• Journal of the Korean Chemical Society
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• v.25 no.6
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• pp.383-389
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• 1981

Thianthrene cation radical perchlorate reacts with N-arylsulfonamides such as p-toluenesulfonanilide, benzenesulfonanilide, N-(2-methylphenyl)benzenesulfonamide, and N-phenyl-p-toluenesulfonanilide to give 5-(p-N-p-toluenesulfonamidophenyl)-(1a), 5-(p-N-benzenesulfonamidophenyl)-(1b), 5-(4-N-benzenesulfonamido-3-methylphenyl)-(1c), and 5-(p-N-phenyl-N-p-toluenesulfonamidophenyl thianthrenium perchlorate (1d), respectively. In the meantime, 1d reacts further with thiathrene cation ratical to form diperchlorate(1e). The structure of 1a~1e is very similar to 5-(p-acetamidophenyl) thianthrenium perchlorate which has been obtained from the reaction with acetanilide. However, the discrepancy in the stoichiometry between two reactions indicates that the reaction with sulfonamide appears not to proceed with a single mechanism.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.6
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• pp.637-641
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• 2008

The aims of this research were to manufacture tailored powder activated carbon having a higher prechlorate removal efficiency and to compare perchlorate removal efficiency with different carbon materials for applying to the drinking water treatment plant. Activated carbon pre-loaded with cetyltrimethylammonium chloride(CTAC) has been researched to be an effective adsorbent for removing perchlorate in the water. 10,000 mg/L tailored powder activated carbon were manufactured by mixing 5.0 g of powder activated carbon(PAC) into 500 mL of 5,000 mg/L CTAC solution. The tailored powder activated carbon had 10 times higher perchlorate removal efficiency than virgin powder activated carbon. The residual perchlorate gradually decreased with the first 15 minute contact time with the tailored powder activated carbon, however, the longer contact time did not affect perchlorate removal. Tailored powder activated carbon by manufactured with 1,083 mg/g iodine value carbon had almost 4 times higher perchlarate removal efficiency than the 944 mg/g iodine value carbon. Dosage of 5 mg/L tailored powder activated carbon, which can adaptable dosage at the treatment plant, could decrease the perchlorate concentration from 50 $\mu$g/L to 15 $\mu$g/L.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.12
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• pp.1298-1304
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• 2005

This study was performed to evaluate the characteristics of the competition between two electron acceptors, perchlorate and nitrate, with Citrobacter Amalonaticus strain JB101. In addition, the applicability of membrane bioreactor(MBR) for perchlorate removal was evaluated. The maximum growth rate of strain JB101 on perchlorate and nitrate are 0.27 and 0.58 $hr^{-1}$, and maximum substrate utilization rates were 35.1 mg $ClO_4^-/g$ protein-day and 45.6 mg $NO_3^-/g$ protein-day, respectively. Nitrate was a competitive inhibitor for perchlorate, and strain JB101 prefer nitrate to perchlorate as electron acceptor. Complete removal of perchlorate could be achieved up to the surface leading rate of 4.6 g $ClO_4^-/m^2-day$ with the MBR fed with 20 mg $ClO_4^-/L$(HCMBR). When 5 mg/L of nitrate was added to the same influent, perchlorate removal efficiency decreased to 96.5%, while nitrate was completely removed. For the MBR fed with 0.7 mg/L of perchlorate (LCMBR), the maximum perchlorate removal efficiency was 100% up to the loading rate of 0.23 g $ClO_4^-/m^2-day$. Membrane fouling was found to be a problem at high leading rate for both MBRs. The acetate consumption ratio per perchlorate was $13.7{\sim}51.7\;e^-eq./e^-eq.$ in LCMBR, while the value was $2.5{\sim}3.6\;e^-eq./e^-eq.$ in HCMBR. This difference could be related to the acetate consumption with oxygen as electron acceptor. Therefore, the amount of acetate addition must be determined considering the concentrations of other electron acceptors in the influent.

• Journal of the Korean Chemical Society
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• v.25 no.3
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• pp.190-198
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• 1981

In contrast with pmr (only multiplets at ${\delta}6.6$∼7.8 ppm) spectrum of triphenyl-9-thioxanthenylphosphonium perchlorate and tri-o-methoxyphenyl-9-thioxanthenylphosphonium perchlorate, tri-n-butyl-9-thioxanthenylphosphonium perchlorate and tribenzyl-9-thioxanthenylphosphonium perchlorate showed a doublet at ${\delta}5.58$ and 5.70ppm, respectively, assigned to a methine proton. This value is slightly larger than the corresponding values (${\delta}5.05$~5.30) of 9-arylthioxanthenes but clearly differentiated from those of aromatic protons. This result implys that the downfield shift of a methine proton of triaryl-9-thioxanthenylphosphonium perchlorate is not due to inductive effects of an electron deficient phosphorus atom but paramagnetic deshielding effects by three aryl groups on phosphorus.

