• Title/Summary/Keyword: 공중합

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Quality and Shelf-Life of Vacuum Packed RTE (Ready-To-Eat) Hamburg Steak Depending on the Oxygen Permeability of Packaging Material and the Storage Temperature (포장재의 산소투과도와 저장온도에 따른 즉석섭취형 햄버그스테이크의 품질 및 저장성)

  • Lim, Ji Hoon;Lee, Sung Ki;Chung, Seung Hee;Lee, Keun Taik
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.95-102
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    • 2016
  • This study investigated the effects of the oxygen permeability of vacuum packaging film and the storage temperature on the quality and shelf life of Hamburg steaks during storage for 14 days. Control samples (C) were packaged in a polyamide/polyethylene (PA/PE) film and stored at $5^{\circ}C$. Treatment samples were either packaged in an ethylene vinyl alcohol/polyethylene (EVOH/PE) copolymer film and stored at $5^{\circ}C$ (T1), and in a PA/PE film and stored at $-18^{\circ}C$ (T2). The initial total plate count (TPC) was 3.6 log cfu/g. In T1 samples, TPC and Brochothrix thermosphacta counts were increased, similar to those in C samples, whereas Pseudomonas spp. counts were significantly lower than those in C samples during storage. Over the storage period, the volatile basic nitrogen values increased most rapidly in C samples, followed by T1 and then T2 samples. The values of thiobarbituric acid reactive substances steadily increased in all samples during storage. The colour parameters were not significantly different among the samples during storage. T1 samples maintained sensory qualities in flavour and off-odour parameters for two days longer than C samples did. At day 12, T2 samples were evaluated as being below the marketability score of 5.0 for texture. In conclusion, using high oxygen barrier films like EVOH/PE copolymer for packaging Hamburg steaks could extend the sensory qualities in view of flavour and off-odour during chilled storage. However, frozen storage at $-18^{\circ}C$ is recommended when the storage period is extended beyond 14 days at $5^{\circ}C$.

Physical Properties of High-Solid Coatings with Acrylic Resins Containing Acetoacetoxy Group and Allophanate-Trimer (Acetoacetoxy기 함유 아크릴수지와 Allophanate-Trimer에 의한 하이솔리드 도료의 도막물성)

  • Jo Hye-Jin;Shim Il-Woo;Park Hong-Soo;Kim Seung-Jin;Kim Seong-Kil
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.230-237
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    • 2006
  • Copolymers(HSA-98-20, HSA-98-0, HSA-98+20) which we acrylic resin containing 80% solid content were synthesized by the reaction of monomers, including methyl methacrylate, n-butyl acrylate, and 2-hydroxyethyl acrylate with a functional monomer, acetoacetoxyethyl methacrylate (AAEM), which nay give improvements in cross-linking density and physical properties of films. The physical properties of prepared acrylic resins, containing AAEM, are as follows viscosities, $1420\sim5760cps$ ; number average molecular weight, $2080\sim2300g/mol$; polydispersity index, $2.07\sim2.19$ ; and conversions, $88\sim93%$. In the next step, high-solid coatings (HSA-98-20C, HSA-98-0C, HSA-98+20C) were prepared by the curing reaction between acrylic resins containing 80% solid content and isocyanate at room temperature. Various properties were examined on the film coated with the prepared high-solid coatings. The introduction of AAEM to the coatings enhanced the abrasion resistance and solvent resistance, which indicated the possible use of high- solid coatings for top-coating materials of automobile. Since the curing by viscoelastic measurement occurred in sequence of HSA-98+20C > HSA-98-0C > HSA-98-20C, it was concluded that the curing rates became faster with incresing $T_g$ values.

Preparation and Characterization of Random Copolymer Electrolyte Membranes Containing PFCB (Perfluorocyclobutane) Group (PFCB (Perfluorocyclobutane) Group을 포함한 랜덤 공중합체 고분자 전해질 막 제조 및 특성연구)

