• Title/Summary/Keyword: 고화제

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Environmental Assessment of $Cr^{6+}$ Occurring in Stabilizing Processes of Soft Sea-Bottom using Cement Stabilizers (시멘트 고화제 고결공법에서 발생하는 $Cr^{6+}$의 환경영향 검토)

  • 오영민;김경태
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.4
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    • pp.319-321
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    • 2002
  • Recently, the injection of cement stabilizer is used as one of ways to improve soft sea-bottom. However, this method makes an argument with $Cr^{6+}$subject to emerge to the seawater from the cement stabilizer. To investigate the amount of$Cr^{6+}$field measurements were carried out in Ochun harbor of Chunsoo Bay. The analysis shows the amount of $Cr^{6+}$in the seawater met the demand of environmental criterion.

Strength Characteristics of Solidified Soil with Hardening Agents made of Industrial By-Products (산업부산물을 이용한 지반고화제 혼합토의 강도특성)

  • Kim, Youngsang;Yu, Geunmo;Mun, Kyoungju
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.6
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    • pp.19-26
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    • 2012
  • In this study, geotechnical tests including unconfined compression test were carried out to evaluate the ground improvement effect of the hardening agent, which has been developed by using inter-chemical reactions between slag, fly ash, phosphogypsum and bypass dust on the weathered granite soil and dredged marine clay. Test results show that the strength of weathered granite soil mixed with hardening agent B-2, which uses phosphogypsum as an activator, is higher than that of B-1, which uses bypass dust as an activator. Strengths of B-1 & B-2 hardening agent mixed soil show only 44%~60% of strength of OPC(Ordinary Portland Cement, OPC) mixed soil. However, since B-1 and B-2 agents are made of industrial by-products, they seem economically more effective than ordinary portland cement as well as other present hardening agents. Test results on dredged marine clay show that unconfined compression strength increases with amount of agent and curing days. Unconfined compression strength of 14% B-1 agent mixed soil increases linearly with curing days and reaches only 40% of OPC mixed soil. While unconfined compression strength of 14% B-2 agent mixed soil increases exponentially and reaches 133% of OPC mixed soil. Relationship between deformation modulus and unconfined compression strength of B-1 and B-2 mixed soil can be expressed as $E_{50}=(20{\sim}47)_{qu,28}$, which is similar with lower limit of OPC mixed dredged marine clay.

Strength and Compaction Characteristics of Binder-Stabilized Subgrade Material in Ulsan Area - Main Binder Components : CaO and SO3 - (고화제로 안정처리 된 울산지역 노상재료의 강도 및 다짐특성 - 주 성분이 CaO와 SO3인 고화제 -)

  • Han, Sang-Hyun;Yea, Geu-Guwen;Kim, Hong-Yeon
    • Journal of the Korean Geotechnical Society
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    • v.34 no.12
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    • pp.105-113
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    • 2018
  • In this study, the engineering properties including bearing capacity of subgrades stabilized with a binder are analyzed by laboratory and field experiments. The main components of the binder are CaO and $SO_3$. After the binder was mixed with a low plasticity clay, the passing rates were relatively decreased as the sieve mesh size increased. Not only did the soil type change to silty sand, but engineering properties, such as the plasticity index and modified California bearing ratio (CBR), were improved for the subgrade. A comparison of the compaction curves of the stabilized subgrade and field soil compacted with the same energy demonstrated an increase of approximately 6% in the maximum dry unit weight, slight decrease in optimum moisture content, and considerable increase improvement in grain size. In the modified CBR test, the effect of unit weight and strength increase of the modified soil (with a specific amount of binder) was remarkably improved. As the proportion of granulated material increased after the addition of binder, the swelling was reduced by 3.3 times or more during initial compaction and 6.5 times by final compaction. The unconfined compressive strength of the specimens was maintained at the homogeneous value with a constant design strength. The stabilized subgrade was validated by applying it in the field under the same conditions; this test demonstrated that the bearing capacity coefficients at all six sites after one day of compaction exceeded the target value and exhibited good variability.

