• Economic and Environmental Geology
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• v.25 no.3
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• pp.233-243
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• 1992

Ore mineralization of the Hwanghak copper deposit in the Ogsan area occurred in three stages of quartz (stage I and II) and calcite (stage III) veining along fissures in Early Cretaceous sedimentary rocks. Ore minerals are pyrite, pyrrhotite, chalcopyrite (dominant), sphalerite, hematite, galena, and Ag-, Pb-, and Bi-sulfosalts. These were deposited during the first stage at temperatures between $370^{\circ}C$ and < $200^{\circ}C$ from fluids with salinities between 0.5 and 7.6 equiv. wt. % NaCl. There is evidence of boiling and this suggests pressures of less than 180 bars during the first stage. Equilibrium thermodynamic interpretation accompanying with mineral paragenesis and fluid inclusion data indicates that copper precipitation in the hydrothermal system occurred due to cooling and changing in chemical conditions ($fs_2$, $fo_2$, pH). Gradual temperature decrease from $350^{\circ}$ to $250^{\circ}C$ of ore fluids by boiling and mixing with less-evolved meteoric waters mainly led to copper deposition through destabilization of copper chloride complexes. Sulfur isotope values of sulfide minerals decrease systematically with paragenetic time from calculated ${\delta}^{34}S_{H_2S}$ values of 8.2 to 4.7‰. These values, together with the observed change from sulfide-only to sulfide-hematite assemblages and fluid inclusion data, suggest progressively more oxidizing conditions, with a corresponding increase of the $sulfate/H_2S$ ratio of hydrothermal fluids. Measured and calculated hydrogen and oxygen isotope valutls of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.75-84
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• 2021

In this study, the correlation between cement quality(chemical composition, mineral composition, and compressive strength) and amount of waste alternative fuels used in the cement manufacturing process and was investigated. Cement manufacturing facility using coal, soft plastics(plastics that are easily scattered by wind power, such as vinyls), hard plastics(plastics that do not contain foreign substances, waste rubber, PP, etc.) and reclaimed oil was analised. Data was collected for 3 years from 2017 to 2019 and let the amount of fuels used as an independent variable and cement quality data as a dependent variable. As a result, depending on the type and quality of the alternative fuel has not a significant effect on the chemical composition(Cl and LSF) and mineral composition(f-CaO, C3S contents). Contrary to the concern that the compressive strength of cement would decrease, there was a significant positive correlation between amount of alternative fuel used and cement compressive strength.

• Resources Recycling
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• v.30 no.4
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• pp.11-19
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• 2021

Arsenic (As) oxidation followed by precipitation from a high-As(III)-containing leaching solution derived from a sulfidic ore was investigated in this study to remove aqueous As from the solution using activated carbon (AC) with air injection as an oxidant. To obtain the initial leaching solution, a domestic sulfidic ore was leached in a sulfuric acid solution at pH 1 and 50℃ for 95 h, and approximately 7 g/L of Fe and 3 g/L of As were leached out. To determine the effect of the oxidative reaction utilizing AC with air injection, the leaching solution was tested under the following five oxidative conditions at an initial pH of 1 and 90℃ for 72 h: air-only injection; air injection with 1, 5, and 10 w/v% of AC addition; and H₂O₂ addition. The tests in the presence of both air and AC revealed that the oxidation kinetics and As removal were improved by the reaction between the metallic species and the surface group formed on the AC surface. In addition, the greater the amount of AC added, the better was the reaction efficiency, removing 93-94% of As with more than 5 w/v% of AC addition. Finally, X-ray diffraction analysis confirmed that the precipitate formed from the oxidative reaction was scorodite (FeAsO₄·2H₂O).

