• Korean Chemical Engineering Research
• /
• v.58 no.4
• /
• pp.618-623
• /
• 2020

Spherical phenolic resin beads were synthesized by suspension polymerization at 98 ℃ from phenol, ortho-cresol, formaldehyde, with triethylamine as a basic catalyst, and spherical phenol-cresol copolymer resin beads with relatively low crosslinking density as well. Phenol reacts with formaldehyde at two ortho- and one para- positions to form a crosslinked structure, but ortho-cresol instead of phenol reduces the crosslinking density during copolymerization due to the methyl group at a ortho- position. As a result, spherical phenol-cresol copolymer beads showed more shrinkage with decreasing apparent density compared to the spherical phenol beads when carbonized at 700 ℃ under nitrogen. As the molecular weight of the cresol oligomer increases, the pore radius of the carbonized copolymer beads decreases, which is consistent with the density and shrinkage results. It was confirmed that the characteristics such as density decrease, shrinkage, yield and so on during carbonization can be controlled by controlling the degree of crosslinking of the spherical phenolic resin particles with cresol.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.11 no.3
• /
• pp.388-402
• /
• 2000

The radiation characteristics of leaky antenna from the dielectric-coated conducting cylinder with periodic corrugation are investigated theoretically for the infinite and finite periodic structures. For the infinite periodic structure, mode-matching method is applied. The integral equation is derived for the finite periodic structure by use of the Fourier transform and mode expansion and a simultaneous linear equation is obtained. The influences of the corrugation slot width, corrugation depth, dielectric thickness, cylinder radius, and finite corrugation number on the radiation characteristics (leakage constant, phase constant, and radiation pattern) are investigated. The results of the finite periodic corrugations are compared with those of the infinite extent structure and good agreement is found. To reduce high side lobe levels of the uniform finite periodic structure, tapering process on the beginning and end section of antenna and nonuniform quasi-period slot arrays are considered. Especially, for the corrugation period, width and depth used for a corrugated surface wave antenna, through the proper tapering process, end-fire radiation pattern with reduced side lobe levels is given.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.8
• /
• pp.5060-5066
• /
• 2015

The number of shop needed for the fabrication of sphere type LNG tank is proportional to that of the tank radius to be constructed. Due to limitation of facility investment including building sites, it is practically difficult to fabricate various size tanks of perfectly spherical shape in the yards. The efficient method to increase cargo tank capacity is to extend vertically the conventional sphere type LNG tank by inserting a cylindrical shell structure. In this study, equations for static design loads are developed for sphere type LNG tank with central extension. The results of this study will be combined with dynamic design loads to build the simplified analysis method which enable the precise initial estimate instead of time consuming finite element analysis.

• Journal of Adhesion and Interface
• /
• v.15 no.2
• /
• pp.63-68
• /
• 2014

Hollow mesoporous carbon nitride material with sphere shape was synthesized using polystyrene sphere as template and cyanamide as nitrogen and carbon atom sources via thermal treatment process. The process of the silica removal is not necessary because silica as template is not in use for the synthesis of hollow mesoporous carbon nitride material and any solvents are also not in use. The size of polystyrene spheres was about 170 nm. Hollow diameter and wall thickness were 82 nm and 13 nm, respectively, in hollow mesoporous carbon nitride sphere. Surface area, mesopore size and pore volume of hollow mesoporous carbon nitride material was $188m^2g^{-1}$, 3.8 nm and $0.35cm^3g^{-1}$, respectively. The wall in hollow sphere has graphitic structure. Hollow mesoporous carbon nitride material has potential applications in the area of fuel cell, catalysis, photocatalysis, electroemmision device, etc.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.4 no.1
• /
• pp.59-64
• /
• 2006

Ion exchange resin particles should not be found in steam generator(S/G) sludge. The suspicious spherical resin particles observed in S/G sludge sample were characterized for particle size distribution under optical microscope using the micro-technique, for element analysis by the electron probe micro analysis (EPMA), and for molecular identification by the IR spectroscopy. The particle sizes are distributed from 1 to $200{\mu}m$ for the sludge, while 40 to $500{\mu}m$ for the spherical resin particles. The results of the elemental analysis showed different major impurities: Si, Al, Mn, Cr, Ni, Zn and Ti for the sludge particles, while Si, Cu, Zn for the spherical resin particles. However, both particles contain Fe as a matrix of magnetite $(Fe_3O_4)$. IR spectrum of the spherical particles was not quite similar to the IR spectrum of ion exchange resins used in S/G system. These results indicate that the spherical particles are not related to ion exchange resin particles and may be formed by the process of the sludge formation.

