• Title/Summary/Keyword: 공정열

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SND in Fludized Media Aerobic Tank of Membrane-BNR Process (Membrane-BNR 공정의 유동상 담체 호기조내 SND 평가)

  • Lee, Jung-Yeol;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.25 no.2
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    • pp.322-328
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    • 2009
  • The advantage of simultaneous nitrification and denitrification (SND) is to reduce requirement of oxygen as well as tank volume. The fludized media was used in the oxic (aerobic) tank of Membrane-BNR to enhance the efficiency of SND. Nowadays, the interest of applying membrane to the wastewater treatment plant has been increased, which is proved by a lot of research published about the MBR. The Membrane-BNR, consisted of total 5 reactors might be called the compact process by using the fludized media and having short HRT of 6.5 hr. It could attain the further removal of not only the organics but also nutrients such as T-N and T-P. The mode A and B were identified with or without the step feed of influent. The mode A was classified with 3 modes according to the different DO concentration in the fludized media aerobic reactor, and the mode B with step feed was operated with the optimum DO condition. The step-feed was capable of improving TN removal efficiency under the domestic wastewater with the low ratio C/N. On the other hand, the efficiency of SND with the 1.0~1.5 mg/L DO in the oxic media tank was better than the one with below 1.0 mg/L, on which the nitrification did not happen enough, and with above 3.5 mg/L, on which the reduction of anoxic area in the tank happened. It means that the profitable nitrification should be performed prior to the denitrification step. The removal efficiency of nitrogen by SND was about 20% among of total denitrified nitrogen. And some organic carbon consumed could be reduced by the endogeneous denitrification.

Numerical Investigation of Micro Thermal Imprint Process of Glassy Polymer near the Glass Transition Temperature (열방식 마이크로 임프린트 공정을 위한 고분자 재료의 수치적 모델링과 해석)

  • Lan, Shuhuai;Lee, Soo-Hun;Lee, Hye-Jin;Song, Jung-Han;Sung, Yeon-Wook;Kim, Moo-Jong;Lee, Moon-G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.45-52
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    • 2009
  • The research on miniature devices based on non-silicon materials, in particular polymeric materials has been attracting more and more attention in the research field of the micro/nano fabrication in recent years. Lost of applications and many literatures have been reported. However, the study on the micro thermal imprint process of glassy polymer is still not systematic and inadequate. The aim of this research I to obtain a numerical material model for an amorphous glassy polymer, polycarbonate (PC), which can be used in finite element analysis (FEA) of the micro thermal imprint process near the glass transition temperature (Tg). An understanding of the deformation behavior of the PC specimens was acquired by performing tensile stress relaxation tests. The viscoelastic material model based on generalized Maxwell model was introduced for the material near Tg to establish the FE model based on the commercial FEA code ABAQUS/Standard with a suitable set of parameters obtained for this material model form the test data. As a result, the feasibility of the established viscoelastic model for PC near Tg was confirmed and this material model can be used in FE analysis for the prediction and improvement of the micro thermal imprint process for pattern replication.

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Nano-sized Gd2O3:Eu Phosphor Prepared by Spray Pyrolysis (분무열분해 공정에 의해 합성되어진 나노 크기 Gd2O3:Eu형광체)

  • Kim, Eun-Joung;Kang, Yun-Chan;Park, Hee-Dong;Ryu, Seung-Kon
    • Korean Journal of Materials Research
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    • v.12 no.10
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    • pp.771-775
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    • 2002
  • $Gd_2$$O_3$:Eu phosphor particles with nano-sized and non-aggregation characteristics were prepared by spray pyrolysis using the spray solution containing polymeric precursor and $Li_2$$CO_3$ flux material. Nano-sized $Gd_2$$O_3$:Eu phosphor particles had higher brightness than the commercial $Y_2$$O_3$:Eu phosphor particles. The $Gd_2$$O_3$:Eu phosphor particles had nano-size and non-aggregation characteristics after heat-treatment at $1000^{\circ}C$ when the addition amount of $Li_2$$CO_3$ flux was 1 wt.% and 3 wt.%. The mean size of particles were 200 nm and 400 nm when the amount of flux was 1 wt.% and 3 wt.%, respectively. The prepared phosphor particles had higher photoluminescence intensity than that of the commercial product regardless of the content of$ Li_2$$CO_3$ flux and had the maximum brightness when the content of flux was 5 wt %. The photoluminescence intensity of the nano-sized $Gd_2$$O_3$:Eu phosphor particles containing 3 wt.% $Li_2$$CO_3$ flux was 125% in comparison with that of the micron-sized $Y_2$$O_3$:Eu commercial product.

