• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06b
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• pp.55-85
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• 1996

지르코니아 분말은 ZrO2 결정상이 온도변화에 따라 부피변화를 수반하는 상전이변태를 나타낸다. 단사정 ZrO2가 110$0^{\circ}C$에서는 정방정으로, 2$700^{\circ}C$ 내외에서는 입방정으로 결정구조가 가역적으로 변한다. 이 ZrO2에 금속산화물을 고용시키면 형석 (CaF2:Florite)형의 입방정 결정구조가 실온에서도 안정하게 존재하게 된다. 안정화제 산화물은 caO, MgO등 2가 산화물외에 3가 또는 4가의 금속산화물로서 Sc2O3, Y2O3, Sm2O3, Nd2O3, Gd2O3, Y2O3, CeO2 등이며 이들은 금속이온의 원자가가 변하기 쉬운 희토류 산화물이다. 안정화 지르코니아는 형석형 결정구조이며 결정화학적으로 보면 금속양이온이 산소이온에 대해서 정육면체형의 8배위를 하고 있다. 이때 이온반경비(양이온/음이온)에 따라 Zr+4자리와 O-2자리의 격자위치와 모양이 형성되므로 비틀어진 정육면체구조이건 이상적인 정육면체 형석구조를 이룬다. 이는 지르코니아의 결정상의 2상-3상인 부분안정화 지르코니아다결정체(PSZ : partially stabilized zirconia)이거나 단일상-2상인 정방정 지르코니아다결정체(TZP : tetragonal zirconia polycrystal)의 결정구조를 가지는데 기인한다. PSZ는 주로 MgO, CaO를 안정화제로 고용시켜 입방정 영역에서 소결하고 이를 다시 입방정과 정방정의 상 영역에서 열처리하여 입방정 입자내부에 정방정을 석출 형성시킨 것이며 TZP는 Y2O3 및 CeO2를 고용시켜 PSZ와 다르게 일반적인 상압소결한 정방정 결정상의 미립자이다. 산화지르코늄 분말은 지르콘사에서 열분해시킨 지르코늄소결.융해괴(caustic fusion clinker)를 산처리하여얻어진 지르코늄산용액(zirconyl acid solution : cloride, sulfide, nitride 등)으로부터 제조된다. 고순도 산화지르코늄은 용액 결정석출법에 의해 ZrOCl2.8H2O, 5ZrO2.3SO3.15H2O, ZrO(NO3)2.xH2O 등의 지르코늄 수화물만을 재결정화시킨 것으로부터 얻을 수 있으며 이 지르코늄염 수용액으로부터 입자미세구조를 효과적으로 제어하여 산화지르코늄 및 안정화 지르코니아 분말제조가 가능하다. 안정화 지르코니아 분말은 ZrO2와 안정화산화물의 고용을위하여 가열처리를 필요로 하며 일정온도에서 최적상태로 숙성하므로서 2가지 상(phase) 이상의 고용체를 가지게 된다. 안정화 지르코니아 분말은 고용처리온도를 낮추고 효과적으로 생성시키기 위해서는 지르코늄 및 안정화제염을 혼합하고 습식 직접합성하여 저온에서 고용체의 합해진상 영역을 생성시키는 것이다. 이는 지르코니아 원료분말의 미세구조를 제어하므로서 가능하며 이때 화학성분조성과 크기형태가 균일하게 분포된 입자분말을 얻을 수 있다.

• Journal of the KSME
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• v.57 no.10
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• pp.48-52
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• 2017

이 글에서는 공간적으로 형상 제어된 나노구조물의 자기조립화(self-assembly)를 이용하여 고용량의 이온흐름이 가능한 나노전기수력학 기술에 대한 소개와 더불어, 이를 활용한 이온 다이오드, 고효율 마이크로 믹서, 이온농도차 발전 응용 및 향후 생체 내 이온검출 센서, 인체 삽입형 디바이스, 뇌-기계 인터페이스 연구에 대한 전망을 소개하고자 한다.