• Korean Chemical Engineering Research
• /
• v.44 no.4
• /
• pp.375-381
• /
• 2006

In this sturdy, spherical activated carbon(SPAC) contained $TiO_2$ was made by ion-exchanged treatment and heat treatment for applying fluidizing bed system. The ion-exchange resin was treated by $TiCl_3$ aqueous solution. The treated resin and raw resin were heat-treated under nitrogen condition to convert into Ti-SPAC. During the heat-treatment, burn-off weight amounts and the element were measured by means of TGA and TGA/MS, individually. The physicochemical properties of Ti-SPAC was characterized by means of XRD, SEM, EDS, BET, EPMA, ESR, intensity and titanium content. The Ti-SPAC had spherical shape with diameter size about $350{\mu}m{\sim}400{\mu}m$ and $617m^2/g$ specific surface area. Structure of $TiO_2$ in Ti-SPAC was anatase and rutile form. Also, $TiO_2$ on SPAC were found that the $TiO_2$ were uniformly distributed through EPMA analysis. Moreover, the Ti-SPAC showed indirect photocatalyst activity estimation through ESR analysis, characteristics of photocatalyst potentially. Over all results, Ti-SPAC was used in fluidizing bed UV/photocatalyst system to remove HA(Humic Acid). That results were HA removal efficiency was about 70％ and Ti-SPAC intensity was preserved during reaction. Ti-SPAC showed practical possibility as photocatalyst in fluidizing bed system.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2010.10a
• /
• pp.453-454
• /
• 2010

• Journal of the Korean Institute of Telematics and Electronics
• /
• v.5 no.2
• /
• pp.1-7
• /
• 1968

The characteristics of periodical discontinuities (The array of slots on the broadside of rectangular waveguide) are analysed and represented by T equivalent circuits.)

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.5
• /
• pp.262-267
• /
• 2017

The number of shops needed for the fabrication of a sphere type cargo tank for an LNG carrier is proportional to the size of the tank to be constructed. Due to the limitations of facility investment, it is difficult to fabricate various size tanks with a perfectly spherical shape in the (factory). An efficient method of increasing the capacity of the cargo tank is to extend the conventional sphere type LNG tank vertically by inserting a cylindrical shell structure. In this study, equations for the dynamic pressure distribution due to horizontal acceleration are derived for a sphere type LNG tank with central extension. The derived equations can be easily applied to the design and structural assessment of a sphere type LNG tank with central extension. Furthermore, the results of this study can be combined with the static design loads previously reported by Shin & Ko [9], in order to establish a simplified analysis method which enables a precise initial estimate to be obtained, thereby obviating the need for a time consuming finite element analysis.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2005.06a
• /
• pp.129-136
• /
• 2005

There should not be ion exchange resin particles in S/G sludge. The suspicious spherical resin particles observed in S/G sludge sample were characterized for particle size distribution under optical microscope using the micro-technique, for element analysis by the electron probe micro analysis (EPMA), and for molecular identification by the IR spectroscopy The particle sizes are distributed from 1 to 200 ${\mu}m$ for the sludge, while 40 to 500 ${\mu}m$ for the spherical resin particles. The results of the elemental analysis showed different major impurities: Si, Al, Mn, Cr, Ni, Zn and Ti for the sludge particles, while Si, Cu, Zn for the spherical resin particles. However, both particles contain Fe as a matrix of hematite ($Fe_{3}O_4$). IR spectrum of the spherical particles was quite different from that of ion exchange resins used in S/G system. These results indicate that the spherical particles are not related to ion exchange resin particles and formed by the process of the sludge formation.