• Title/Summary/Keyword: 광화학적

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Effect of Ozone Concentration on AOP Efficiency of Secondary Effluent from Pig Slurry Purification System (오존 접촉농도가 양돈슬러리 2차 처리수의 고도처리 효율에 미치는 영향)

  • Jeong, K.H.;Jeon, S.K.;Ryu, S.H.;Kim, J.H.;Kwag, J.H.;Ann, H.K.;Jeong, M.S.;Yoo, Y.H.
    • Journal of Animal Environmental Science
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    • v.17 no.3
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    • pp.181-188
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    • 2011
  • With an increasing livestock population, animal manure production has been steadily increasing in Korea. This trend has forced farmers to spend more money for animal manure treatment in their farm. Therefore, research utilizing animal manure as a renewable resources has become increasingly important. The purpose of this study was to develop a stable advanced wastewater treatment system can be applied to conventional animal wastewater treatment processes and evaluate its contribution to reduce effluent discharge volume by recycling as flushing water. AOP (advanced oxidation process) process improved wastewater treatment efficiency in terms of color, suspended solids (SS) and chemical oxygen demand (COD). Due to the addition of Hydrogen peroxide ($H_2O_2$), pathogens, Salmonella and E. coli, reduction was accomplished. To enhance ozone treatment effect, three levels of ozone test on secondary effluent of pig slurry purification system were conducted. At the level of 5 g/hr, 6.7 g/hr and 8.4 g/hr color of secondary effluent of pig slurry purification system were decreased from 2,433 to 2,199, 2,433 to 1,980 and 2,433 to 243, respectively.

Occurrence and Geochemistry of Argyrodite, a Germanium-Bearing Mineral(Ag8GeS6), from the Weolyu Ag-Au Hydrothermal Vein Deposits (월류(月留) 은(銀)-금(金) 열수광상(熱水鑛床)에서 산출된 함(含) Ge 광물(鑛物)인 Argyrodite의 산상(産狀)과 지구화학(地球化學))

  • So, Chil-Sup;Yun, Seong-Taek;Choi, Seon-Gyu
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.117-127
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    • 1993
  • Ag-Au vein ores from the Weolyu mine, Youngdong district, contain significant germanium (up to 145g/t, average 34.9g/t), in the form of argyrodite ($Ag_8GeS_6$). Mineral chemistries of argyrodite and its associated minerals were determined by electron probe microanalysis. Twenty eight elements in thirteen ore samples were analyzed using an ICP mass spectrometer. Argyrodite occurs in the paragenetically later mineral assemblage consisting of carbonates+quartz+native silver+argentite+Ag-sulfosalts, indicating that the germanium mineralization represents the culmination of a complex mineral sequence which includes early gold and late silver deposition. The mean formula of the argyrodite is $Ag_{7.90}\;(Ge_{0.76}Sn_{0.04})S_6$, with minor amounts of Cu, Fe, Sb, As, Sn, and Zn. The Weolyu argyrodite shows systematic substitutions of Ag by Cu, and of Ge by Sb. Chemical analyses of vein ores indicate that metals were precipitated in the order of $Fe{\rightarrow}Pb$, $Zn{\rightarrow}Cu{\rightarrow}Ag$, Sb, As, Ge. Germanium has a strong geochemical affmity with As and Sb, and Cu, Pb, Zn, Mo, and Sr show weak positive correlations with Ge. Germanium deposition at Weolyu was mainly a result of cooling of hydrothermal fluids (down to $175^{\circ}C{\sim}210^{\circ}C$, due to increasing involvement of cooler meteoric waters in the epithermal system.

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A Geochemical Study on Trace Elements of the Onjong Granite in Relation to Mineralization, Pyeonghae Area (평해지역 온정화강암 중 미량원소와 광화작용의 관계에 대한 지화학적 연구)