• Economic and Environmental Geology
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• v.56 no.4
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• pp.475-499
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• 2023

To infer the provenance of raw iron materials utilized in iron production at the archaeological sites in Gyeongsang province, petrographic and geochemical analyses were conducted for smelting samples and major iron ores sourced from ore deposits. The smelting samples excavated from various iron archaeological sites were classified into different types according to their refining processes, such as iron bloom, iron bloom slag, pig iron, pig iron slag, forging iron flake, smithery iron, iron flake, and arrowhead. These samples exhibited discernable differences in their mineralogical components and texture. The enrichments of major elements such as aluminum and calcium in silicate minerals of the residual slags and the high contents of trace elements such as nickel and copper in some iron-making relics reflect the characteristics of raw iron ores, and thus can be regarded as potential indicators for inferring the provenance of source materials. In particular, the compositional ranges of Pb-Sr isotope ratios for the iron smelting samples were classified into three categories: 1) those exhibiting similar ratios to those of the raw iron ores, 2) those enriched in strontium isotope ratio, and 3) those enriched in both lead and strontium isotope ratios. The observed distinct Pb-Sr isotope characteristics in the iron smelting samples suggest the potential contribution of specific additives being introduced during the high-temperature refining process. These results provide a new perspective on the interpretation of the provenance study of the iron archaeological samples in Gyeongsang province, particularly in terms of the potential contribution of additives on the refining process.

• Journal of The Korean Association For Science Education
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• v.29 no.1
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• pp.116-136
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• 2009

Since there are differences in the content, structure and functions of interpersonal communication during the practice of school science classes, it needs to articulate the difference of the modality of pedagogical practice in order to understand science teaching in detail. These characteristics of science teaching can be investigated by further insightful analysis on language in the science classroom. In this study, classroom discourse language codes using Bernstein's code theory were analyzed in the case of a middle school science class on the unit of minerals. The discourse language code was identified by the value of classification, which revealed power relations to the contexts of discourse and participants of discourse. It was also identified by the value of framing, which showed hierarchical relation between teacher and students as discourse subjects, and discursive control on the initiative of discourse. The results addressed that six types of discourse language codes were constructed and that those language codes reflected diverse modalities of science teaching from student-centered instruction to teacher-centered instruction in relation to classroom discourse. The modality of science teaching according to the transition tendencies of discourse language code showed dynamic variations of 'controlled student-centeredness inducing teaching' - 'positional student-centeredness permissive teaching' - 'controlled students' participation permissive teaching' - 'controlled student-centeredness facilitative teaching' - 'student-centeredness enhancing teaching'. In addition, results released that discursively and hierarchically weak control of discourse is necessary for enhancing student-centeredness of science teaching. Moreover, teaching practice enhancing student-centeredness can be accomplished by the harmony of a teacher's perception of discourse language code and his/her orientation to constructivist teaching and student-centered teaching.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05d
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• pp.113-118
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• 2003

투어멀린(Tourmaline)은 비대칭 쌍극자를 가진 천연 유극성 결정체로 광물 중에서 영구전기분극을 띄고 있는 유일한 물질로써 일명 "전기석"이라고 알려져 있다. 분극에 의한 자체 미약전류(약 $60{\mu}A$)와 함께 음이온 및 원적외선의 발생으로 최근 우리주변에서 건강과 환경을 위한 관심고조의 대상인 육방정계의 압전성 및 초전성을 띄는 붕규산염(주요성분: Mg, Fe, B, Si, Ca)으로, 투어멀린 원석이나 그 복합세라믹체의 면역지수가 ~1000에서 ~400,000 이상인 점을 비롯하여 그 유용성을 이용하려는 새로운 아이디어 신상품들이 계속 개발되고 있다. 뿐만 아니라 물분자를 만나면 수소$(H^+)$와 수산기 $(OH^-)$로 전기분해 하여 친수기와 소수기 부분으로 구분하며, $H^+$와 $OH^-$는 각각 $H_2O$와 결합하여 활성이 강한 hydronium ion$(H_3O^+)$을 생성하고, 물 속에서 계속 불안정한 상태로 존재하는 수산기는 계면활성 작용이 있는 hydroxyl ion$(H_3O_2^-)$을 형성하여 물을 약 알카리성 (pH~7.4)으로 바꿔주며, 물분자 클러스터 세분화와 미네랄을 용출, 공급하여 이 물이 체내에 흡수되면 살균, 항균성의 면역기능을 갖게 되며, 혈액정화 기능과 자율신경 자극으로 교감신경의 흥분을 억제해 준다. 이와 함께 전기분극을 띈 투어멀린 입자는 다른 물질에 비하여 경이적 수치의 원적외선을 발생하여 강력한 열 효과와 높은 침투력으로 인체의 혈액순환 촉진과 혈전용해 작용을 주어 건강과 활력에 도움을 주는 것으로 확인되어 많은 관심을 끌고 있다. 따라서 유익한 이용가치를 인정받고 있는 천연 투어멀린을 단독 형태나 또는 서로 상승효과를 줄 수 있는 유용한 타 물질과 혼합물을 구성하여 성형 또는 EPD 방법으로 전착한 후 소결 처리하여, 소결체의 특성 분석과 함께 물에 대한 전기 화학적 작용 및 항균 효과를 조사, 확인하여 수질개선 효과를 분석하고 그 응용성을 개발, 확보하였다.