Determination of the Trace Elements in $UO_2$ Powder by ICP-AES Directyl Coupled with Extraction Chromatography (추출크로마토그래피와 유도결합플라스마 원자방출분광법을 이용한 이산화우라늄분말 중 미량금속불순물 분석)

  • Choi, Kwang-Soon;Lee, Chang-Heon;Pyo, Hyung-Yeal;Han, Sun-Ho;Suh, Moo-Yul;Eom, Tae-Yoon;Lee, Gae-Ho
    • Journal of the Korean Chemical Society
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    • v.37 no.9
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    • pp.813-819
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    • 1993
  • An ICP-AES system directly connected with a separation column was used in order to determine the trace elements in $UO_2$ powder promptly and reduce the volume of the waste solution. The outlet of a separation column, which was filled with Teflon powder ($330\;{\mu}m$) coated with tri-n-butyl phosphate (TBP) as extractant, was directly connected with sample injection tube of ICP-AES. Eleven elements including molybdenum in $UO_2$ powder were separated and determined simultaneously. Recoveries of these elements were $91{\sim}110%$ and these results were agreed with those of solvent extraction methods. This method was applicable to quality control in manufacturing nuclear fuel.

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Stress Modeling of the Laser Drilling Process in Carbon Steel (레이저 드릴링을 통한 강판 가공 시 응력 모델링)

  • Lee, Wooram;Kim, Joohan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.7
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    • pp.857-864
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    • 2013
  • A laser machining process has been applied in many manufacturing fields and it provides an excellent energy control for treating materials. However, a heat effect during laser machining can deteriorate material properties. Specifically, a thermally induced stress can be a problem in laser-machined structures on a metal surface. In this study, temperature and stress on cold-rolled carbon steel sheet machined with laser hole drilling were explored in an experimental approach and a numerical method. Stresses by temperature gradients inside the materials were generated in fast cooling. The stresses were measured by using a hole-drilling method and the material properties of carbon steel (SCP1-S) were obtained in the experiment. It was found that the stress predicted from the numerical analysis was in agreement with the stresses measured by using the hole-drilling method. The analysis can be applied for evaluating structure characteristics machined with a laser.

Effects of Demolding Temperature on Formability and Optical Properties of Anti-reflective Nanostructure (반사방지 나노구조의 성형성과 광학적 특성에 대한 이형 온도의 영향)

  • Yeo, N.E.;Shim, Y.B.;Cho, S.U.;Kim, D.I.;Kim, K.N.;Jang, K.S.;Jeong, M.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.91-96
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    • 2016
  • In this study, effects of demolding temperature (DT) on the formability and optical properties were evaluated in order to optimize thermal nanoimprint lithography for anti-reflective film. Characterization on optical property showed that optical performance was gradually enhanced as the DT increased up to $70^{\circ}C$ while the transmittance and the reflectance was degraded as the DT increased further to $100^{\circ}C$. In addition, similar behavior was observed from formability analysis. It was contributed to the formation of free volume and viscose flow. Therefore, it was concluded that the formability and optical property are highly influenced by the formation of free volume and viscous flow of polymer depending on the DT.

Physiological Changes of Saccharomyces cerevisiae by High Voltage Pulsed Electric Field Treatments (고전압 펄스 전기장 처리에 의한 Saccharomyces cerevisiae의 생리적 변화)

  • Park, Hee Ran;Yoon, So Jung;Park, Han-Sul;Shin, Jung-Kue
    • Korean Journal of Food Science and Technology
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    • v.45 no.5
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    • pp.590-597
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    • 2013
  • High voltage pulsed electric fields (PEF) treatment is a promising non-thermal processing technology that can replace or partially substitute for thermal processes. The aim of this research was to investigate the microbial inactivation mechanisms by PEF treatment in terms of physiological changes to Saccharomyces cerevisiae. PEF was applied at the electric field strength of 50 kV/cm, treatment time of 56 ${\mu}s$ and temperature of $40^{\circ}C$. The microbial cells treated with PEF showed loss of salt tolerance on the cell membrane and collapse of the relative pH gradient on in-out of cells. Cell death or injury resulted from the breakdown of homeostasis, decreased $H^+$-ATPase activity, and loss of glycolysis activity.