  • Lee, Jae Yeong;Lee, Jin Gook
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.245-258
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    • 1992
  • The variations of certain major and trace elements of the Onjong granite mass was studied on the basis of petrological and geochemical characteristics and compared with those of the Eonyang-Yucheon granite masses in order to investigate the geochemical differences of the granitic rocks in relation to mineralization between Pb-Zn ore district and Pb-Zn-Mo-W ore district in Kyeongsang basin. The Onjong granite mass is classified into granodiorite and monzo-granite, and the Eonyang-Yucheon granite masses into monzo-granite by the Streckeisen's diagram. Between both granite masses there are clear differences in contents of certain major elements and lithophile trace elements. The former have high contents of Ca (2.94%), Mg (1.66%) and Sr (365 ppm), and low contents of K (3.52%), Na (3.51%), Rb (116 ppm), Ba (640 ppm) and Li (18.9 ppm), whereas the latter have high contents of K (4.02%), Na (4.28%), Rb (145 ppm), Ba (695 ppm) and Li (19.3 ppm), and low contents of Ca (1.42%), Mg (0.43%) and Sr (161 ppm). Except for Mo, there are not clear differences in chalcophile trace elements between two granite masses: the Onjong granite mass has higher Mo content (7.1 ppm) lnan that (1.7 ppm) of the Eonyang-Yucheon granite masses, but Pb and Zn contents are similar between the Onjong granite mass (Pb=8.7 ppm, Zn=37.1 ppm) and the Eonyang-Yucheon granite masses (Pb=7.8 ppm, Zn=39.8 ppm). Ca and Sr contents of the Onjong granite mass (Ca> 1.5%, Sr> 270 ppm) are higher than those of the Eonyang- Yucheon granite masses (Ca<1.5%, Sr<270ppm), and Rb/Sr, Rb-Rb/Sr and K-Rb/Sr ratios are clearly distinguishable between the Onjong granite mass(Rb/Sr<0.51, Rb-Rb/Sr>250 and K-Rb/Sr>5.2) and the Eonyang- Yucheon granite masses (Rb/Sr>0.51, Rb-Rb/Sr<250 and K-Rb/Sr<5.0). Thus, variations of certain major and trace elements and ratios are applicable as geochemical index to distinguish the types of mineralization of the ore districts related to the Cretaceous granitic rocks in the Kyeongsang basin.

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Developmental Aspects of Hongcheon Fe-REE Ore Body (홍천 철-희토류광체의 발달양상)

  • Lee, Han Yeang;Ryoo, Chung Ryul
    • The Journal of the Petrological Society of Korea
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    • v.21 no.4
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    • pp.397-403
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    • 2012
  • Fe-REE deposits occurred in Jaeunri, Hongcheon formed by carbonatitic melts consist of 3 parts such as northern, middle and southern ore bodies showing discontinuous distribution, and extension shape of ore bodies can be figured through field survey and geometric analysis. Foliations in gneiss around northern and middle ore bodies represent NNE, whereas toward south its direction changes gradually from NE to ENE and finally N-S direction appears in southern ore body. From Jaeungyo to Saemaeulgyo geometric analysis from field work gives that fold shape in this area is open synclinal fold concavely and gently to NW with $45^{\circ}$ northwestward plunging axis, in contrast small scale anticline with $45^{\circ}$ northwestward plunging axis in Yagsooteo area near western part of Saemaeulgyo. Dragging effect could be occurred on these folds by WNW trending dextral strike-slip fault from Yagsooteo to Saemaeulgyo. New ore body can be confirmed from folding structure estimated by trend of foliation, and thus unidentified ore body may be exist under alluvial surface from middle to southern ore body and its distribution could show reversed "ㄱ", one of Korean consonants, considering with estimated strike and dip of foliations. This estimated extension of ore body figured out by structural analysis in the studied area works an important role for measuring of ore reserve and selecting of drilling site to find new ore body.

Comparison between QraypenTM Imaging and the Conventional Methods of Visual Inspection and Periapical Radiography for Proximal Caries Detection in Primary Molars: An In Vivo Study (유구치 인접면 우식 병소 진단에 있어 QraypenTM과 시진 및 구내 치근단 방사선의 비교)

  • An, So-Youn;Park, So-Young;Shim, Youn-Soo
    • Journal of dental hygiene science
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    • v.16 no.5
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    • pp.349-354
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    • 2016
  • The purpose of this study was to evaluate the efficacy of the newly-developed $Qraypen^{TM}$ (All In One Bio, Korea) system for the diagnosis of early proximal caries by comparing it with the conventional methods of visual inspection and periapical radiography. This study was carried out from July 2015 to April 2016 targeting 32 children aged 7~12 years who visited Y-Dental Clinic for school oral health examinations. Two investigators selected and examined a total of 153 primary molars that had not undergone restorative treatment. Comparisons were carried out between visual inspections, readings of posterior periapical radiography images, and readings of $Qraypen^{TM}$ images. This study revealed that the percentage of interproximal surfaces of primary molar teeth without caries incidence was 83.7% using $Qraypen^{TM}$ imaging and 84.9% using visual inspection and periapical radiography. The differences between the two methods were not statistically significant. Thus, $Qraypen^{TM}$ is expected to be a useful and convenient auxiliary diagnostic device that can facilitate the detection of hidden proximal caries in primary molars.