• Journal of Periodontal and Implant Science
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• v.33 no.4
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• pp.729-738
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• 2003

Nicotine is one of the major components of cigarette smoking which causes various systemic and local diseases to human body. The purpose of the present study was to investigate the effects of nicotine on bone mineralization in human fetal osteoblasts cell line(hFOB1). To compare the alkaline ph-osphatase(ALP) synthesis, hFOBl were cultured with DMEM/F-12 1:1 Mixture and 100 pg/ml, 1 ng/ml, 10 ng/ml, 100 ng/ml, 1 ${\mu}g$/ml, 10 ${\mu}g$/ml, 100 ${\mu}g$/ml of nicotine. And to compare the calcium accumulation, hFOB1 cultured for 23 days were quantified and photographed. ALP activity of hFOB1 exposed to nicotine was not significantly changed at a lower concentrations of nicotine, but was significantly decreased at a higher concentrations (10 ${\mu}g$/ml, 100 ${\mu}g$/ml) of nicotine (p<0.05). A quantified calcium acculation in hFOB1 was significantly decreased at 1,10, and 100${\mu}g$/ml of nicotine (p<0.05). Significantly decreased calcium deposition was observed at 1, 10, and 100${\mu}$/ml of nicotine. These results indicate that a higher concentration of nicotine show a negative effects on mineralization of hFOB1.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.778-781
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• 2003

투어멀린(Tourmaline)은 비대칭 쌍극자를 가진 유극성 결정체로 광물 중에서 영구적으로 전기분극의 특성을 띄고 있는 유일한 물질로써 일명 "전기석"이라고 알려져 있고, 자체의 미약전류(약 0,06mA)와 함께 음이온 및 원적외선의 발생으로 최근 들어 우리 주변에서 건강과 환경을 위한 관심고조의 대상인 육방정계의 압전성 및 초전성을 띄는 붕규산염(주요성분: Mg, Fe, B, Si, Ca)으로, 원석(면역지수 ~1000)에 비해 수백 배의 효력이 있는 투어말린 세라믹(면역지수 ~418,000)을 비롯하여 이것을 이용한 새로운 아이디어 신상품들이 계속 개발되고 있다. 뿐만 아니라, 물분자를 만나면 수소(H$^{+}$)와 수산기(OH$^{-}$)로 전기분해하여 친수기와 소수기 부분으로 구분하며, H$^{+}$와 OH$^{-}$는 각각 $H_2O$와 결합하여 활성이 강한 hydronium ion(H$_3$O$^{+}$ 과 계면활성 작용이 있는 hydroxyl ion(H$_3$O$_2$$^{-}$)을 생성하며, 물속에서 계속 불안정한 상태로 존재하는 수산기는 hydroxyl (-)ion을 형성하여 약 알카리성(pH~7.4)을 띄고 물의 클러스터 세분화와 미네랄을 공급해 줌으로 체내에 들어오면 살균, 항균능력이 있는 면역기능을 갖게 되며, 혈액을 정화하고 자율신경을 자극하여 교감신경의 흥분을 억제한. 이와 함께 전기분극을 띈 투어멀린 입자는 다른 물질에 비하여 경이적 수치의 원적외선을 발생하여 강력한 열 효과와 높은 침투력으로 인체의 혈액순환 촉진과 혈전용해 작용으로 건강과 활력에 도움을 주는 것으로 확인되어 많은 관심을 끌고 있다. 따라서 유익한 이용가치를 인정받고 있는 투어멀린을 유용한 타 물질과 혼합물을 구성하여 성형 또는 EPD 전착하여 소결한 뒤, 소결체의 특성을 분석하여 그 응용성을 개발, 확보하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.207-211
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• 2011