광미/광폐석 처리를 위한 고형화 공정 실증 실험

  • Jeon Ji-Hye;Choi Ae-Jeong;Kim In-Su;Lee Min-Hui;Jang Yun-Yeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.166-170
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    • 2006
  • 본 연구에서는 폐광산 주변에 산재되어 있는 광미/광폐석을 처리하기 위하여 고형화 실증 실험을 수행하였다. 고형화 공정에서 흔히 사용하는 포틀랜드 시멘트와 MSG-E, MSG-N을 고화제로 사용하였으며 현장 광미 및 광폐석을 대상으로 고화체를 양생하고 고화체의 압축강도 및 중금속 용출 정도를 측정하였다. 고화체의 물리/화학적 특성을 비교하기 위해 광미/고화제 비율, 배합수/고화제 비율 그리고 고화체 양생기간을 실험인자로 설정하였다. 실험 결과 광미/고화제의 비율 1:1 만을 고려하더라도 중금속 용출의 급격한 감소가 이루어지는 것을 확인할 수 있었으며 광미/고화제의 비율을 3:1 이하로 유지시키는 경우, 고화체의 압축강도가 현행 폐기물 관리법(20조 관련)에서 규정하고 있는 차단형 매립시설 내부막의 압축강도 기준인 $0.21kgf/mm^2$ 보다 높은 것으로 나타났다. 다양한 pH를 갖는 수용액에 대하여 시간에 따른 고화체의 중금속 용출률을 측정한 결과, 수용액의 pH가 1과 13인 강산/강염기 용액에서 일부 중금속의 용출 농도가 지하수 생활용수 기준치를 초과하였으나, pH와 3 - 11인 경우에는 중금속 용출률이 급격히 감소하여 모두 기준치 이하를 나타내었다. 또한, pH가 1과 13인 수용액의 경우에도 고화체와 반응하는 시간이 증가할수록 고화체의 buffering 효과에 의해 수용액의 pH가 감소하였다. 이러한 결과는 현장에서 접촉수의 pH가 강산이나 강염기라 하여도, 고화체의 buffering 효과에 의해 시간이 지남에 따라 수용액의 pH가 낮아져 고화체로부터의 중금속 용출은 매우 감소할 것임을 의미한다.ss of an active application defined using the model. The technique is developed in a platform- and language-independent way, and it is algorithmic and can be automated by computer program. We give an example dealing with network auction to illustrate the use of the model and the verification technique.품으로 내부 온도분포를 측정하였으며, 유한차분법 프로그램으로 대류열전달계수를 결정하였다. 대류열전달계수는 792에서 2,107 W/m$^2$로 분석되었다. 대류열전달 계수는 액상식품과의 상대속도가 증가함에 따라서 증가하였고, 점도가 증가함에 따라서는 감소하였다.ce of precision/recall of 90.99%/92.52%, and 93.39%/93.41% respectively. 의한 변성에 부분적으로 보호 작용을 나타 낼 것으로 추정된다.경(製麴72時間頃)의 활성(活性)은 보리쌀국(麴), 밀가루국(麴), 찹쌀국(麴), 고구마국(麴)의 순이었다.험 결과 오전용 사료는 관행적인 산란계 배합사료에서 Ca공급제를 제외한 것을 급여하고, 오후용 사료는 Ca공급제를 3배 첨가한 T2처리로 15:00~16:00시에 교체급여를 하면 사료섭취량 감소와 사료비 절감면에서 바람직할 것으로 사료되며, 고에너지-고단백질-저Ca의 분말사료와 저에너지-저단백질-고Ca의 펠렛사료를 혼합급여하면 산란계의 사료

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Soil Treatment by Eco-Friendly Consoildation Soil (친환경 무기계 토양개량 고화제에 의한 해양오염토 처리)

  • Han, Doo Hee
    • Journal of Convergence for Information Technology
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    • v.7 no.1
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    • pp.67-73
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    • 2017
  • Paper sludge ash, blast furnace slag, fine powder quicklime, anhydrous gypsum, and fly ash as the main ingredients were prepared to suit the salty soils of marine soils. The solidification component is a kind of recycled ceramic, and CaO plays an important role in solidification. The neutralization time after solidification was about 2 weeks, and the compressive strength was about 12N/mm2 in the mortar test after one week incubation with standard yarn. This is about 14 times stronger than the solidifying agent used in the metropolitan area. As a result of applying plate load test to saltous marine soils, we obtained the yield load that can pass the large scale even after 5 days. In the uniaxial compressive strength test, shear strength of about 300 kPa was obtained after 5 days. It will be useful for supplementing the soft ground in the area where marine reclamation is much like the Incheon area.

