• Title/Summary/Keyword: 고착

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Study of dyeing properties by swelling agent on m-Aramid (Swelling agent의 화학적 특성에 따른 m-Aramid의 염색성 고찰)

  • Kim, Eun-Mi;Joo, Jong-Hyun;Choi, Jea-Hong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.47-47
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    • 2011
  • 최근 m-Aramid 섬유의 염색에 대한 연구가 진행되면서 기존의 원착법 및 초고온고압법 등 상업성이 낮거나 제약이 많았던 염색법에서 차츰 cationic dye를 이용한 염색법이 상용화되고 있다. m-Aramid 섬유는 amide기의 분자 간 수소결합으로 인하여 결정화도를 증가시킴으로서 고강도, 고탄성의 특성을 가질 수 있지만, 강력한 분자구조와 고결정성의 치밀구조로 인하여 염료가 섬유의 분자구조 내부로 확산, 염착되기 어려운 단점을 가지기도 한다. 따라서 m-Aramid 섬유를 침염법으로 염색 시, 섬유의 치밀구조를 이완시켜줄 수 있는 swelling agent가 중요하게 작용한다. 본 연구에서는 cationic dye를 이용하여 swelling agent의 영향성을 살펴보았다. 사용된 시료는 100% m-Aramid 섬유이며, C.I. Basic Yellow 28, Red 46, Blue 54를 사용하여, 욕비 1:10, $NaNO_3$ 7g/l의 조건으로 $130^{\circ}C{\times}60$분간 염색하였다. 이때 사용된 Swelling agent는 두 가지로 각각 1-phenoxypropan-2-ol(S1)과 N-methyl formanilide(S2)를 주성분으로 한다. 염색 시 염료의 농도는 0.5~7% o.w.f.이며, 염색 전 후 염욕을 UV-VIS을 통해 absorbance값을 측정하여 산출한 염착율과, CCM을 사용하여 최대흡수 파장에서 산출 된 K/S값을 비교 고찰 하였다. 각각의 염색물을 비교한 결과 Red 염료를 제외한 yellow 및 blue 모두 3% o.w.f. 염료농도까지 90% 이상의 흡착율을 보였으며, S1에 비해 S2의 경우 염착율이 근소하게 높은 결과를 보였다. 반면 K/S 값을 비교해보면, S2를 사용하였을 때 10%~60% 높은 K/S값을 보였다. 염착율은 비슷하지만 K/S값의 차이를 보이는 이유는 염색이 끝난 후 수세과정에서 섬유표면에 미고착된 염료들이 빠져나가는 것으로, 이를 통해 S2의 경우 섬유의 내부로 염료를 잘 고착시켜 줌으로서 수세안정성이 S1에 비에 우수한 결과를 보인 것으로 고찰된다.

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A study on the Equilibrium sorption of Silk fibroin by Reactive dye. (견에 대한 반응성 염료의 평형론적 연구)

  • 오병주;탁태문
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.40-46
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    • 1985
  • The equilibrium sorptions of C.I. Reactive Blue 19 and C.I. Reactive Blue 19 and C.I. Acid Blue 138 on Silk fibroin were investigated in the range of 50$^{\circ}C$, 70$^{\circ}C$, 90$^{\circ}C$ and to the pH range from 2.0 to 10.5. The results obtained are summarized as follows: 1) The amount of sorption of reactive dye was increased with the decrease of pH in dyeing solution and temperature. The amount of fixation showed the maximum value to pH 8.5 and 70$^{\circ}C$. 2) In acidic region, the sorption behavior of acid dye was similar to that of reactive dye, and Langmuir adsorption constant was increased with the decrease of pH. 3) Langmuir constant of both dyes was decreased with the increase of temperature, while standard affinity was increased. 4) The reaction of both dyes was exothermic and the values of $\Delta$S$^{\circ}$ were positive. 5) It was found that the sorption behavior of dyes against Silk fibroin could be described as Langmuir adsorption and Nernst distribution in lower pH region.

