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Selective Oxidation of Acrolein over Cupric Salt of 12-Molybdophosphoric Acid (12-몰리브도 인산 동염 촉매상에서 아크롤레인의 선택 산화반응)

  • Kim, Kyung-Hoon;Na, Suk-Eun;Park, Dae-Won
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.721-730
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    • 1993
  • Various catalysts of $Cu_xH_3-{_{2x}}PMo_{12}O_{40}{\cdot}_nH_2O$ with different x-values have been prepared and characterized by thermal analysis, X-ray powder diffraction, infrared spectroscopy, BET surface-area measurement, electron microscopy, and temperature programmed desorption of ammonia. The properties of these catalysts in acrolein oxidation have been investigated in a continuous-flow fixed-bed reactor. The catalysts lost their water of crystallization at about $200^{\circ}C$ and their constitutional water between 300 and $400^{\circ}C$. The Keggin structure of the catalysts was identified by infrared spectroscopy. The decomposition of Keggin anion, $(PMo_{12}O_{40})^{3-}$, was increased with the increase of substituted copper content and identifiable $MoO_3$ and $P_2O_5$ as decomposition products were observed. The conversion of acrolein decreased with the increase of x probably due to the decrease of specific surface area and of total amount of acid sites. But specific reaction rate and selectivity to acrylic acid were maximized at x=1.0, and it showed specific acid site distributions.

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Petrological Characteristics of the Daejeonsa Basalt in the Mt. Juwang area, Cheongsong-gun, Gyeongsang but-do, Korea (경북 청송군 주왕산지역의 대전사 현무암의 암석학적 특성)

  • Koh, Jeong-Seon;Ahn, Ji-Young;Yun, Sung-Hyo
    • Journal of the Korean earth science society
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    • v.21 no.5
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    • pp.553-562
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    • 2000
  • Daejeonsa basalt in the Mt. Juwang area is composed of 12 lava flows alternate with 9 peperites, and each lava and peperite has variable thickness. Globular peperites yielded in Daejeonsa basalt are mixed basalt clasts with reddish shale. Based on field description, when lava flows over unconsolidated wet shale or injectes into unconsolidated wet shale, peperites were formed at the contacts between lava and shale. Daejeonsa basalt are massive lava flows with rare vesicules: some vesicules are found in upper part of a flow unit. The basalt has mainly pseudomorphs of olivine as phenocryst, and also plagioclase and clinopyroxene phenocrysts in rocks with higher Mg-number. Matrix is mainly subophitic texture, sometimes showing ophitic and intergranular textures due to different cooling rate. Clinopyroxene is augite(Wo$_{41.6}$En$_{45.1}$Fs$_{13.3}$), and plagioclase is mostly labradorite(An$_{55.0}{\sim}_{67.7}$), but some is andesine(An$_{44.3}$) and bytownite(An$_{74.5}$). Oxide minerals are composed of titanomagnetite and ilmenite.

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Optimal Transmission Scheduling for All-to-all Broadcast in WDM Optical Passive Star Networks) (수동적인 스타형 파장 분할 다중 방식인 광 네트워크에서의 전방송을 위한 최적 전송 스케쥴링)

  • Jang, Jong-Jun;Park, Young-Ho;Hong, Man-Pyo;Wee, Kyu-Bum;Yeh, Hong-Jin
    • Journal of KIISE:Computer Systems and Theory
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    • v.27 no.1
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    • pp.44-52
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    • 2000
  • This paper is contented with packet transmission scheduling problem for repeating all-to-all broadcasts in WDM optical passive-star networks in which there are N nodes and k wavelengths. It is assumed that each node has one tunable transmitter and one fixed-tuned receiver, and each transmitter can tune to k different wavelengths. The tuning delay represents the time taken for a transmitter to tune from one wavelength to another and represented as ${\delta}$(>0) in units of packet durations. We define all-to-all broadcast as the one where every node transmits packets to all the other nodes except itself. So, there are in total N(N-1) packets to be transmitted for an all-to-all broadcast. The optimal transmission scheduling is to schedule In such a way that all packets can be transmitted within the minimum time. In this paper, we propose the condition for optimal transmission schedules and present an optimal transmission scheduling algorithm for arbitrary values of N, k, and ${\delta}$ The cycle length of the optimal schedules is $max{[\frac{N}{k}](M-1)$, $k{\delta}+N-1$}.

