• Title/Summary/Keyword: 광화학적

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Estimation of Influence of Milking System Type on Milking Center Effluent Amount and its Characteristics (착유시스템 유형별 세척수의 발생량과 특성)

  • Choi, D.Y.;Kwag, J.H.;Park, C.H.;Jeong, K.H.;Kim, J.H.;Yoo, Y.H.;Jeong, M.S.;Han, C.B.;Choi, H.L.
    • Journal of Animal Environmental Science
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    • v.14 no.3
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    • pp.149-158
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    • 2008
  • The purpose of this study was to determine the effect of milking system type on milking center effluent production through the four seasons. Four different types of milking systems (Bucket, Pipeline, Tandem and Herringbone) were estimated, in duplicate, through the different seasons. The following conclusions can be drawn from this study. 1. The quantity of wastewater produced from Tandem and Herringbone milking systems were significantly larger than Bucket milking system (p<0.05). 2. The main wastewater production was from the washing of milking apparatus. Tandem and Herringbone milking systems produced 398.8 and $407.7{\ell}$/day of wastewater, respectively, for apparatus washing. These values were significantly higher than the other milking systems during the summer (p<0.05). 3. The average wastewater production from the various milking systems was $15.4{\ell}$/head/day. The quantity of wastewater production during summer ($16.4{\ell}$/head/day) season was higher than of the other seasons. 4. The highest level of $BOD_5$ ($906.4mg/\ell$) was produced from the washing of the parlor floor and the lowest level of $BOD_5$ ($212.4mg/\ell$) was produced from the washing of the udders of the cows. 5. The pH of dairy wastewater was in the range of $7.3{\sim}8.2$ and the average levels of $BOD_5$, COD, SS, T-N, and T-P were 731.2, 479.0, 751.6, 79.1, $14.7mg/\ell$, respectively. Following conclusions can be drawn from this experiment. The quantities of wastewater production from Bucket, Pipeline, Tandem and Herringbone milking system were 143.9, 487.9, 914.0, and $856.7{\ell}$, respectively. The average wastewater produced from the milking systems was $15.4{\ell}$/head per day. In order to effectively manage on the wastewater from milking systems, dairy farms need to consider the milking system type and farm size when determining the optimum wastewater treatment system.

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THE EFFECT OF FLUORIDE VARNISH AND ACIDULATED PHOSPHATE FLUORIDE GEL ON ARTIFICIAL CARIES LESION (Fluoride varnish와 acidulated phosphate fluoride gel이 인공우식 병소에 미치는 영향)

  • Kim, Kwang-Hyon;Hahn, Se-Hyun;Kim, Chong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.1
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    • pp.159-165
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    • 2001
  • Fluoride has been used widely for the prevention of dental caries. Many dental professionals applicated acidulated phosphate fluoride(APF) gel for the purpose of prevention of dental caries in recent years. However, the topical application of fluoride varnish is growing and getting much recognition in many parts of Europe and Scandinavia. The main purpose of this study was to compare the effect of fluoride varnish and acidulated phosphate fluoride gel on artificial caries lesion. The artificial caries lesion was caused on the sound bovine enamel and divided 60 specimens into three groups each containing twenty for the purpose of study. No application was done on group 1, which acted as control group. Group 2 was treated with the topical application of fluoride varnish and removed after 1 hour Group 3 was treated with APF gel and removed after a minute. The cycle of remineralization/demineralization went on in vitro and the microhardness was measured for the each group after 5 and 15days. The following results were obtained : 1. According to the results after 5 days, the microhardness of groups 2 and 3 were significantly higher than group 1, the control group(p<0.05) Similar results was also noticed after 15 days(p<0.05) 2. In comparison of microhardness between groups 2 and 3 after 5days, there were no significant differences between them. The results after 15 days was also similar 3. Much difference in microhardness wasn't present in groups 2 and 3 after 5 and 15days. However, the microhardness of the group 1 dropped significantly in the result of 15 days and 5 days(p<0.05).