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The effect of dead coral skeletons on the water quality and sessile mollusks in the closed system (폐쇄시스템 내에서 죽은 산호골격이 수질과 고착성 연체동물에 미치는 영향)

  • Lee, Nam Hyeon;Han, Kyung Nam
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.187-196
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    • 2012
  • Recently, for the purpose of constructing artificial ecosystem, the public aquarium and experimental mesocosm systems are receiving attention. To design and establish an aquarium and mesocosm system, there is need of several materials for simulating the environment, such as sediments, rocks, and plants. Expecially for sessile mollusks, there must be proper materials to which sessile invertebrates can adhere. Nowadays, many aquariums and mesocosm systems are using dead coral skeletons for sessile mollusks. This study was proceeded to have data on the effect of dead coral skeletons on water qualities with the experiment on the environmental factors. For this purpose, I made glass tank for experiment, chose two types of dead coral skeletons imported from the Indonesia and observed the change of water qualities and decomposition efficiency of TAN (total ammonia-nitrogen), nitrite ($NO_2{^-}$) and nitrate ($NO_3{^-}$). As a result, the lager the surface area was, the more TAN, nitrite and nitrate decomposition rate increased. In addition, coral skeletons covered with crustose algae and bacteria in the tank showed faster TAN, nitrite and nitrate removal rate and stabilization. Accordingly, this experiment suggested that dead coral skeletons could be used as a sub filter for the closed system as well as an adhering plate.

Parametric Equation of Hough Transform for Log-Polar Image Representation (로그폴라 영상 표현을 위한 매개변수 방정식의 Hough 변환)

  • Choi, Il;Kim, Dong-su;Chien, Sung-Il
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.39 no.4
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    • pp.455-461
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    • 2002
  • This paper presents a new parametric log line equation of polar form for Hough transform in log-polar plane, in which it can remove the well-known unboundedness problem of Hough parameters. Bolduc's method is used to generate a log-polar image dividing the fovea and periphery from a Cartesian image. Edges of the fovea and periphery are detected by using the Sobel mask and the proposed space-variant gradient mask, and are combined in the log-polar plane. The sampled points that might constitute a log line are quite sparse in a deep peripheral region due to severe under-sampling, which is an inherent property of LPM. To cope with such under-sampling, we determine the values of cumulative cells in Hough space by using the space-variant weighting. In our experiments, the proposed method demonstrates its validity of detecting not only the lines passing through both the fovea and periphery but also the lines in a deep periphery.

Fault Tolerant Gaits of a Hexapod Robot with a Foot Trajectory Adjustment (다리 궤적을 조정하는 육각 보행 로봇의 내고장성 걸음새)

  • Yang Jung-Min
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.42 no.3 s.303
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    • pp.1-10
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    • 2005
  • This paper proposes a novel fault-tolerant gait planning of a hexapod robot considering kinematic constraints. The failure concerned in this paper is a locked joint failure for which a joint in a leg cannot move and is locked in place. It is shown that the conventional fault-tolerant gait of a hexapod robot for forward walking on even terrain may be fallen into deadlock, depending on the configuration of the failed leg. For coping with such deadlock situation, a novel fault-tolerant gait planning is proposed. It can avoid deadlock by adjusting the position of the foot trajectory, and has the same leg sequence and stride length as those of the conventional fault-tolerant gait. To demonstrate the superiority of the proposed scheme, a case study is presented in which a hexapod robot, having walked over even terrain before a locked joint failure, could avoid deadlock and continue its walking by the proposed fault-tolerant gait planning.

Conservation of a Bronze Incense Burner from Chungung-dong, Hanam (하남시 춘궁동 출토 청동현향로(靑銅懸香爐)의 제작기술과 보존처리)

  • Jeong, Subin;Park, Haksoo
    • Conservation Science in Museum
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    • v.16
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    • pp.32-45
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    • 2015
  • The bronze incense burner, discovered in Chungung-dong, Hanam, Gyeonggi-do in 1971, is a hanging incense burner dating from the Goryeo period. The incense burner was covered with a thick layer of clay. The object was in a severely deteriorated state, affected by bronze disease which resulted in extensive corrosion. Numerous cracks were present across its surface, and some parts had been broken off. To preserve and display the bronze incense burner in a stable condition, deposits of foreign material were removed from the surface, and the weakened metal was strengthened. Cracked and broken areas were reinforced using woven glass fiber, followed by the application of epoxy resin to restore the shape. To investigate the method of production, a chemical analysis was performed, and the microstructure was examined. The chemical analysis revealed that the body of the incense burner as well as the ear, loop, lid and the knob were cast in a ternary alloy of Cu-Sn-Pb. Moreover, copper nails with high copper content were used to securely join the ear to the body of the incense burner. The microstructure was mainly α-phase, and non-intermetallic inclusions composed of Cu and S were detected.