• Nuclear Engineering and Technology
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• v.12 no.2
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• pp.99-105
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• 1980

The distribution of $^{55}$ Mn and $^{38}$ Cl recoil species following radiative neutron capture in permanganates, chlorates and perchlorates has been investigated by using ion-exchange chromatography method. The whole of the $^{55}$ Mn radioactivity in permanganates appeared in two valence states, the $^{38}$ Cl radioactivity in chlorates in two valence states and also the $^{38}$ Cl radioactivity in perchlorates in three valence states. Recoil energy was calculated. The internal conversion of $^{38}$ Cl isomer transition affects the retention value. The greater the radii of the cation, the higher is the probability of the recoil atom breaking through the secondary cage. In ammonium salt, the ammonium ion behaves as a reducing agent. Crystal structures with their greater free space have shown low retention.

• Journal of the Korean Chemical Society
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• v.27 no.2
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• pp.142-149
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• 1983

Reaction of thianthrene cation radical perchlorate (1) with cumene (4), p-chlorocumene (2), and p-nitrocumene (3) hydroperoxides in acetonitrile at room temperature afforded, inter alia, thianthrene as a common product and 5-(4'-hydroxyphenyl) thianthrenium perchlorate (5) for 4, 5-(5'-chloro-2'-hydroxyphenyl) thianthrenium perchlorate (7) and 5-acetonylthianthrenium perchlorate (6) for 2 and 6 for 3, respectively. Stoichiometry of these reactions showed that 2 moles of 1 gave rise to 1mole of thianthrene and 1 mole of thianthrenium salt (or salts). Nucleophilic reactivity to 1 was found to be in the order of phenol > > p-chlorophenol ${\sim}$ acetone > > p-nitrophenol. Apart from acid-catalyzed heterolytic decomposition of hydroperoxides, small amount of homolytic decomposition products were found from 3 and 4.

• Analytical Science and Technology
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• v.26 no.1
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• pp.11-18
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• 2013

Perchlorate ($ClO{_4}^-$) is the material that is used as propellants of rockets and material of explosive as a form of ammonium perchlorate salts. Ammonium perchlorate solution of high concentration is recovered from expired rocket through demilitarization process by the water-jet method. If people take perchlorate in food and water, it interferes with adsorption of iodide which is the substance needed to synthesize thyroid hormone in the thyroid gland. It has an bad influence upon disturbing pregnancy and synthesis of growth hormone. So the effective method is necessary to remove perchlorate anion in water. By considering economic aspect, we studied effective desorption (regeneration) of perchlorate anion from adsorbent with studies on removal and adsorption of perchlorate anion. Desorption experiment was conducted as batch type. Depending on various conditions (concentration, pH, cation anion form) elution, we evaluated amount, efficiency of desorption(amount of adsorption/desorption ${\times}$ 100). Also, research confirmed the efficiency of mixed resins between anion exchange resin and activated carbon and expected synergic effect from advantages of both adsorbents.

• Journal of the Korean Chemical Society
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• v.24 no.1
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• pp.34-43
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• 1980

The reaction of thianthrene cation radical perchlorate with thioxanthene in acetonitrile gave thianthrene and dark reddish thioxanthylium ion instead of thioxanthene cation radical. Addition of aromatic nucleophiles such as anisole, aniline, N,N-diethylaniline, catechol, ethylbenzene, to the above mixture yielded the corresponding thioxanthenes with substituent at 9 position. Reactions with dibenzo-18-crown-6-ether, diphenylmercury, and triphenylphosphine gave similar products. However, reactions with aromatics with electron-withdrawing group were either too slow or inert to such a reaction.

• Journal of the Korean Chemical Society
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• v.26 no.2
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• pp.107-113
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• 1982

Addition of dimedone to thioxanthylium ion generated from the oxidation of thioxanthene by thianthrene cation radical perchlorate in acetonitrile gave 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthylium perchlorate (2), whereas from the reverse addition between two reactants was obtained initially 9-(4,4-dimethylcyclohexane-2,6-dionyl)thioxanthene (1), which then underwent further reaction to give 2. The compound 2 was readily deprotonated in aq acetone to give 9-(4,4-dimethylcyclohexane-2,6-dionylidene)thioxanthene (3). However, 3 turned out to be in equilibrium with 2 in which three isosbestic points at 219, 289, and 348 nm were recorded in aq acetonitrile. The intensity and the position of the maximum absorption of 3 near 380 nm vary depending on the solvents which has been explained in terms of the solvent-solute interactions.

• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.159-165
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• 2009

The synthesis of 2-amino-5-substituted-1,3,4-oxadiazoles 4 were carried out from the electrooxidation of semicarbazone 3 at the platinum electrode under controlled potential electrolysis in an undivided cell. This is an environmentally benign method in the field of synthetic organic chemistry. The non-aqueous solvents acetic acid and acetonitrile and a supporting electrolyte lithium perchlorate were used for the electrolysis in the electrooxidation. The products were structurally charecterised by IR, $^1H$-NMR, $^{13}C$-NMR and elemental analysis.