코어-쉘 나노입자가 PMMA 박막 안에 분산된 나노 복합체를 사용하여 제작한 유기 쌍안정성 메모리 소자의 동작 메커니즘

  • Yun, Seon-Ung;Park, Hun-Min;Yun, Dong-Yeol;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.366-366
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    • 2012
  • 무기물 나노입자를 포함한 유기 박막인 나노 복합체를 사용하여 제작한 비휘발성 메모리 소자는 공정의 간단함과 낮은 전력구동이 가능하다는 장점 때문에 차세대 비휘발성 메모리 소자로 각광받고 있다. 다양한 나노입자를 포함한 유기 박막을 사용한 비휘발성 메모리 소자에 대한 연구는 많이 진행되었지만, 코어-쉘 나노입자가 poly (methylmethacrylate) (PMMA) 유기 박막에 분산되어 있는 나노 복합체를 활성층으로 사용하여 제작한 비휘발성 유기 메모리 소자의 전기적 특성과 메모리 메커니즘에 대한 연구는 비교적 미미하다. 본 연구에서는 코어-쉘 나노 입자가 PMMA 박막 안에 분산되어 있는 나노복합체를 사용한 비휘발성 메모리 소자를 제작하여 전기적 특성, 정보 유지력 및 메모리 스위칭 동작에 대하여 관찰 하였다. 소자 제작을 위해 hexane 안에 들어 있는 코어-쉘 나노입자를 Chlorobenzene에 용해되어 있는 PMMA에 넣어 초음파 교반기를 사용하여 나노입자를 고르게 분산하였다. 코어-쉘 나노입자가 PMMA에 고르게 분산 된 용액을 전극으로 사용 할 Indium-tin-oxide가 성장된 glass 위에 스핀코팅을 한 후 열처리를 하여 용매를 제거한 후 코어-쉘 입자가 PMMA에 분산되어 있는 박막을 형성하였다. 코어-쉘 입자가 PMMA에 분산된 나노복합체 위에 Al을 상부전극으로 열 증착하여 비휘발성 메모리 소자를 제작하였다. 제작된 소자의 전류-전압 (I-V) 특성을 측정결과는 특정한 두께에서 낮은 전도도 (ON state)와 높은 전도도 (OFF state)가 존재하는 쌍안정성 특성을 확인하였다. 코어-쉘 나노입자가 포함되지 않은 소자에서는 쌍안정성 특성이 보이지 않아 코어-쉘 나노입자가 비휘발성 메모리 소자의 기억 특성을 나타내는 중요한 저장 매체가 됨을 알 수 있었다. 제작된 메모리 소자의 메모리 동작에 대한 메커니즘 설명은 I-V와 에너지 밴드 구조를 사용하여 설명할 것이다.

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Development of Innovation DME Process from Natural Gas and Biomass in KOREA (천연가스와 바이오매스로부터 개선된 DME 공정의 개발)

  • Cho, Wonjun;Song, Taekyong;Baek, Youngsoon;Kim, Seung-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.107-107
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    • 2010
  • Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas have played an important role of synthesizing the valuable chemical compound, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuels and chemical production. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C/min$ in thermogravimetric analysis. Bubbling fluidized bed reactor were use to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, CO2, H2 and a small fraction of C1-C4 hydrocarbons.

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A Comparative Study on Adsorption Characteristics of PCBs in Transformer Oil Using Various Adsorbents (여러 흡착제를 이용한 변압기 오일 중의 PCBs 흡착특성에 관한 비교연구)

  • Ryoo, Keon Sang;Hong, Yong Pyo;Ahn, Chun Ju
    • Journal of the Korean Chemical Society
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    • v.56 no.6
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    • pp.692-699
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    • 2012
  • The aim of the present study is to explore the possibility of utilizing loess and fly ash as well as activated carbon for the adsorptive removal of PCBs in transformer oil. Here, we investigated the effect of various factors such as temperature (5, 25, 55), contact time (30 min-3 day) and adsorbent does (1, 2.5, 5, 10 g) in detail. It was found that PCBs adsorption rate from transformer oil by activated carbon is more favored than loess at the equilibrium time of 60 minutes. The equilibrium data for both activated carbon and loess is fitted well to the Freundlich isotherm model. The rate constant and activation energy of PCBs adsorption in transformer oil on each adsorbent was analyzed by fitting a kinetic model at 5, 25 and $55^{\circ}C$. From the thermodynamic parameters, the PCBs adsorption process for transformer oil/activated carbon and loess system is spontaneous and endothermic in nature.