 컸는데 진해만 내의 저층 또는 외해의 깊은 수심을 갖는 정점에서 등급이 좋지 알았다. Chl-a는 진해만 내 또는 가덕수도에서 높은 분포였으며, 신항과 가덕도 남쪽에서는 과거보다 낮은 농도였다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 1997.05a
• /
• pp.30-38
• /
• 1997

고속도로변에 설치된 retention pond는 drainage system의 일부분으로 우기에 빗물의 양을 조절하고 고속도로 노면에서 운반되어 retention pond에 유입된 오염된 입자를 침전, 제거시키기 위해 설치되었다. 빗물에 입자상태로 이동된 납, 아연, 카드뮴를 제거하기 위해 설치된 retention pond의 효과를 평가하기 위해 수리지질학적 연구 및 부유퇴적물의 물리화학적 특징을 규명하기 위한 연구가 수행되었다. 부유퇴적물과 비교하기 위해 심하게 오염된 roadside soil과 오염되지 않은 background soil에 대해서도 연구가 수행되었다. 부유퇴적물의 중금속함량은 background Sologne soil에 비해 원소에 따라 2-8배 높다. 그러나, roadside soil의 중금속함량은 부유퇴적물에 비해 7-26배 높다. Sequential extraction methods를 이용하여 분석한 결과 심하게 오염된 roadside soil에 존재하는 납, 아연, 카드뮴은 대부분 쉽게 용해될 수 있는 상태 (Fraction FII, FIII)로 존재하며 반면에 규산염광물과 수반되는 금속함량의 비율은 매우 낮다. 부유퇴적물에서는 규산염광물과 수반되는 금속함량이 전체 금속함량의 1/3까지 크게 증가한다. Roadside soil 과 부유퇴적물사이의 중금속함량 차이가 매우 큰 것은 중금속의 대부분이 retention pond에 이르기 전에 고속도로변과 배수로 일부에 축적되어 모두 상실하기 때문이다.

• Ocean and Polar Research
• /
• v.32 no.3
• /
• pp.331-336
• /
• 2010

The CREAMS (Circulation Research of the East Asian Marginal Sea) survey in 1999 revealed a sharp mid-depth discontinuity of the phosphate:silicate ratio in all basins of the East/Japan Sea. Incidentally, this discontinuity layer corresponds to the oxygen minimum layer. Directly below the discontinuity layer, oxygen concentration is increased. This increase in oxygen concentration is interpreted as a proof of intermediate water formation. Oxygen minimum indicates that the water parcel is old and stable against mixing. So it seems be an efficient barrier to vertical exchange of materials. This means that, once materials enter the lower domain, they rarely return to the upper domain. Therefore, the biogeochemistry of the East/Japan Sea depends heavily on material input through the Korea Strait, and flux is expected to be sensitive to the climate change. As a result, the East/Japan Sea ecosystem seems vulnerable to tipping (regime shift), which occurred on a decadal time scale.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.3 no.1
• /
• pp.25-33
• /
• 1998

Temporal and spatial variations of nutrient elements (ammonia, nitrate, nitrite, phosphate and silicate) in surface seawater off the west coast of Korea were investigated during three periods of field survey aboard R/V Eardo of KORDI (May 1995 and June 1996) and a patrol vessel of the National Maritime Police (November 1995). In general, the concentrations of nutrient elements were lowest in June and highest in November except for ammonia that showed the lowest concentration in May and the highest in November. The results tell us that the development of thermocline and tidal front restricts riverine and benthic supply of nutrient elements to surface waters in June in the offshore regions of the study area which become nutrient-depleted due to phytoplankton bloom in spring. In late fall (November) the level of nutrient concentrations of the surface waters of the study area become high due to vigorous vertical mixing within the water column, which supplies nutrient-enriched bottom water to the surface waters.