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Interpretation of the Magnetic Logs for a Finite Line of Magnetic Dipoles Model (유한 선형 자기쌍극자 모델에 대한 검층자료의 해석)

  • Kim, Jin Hu
    • Journal of the Korean Geophysical Society
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    • v.2 no.2
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    • pp.135-142
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    • 1999
  • Interpretations of 3-component magnetic logging data obtained for a reinforced bar as a model of the line of the magnetic dipoles are conducted using a least squared inversion technique. The length of the bar is 1.12 m, sampling interval is 0.05 m, the distance between the bar and the borehole is 0.3 m, and the top of the bar is fixed at 0 m of depth. The bar is set to be approximately vertical. Magnetic anomalies smoothed with FFT are used as input data for the inversion. For the interpretation of magnetic logging data the depth to the top, the length, the magnetic moment per unit length, the direction of the magnetization (declination and inclination), and the bearing and plunge of the line of magnetic dipoles are left as unknown parameters. The comparison of the results obtained from the individual inversion of the horizontal component or the vertical component of the magnetic anomalies, and those from the simultaneous inversion of horizontal and vertical component of the magnetic anomalies shows that there exist some disagreements between each inversion result. The depth to the bottom of the bar, which is actually 1.12 m, is estimated as 1.18 m, and the inclination of the magnetization is estimated as -76°by simultaneous inversion. The negative value of the inclination indicates that the strength of the remnant magnetization is much greater than that of the induced magnetization, so that the direction of the resultant magnetization points to the top of the bar.

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Efficient Resource Allocation Schemes for Relay-based Cooperative Networks in 3GPP LTE-Advanced Systems (3GPP LTE-Advanced 시스템에서 릴레이 기반의 협력 네트워크를 위한 효율적인 자원할당 기법)

  • Kim, San-Hae;Yang, Mo-Chan;Lee, Je-Yeon;Shin, Yo-An
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.6A
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    • pp.555-567
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    • 2010
  • Unlike single-hop systems, multi-hop systems that use relay nodes assign a part of the overall resources to relay communications. If efficient resource allocation schemes are not adopted, this leads to a loss of resources. Moreover, because we may not be able to guarantee high-link performance due to the adjacent-cell interference in relay-based cellular systems, resource efficiency can be severely decreased. In this paper, we propose efficient resource allocation schemes for downlink relay-based networks in 3GPP (3rd Generation Partnership Project) LTE (Long Term Evolution)-Advanced systems. Unlike conventional schemes that have static resource regions for each data link, the proposed schemes dynamically allocate the resources of each link to resource blocks, by considering the channel state and the capacity of each link. We also propose resource overlapping schemes in which two different links overlap at the same resource region, so as to improve cell or user throughput performance. The proposed resource overlapping schemes do not require additional processes such as interference cancellation in users, thank to considering additional interference from resource overlapping in advance.

Study on Comparison of Dental Prosthesis Condition according by Educational Level (교육수준에 따른 구강 보철물 상태 비교 연구)

  • Kim, Hye Youn;Lee, Mi Hee;Kim, Ji Hye
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.123-129
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    • 2017
  • This study investigated the dental prosthesis condition from the sixth primitive data of Korea National Health and Nutrition Examination Survey to analyze and compare the necessity of existent dental prosthesis condition, dental bridge and dentures in order to determine the real oral health condition by educational level targeting adults aged over 20 years old. From the results, based on demographic-sociologic features, 32.2% of females were under elementary school graduation level, which was lower than males, and the educational level decreased with increasing age, and these trends were statistically significant. As for income level, 45.3% of university graduates had the highest income level and 77.4% of this age group were professionals, which was the highest percentage and was statistically significant. In terms of dental prosthesis condition according to educational level, the under elementary school graduation group had the most dental prosthesis and the greatest need for partial dentures and full dentures. As for the necessary number of fixed implants, the upper jaw had the most number of fixed implants and in the lower jaw, the under middle school graduation needed the most fixed implants.