The Effect of Estrogen Deficiency on Rat Pulpodentinal Complex (에스트로겐 호르몬 결핍 백서에서의 상아-치수 복합체의 변화에 관한 연구)

  • Kim, Mi-Ri;Yang, Won-Kyung;Baek, Jin;Kim, Jong-Jin;Kim, Won-Kyung;Lee, Young-Kyoo
    • Restorative Dentistry and Endodontics
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    • v.30 no.5
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    • pp.402-408
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    • 2005
  • The purpose of this study was to investigate the effects of estrogen deficiency on pulpodentinal complex of tooth in ovariectomized rats. Thirty female Sprague-Dawley rats, 10 weeks old, were used. Rats were grouped into two groups. One group (n = 15) was subjected to sham surgery (SHAM) and the other group (n = 15) was ovariectomized bilaterally (OVX). Animals were sacrificed 12 weeks later, and their mandibular molars and associated periodontal supporting tissues were dissected out, and fixed in $10\%$ buffered formalin. For comparison of groups, immunostained for osteonectin. Histomorphometrical measurement of change of teeth was performed using an image analysis system and paired t-test was used and the level of significance for overall differences was set at p < 0.05. In immunostaining of osteonectin, they were significantly different from each other. The predentin thickness in OVX rats was wider than in SHAM rats. And in SHAM rats, osteonectin was more specifically stained in predentin areas than in OVX rats. These results indicate that estrogen deficiency increased the unmineralized predentin areas and decreased osteonectin content in pulpal tissues in rats. If our result is applicable to human studies, odotoblast is affected by estrogen deficiency.

IN VITRO EVALUATION OF EXPERIMENTAL FLUORIDE TAPE IN INHIBITION OF ENAMEL DEMINERALIZATION (불소 테이프의 법랑질 탈회 억제 효과에 관한 실험적 평가)

  • Kim, Min-Jung;Lee, Sang-Ho;Lee, Nan-Young;Park, Seung-Hyo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.39 no.2
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    • pp.129-138
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    • 2012
  • The aim of this in vitro study was to evaluate the effectiveness of experimental 2.26% fluoride-polyvinyl alcohol (F-PVA) tape in inhibition of enamel demineralization using enamel surface microhardness (SMH) analysis and scanning electron microscopy (SEM) examination. Enamel specimens (n=60) randomly assigned to four groups: control group, F-PVA tape group, fluoride varinish (F-varnish) group, casein phosphopeptide-amorphous calcium phosphate (CPP-ACFP) group. After topical application, pH-cycling was processed. Then, SMH was measured and the percentage loss of surface microhardness (%SML) was calculated. For the SEM examination, five sample specimens in each group were treated and the morphologic character was evaluated. After pH-cycling, the SMH values of the enamel specimens of F-PVA tape and F-varnish group were significantly higher than that of CPP-ACFP group, there was no significant difference between F-PVA tape and Fvarnish group. With SEM examination, enamel surfaces in the F-PVA tape group and F-varnish group showed numerous spherical and ovoid crystals formed on the enamel surface were also observed. The density of crystals was higher than that of both control group and CPP-ACFP group. F-PVA tape is effective in inhibition of enamel demineralization. Also, F-PVA tape's inhibition of enamel demineralization is comparable to that of F-vanish and greater than that of CPP-ACFP.

A Geochemical Study on the Chindong and Yucbeon - Eonyang Granites in Relation to Mineralization (진동화강암 및 유천-언양화강암의 광화작용에 관한 지화학적 연구)