• Economic and Environmental Geology
• /
• v.35 no.6
• /
• pp.491-508
• /
• 2002

While about 80% of Jeju soils are classified as Andisols, the soils derived from volcanic ash in Dangsanbong are not Andisols. There is a significant difference of precipitation in localities of Jeju island. The study area is characterized by the lowest amount of annual rainfall in Jeju Island, and by the layered silicates as dominant solid phase in clay fraction. The purpose of this study was to characterize the mineralogy of the non-Andie soils in detail, especially hydroxy-interlayered silicates. Two major soil horizons are recognized in the soil profile developed in the Dangsanbong area, which can be designated as A and C. The soil pH($H_{2}0$), ranges from 6.6 to 7.3 increasing with depth, is higher than that of typical Andisols(pH<6.0). While the pH(NaF), ranges from 9.49 to 9.81, indicates that significant amount of amorphous phases might be present as exchanging complexes. It is estimated to about 1.542.88 wt% by using chemical selective dissolution. The organic content of surface horizon is about 2 wt%. This soil are composed of quartz, feldspar and olivine as major constituents with minor of silicate clays. Quartz is frequently observed in A and distinctly decreases in its amount with depth, while olivine is dominant phase in C and rarely observed in A. In the <0.2$\mu\textrm{m}$ size fraction, smectite and kaolinite/smectite interstratification are dominant with minor of illite. The amounts of smectite decrease with depth, while the amounts of kaolinite/smecite interstratification increase with depth, which indicates the trend of mineral transformation with increasing the degree of weathering. The proportion of kaolinite in kaolinite/smectite interstratification is about 85%, and is not changed significantly through the profile. In the 2-0.2$\mu\textrm{m}$size fraction, vermiculite, smectite, illite and kaolinite are major components with minor of chlorite. Most of chlorite are interstratified with smectite. Chlorite which is not interstratified with smectite occurs only in surface horizon. The proportion of the chlorite in the chlorite/smectite interstratification is 59-70(%) and increases with depth. Hydroxy-interlayered vermiculite(HIV) with hydroxy-Fe/AI in their interlayers occurs in both A and C horizon. The amounts of hydroxy-Fe/AI decrease with depth. Hydroxy-interlayered smectite(HIS) of which interlayers might be composed of hydroxy-Mg/Al occurs only in C horizon. As the results of mineralogical investigation for the soil profile in the study area, clay minerals might be changed and evolved through the following weathering sequences: 1) Smectite Kaolinite, HIS, Vermiculite, 2) Vermiculite HIV Chlorite.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.19 no.1
• /
• pp.53-65
• /
• 2014

In order to estimate the effect of nutrients addition for phytoplankton growth and community compositons in spring and summer season, we investigated the abiotic and biotic factors of surface and bottom waters at 20 stations of inner and offshore areas in Gwangyang Bay, Korea. Nutrient additional experiments were also conducted to identify any additional nutrient effects on phytoplankton assemblage using the surface water for the assay. Bacillariophyceae occupied more than 90% of total phytoplankton assembleges. Of these, diatom Eucampia zodiacus and Skeletonema costatum-like species was mainly dominated in spring and summer, respectively. Here, we can offer the season why the two diatom population densities were maintained at high levels in both seasons. First, light transparency of spring season in the euphotic zone was greatly improved in the bay. This improvement is one of important factor as tigger of increase in E. zodiacus population. Second, low salinity and high nutrient sources supplied by Seomjin River discharge are a main cue for strong bottom-up effects on S. costatum-like species during the summer rainy season. Based on the algal bio-assays, although maximum growth rate of phytoplankton communities at inner bay (St.8) were similar to those of outer bay (St.20), half-saturation constant ($K_s$) for phosphate at outer bay was slightly lower than those of inner bay. This implied that adapted cells in low nutrient condition of outer bay may have enough grown even the low phosphate and they also have a competitive advantage against other algal species under low nutrient condition. In particular, efficiency of N (+) addition in summer season was higher compared to control and P added experiments. In the bay, silicon was not a major limiting factor for phytoplankton growth, whereas nitrogen (N) was considered as a limiting factor during spring and summer. Therefore, a sufficient silicate supply form water mixing Si recycled from diatom decomposition and river water is favorable form maintaining diatom ecosystems in Gwangyang Bay.