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Assessment of Optimum Hydraulic Retention Time (HRT) for Maximum Biogas Production and Total Volatile Solid (TVS) Removal Efficiency of Semi-Continuously Fed and Mixed Reactor (SCFMR) Fed with Dairy Cow Manure (젖소분뇨로부터 최대 바이오가스 생산과 유기물 제거효율을 달성하기 위한 반건식 간헐주입 연속혼합 혐기성반응조의 최적 수리학적 체류시간 도출을 위한 연구)

  • Kang, Ho;Kim, Sun-Woo;Jeong, Ji-Hyun;Ahn, Hee-Kwon;Jung, Kwang-Hwa
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.12
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    • pp.696-704
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    • 2015
  • This study was carried out to evaluate the optimum operational condition of Semi-continuously Fed and Mixed Reactor (SCFMR) to treat the dairy cow manure and saw dust mixture. Step-wise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) were utilized until the biogas volume became significantly decreased at mesophilic temperature ($35^{\circ}C$). The optimum operating condition of the SCFMR fed with TS 13% dairy cow manure and saw dust mixture was found to be an HRTs of 25 days and its corresponding OLRs of $4.45kg\;VS/m^3-day$. At this condition the biogas and methane production rates were 1.44 v/v-d and 1.12 v/v-d (volume of biogas per volume of reactor per day), respectively and the TVS removal efficiency of 37% was achieved. The successful operation with such a high OLR was due to the high reactor alkalinity concentration of 14,500~15,600 mg/L as $CaCO_3$ as a result of the characteristic of the original substrate, dairy cow manure and saw dust mixture whose alkalinity was more than 8,000 mg/L as $CaCO_3$. The parameters for the reactor stability, the ratios of volatile acids and alkalinity concentrations (V/A) and the ratio of propionic acid and acetic acid concentrations (P/A) appeared to be 0.11 and 0.43, respectively, that were greatly stable in operation. Free ammonia toxicity was not experienced due to the long term acclimation by the reactor TS content ranged 7.2~10.4% during the entire operational period.

U-Pb(SHRIMP) and K-Ar Age Dating of Intrusive Rocks and Skarn Minerals at the W-Skarn in Weondong Deposit (원동 중석 스카른대에서의 관입암류와 스카른광물에 대한 U-Pb(SHRIMP) 및 K-Ar 연대)

  • Park, Changyun;Song, Yungoo;Chi, Se Jung;Kang, Il-Mo;Yi, Keewook;Chung, Donghoon
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.3
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    • pp.161-174
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    • 2013
  • The geology of the weondong deposit area consists mainly of Cambro-Ordovician and Carboniferous-Triassic formations, and intruded quartz porphyry and dyke. The skarn mineralized zone in the weondong deposit is the most prospective region for the useful W-mineral deposits. To determine the skarn-mineralization age, U-Pb SHRIMP and K-Ar age dating methods were employed. The U-Pb zircon ages of quartz porphyry intrusion (WD-A) and feldspar porphyry dyke (WD-B) are 79.37 Ma and 50.64 Ma. The K-Ar ages of coarse-grained crystalline phlogopite (WD-1), massive phlogopite (WDR-1), phlogopite coexisted with skarn minerals (WD-M), and vein type illite (WD-2) were determined as $49.1{\pm}1.1$ Ma, $49.2{\pm}1.2$ Ma, $49.9{\pm}3.6$ Ma, and $48.3{\pm}1.1$ Ma, respectively. And the ages of the high uranium zircon of hydrothermally altered quartz porphyry (WD-C) range from 59.7 to 38.7 Ma, which dependson zircon's textures affected by hydrothermal fluids. It is regarded as the effect of some hydrothermal events, which may precipitate and overgrow the high-U zircons, and happen the zircon's metamictization and dissolution-reprecipitation reactions. Based on the K-Ar age datings for the skarn minerals and field evidences, we suggest that the timing of W-skarn mineralization in weondong deposit may be about 50 Ma. However, for the accurate timing of skarn mineralization in this area, the additional researches about the sequence of superposition at the skarn minerals and geological relationship between skarn deposits and dyke should be needed in the future.