Anaerobic Corrosion Properties of Sangpyeongtongbo Excavated at Bigyeongdo, Seosan (서산 비경도 출수 상평통보의 혐기성 부식 특성)

  • Kim, Kyu Been;Chung, Kwang Yong
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.167-179
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    • 2017
  • In this study, Sangpyeontongbo excavated at Bigyeongdo, Seosan, were investigated to determine the components of the corrosion products that were formed while they were buried underwater in an anaerobic environment. The causes of corrosion product formation were also determined. Microstructure observation, element mapping, principle component analysis for each year, and the detection of corrosion products were carried out. Results indicate that the concretions of corrosion products on the surface are needle-, hexahedral-, and octahedral-shaped; Pb, Cu, and S were among the elements detected. The Cu-S layer was clearly verified using element mapping. An analysis of major elements for each layer showed that Cu, S, and Pb were present and that most Zn was eliminated. The corrosion products detected were $PbCO_3$ (concretion) and $Cu_{1.96}S$ (metal). Accordingly, the anaerobic corrosion properties of Sangpyeongtongbo are summarized as follows: dezincification, copper sulfide, and lead compound.

Study of Failure Examples Involved in Turbocharger System of the Diesel Engine a Vehicle (디젤 엔진 자동차의 터보차저 시스템과 관련된 고장사례 연구)

  • Lee, IL Kwon;Lee, Jeong Ho
    • Journal of the Korean Institute of Gas
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    • v.21 no.2
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    • pp.26-31
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    • 2017
  • The purpose of this paper is to study for turbocharger system in a vehicle of diesel engine. The first example, it certified the fact that a car engine is not to accelerate by clogged the exhaust tube as the turbine was damaged because of turbine wheel broken. The a vehicle with turbocharger must to stop engine operation after maintaining the appropriate idle revolution as it can be the sticking phenomenon if the operator immediately stop the engine being high revolution. The second example, it knew the phenomenon of acceleration faulty that the rod of VGT actuator that operating the turbocharger adhered with the bracket of VGT. The third example, it confirmed the power insufficiency phenomenon when driving by of alternator resistor and fan intercooler fan relay connector mistaken assembly. Therefore, the operator have to scrutinize manage no the failure of turbocharger system.

A Study on the Effect of Credit Card Usage on the Intention to Use Mobile Payment (신용카드 사용이 모바일 간편결제 이용의도에 미치는 영향에 관한 연구)

  • Lee, Eun-Mi;Goo, Jayoung James
    • Journal of Digital Convergence
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    • v.18 no.4
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    • pp.149-161
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    • 2020
  • This paper aims to explore the question of whether the environment in Korea where credit card use is prevalent affects the intention to accept Fintech-based mobile payment. The institution that encourages the credit card use such as credit card receipt obligation may lead to the lock-in and build infrastructures to influence the acceptance of new payment acceptance. This paper investigates how the perceived of use, usefulness, accessibility and stability affect the intention to use mobile payment based on the Technology Acceptance Model(TAM) model with the mediator of lock-in and moderator of credit card receipt obligation. In the results, we found that the perceived usefulness, perceived ease of use and accessibility positively impact on the intention of mobile payment usages. It is also observed that the usefulness and accessibility of credit cards positively mediate to the intention of mobile payment use.

Influences of Magnetization Reversal and Magnetic Interaction on Coercivity of Sr-Ferrite Particles with Different Sizes (크기가 다른 Sr-Ferrite 입자의 자화 역전과 자기 상호작용이 보자력에 미치는 영향)

  • Kim, Hyeon Soo;Jeong, Soon Young;Kim, Kyung Min;Kwon, Hae-Woong
    • Journal of the Korean Magnetics Society
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    • v.27 no.1
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    • pp.23-29
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    • 2017
  • In this study, the influences of magnetization reversal and magnetic interaction on the coercivity of Sr-ferrite particles with different sizes were investigated through various magnetic measurements. The shape of the initial magnetization curve and the magnetic field dependence of the coercive force indicate that the magnetization reversal changes from domain nucleation to wall pinning as the particle size decreases. On the other hand, the Henkel plot, interaction field factor and ${\Delta}M(H)$ obtained from the DCD and IRM curves show that the strength of the dipolar interaction is increased with increasing the particle size. Therefore, it can be concluded that coercivity is closely related to magnetic interaction as well as magnetization reversal mechanism.