• Title/Summary/Keyword: 광감도

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Extraction-Spectrophotometric Determination of Cimetidine in Pharmaceutical Samples as an Ion Pair with Bromothymol Blue (티몰블루와 함께 이온쌍으로서 약제 샘플에서 시메티딘의 추출-분광광도 측정)

  • Zargar, B.;Pourreza, N.;Shahrouz, M.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.46-49
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    • 2011
  • A highly sensitive and selective extraction-spectrophotometric method has been developed for determination of trace amounts of cimetidine. This method is based on the extraction of cimetidine as an ion pair with bromothymol blue (BTB) into chloroform and measuring its absorbance at 417 nm. The effect of different variables such as pH, concentration of BTB, volume of chloroform and shaking time was investigated. The effect of interfering ions on the extraction was also studied. The calibration curve was linear in the range of 0.25-8 ${\mu}gmL^{-1}$ with correlation coefficient of 0.9997. The detection limit based on 3Sb was 0.14 ${\mu}gmL^{-1}$ and relative standard deviation for 10 replicated measurements of 1.0 and 4.0 ${\mu}gmL^{-1}$ of cimetidine was 3.2 and 1.49%, respectively. The proposed method was applied to the determination of cimetidine in pharmaceutical samples with good recoveries.

저압 광산란 입자측정센서 개발 및 성능 평가

  • Mun, Ji-Hun;U, Dae-Gwang;Kim, Myeong-Jun;Yun, Jin-Uk;Jeong, Hyeok;Gwon, Yong-Taek;Gang, Sang-U;Yun, Ju-Yeong;Sin, Yong-Hyeon;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.327-327
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    • 2010
  • 디스플레이 및 반도체 산업이 발전함에 따라 회로의 선폭이 점차 줄어들고 있으며, 이에 따라서 대표적인 오염원이 되는 오염입자의 임계 직경(critical diameter) 또한 작아지고 있다. 현재 반도체 및 디스플레이 산업에서 사용되는 측정방법은 레이저를 이용하여 공정 후 표면에 남아 있는 오염입자를 측정하는 ex-situ 방법이 주를 이루고 있다. Ex-situ 방법을 이용한 오염입자의 제어는 웨이퍼 전체를 측정할 수 없을 뿐만 아니라 실시간 측정이 불가능하기 때문에 공정 모니터링 장비로 사용이 어려우며 오염입자와 공정 간의 상관관계 파악에도 많은 제약이 따르게 된다. 이에 따라 저압에서 in-situ 방법을 이용한 실시간 오염입자 측정 기술 개발이 요구되고 있다. 본 연구에서는 저압 환경에서 실시간으로 입자를 모니터링 할 수 있는 장비를 입자의 광산란 원리를 이용하여 개발하였다. 빛이 입자에 조사되면 크게 산란 및 흡수현상이 일어나게 되는데, 이 때 발생하는 산란광은 입자의 크기와 관계가 있으며 Mie 이론으로 널리 알려져 있다. 현재 이를 이용한 연구가 국내 및 국외에서 진행되고 있다. 수 백 nm 대의 입자를 측정하기 위해서는 빛의 강도가일정 수준 이상 되어야 하며, 이를 측정할 수 있는 수신부의 감도 또한 중요하다. 본 연구에서는 빛의 직경을 100 um 이하까지 집속할 수 있는 광학계를 상용 프로그램을 이용하여 설계하였으며, 강도가 약한 산란광 측정을 위하여 노이즈 제거 필터링 기술 등이 적용된 수신부 센서를 개발하여 전체 시스템에 적용하였다. 교정은 상압과 저압에서 수행 하였으며 약 5%의 측정효율로 최소 300 nm 이하의 입자까지 측정이 가능함을 확인 하였다. 또한, 타사의 실시간 입자 측정 센서와의 비교 실험을 통하여 성능평가를 수행하였다. 기존 광산란 방식 센서보다 높은 성능의 센서를 개발하기 위하여 추후 연구를 진행할 계획이며, 약 200 nm 이하의 입자까지 측정이 가능할 것으로 기대된다.