  • Kim Jeong-Hoon;Kim Dong-Jin;Chang Bong-Jun;Lee Soo-Bok;Joo Hyeok-Jong
    • Membrane Journal
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    • v.16 no.3
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    • pp.221-229
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    • 2006
  • This study is about the preparation and characterization of sulfonated random copolymer membranes containing perfluorocyclobutane (PFCB), fluorenyl, and sulfonyl units. The polymers were prepared through three synthetic steps, that is, the synthesis of a trofluorovinylether-terminated monomer, its thermal polymerization, and post-sulfonation using chlorosulfonic acid. A series of sulfonated random copolymers with different ion exchange capacity (IEC) were prepared by changing contents of fluorenyl uints in polymers with fixed molar ratio of chlorosulfonic acid during the post-sulfonation reaction. All the synthesized compounds were characterized by FT-lR, $^1H-NMR$, $^{19}F-NMR$, and Mass spectroscopy. As the content of sulfonated fluorenyl units increased, the IEC, water uptake, and ion conductivity of the sulfonated random copolymer membranes increased. The sulfonated random copolymer S-1 and S-2 showed higher values of ion conductivity than the Nafion-115 in a wide range of temperatures ($25{\sim}80^{\circ}C$).

Synthesis and Application of Sorbic Acid Grafted Hydrogenated Dicyclopentadiene Hydrocarbon Resin (소르빅산 변성 수소첨가 DCPD계 석유수지의 합성 및 응용)

  • Kong, Won Suk;Park, Jun Hyo;Yoon, Ho Gyu;Lee, Jae Wook
    • Journal of Adhesion and Interface
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    • v.16 no.1
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    • pp.29-34
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    • 2015
  • Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.

TACAN modulation generator for antenna purpose that precisely adjusts factor of modulation (변조도를 정밀하게 조정 하는 TACAN 안테나용 변조신호발생기)

  • Kim, Jong-Won;Son, Kyong-Sik;Lim, Jae-Hyun
    • Journal of Digital Convergence
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    • v.15 no.4
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    • pp.275-284
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    • 2017
  • TACAN(TACtical Air Navigation) was created to support military aircraft's short range navigation (200~300 mile). TACAN must fulfill a condition of MIL-STD-291C, the U.S. Military Standards, which addresses the sum of 15Hz and 135Hz should be within 55%, following the factor of modulations for both to be $21{\pm}9%$ each. Within the existing TACAN antenna, modulation factor for 15Hz and 135Hz are created differently depending on its diameter, wavelength, angle of gradient, internal modulation method or using frequency code. It brings up a problem where applications needed to be stopped and repaired when modulating signal exceeds the standard of MIL-STD-291C since the existing TACAN antenna does not have coordination function. Hence, plan and produce a modulating signal generator using FPGA, and check the changes in the modulation factor for 15HZ and 135Hz, depending on the values that have been set in each criteria. Moreover, allow the modulating signal generator to be automatically adjusted based on the monitoring signal emitted by antenna, and place alarm sound just in case if it exceeds the standard.

Study on the Silicone Contact Lens Using AA and BMA (AA(Acrylic acid)와 BMA(Butyl methacrylate)를 이용한 실리콘 콘택트렌즈에 관한 연구)

  • Kim, Tae-Hun;Yae, Ki-Hun;Kweon, Young-Seok;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.11 no.3
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    • pp.259-265
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    • 2006
  • We polymerized material of AA(Acrylic acid) and BMA(butyl methacrylate) to make up for the weak points of hydrogel contact lens. The synthesis process of silicone synthesis is as follows. Acrylate-PDMS(Polydimethylsiloxane)-Urethane prepolymer was composed after Diisocynate reacted with HEMA(2-hydroxyethylmethacrylate) under the catalyst and it reacted again with bis(hydroxyalkyl) terminated poly(dimethylsiloxane) with high oxygen transmissibility characteristics. HEMA(2-hydroxyethylmethacrylate) was used to make prepolymer that can be polymerized and the urethane was used to improve elasticity and oxygen transmissibility, copolymerization was performed with conventional hydrogel contact lens materials to make silicone hydrogel contact lens with higher oxygen transmissibility. For manufacturing of contact lens, We added BMA(Butyl methacrylate) with better elasticity and flexibility, and AA(Acrylic acid) with higher moisturizing to used contact lens materials. AIBN (Azobis2-methylpropionitrile) as initiator and EGDMA(Ethylene Glycol Dimethacrylat) as crosslinking agent were used and the lens with higher oxygen transmissibility and better moisturizing were manufactured complying with basic contact lens properties, which have several combination trial of each monomer characteristics. Compounding SN which included SILICONE, HEMA, NVP and EGDMA etc was showed by swelling ratio of 9.38% and water content of 23.7%. SN was showed by swelling ratio of 9.38%, water content of 23.7% and a visible ray transmissibility of 89%. SB which added BMA in the SN was showed by swelling ratio of 12.50%, water content of 18.56% and a visible ray transmissibility of 88%. SAB which added both AA and BMA in the SN was showed by swelling ratio of 8.33%, water content of 12.93% and a visible ray transmissibility of 88%.

