• Title/Summary/Keyword: 공기 투과도

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Frequency- and Porosity-dependent Acoustic Characteristics of Porous Medium with Water- and Air-filled Pores (물과 공기 다공을 갖는 다공성 매질의 주파수 및 다공율 변화에 따른 음향특성)

  • Lee Kang Il;Roh Heui-Seol;Yoon Suk Wang
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.209-212
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    • 2001
  • 수중에서 물과 공기 다공을 갖는 다공성 매질의 주파수 및 다공율 변화에 따른 음향특성을 고찰하였다. 다공성 매질로서 원통형 다공을 인위적으로 균일하게 배열한 판형 루사이트 (Lucite)를 사용하였다. 수중에서 음파를 다공성 매질의 원통형 다공의 축 방향과 평행하게 입사하였을 때, 빠른 파 (fast wave)는 다공 내의 매질에 영향을 받지 않으나, 느린 파 (slow wave) 및 원통형 다공을 전파하는 비평면 고차 정상 모드 파 (nonplanar higher normal mode wave)는 다공 내의 매질에 크게 영향을 받는다. 3MHz부터 4MHz까지의 주파수 영역에서 전체 파 (total wave), 빠른 파 및 느린 파의 음속 및 음압투과계수를 주파수 및 물과 공기 다공율 변화에 따라 측정하였다. 비강체 다공성 매질에서의 음파 전파특성에 대한 MBA (modified Biot-Attenborough) 모델의 이론 결과와 실험결과를 비교, 분석하였다.

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Membrane-Based Direct Air Capture: A Review (막 기반 직접공기포집: 총설)

  • Seong Baek Yang;Kwang-Seop Im;Km Nikita;Sang Yong Nam
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.85-95
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    • 2024
  • Direct air capture (DAC) technology plays a crucial role in mitigating climate change. Reports from the International Energy Agency and climate change emphasize its significance, aiming to limit global warming to 1.5 ℃ despite continuous carbon emissions. Despite initial costs, DAC technology demonstrates potential for cost reductions through research and development, operational learning, and economies of scale. Recent advancements in high-permeance polymer membranes indicate the potential of membrane-based DAC technology. However, effective separation of CO2 from ambient air requires membranes with high selectivity and permeability to CO2. Current research is focusing on membrane optimization to enhance CO2 capture efficiency. This study underscores the importance of direct air capture, evolving cost trends, and the pivotal role of membrane development in climate change mitigation efforts. Additionally, this research delved into the theoretical background, conditions, composition, advantages, and disadvantages of permeance and selectivity in membrane-based DAC.

Permeation Characteristics of Water Vapor Through PVA/PSSA_MA/THS-PSA Membranes (PVA/PSSA-MA/THS-PSA 막의 수증기 투과특성에 관한 연구)

  • Rhim, Ji-Won;Cho, Hyun-Il;Kim, Dae-Hoon;Ha, Seong-Yong;Nam, Sang-Yong
    • Membrane Journal
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    • v.17 no.2
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    • pp.140-145
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    • 2007
  • In this study, 3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA) was added to poly(vinyl alcohol) (PVA) membranes crosslinked with poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) to improve the separation characteristics toward water vapors in the air. The prepared membranes varying both PSSA_MA and THS-PSA amounts were also synthesized at different cross linking temperatures. Then, in order to investigate the separation characteristics of the resulting membranes, the dynamic vapor sorption (DVS) and vapor permeation experiments were carried out. The increase of cross-linking temperature showed longer time to reach the equilibrium sorption state from the dynamic vapor sorption experiments. PVA/PSSA_MA (3%)/THA-PSA(7%) prepared at $120^{\circ}C$ gave the highest permeability of 480 barrer at $35^{\circ}C$.