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Diffraction Characteristics for Optical Bio-Sensor of Bi-level Grating with Mushroom Profile (버섯형 이중 격자구조의 광 바이오센서에 대한 회절 특성)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.22 no.2
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    • pp.129-134
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    • 2022
  • The resonant bio-sensor of bi-level grating structure with mushroom profile has been designed for operating in the near-infrared (NIR) wavelength range under transverse electric (TE) polarization. The rigorous modal transmission-line theory (MTLT) is applied to determine the optical characteristics, and the reflection resonance of the grating structure is analyzed by varying their geometrical parameters. The numerical result shows that an excited sharp Fano resonance (FR), which does not occur in single layer grating, is demonstrated. The relationship between structure parameters of bi-level grating and the reflectance spectrum in order to guarantee the appearance of FR in the designed structure is fully investigated. An optical bio-sensor with a potential sensitivity of 112.9~214.3 deg/RIU and 447 nm/RIU is designed based on the proposed structure. The proposed mushroom profile may serve as a powerful sample for the design of optical bio-sensors with a wide range of applications.

A study on the changes of the noise reception sensitivity in the optical system (광시스템의 잡음에 따른 수신감도 변화에 관한 연구)

  • Ra, Yoo-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.677-682
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    • 2015
  • In this paper, we investigated the effect of light on the performance of the receiver system noise and external noise added from the ever-present influence in general optical system. And calculated the reception sensitivity of the receiver at the time of off-keying transmission - from the optical transmission system in consideration of the case that the photo detector has a quantum yield of less than one-one. Not less than 50 it was confirmed that it is possible to configure the low power system is calculated and compared with the case where less than 300 the receiver sensitivity of the optical system to maintain the standard error probability. However, even if these values were considered, and the preamplifier in the receiver, considering a case of using a low-output light source, so that a heavy burden in the value less than the actual system installation, using the light source having less than the output, as shown in Figure 3, the results that were obtained also may be used.

Fabrication and characterization of CdS photoconductive cell by the print/sintering method (인쇄/소결 방법에 의한 CdS 광전도 셀 제작과 특성)

  • Jeong, Tae-Soo;Kim, Taek-Sung;Jeong, Cheol-Hoon;Lee, Hoon;Shin, Yeong-Jin;Hong, Kwang-Joon;Yu, Pyeong-Yeol
    • Journal of Sensor Science and Technology
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    • v.7 no.5
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    • pp.350-355
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    • 1998
  • We fabricated a photoconductive cell made of polycrystalline CdS thick film which has high photo-sensitivity using a print/sintering method. The resultant grain size is about $4\;{\mu}m$. When $CuCl_2$ of 0.06 to 0.12 mg is added, the sensitivity and the ratio of photocurrent to dark current are 0.8 and $10^5$, respectively. The response wavelength is 511 nm. The rise and decay response times are 50 and 20 ms, respectively. In addition, the maximum power dissipation is beyond 80mW. We noticed that the addition of $CuCl_2$ between 0.06 and 0.12 mg to 1g of CdS results in a reliable formation of photoconductive sensor.

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Design and Implementation of Radio Sensor Receiver for Measuring the Position of the Sun (태양 위치 측정용 전파 센서 수신기의 설계 및 제작)

  • Park, Jin-Woo;Choi, Yeon-Ung;Cho, Hong-Lyul;Son, Hong-Min
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.9
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    • pp.943-953
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    • 2009
  • In this paper, we propose a radio sensor to measure the position of the sun for the solar tracker of a photovoltaic system. In order to satisfy the requirement for the measurement accuracy within ${\pm}5^{\circ}$, the sensor receiver with high gain, high sensitivity and wide bandwidth is designed and implemented. The receiver has the bandwidth of 104 MHz, the system gain of 69 dB and the sensitivity of 0.46 K at 5.1 GHz. The processes of design and implementation of the radio sensor receiver are described in this paper. The effectiveness of the proposed radio sensor in the measurement of the position of the sun is demonstrated experimentally under the condition of cloud cover. The results show the radio sensor can measure the position of the sun within the accuracy of ${\pm}4^{\circ}$ successfully.