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The Concentration of Indoor Air Quality and Correlations of Materials at Multiple-use Facilities in Gwangju (광주지역 다중이용시설에서 실내공기질 농도와 상관성 분석)

  • Lee, Dae-Haeng;Lee, Se-Haeng;Bae, Seok-Jin;Kim, Nan-Hee;Park, Kang-Soo;Kim, Do-Sool;Paik, Ke-Jin;Moon, Yong-Woon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1001-1010
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    • 2010
  • The purpose of this study is to investigate the concentration levels of particle materials ($PM_{10}$, asbestos), gas materials ($CO_2$, CO, $NO_2$, HCHO, Rn, VOCs) and total suspended colony (TSC), and the correlations among these materials in indoor air quality of 54 multiple-use facilities and 15 public-use facilities of Gwangju. The highest mean concentration of $PM_{10}$ was $69.2\;{\mu}g/m^3$ at indoor parking place, followed by childcare facilities, large commercial building and subway station building. The highest mean concentration of CO was 2.7 ppm at indoor parking place and that of $CO_2$ was 604.1 ppm at medical service facilities. The highest mean concentration of $NO_2$ was 0.036 ppm at indoor parking place. The geomean concentration of HCHO was $3.6\;{\mu}g/m^3$ in all facilities and the highest was $631.8\;{\mu}g/m^3$ at art gallery. The geomean concentration of VOCs (5 species) was $24.14\;{\mu}g/m^3$ in all facilities and toluene was the highest material of $15.30\;{\mu}g/m^3$, followed by xylene, ethylbenzene, benzene and styrene. The highest mean concentration of TSC was $625.3\;CFU/m^3$ at jjimjilbang, followed by childcare facilities, medical service facilities and large commercial building. The highest of asbestos was 0.0072 each/cc at childcare facilities and that of radon was 1.41 pCi/L at art gallery. PM10 showed positive correlations to TSC with $R^2\0.5332$ by lognormal equation at childcare facilities. CO2 showed positive correlations to CO at childcare facilities and indoor parking place. Lognormal equation fitted to the VOCs data more than normal equation in all facilities.

Isolation of Nontuberculous Mycobacteria by DNA Probe and Clinical Characteristics of Patients with NTM Pulmonary Disease (DNA probe를 이용한 비결핵항산균의 분리 및 폐질환자들의 임상적 특징)

  • Kim, Hee Kyoo;Kim, Yu Ri;Park, Jung Pil;Kim, Nang Hee;Ok, Chul Ho;Jung, Maan Hong;Jang, Tae Won;Jeong, Seok Hoon;Kim, Cheol Min;Park, Hee Kyung
    • Tuberculosis and Respiratory Diseases
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    • v.58 no.3
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    • pp.248-256
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    • 2005
  • Background : Nontuberculous mycobacterial (NTM) infections are increasingly being recognized as a cause of chronic pulmonary disease. This study describes the prevalence of NTM species from clinical specimens and the clinical characteristics of NTM pulmonary disease. Material and Methods : The NTM isolated from March 2003 to December 2003 at the Kosin Medical Center were identified using an oligonucleotide chip containing the internal transcribed space (ITS) sequence. The medical records of the patients with the NTM isolates, who fulfilled the 1997 ATS diagnostic criteria for NTM pulmonary disease, were analyzed, retrospectively. Results : Twenty four species (24.2%) of NTM were isolated from 99 cultured AFB specimens. M. avium complex (MAC) (13 isolates), M. szulgai (3), M. kansasii (2), M. malmoense (2), M. abscessus (1), M. chelonae (1), M. scrofulaceum (1), and unclassified (1). Of the 23 patients with isolated NTM, 11 patients were found to be compatible with a NTM pulmonary infection according to the ATS criteria; MAC was found in 6 cases (54.5%), M. szulgai in 2 cases (18.2%), and M. abscessus, M. szulgai, M. kansasii and M. malmoense in 1 case each (9.1%). Ten patients (91%) were male and the median age at diagnosis was 61 years. In the pre-existing diseases, malignant disease was found in 6 cases including 5 patients with lung cancer, and history of old pulmonary tuberculosis was identified in 4 cases. The radiological patterns showed lung destruction lung in 3 cases, a cavitary mass in 3 cases, a nodular pattern in 2 cases, and reticulonodular, consolidation and a bronchiectasis pattern were in 1 case each. Conclusion : Various types of NTM pulmonary diseases were found in a tertiary hospital at Busan, Korea. The NTM pulmonary diseases were caused by MAC, M. szugai, M. kansasii, M. malmoense, M. abscessus, M. chelonae, and M. scrofulaceum in the order of frequency.