Characteristics of Organic Polymer Soil Pavement Curing Condition (양생조건에 따른 유기계 폴리머 흙 포장의 특성)

  • Hwang, Sungpil;Jeoung, Jaehyeung;Lee, Yongsoo;Ryu, Sanghun
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.12
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    • pp.35-42
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    • 2014
  • The efforts to reduce carbon emission have been made in many aspects and in road, the study to develop the construction method which will replace asphalt and cement is also underway. But given the low cost and high performance offered by cement, among many solidification agents, it's difficult to seek the competent alternative. Polymeric material has been used in various ways for its advantages including lightweight and easy process for complex function and generates less carbon emission, and thus it would possibly be efficient if it replaces soil pavement using cement. This study, using three different types of organic polymeric solidification agents with different solidification principle, is intended to identify the difference in strength depending on curing method, natural dry or oven dry. Applicability of organic polymeric solidification agents to walkway and bike lane was investigated and as a result of unconfined strength test, all of them satisfied the minimum strength requirements of bike lane. Furthermore, strength characteristics of soil pavement depending on variation of water content was evaluated to identify the relationship, thereby appropriate curing method using organic polymeric solidification agent is proposed.

Effects of Anticaking Agents on the Physicochemical Properties of Freeze-dried Kiwifruit Powders (고화방지제의 첨가가 참다래 동결건조분말의 물리화학적 특성에 미치는 영향)

  • Oh, Hyun-Jeong;Lim, Ja-Hun;Lee, Ju-Yeon;Oh, Young-Ju;Lim, Sang-Bin
    • Culinary science and hospitality research
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    • v.20 no.1
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    • pp.178-188
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    • 2014
  • Two kinds of anticaking agents (dextrin, polydextrose) were combined with kiwifruit paste at 5% w/w ratio and freeze-dried to prepare a powdered material. The physiochemical characteristics of kiwifruit powders with anticaking agents were compared with those without anticaking agents as the control. The yield was higher in the powders with anticaking agents than the control. Moisture content, acidity, and total phenolics were lower in the powders with anticaking agents than the control. The contents of vitamin C was higher in the powders with anticaking agents than the control, but was no significant difference with different anticaking agent types. There were no significant differences in free sugar content (fructose, glucose, total sugar) and organic acid content (oxalic acid, lactic acid, total) depending on the anticaking agent types. Hunter's L-value was significantly high in the order of the samples with dextrin, the control, and polydextrose, while a-value showed an opposite tendency. Browning index, water solubility, and swelling power didn't show any significant difference. However, the hygroscopicities with elapsed time were lower in the powders with anticaking agents than the control. Therefore, the kiwifruit powder combined with dextrin or polydextrose as an anticaking agent at 5% w/w ratio could be used as a food biomaterial with a good quality in moisture, vitamim C, color value, browning index, water solubility, and hygroscopicity.

Study of Solidification by Using Portland and MSG(micro silica grouting) Cements for Metal Mine Tailing Treatment (금속 광미 처리를 위한 포틀랜드 시멘트와 MSG(micro silica grouting) 시멘트 고형화 실증 실험 연구)