Effect of the Structure of the Smallest Poresize Layer on the Permeability of PES Microfiltration Membranes (최소 기공층 구조가 PES계 정밀여과막 투과 성능에 미치는 영향)

  • Kim, No-Won
    • Membrane Journal
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    • v.19 no.1
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    • pp.25-33
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    • 2009
  • PES (polyethersulfone) membranes with highly enhanced their asymmetry were prepared by phase inversion process. The membranes were prepared by using PES/DMF (N,N-dimethylformamide)/TSA (p-toluenesulfonic acid)/PVP (polyvinylpyrrolidone) casting solution and water coagulant. The pre-coagulation of membrane surface which was induced by an addition of TSA as a demixing agent and PVP as a swelling polymer in the PES solution and humid exposure time, played a crucial role in determining morphological properties and the PWP (pure water permeation) performance. The PES solution was coated on polyester film under condition of 80% humidity for a while ($72{\sim}144$ sec) before immersing in a coagulation bath. The characterization of membranes was carried out by a capillary flow porometer, a FE-SEM and a permeation test apparatus. As the thickness of the smallest pore size layer (SPL) decreased, the asymmetry of membrane increased under conditions of 20 wt% of TSA and 10 wt% of PVP in 11 wt% of PES solution during longer humid contact time. As a result, the membranes showed a remarkable increase of PWP.

Preparation of Asymmetric Membranes by Addition of Nonsolvent (비용매 첨가제를 이용한 비대칭막의 제조)

  • Kim, Nowon
    • Membrane Journal
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    • v.25 no.1
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    • pp.32-41
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    • 2015
  • High performance polysulfone microfiltration membranes with a high were successfully prepared by vapor induced phase separation (VIPS) coupled with non-solvent induced phase separation (NIPS) process. Asymmetric Membranes were prepared with PSF/DMF/PVP/PEG/DMSO/water mixed solutions and water/IPA coagulant. PSF, DMF, PVP, PEG, DMSO, water was used as a membrane polymer, a solvent, a hydrophilic polymer additive, a polar protic liquid polymer, a polar aprotic nonsolvent, and a polar protic nonsolvent in the casting solution, respectively. The addition of polar aprotic nonsolvents, and polar protic nonsolvents is a convenient and effective method to control membrane structure. In order to control the morphology of polymeric membranes, the spontaneous emulsification induced by drawing water vapor into the exposed casting solution surface has been used. Control of the internal morphology of polymeric membranes by using mixed coagulation solution such as water and IPA is discussed in the present work. The pure water permeability, pore size distribution, surface hydrophilicity and membrane morphology were investigated. Due to the addition of DMSO to casting solution, the mean pore size increased almost $0.2{\mu}m$ and the water flux increased about 1000-1800 LMH.

The Estimating an Effect of Rapid Flux Increase to a Membrane in the Intermittent Aeration MBR Process Using Alum Treatment (응집제를 활용한 간헐포기 MBR공정에서 순간플럭스 증가가 분리막에 미치는 영향 평가)

  • Choi Song-Hyu;Cho Nam-un;Han Myong Su
    • Membrane Journal
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    • v.15 no.1
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    • pp.70-83
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    • 2005
  • By supplying air intermittently in various mode, the effects of oxic/anoxic time ratio and air scrubbing in aeration condition on the membrane flux and permeability were investigated. When suction pump stops, vacuum pressure remains inside the suction pump. Therefore, the effect of remaining vacuum pressure in the suction pump on fouling of membrane was investigated. The effect of EPS (Extra cellular Polymeric Substance) which is generated due to the long SRT and high concentration of MLSS and the dose of coagulant on the membrane were also investigated. The suitable oxic/anoxic time ratio for the best removal efficiency of organic matter and nitrogenous matter was 40 minutes (Oxic) : 20 minutes (Anoxic). At this time ratio, alum was dosed into the aeration tank. The result of dosing alum was that the concentration of alum solution might affect nitrification and denitrification. To remove 1 mg/L of phosphorus in MBR process, it needs 0.75 mg/L of alum solution.

Transmembrane Pressure of Backwashing, Filtration/Relaxation and the Sinusoidal Flux Continuous Operation Modes for Submerged Plate Membrane (역세척, 여과/이완 및 사인파형 연속투과 운전방식에 따른 침지형 평막의 막간차압)

  • Kim, Jae Hyo;Kim, Eun Soo;Chung, Kun Yong
    • Membrane Journal
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    • v.29 no.4
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    • pp.216-222
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    • 2019
  • In this study, permeation experiments were conducted using naturally circulating spherical beads, backwashable plate membrane and the air supplied from the bottom of the MBR. The activated sludge solution was maintained at 8,000 mg/L of MLSS and compared transmembrane pressure (TMP) with respect to FR (filtration and relaxation), FR/BW (filtration and relaxation/backwashing), SFCO (sinusoidal filtration continuous operation) and SFCO/BW (sinusoidal filtration continuous operation/backwashing). As the backwashing flux decreased from 47 to $14L/m^2{\cdot}hr$, the TMP increased generally, but the TMP of FR system increased significantly comparing with SFCO. In addition, the backwashing method reduced more TMP comparing to the cleaning method using spherical beads, and it was confirmed that the operation method using the spherical beads and the backwashing simultaneously is more effective than each method.