A Transmission Scheduling Algorithm for All-to-all Broadcast in Optical Passive Star Interconnections (Passive Star형 광상호연결망에서의 All-to-all 방송을 위한 송수신 스케쥴링 기법)

  • Chang, Seok-Mun;Byeon, Kwang-June;Yeh, Hong-Jin;Wee, Kyun-Bum;Hong, Man-Pyo
    • The Transactions of the Korea Information Processing Society
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    • v.5 no.8
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    • pp.2013-2026
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    • 1998
  • In optical passive star interconnections, all packets are transmitted between nodes ina broadcast and-select manner. It is assumed that each node has a innable transmitter and a fixed-savelength receiver, ad that all packet lengths are equal so that each transmission can be done in a unit time. The tuning delay, denoted by $\delta$, means the amount of time for transmitter to change its wavelength to another one. The problec is , given ay value of the mumber of nodes N and the number of wavelengths $\kappa$ according to WDM implementations, to find transmission schedules with minimum cycle length for all-to all brondcaxt where no one sends any packet to itself. In this paper, we prove that the cycle length of optimal transcission schedules should be at least $max[[{\frac{N}{k}](N-1)}]$,$k\delta$$+N-1$. A novel algorithm for optimal transmission schedules is then presented when N-1 is divisible by $\kappa$. This algorithm also can be used for any values of N and $\kappa$ if the tuning delay $\delta$ does not affect strictly the cycle length of transmission schedules, i,e, $[\frac{N}{k}](N-1)$ > $\kappa\delta$+N-1.

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Alteration of Anaerobic Bacteria and S. mutans Count in Oral Cavity after Occlusal Stabilization Appliance Use (교합안정장치 사용에 따른 구강 내 혐기성 세균과 S. mutans의 변화)

  • Byun, Jin-Seok;Suh, Bong-Jik
    • Journal of Oral Medicine and Pain
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    • v.32 no.4
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    • pp.375-381
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    • 2007
  • Occlusal stabilization appliance is one of the most common treatment option for management of temporomandibular disorders. It acts in oral cavity for several hours per day, and usually it will take at least 6 months to 2 years of total wearing periods to take a treatment goal. In the oral cavity, occlusal stabilization appliance, unintentional manner, is able to acts as a reservoir of bacteria and protect bacteria from saliva and oxygen. This condition is so favorable to many bacteria such as S. mutans and other anaerobes, usually have been reported as causative factors of dental caries, periodontal disease and oral malodor. In this study, we investigated anaerobic bacteria and S. mutans count before and after occlusal stabilization appliance use to evaluate the possible role of occlusal stabilization appliance as protector of these bacteria. Four men(average 27.5 years) wore maxillary occlusal stabilization appliance at each night(average 9 hours) for 5 days. we swabbed saliva-plaque mixed sample at 3 different site(maxillary left 2nd molar, maxillary left central incisor, mandibular left 2nd molar) before and after occlusal stabilization appliance use. Each samples were plated in (1) anaerobic blood agar medium, (2) selective S. mutans medium(MS-MUTV) and incubated in anaerobic chamber($CO^2$ 10%, $37^{\circ}C$) for 72 hours. Each bacterial colony forming unit(CFU) were counted with naked eyes. From obtained data, we can conclude as follows: 1. There was some changes about anaerobic bacteria and S. mutans count in oral cavity after occlusal stabilization appliance use. 2. The number of anaerobic bacteria was significantly increased at maxillary 2nd molar(P=0.003), maxillary central incisor(P=0.020) after occlusal stabilization appliance use compared with before. 3. Occlusal stabilization appliance use itself had indirect effect to increase the number of anaerobic bacteria at other uncovered opponent tooth site. 4. The number of S. mutans was significantly increased at maxillary 2nd molar(P=0.043), maxillary central incisor (P=0.049) after occlusal stabilization appliance use compared with before. 5. Occlusal stabilization appliance use itself had not any effect on the number of S. mutans at other uncovered opponent tooth site.