하천공사의 매립 및 준설 시 뿐만 아니라 최근에는 호우 시에도 발생하는 고농도 오탁수의 유출 확산으로 인하여 주변 수역의 수산자원 및 자연환경에 심각한 영향을 미치고 있다. 특히 유사는 하천과 호소에 유입되어 탁도를 증가시켜 수자원의 이용가치를 저하시키며, 박테리아나 각종 미생물의 이동 매개체가 되고 있다. 또한 퇴적된 유사는 유량이 증가하면 다시 침식되어 부유상태가 되며 이때에 영양염류나 독성물질이 재용출 되기도 하는 등 하천의 물리 및 토양환경의 장 단기적인 변화를 유발하는 원인이 된다. 결국 유사는 다양한 방식으로 하천과 호소의 생태환경에 큰 변화를 초래한다. 부유토사의 발생 가능한 피해의 범위와 정도는 유역의 부유토사 발생율과 하천, 호소 퇴적물의 성분종류와 입도분포, 그리고 유속에 따라 결정된다. 따라서 탁수의 영향범위를 예측하고, 악영향이 예측될 경우에는 탁도를 저하시킬 수 있는 오탁물질의 저하기법을 적용하여 그 대책을 수립하여야 한다. 현재 정부가 역점을 두고 있는 4대강 살리기 사업 중 하나인 하천 준설 사업 시 발생되는 고농도 오탁수는 주변 수역의 수자원 및 자연환경에 심각한 영향을 미치므로 자연환경의 보존, 해양자원을 보호하기 위하여 오탁물질의 제어가 반드시 필요한 실정이다. 기존의 오탁 저감시설이나 방법의 경우 오탁물질의 확산을 제어하는데 한계가 있고 오탁물질의 종류와 관계없이 일률적으로 시공함으로서 오탁제어 효과가 의문 시 되고 있다. 이러한 문제점을 개선하기 위하여 오탁물질의 확산 범위를 줄이고 침강효율을 높이는 방법을 찾아 오탁확산 제어 효율을 개선할 필요가 있다. 본 연구에서는 오탁물질 제어 시 2차 응집물로 인한 오염이 발생하는 않는 천연광물 제올라이트를 이용한 실내실험을 통하여 고농도 탁수의 탁도 저감효율을 파악하여 고농도 탁수의 탁도 저감에 대한 제올라이트의 적용 가능성을 살펴보았다. 4대강 살리기 사업 중인 OO강 OO공구의 OO보 현장에서 하천 준설 시 발생하는 고농도 탁수를 이온을 첨가한 제올라이트를 이용하여 확산제어에 관한 효과를 검토한 결과 2,000NTU 정도의 고농도로 유하하는 탁수에 대하여 제올라이트 혼합 후 20분이 경과한 시점에 제거효율이 90%이상으로 제올라이트의 탁수저감 효과가 대단히 크다는 것을 알 수 있었다.

• Geophysics and Geophysical Exploration
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• v.1 no.2
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• pp.110-115
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• 1998

Self-potential, VLF-EM and dipole-dipole resistivity methods have been widely used for exploration of conductive sulfide ore deposit, because of the convenience and low cost of field work and the reliability of their results. The geophysical responses for vein-type sulfide outcrop of Changkoom mine located in Bukwi-Myon, Jinan-Gun, Chollabuk-Do were investigated and compared with its drilling results. The geology around the survey area is composed of acidic volcanics and sediments of Yuchon Group. And sulfides bearing pyrite, pyrrotite, galena etc. are deposited in disseminated or vein type within acidic volcanics. Typical geophysical responses were detected from the above vein type ore body, respectively. From the shape and extent of S.P. anomaly, ore body is dipping westward and extending about 50 m. It is detected that the VLF EM response matching the outline of ore zone is considered as indication of dyke dipping westward. And also resistivity response indicating conductive dipping dyke is detected. From drilling results for outcrop and geophysical anomalies, the shape of ore body is vein type dipping about $70^{\circ}W$ and extending about 50 m.