A Geochemical Indicator in Exploration for the Kalaymyo Chromitite Deposit, Myanmar (미얀마 깔레이미요 크롬철석광상 탐사의 지구화학적 인자)

  • Park, Jung-Woo;Park, Gyuseung;Heo, Chul-Ho;Kim, Jihyuk
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.423-433
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    • 2017
  • Korea Institute of Geoscience and Mineral Resources and Department of Geological Survey and Mineral Exploration in Myanmar have explored the Kalaymyo chromitite deposit, Myanmar since 2013. It is now necessary to find a geochemical indicator for efficient mineral exploration in the future and building a 3D geological model for this ore deposit. Mantle podiform chromitite is a major type of Cr ore in this region, which is considered to be formed by mantle-melt interaction beneath the mantle-crust boundary of oceanic lithosphere. In this study we measured major element composition of spinels in harzburgite, dunite and chromitite, and examined the hypothesis that spinel Cr#(molar Cr/(Cr+Al)${\times}$100) can be used as a geochemical indicator in exploration for the Kalaymyo chromitite. The results show that there is a clear correlation between spinel Cr# and distribution of chromitite. The spinel Cr# of harzburgite increases with decreasing the distance from the chromitite bodies. The spinel composition is also closely associated with texture and occurrence of spinels. The high Cr# spinels (30-48) are subhedral to euhedral and enclosed by olivine whereas the low Cr# spinels (16-27) are anhedral and commonly associated with pyroxenes. Often the low Cr# spinels show symplectite intergrowths with pyroxenes, indicating their residual nature. These petrological and geochemical results suggest that the high Cr# spinels have resulted from mantle-melt interaction. We suggest that spinel Cr# can be used as a geochemical indicator for Cr ore exploration and as one of critical factors in 3D geological model in the Kalaymyo chromitite deposit.

Characteristics of Lode Development and Structural Interpretation for the High Au Contents within the Fault Gouge Zones in Jinsan Au Mine, Chungcheongnam-do (충남 금산 진산금광산의 광맥 발달특성과 단층점토에 농집된 고품위 금함량에 대한 구조지질학적 해석)

  • Shin, Dongbok;Gwon, Sehyeon;Kim, Young-Seog
    • Economic and Environmental Geology
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    • v.48 no.2
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    • pp.103-114
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    • 2015
  • Jinsan gold deposit is a hydrothermal vein type deposit consisting of several fissure filling quartz veins developed within the Changri Formation of the Ogcheon Supergroup in Geumsan, Chungnam. This study is to provide an efficient exploration and development strategies based on the characteristics of the geology, geological structure, core logging, and ore vein occurrence and grade for the four pits (New pit, Main pit, Yanghapan pit and Teugho pit). Quartz veins are mostly developed with the strike of $N10^{\circ}-25^{\circ}W$ and $N5^{\circ}-20^{\circ}E$, and the thickness is in the range of 0.1~0.5 m, sometimes extending to over 1m. Although the quartz veins commonly form massive shape, they sometimes show zonal structure, comb structure as well as brecciated texture. Major ore minerals are pyrite and chalcopyrite, and pyrrhotite, sphalerite, galena, marcasite, electrum and chalcocite are also accompanied as minor phases. Gray and milky white quartz veins, which are occasionally crosscut by calcite vein, also include fluorite. Ore evaluations for the 22 samples revealed that the samples from the pits generally have very low Au contents, lower than 1 g/t, but some clay samples of drilled core show very high Au concentrations, up to 141 g/t, indicating that Au content is much higher within fault gouges rather than within fresh quartz veins. This may represent that gold might have been reworked and reprecipitated by hydrothermal fluids in association with reactivation of the faults, and thus suggest that ore occurrence in this deposit is very complex and irregular and therefore more precise and systematic exploration is required.