  • Jeon, Ji-Hye;Kim, In-Su;Lee, Min-Hee;Jang, Yun-Young
    • Economic and Environmental Geology
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    • v.39 no.6 s.181
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    • pp.699-710
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    • 2006
  • Batch scale experiments to investigate the efficiency of the solidification process for metal mine tailing treatment were performed. Portland and MSG (micro silica pouting) cements were used as solidifier and three kinds of mine tailings (located at Gishi, Daeryang, and Aujeon mine) were mixed with cements to paste solidified matrices. Single axis com-pressible strengths of solidified matrices were measured and their heavy metal extraction ratios were calculated to investigate the solidification efficiency of solidified matrices created in experiments. Solidified matrices ($5cm{\times}5cm{\times}5cm$) were molded from the paste of tailing and cements at various conditions such as different tailing/cement ratio, cement/water ratio, and different cement or tailing types. Compressible strengths of solidified matrices after 7, 14, and 28 day cementation were measured and their strengths ranged from 1 to $2kgf/mm^2$, which were higher than Korean limit of compressible strength for the inside wall of the isolated landfill facility ($0.21kgf/mm^2$). Heavy metal extractions from intact tailings and powdered matrices by using the weak acidic solution were performed. As concentration of extraction solution for the powdered solidified matrix (Portland cement + Gishi tailing at 1:1 w.t. ratio) decreased down to 9.7 mg/L, which was one fifth of As extraction concentration for intact Gishi tailings. Pb extraction concentration of the solidified matrix also decreased to lower than one fourth of intact tailing extraction concentration. Heavy metal extraction batch experiments by using various pH conditions of solution were also performed to investigate the solidification efficiency reducing heavy metal extraction rate from the solidified matrix. With pH 1 and 13 of solution, Zn and Pb concentration of solution were over the groundwater tolerance limit, but at pH $1{\sim}13$ of solution, heavy metal concentrations dramatically decreased and were lower than the groundwater tolerance limit. While the solidified matrix was immerged Into very acidic or basic solution (pH 1 and 13), pH of solution changed to $9{\sim}10$ because of the buffering effect of the matrix. It was suggested that the continuous extraction of heavy metals from the solidified matrix is limited even in the extremely high or low pH of contact water. Results of experiments suggested that the solidification process by using Portland and MSG cements has a great possibility to treat heavy metal contaminated mine tailing.

Mechanical Characteristics of Light-weighted Foam Soil Consisting of Dredged Soils (준설토를 이용한 경량기포혼합토의 역학적 특성 연구)

  • 김주철;이종규
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.309-317
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    • 2002
  • The mechanical characteristics of Light-Weighted Foam Soil(LWFS) are investigated in this research. LWFS is composed of the dredged soil from offshore, cement and foam to reduce the unit-weight and increase compressive strength. For this purpose, the unconfined compression tests and triaxial compression tests are carried out on the prepared specimens of LWFS with various conditions such as initial water contents, cement contents, curing conditions and confining stresses. The test results of LWFS indicated that the stress-strain relationship and the compressive strength are strongly influenced by the cement contents rather than the intial water contents of the dredged soils. On the other hand, the stress-strain relationship from triaxial compression test has shown strain-softening behavior regardless of curing conditions. The stress-strain behavior for the various confining stress exhibited remarkable change at the boundary where the confining stress approached to the unconfined compression strength of LWFS. In order to obtain the ground improvement of the compressive strength above 200kPa, the required LWFS mixing ratio is found to be 100%~160% of the initial water contents of dredged soil and 6.6% of cement contents.

Mechanical and Germination Characteristics of Stabilized Dredged Soil (고화준설토의 역학적 특성과 식생 발아 특성)

  • Lee, Miji;Mun, Kyoungju;Yoon, Gillim;Eum, Hyunmi;Kim, Yuntae
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.3
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    • pp.33-40
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    • 2014
  • In this paper, mechanical and germination characteristics of stabilized dredged soils were investigated to recycle dredged soil in eco-friendly manner such as waterfront construction. Non sintering binder (NSB), which was developed by using interchemical reactions between slag, high-calcium fly ash, alkali activator on the dredged marine clay, was added to dredged soil. Ordinary portland cement was also used for the comparison of two binders. Experimental tests such as flow test and unconfined compressive test were carried out to evaluate characteristics of stabilized dredged soil. Leaching test, pH measure, vegetation germination test were also conducted to consider environmental applicability. The unconfined compressive tests shows that unconfined compressive strength (UCS) also increases with the increase of curing time and mixed ratio. UCS of NSB mixtures were higher than those of OPC mixtures. Germination tests showed that germination and sprouting date are better in NSB mixture than OPC mixture. It can be explained that germination decreased as pH and 7-day strength increased.