The Purpose and background of this study (노인질환에 대한 한양방동시종합검진 결과에 대한 보고)

  • Gwon, Gyeong-Suk;Lee, Tae-Hwan;Song, Jeong-Mo;Kim, In-Seop;Yun, Ho-Yeong;Im, Jun-Gyu
    • The Journal of Korean Medicine
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    • v.15 no.2 s.28
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    • pp.9-27
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    • 1994
  • This study is to analyze of senile disease status and the social problem according to increased old ages, and then to find distributions of old man's diseases and health status efficiency of oriental-occidental contemporary health examination. And it is the first oriental-occidental contemporary health examination of old man performed by JeonJu Woosuk University Oriental Medicine Hospital and Woosuk-Clinic in nation. Methods The objects in this research are 641's old man of KimJe Gun's over 60's years performed medical examination at JeonJu Woosuk University Oriental- Mmedicine-Hospital and Woosuk-Clinic by oriental-occidental medical contemporary exam., from 1994, 24th June till 1994. 13th July. The 1st occident medical examination methods were consisted of chest x-ray check. blood and urine exam., measurement of blood pressure, visual power and audiometry. The Oriental medical examination methods were consisted of four diagnostics (望,聞,問,切), present illness. chief complaint, past history, families history, social history by question and SA Sang constitution test index. The results and conclusions The results and conclusions are the next: 1. In order of distribution. the athletic disease (75.8%),the digestive disease(43.4%), the circulatory disease(41.5%), the respiratory disease(22.3%), EENT disease(8.1%), the endocrinopathy(5.6%), and the genito-urinary disease(5.3%) are the results of the object about 641's old man, by the oriental-occidental medicine's contemporay exam. 2. Distribution of disease distiction are lumbago. gastritis and peptic ulcer. knee joint pain. heart disease. hypertension. chronic bronchitis. asthma. anemia. DM. Tbc. visual disturbance. CVA. etc in order. 3. Disease distribution according to age is almost high incident in 60-75years. Disease incidence is decreased except E.E.N.T disease in over 76years. 4. The relationships of disease and family history are: the 25.0% of CVA pts. has family history and the 11.6% of hypertension pts has family history. so they showed high relative family history. In addition the 5.6% of TBC pts. and the 2.6% of DM pts. have family history. 5. The relationships of disease and drinking are: Drinking proportion is the 36.4% in respiratory disease pts. the 34.7% in hypertension pts. the 33.3% in heart disease pts.. the 28.4% in digestive disease pts.. but because of no surveying drinking amount we can't know the absolut relationships of disease and drinking. 6. The relationships of Disease and smoking are: Smoking proportion is the 44.1% in respiratory disease pts.. the 38.0% in Heart disease pts.. the 29.8% in Hypertension pts.. but because of no surveying of smoking amount. we can't know the absolut relationships of disease and smoking. 7. Distribution of Sasang constitution is : Tae-eum-in 44.8%. So-yang-in 30.7%. So-eum-in 24.6%. Tae-yang-in 0.0%. And disease distribution of Sasang constitution distinction is ; Tae-eum-in has high incidence of circulation disease(50.0%) and respiratory disease(23.1%).So-yang-in has high incidence of athletics disease(77.7%) and EENT disease(12.2%), So-eum-in has high incidence of digestive disease(65.8%). 8. Distribution of abnormal result in occidental medical examination and oriental-occidental contemporal exam result is considerably different. This is the reason of needing oriental medicine exam, for characteristics of Senile. I think that the oriental-occidental contemporary examination in old man is much more effecient than only occident medical examination. This oriental-occidental contemporary examination has many defects because it is the first practice. To participate in the public health program efficiently. I think that we must improve lots of problems and present the model of the oriental-occidental contemporary examination and the project of oriental medicine's for public health.

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