Mineralogical Characterization of the Chuncheon Nephrite: Mineral Facies, Mineral Chemistry and Pyribole Structure (춘천 연옥 광물의 광물학적 특성 : 광물상, 광물 화학 및 혼성 격자 구조)

  • Noh, Jin Hwan;Cho, Hyen Goo
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.57-79
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    • 1993
  • Chuncheon nephrite, which was formed by the polymetasomatic alteration of dolomitic marble, can be classified into pale green, green, dark green, and grey types on the basis of their occurrence, mineralogical and textural characteristics. The nephrites consist obiefly of fibrous or hairlike(length/width ratio>10) cryptocrystalline(crystal width < $2{\mu}m$) tremolite, and include less amounts of micro-crystalline diopside, calcite, clinochlore, and sphene as impurities. The oriented and rather curved crystal aggregate, of nephritic tremolite are densely interwoven, resulting in a massive-fibrous texture which may explain the characteristic toughness of nephritic jade. The characteristic greenish color of the nephrite may be preferably related to Fe rather than Cr and Ni. However, the variation of color and tint in the Chuncheon nephrite also depends on the mineralogical and textural differences such as crystallinity, texture, and impurities. The chemical composition of the nephritic tremolite is not stoichiometric and rather dispersed especially in the abundances of Al, Mg, and Ca. Al content and Mg/Ca ratio for the nephritic tremolite are slightly increased with deepening in greenish color of the nephrite. Fe content in the nephritic tremolite is generally very low, but comparatively richer in the dark green nephrite. In nephritic tremolite, wide-chain pyriboles are irregularly intervened between normal double chains, forming a chain-width disorder. Most nephritic tremolites in the Chuncheon nephrite show various type of chain-width defects such as triple chain(jimthompsonite), quintuple chain (chesterite), or sometimes quadruple chain in HRTEM observations. The degree of chain-width disorder in the nephritic tremolite tends to increase with deepening in greenish color. Triple chain is the most common type, and quadruple chain is rarely observed only in the grey nephrite. The presence of pyribole structure in the nephritic tremolite is closely related to the increase of Al content and Mg/Ca ratio, a rather dispersive chemical composition, a decrease of relative intensity in (001) XRD reflection, and an increase in b axis dimension of unit cell. In addition, the degree and variation of chain-width disorder with nephrite types may support that an increase of metastability was formed by a rapid diffusion of Mg-rich fluid during the nephrite formation.

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Basic Study on the Development of Analytical Instrument for Liquid Pig Manure Component Using Near Infra-Red Spectroscopy (근적외선 분광법을 이용한 돈분뇨 액비 성분분석기 개발을 위한 기초 연구)

  • Choi, D.Y.;Kwag, J.H.;Park, C.H.;Jeong, K.H.;Kim, J.H.;Song, J.I.;Yoo, Y.H.;Chung, M.S.;Yang, C.B.
    • Journal of Animal Environmental Science
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    • v.13 no.2
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    • pp.113-120
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    • 2007
  • This study was conducted to measure Nitrogen(N), Phosphate($P_2O_5$), Potassium ($K_2O$), Organic matter(OM) and Moisture content of liquid pig manure by Near Infrared Spectroscopy(NIRS) and to develop an alternative and analytical instrument which are used for measurement of N, $P_2O_5$, $K_2O$, OM, and Moisture contents for liquid pig manure. The liquid pig manure sample's transmittance spectra were measured with a NIRS in the wavelength range of 400 to 2,500 nm. Multiple linear regression and partial least square regression were used for calibrations. The correlation coefficient(RSQ) and standard error of calibration(SEC) obtained for nitrogen were 0.9190 and 2.1649, respectively. The RSQ for phosphate, potassium, organic matter and moisture contents were 0.9749, 0.5046, 0.9883 and 0.9777, and the SEC were 0.5019, 1.9252, 0.1180 and 0.0789, respectively. These results are indications of the rapid determination of components of liquid pig manure through the NIR analysis. The simple analytical instrument for liquid pig manure consisted of a tungsten halogen lamp for light source, a sample holder, a quartz cell, a SM 301 spectrometer for spectrum analyzer, a power supply, an electronics, a computer and a software. Results showed that the simple analytical instrument that was developed can approximately predict the phosphate, organic matter and moisture content of the liquid pig manure when compared to the analysis taken by NIRS. The low predictability value of potassium however, needs further investigation. Generally, the experiment proved that the simple analytical instrument was reliable, feasible and practical for analyzing liquid pig manure.