Petrochemical study on the Daejeon-sa basalt in the Mt. Juwang area, Cheongsong (청송 주왕산지역 대전사 현무암의 암석화학적 연구)

  • 윤성효;이문원;고정선;김영라;안지영
    • The Journal of the Petrological Society of Korea
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    • v.9 no.2
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    • pp.84-98
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    • 2000
  • Daejeon-sa basalt in the Mt. Juwang area composed of 12 basalt flows alternate with 9 peperites and each basalt and peperite has the variety of thickness. Peperites yielded in Daejeon-sa basalt are mixed of basalt with reddish shale, of which textural type is globular peperite. Basalts yielded in Daejeon-sa basalt are massive basalt without vesicule, although sometimes vesicules are founded in upper within a flow unit. The basalt has mainly pseudomorph of olivine as phenocryst, and also plagioclase and clinopyroxene phenocryst. Matrix is mainly subophitic texture. The plotting result on the TAS diagram shows these basalts belong to the sub-alkaline, and it can be subdivided into calc-alkaline series on the basis of the diagram of Si02 vs. K20 and of alkali index vs. A1203 diagram. According to plots of wt.% oxides vs. wt.% MgO, abundances of A1203 and CaO increase with decreasing MgO while F ~ dOecre~ase . With decreasing MgO compatible elements decrease while incompatible elements increase. In spider diagram of MORB-normalized trace element patterns, HFS elements are nearly similiar with MORB, but LIL elements are enriched. Especially, contents of Ce, F: and Sm are enriched but Nb is depleted. In the chondrite-normalized REE patterns light REEs are enriched than heavy REEs. Tectomagmatic discrimination diagrams shows basalts in the study area are formed in the tectonomagmatic environment of subduction zone under continental margin. This result accord with characters of chemical composition mentioned above. Cr vs. Y diagram and CeM, vs. Ce diagram show that the primary magma of the basalts may formed by the about 15% partial melting of garnet-peridotite in the mantle wedge. After then, Daejeon-sa basalts may formed from evolved magma undergone mainly olivine fractional crystallization and contarnination of crustal materials before eruption.

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Hue Shift Model and Hue Correction in High Luminance Display (고휘도 디스플레이의 색상이동모델과 색 보정)

  • Lee, Tae-Hyoung;Kwon, Oh-Seol;Park, Tae-Yong;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.44 no.4 s.316
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    • pp.60-69
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    • 2007
  • The human eye usually experiences a loss of color sensitivity when it is subjected to high levels of luminance, and perceives a discrepancy in color between high and normal-luminance displays, generally known as a hue shift. Accordingly, this paper models the hue-shift phenomenon and proposes a hue-correction method to provide perceptual matching between high and normal-luminance displays. The value of hue-shift is determined by perceived hue matching experiments. At first the phenomenon is observed at three lightness levels, that is, the ratio of luminance is the same between high and normal-luminance display when the perceived hue matching experiments we performed. To quantify the hue-shift phenomenon for the whole hue angle, color patches with the same lightness are first created and equally spaced inside the hue angle. These patches are then displayed one-by-one on both displays with the ratio of luminance between two displays. Next, the hue value for each patch appearing on the high-luminance display is adjusted by observers until the perceived hue for the patches on both displays appears the same visually. After obtaining the hue-shift values, these values are fit piecewise to allow shifted-hue amounts to be approximately determined for arbitrary hue values of pixels in a high-luminance display and then used for correction. Essentially, input RGB values of an image is converted to CIELAB values, and then, LCh (lightness, chroma, and hue) values are calculated to obtain the hue values for all the pixels. These hue values are shifted according to the amount calculated by the functions of the hue-shift model. Finally, the corrected CIELAB values are calculated from corrected hue values, after that, output RGB values for all pixels are estimated. For evaluation, an observer's preference test was performed with hue-shift results and Almost observers conclude that the images from hue-shift model were visually matched with images on normal luminance display.