  • Lee, Jae Yeong
    • Economic and Environmental Geology
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    • v.22 no.1
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    • pp.21-34
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    • 1989
  • Chindong granites are classified into granodiorite, tonalite and quartz-diorite, and Yucheon - Eonyang granites into monzo-granite by the Streckeisen diagram. These granitic rocks of Cretaceous age show trend of calc-alkaline magma, and the magmatic evolution from basic to acidic rocks is consistant with the general crystallization path of the Cretaceous granitic rocks in the Gyeongsang basin. On the basis of petrological and petrochemical data, variation of major elements (K, Na, Ca, Mg) and trace elements (Rb, Sr, Ba) including ore metals (Cu, Pb, Zn) in the Cretaceous granitic rocks were studied in detail in order to investigate geochemical difference of the granitic rocks in relation to mineralization between Cu province and Pb-Zn province in the Gyeongsang basin. There is clear difference in content of the major elements between Chindong granites and Yucheon-Eonyang granites : Chindong granites have low content of K (1.62%) and Na (2.53%), and high content of Ca (3.75%) and Mg (1.42%) whereas Yucheon-Eonyang granites have high content of K (3.56-3.60%), and low content of Ca (0.96-0.26%) and Mg (0.26-0.21%). There is also clear difference in content of trace lithophile elements between Chindong granites and Yucheon-Eonyang, granites : Chindong granites have low content of Rb (86ppm) and Ba (330ppm), and high content of Sr (405ppm) while Yucheon-Eonyang, granites have high content of Rb (144-161ppm) and Ba (983-1030ppm), and low content of Sr (157-136ppm). The lithophile trace elements of Rb and Sr vary with close relationship to major elements of K and Ca, respectively. Therefore, Chindong granites are much easily distinguished from Yucheon-Eonyang granites by using relationship of K with Rb and Ca with Sr : K<3%, Rb<100ppm, Ca<2% and Sr>200ppm for Chindong granites, and K>3%, Rb>100ppm, Ca<2%, and Sr<200ppm for Yucheon-Eonyang granites. There is not clear difference in content of trace ore metals between Chindong granites and Yucheon-Eonyang granites : Chindong granites of the Cu province have low Cu content (15ppm) which is nearly equal to 13-14ppm of Yucheon-Eonyang granites of the Pb-Zn province, and Yucheon-Eonyang granites have Pb content (29-27ppm) which is rather lower than 37ppm of Chindong granites. But Cu is anomalously high in the mineralized part of Chindong granites in Gunbuk-Haman area, and Zn is apparently higher in Yucheon-Eonyang granites (51-37ppm) than in Chindong granites (29ppm). K/Pb ratio is also c1early distinguishable between Chindong granites (<850) and Yucheon-Eonyang granites (>850). Thus, it may be possible to apply geochemical difference of the granites to distinguish whether a Cretaceous granitic body is Cu related rock or Pb-Zn related rock, and whether it belongs to Cu province or Pb-Zn province in the Gyeongsang basin.

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A Study on the Peak Runoff Reduction Effect of Seolleung·Jeongneung Zone by Applying LID(Low Impact Development) System based on the Landscape Architectural Technology (조경기술기반 LID 시스템 적용을 통한 선릉·정릉 권역의 첨두유출량 분석)

  • Kim, Tae-Han;Choi, Jong-Hee
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.35 no.4
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    • pp.126-133
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    • 2017
  • This study analyzed hydrological changes of stormwater runoff of Seolleung Jeongneung zone according to the application of LID system based on landscape Architectural technology. The results are as follows. First, when flooding occurred in Gwanghwamun in July 27, 2011, the maximum instantaneous rainfall amount was 183 mm/hr recorded at 10:00 on 27th for 10 minutes, and it was confirmed that rainfall intensity more than three times as high as the maximum rainfall of 57.5 mm/hr. Second, it is possible to control peak flow rate in the case of 1,500mm of soil thickness, so that it is possible to improve the vulnerability of flood damage in Seolleung and Jeongneung zone when applying the LID system. Third, in the berm height scenario, peak flow rate control was not controled in all depth level models, but the first stormwater runoff was delayed by 4 hours and 10 minutes compared to the soil thickness scenario. It was interpreted as a relatively important indicator the soil thickness for the initial stromwater runoff reduction and the berm height for the peak runoff. Through this, the systematic adaptation of landscape-friendly ecological factors within the cultural property protection zone could theoretically confirm the effects of flood disaster prevention.

Environmental Impact and Water Foot Print Assessment of Pot Bearing Using Life Cycle Assessment (LCA) (LCA를 이용한 교량용 포트받침 환경영향 및 물발자국 분석)

  • Park, Jihyung;Wie, Daehyung;Ko, Kwanghoon;Hwang, Yongwoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.6
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    • pp.851-857
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    • 2018
  • In this research, LCA analysis of the manufacturing process of pot bearing for fixed, movable in all directions, movable in one direction was carried out to analyze the environmental load using the LCA methodology. Especially, the water footprint that has been and issue in recent years was analyzed. As a result of LCA, it was analyzed that the contribution of the plate was more than 64.2% in all of the six impact categories in the case of fixed pot bearing base, and more than 94% in the category of resource depletion and photochemical oxidant creation. In the case of all direction pot bearing and one direction pot bearing, the contribution of PTFE was the highest in the global warming and stratospheric ozone depletion, and the contribution by the plate was higher in the other impact categories. The water footprint of each type of pot bearing was analyzed as $22.4m^3\;H_2O\;eq/kg$ for one direction pot bearing, $17.1m^3\;H_2O\;eq/kg$ for fixed pot bearing, and $14.1m^3\;H_2O\;eq/kg$ for all direction pot bearing. As a result of life cycle analysis, the contribution of water use in manufacturing was more than 65% in all three types. The results of this study can be used as basic data for decision making in construction method and material selection of bridges in the future.