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Vertical Ozone Distribution over Seoul: Ozonesonde Measurements During June 6~9, 2003 (서울지역 연직 오존 분포: 2003년 6월 6~9일 오존존데 관측)

  • Hwang, Mi-Kyoung;Kim, Yoo-Keun;Oh, In-Bo;Song, Sang-Keun;Lim, Yun-Kyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.2
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    • pp.196-205
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    • 2008
  • Variability in vertical ozone and meteorological profiles was measured by 2Z electrochemical concentration cells (ECC) ozonesonde at Bangyi in Seoul ($37.52^{\circ}N$, $127.13^{\circ}E$) during June $6{\sim}9$, 2003 in odor to identify the vertical distribution of ozone and its relationship with the lower-atmospheric structure resulted in the high ozone concentrations near the surface. The eight profiles obtained in the early morning and the late afternoon during the study period clearly showed that the substantial change of ozone concentrations in lower atmosphere(${\sim}5\;km$), indicating that it is tightly coupled to the variation of the planetary boundary layer (PBL) structure as well as the background synoptic flow. All profiles observed early in the morning showed very low ozone concentrations near the surface with strong vertical gradients in the nocturnal stable boundary layer due to the photochemical ozone loss caused by surface NO titration under very weak vertical mixing. On the other hand, relatively uniform ozone profiles in the developed mixing layer and the ozone peaks in the upper PBL, were observed in the late afternoon. It was noted that a significant increase in ozone concentrations in the lower atmosphere occurred with the corresponding decrease of the mixing height in the late afternoon on June 8. Ozone in upper layer did not vertically vary much compared to that in PBL but changed significantly on June 6 that was closely associated with the variation of synoptic flows. Interestingly, heavily polluted ozone layers aloft (a maximum value of 115 ppb around 2 km) were formed early in the morning on 6 through 7 June under dominant westerly synoptic flows. This indicates the effects of the transport of pollutants on regional scale and consequently can give a rise to increase the surface ozone concentration by downward mixing processes enhanced in the afternoon.

Hidden Porphyry-Related Ore Potential of the Geumseong Mo Deposit and Its Genetic Environment (금성 몰리브데늄광상의 잠두 반암형 광체에 대한 부존가능성과 성인적 환경)

  • Choi, Seon-Gyu;Park, Jung-Woo;Seo, Ji-Eun;Kim, Chang-Seong;Shin, Jong-Ki;Kim, Nam-Hyuck;Yoo, In-Kol;Lee, Ji-Yun;Ahn, Yong-Hwan
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.1-14
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    • 2007
  • The Guemseong mine is located near the southern margin of the Jurassic Jecheon granitoids collectively with the Cambro-Ordovician mixed dolostone-limestone series of the Yeongweol Group, Choseon Supergroup. Here, two spatially distinct types of skarn formation have been observed. The upper transitional skarn is the calcic Mo skarn which has the mineral assemblage of $garnet+hedenbergite+epidote{\pm}wollastonite{\pm}magnetite{\pm}hematite{\pm}amphibole{\pm}chlorite{\pm}vesuvianite$ within the calcite marble. On the other hand, the lower proximal skarn occurs as a discordant magnesian Fe skarn at the contact of Mo-bearing aplitic cupolas with unidirectional solidification texture(UST) within the dolomitic marble. The magnesian Fe skarn has the mineral assemlage $olivine+diopside+magnetite+tremolite+serpentine+talc+chlorite{\pm}phlogopite$. The formation of two different types of skarn and ore mineralization in Geumseong mine have been attributed to multistage and complex metasomatic replacements that ultimately resulted in silicate-oxide-sulfide sequence of metasomatism. An early prograde stage with anhydrous skarn minerals such as olivine, clinopyroxene and/or garnet with magnetite, formed from high temperature (about $500^{\circ}\;to\;400^{\circ}C$) at an environmental condition of low $CO_2$ fugacity ($XCO_2<0.1$) and 0.5 kbar. The later retrograde stage with hydrous silicates such as amphibole, serpentine, phlogopite, epidote and chlorite with molybdenite or hematite, termed from relatively lower temperature (about $400^{\circ}\;to\;300^{\circ}C$).