The Effect of LSC/GDC (50 : 50 vol%) Active Layers on Oxygen Transport Properties of LSCF/GDC (20 : 80 vol%) Dual-phase Membrane (LSC/GDC (50 : 50 vol%) 활성층이 LSCF/GDC (20 : 80 vol%) 복합 분리막의 산소투과 거동에 미치는 영향)

  • Cha, Da-Som;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.367-374
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    • 2014
  • In the present study, disc-type LSCF/GDC (20 : 80 vol%) dual-phase membranes having porous LSC/GDC (50 : 50 vol%) active layers were prepared and effect of active layers on oxygen ion transport behavior was investigated. Introduction of active layers improved drastically oxygen flux due to enhanced electron conductivity and oxygen surface exchange activity. As firing temperature of active layer increased from $900^{\circ}C$ to $1000^{\circ}C$, oxygen flux increased due to improved contact between membrane and active layer or between grains of active layer. The enhanced contact would improve oxygen ion and electron transports from active layer to membrane. Also, as thickness of active layer increased from 10 to $20{\mu}m$, oxygen flux decreased since thick active layer rather prevented oxygen molecules diffusing through the pores. And, STF infiltration improved oxygen flux due to enhanced oxygen reduction reaction rate. The experimental data announces that coating and property control of active layer is an effective method to improve oxygen flux of dual-phase oxygen transport membrane.

Effect of Hollow Composite Yarn Characteristics to the Comfort Property of Fabrics for High Emotional Garment (중공 복합사 특성이 고감성 의류용 직물의 쾌적성에 미치는 영향)

  • Kim, Hyun-Ah
    • Science of Emotion and Sensibility
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    • v.17 no.4
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    • pp.71-78
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    • 2014
  • Composite draw textured yarns(DTY) and air jet textured yarns(ATY) with hollow PET filament have been used for making high emotional fabrics including light weight sports wear garments. This study investigated effect of hollow composite yarns and fabric structural parameters to the comfort properties related to the moisture and thermal transport phenomena for the composite fabrics made of DTY and ATY with hollow PET filament. Wicking property of hollow composite fabric was superior at the high pore size fabric and was not influenced by fabric cover factor. Wicking property of the fabric with ATY was better than that of the fabric with DTY. On the other hand, drying rate of fine pore sized fabric was shorter than that of large pore sized fabric and drying rate of high multi yarn fabric with low cover factor and small pore size was superior than that of hollow composite fabric. The pore size of the fabric was dominant factor in the air permeability and thermal conductivity of hollow composite fabric. High pore sized fabric showed high air permeability and thermal conductivity of hollow composite fabric was nonlinearly inversely proportional to pore size of the fabric.

Optical Properties of $TiO_2$ Thin Films Prepared by Ion-beam Assisted Deposition (이온빔 보조 증착법에 의해 제작된 $TiO_2$ 박막의 광학적 특성)

  • 조현주;이홍순;황보창권;이민희;박대윤
    • Korean Journal of Optics and Photonics
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    • v.5 no.1
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    • pp.9-17
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    • 1994
  • Optical properties of $TiO_2$ thin films prepared by ion-beam assisted deposition(1BAD) were investigated. The result shows that the refractive index of IBAD TiOL thin films measured by an envelope method is closer to that of the corresponding bulk than that of conventionally deposited $TiO_2$ thin films and the packing density of IBAD $TiO_2$ thin films measured by a vacuum-to-air spectral shift of films increases drastically. The vacuum-to-air spectral shift of an IBAD $(TiO_2/SiO_2)$ multilayer interference filter was negligible as compared to that of a conventional interference filter and so the IBAD filter is denser and more stable optically than the conventional filter. Also it is observed that the IBAD and conventional $TiO_2$ thin films are stoichiometric and amorphous.

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