An Integrated Mach-Zehnder Interferometric Sensor based on Rib Waveguides (Rib 도파로 기반 집적 마흐젠더 간섭계 센서)

  • Choo, Sung-Joong;Park, Jung-Ho;Shin, Hyun-Joon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.4
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    • pp.20-25
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    • 2010
  • An integrated Mach-Zehnder interferometric sensor operating at 632.8 nm was designed and fabricated by the technology of planar rib waveguides. Rib waveguide based on silica system ($SiO_2-SiO_xN_y-SiO_2$) was geometrically designed to have single mode operation and high sensitivity. It was structured by semiconductor fabrication processes such as thin film deposition, photolithography, and RIE (Reactive Ion Etching). With the power observation, propagation loss measurement by cut-back method showed about 4.82 dB/cm for rib waveguides. Additionally the chromium mask process for an etch stop was employed to solve the core damaging problem in patterning the sensing zone on the chip. Refractive index measurement of water/ethanol mixture with this device finally showed a sensitivity of about $\pi$/($4.04{\times}10^{-3}$).

Development and Properties of Carbon monoxide Detector for Ambient Air monitoring (대기오염 측정용 일신화 탄소 검출기의 제작 및 특성)

  • Cho, Kyung-Haeng;Lee, Sang-Wha;Lee, Joung-Hae;Choi, Kyong-Sik
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.222-228
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    • 2000
  • A detector for monitoring carbon monoxide (CO) in ambient air by nondispersive infrared (NDIR) spectroscopy has been developed and investigated its sensitivity and stability. The essential parts of the absorption cell are three spherical concave mirrors so as to improve the sensitivity by increasing the light path length in the cell. The radius and center of curvature of mirrors and position in the cell was calculated by computer simulation in order that the light path length may be 16m into the 50cm cell. The number of traversals and optical path properties were confirmed by laser beam alignment in transparent absorption cell. The photoconductive type lead selenide (PbSe) was used as CO sensing material, which was cooled to increase the responsibility by thermoelectric cooling method. The detection limit and span drift of the developed CO detector was 0.24ppm and 0.03ppm(v/v) respectively.

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A Study on the Characteristics Analysis and Design of High Sensitivity Silicon Photodiode for Laser Detector (레이저 검출용 고감도 실리콘 포토다이오드 제조 및 특성 분석에 관한 연구)

  • Lee, Jun-Myung;Kang, Eun-Young;Park, Keon-Jun;Kim, Yong-Kab
    • The Journal of the Korea institute of electronic communication sciences
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    • v.9 no.5
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    • pp.555-560
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    • 2014
  • In order to improve spectrum sensitivity of photodiode for detection of the laser wavelength at 850 nm ~ 1000 nm of near-infrared band, this study has produced silicon-based photodiode whose area is $5000{\mu}m{\times}2000{\mu}m$, and the thickness is $280{\mu}m$. It was packed by the TO-5 type. The electrical properties of the dark currents have valued of approximately 0.1 nA for 5 V reverse bias, while the capacitance showed 32.5 pF at frequency range of 1 kHz and about 32.4 pF at the range of 200 kHz for 0 V. In addition, the rising time of output signal was as fast response as 20.92 ns for 10V. For the optical properties, the best spectrum sensitivity was 0.57 A/W for 890 nm, while it was relatively excellent value of 0.37 A/W for 1,000 nm. Over all, there were good spectrum sensitivity for this diode over the range of 870 ~ 920 nm.

Improvement of Received Optical Power Sensitivity in Asymmetric 2.5Gbps/1.2Gbps Passive Optical Network with Inverse Return to Zero(RZ) coded Downstream and NRZ upstream re-modulation (역 RZ 부호로 코딩된 하향신호의 재변조를 이용한 비대칭 2.5Gbps/622Mbps 수동 광가입자 망에서의 수신 감도의 개선)

  • Park, Sang-Jo
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.3
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    • pp.65-72
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    • 2010
  • We propose the asymmetric 2.5Gbps/622Mbps PON(Passive Optical Network) in order to reduce the bandwith of filter at receiver with inverse RZ(Return to Zero) code coded downstream and NRZ(Non Return to Zero) upstream re-modulation. I theoretically analyze BER(Bit Error Rate) performance and the power sensitivity with the optimal threshold level by performing simulation with MATLAB according to the types of downstream data. The results have shown that the optimal threshold level at the optical receiver could be saturated at 0.33 as the optical received power increase more than -26dBm to keep $10^{-12}$ of BER to a minimum. Also the power sensitivity is more improved by about 3dB by fixing the threshold level at 0.33 than the conventional receiver. The proposed system can be a useful technology for optical access networks with asymmetric upstream and downstream data rates because the optical receiver can be used without controlling threshold levels and that does not require a light source in optical network unit (ONU) and its control circuits in the optical line termination (OLT).