• Journal of the Economic Geographical Society of Korea
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• v.14 no.3
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• pp.325-341
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• 2011

The population and employment of Cheongju have increased rapidly since the 1970s. This study examines the industrial employment change of Cheongju City and performs a shift-share analysis for the employment growth. The data used in this study are mainly from the 1985, 2000 and 2005 Census of Population and Housing. This study first explained the population change and industrial structure of Cheongju, then reviewed the development of shift-share models. Location quotients and specialization coefficients resulted from this study revealed the diversifying tendency in the urban industrial structure. Shift-share analysis employing the modified Arcelus model elucidated the favorable industrial mix and the competitiveness of industrial sectors. As a whole, Cheongju has advantageous industrial structure in comparison with that of the nation. All sectors of Cheongju except several services sectors grew faster than those of the nation and showed positive competitive effects. It is suggested to utilize more disaggregated industrial data in more fractured subperiod in order to pinpoint the competitive industries.

• Proceedings of the Korean Association for Survey Research Conference
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• 2000.06a
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• pp.117-135
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• 2000

The corporate restructuring following the economic crisis in Korea has brought about fundamental changes in the structure and practice of employment relations. However the lack of information on processes and consequences of such changes hinder the appropriate policy making on shop-floor industrial relations. Correct assessment of realities an effective policy making require information on human resource management practices and structure of employment relations at the workplace level. This paper critically examines the experiences of workplace-employee integrated surveys carried out in advanced countries including Australia, Canada, and Britain, to extract methodological implications for such survey in Korea. We focus on the backgrounds of the surveys and practical issues involved in multi-level, longitudinal survey design.

• Survey Research
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• v.1 no.2
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• pp.117-135
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• 2000

The corporate restructuring following the economic crisis in Korea has brought about fundamental changes in the structure and practice of employment relations. However the lack of information on processes and consequences of such changes hider the appropriate policy making on shopfloor industrial relations. Correct assessment of realities and effective policy making require information on human resource management practices and structure of employment relations at the workplace level. This paper critically examines the experiences of workplace-employee integrated surveys carried out in advanced countries including Australia, Canada, and Britain, to extract methodological implications for such survey in Korea. We focus on the backgrounds of the surveys and practical issues involved in multi-level, longitudinal survey design.

• Journal of Labour Economics
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• v.33 no.1
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• pp.85-107
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• 2010

In this article, since the financial crisis, Korean employment movement to service market, productivity gap between manufacturing and service industry was significant compared with other countries. The results from productivity decomposition show that negative structural changes, which employment increase is contrary to the productivity, have been intensified since the financial crisis. It is caused from a different developing pattern. While the proportion of employment was reduced, productivity has improved in manufacturing industry. While the developing was due to the high increase of the employment proportion in service industry, productivity was not improved significantly. This tendency is clearly revealed in international comparisons. In Korea the negative trend of structural changes in service industry are intensified compared to manufacturing industry after the financial crisis.

• 재활복지
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• v.17 no.4
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• pp.177-196
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• 2013

The object of this article is to examine the effect of the quota-levy system on employment outcome of people with disabilities in Korea. Merging the data from disability employment report of 16,246 businesses in 2011 and the macroeconomic indicators such as regional economic condition, the author analyzes the effect of quota-levy system on employment outcome of persons with disabilities by using Hierarchical Linear Model(HLM). The finding is that imposing the levy on businesses affects employment outcome of people with disabilities but regional economic condition does not. The rate of employees with disabilities of the levied business is 0.7%p higher than that of the other business. The result of analysis implies that employment outcome of people with disabilities is influenced by the quota-levy system rather than regional economic condition.

• Journal of Korea Technology Innovation Society
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• v.21 no.4
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• pp.1508-1535
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• 2018

Employment in enterprises is a consecutive decision-making process based on the results of their innovative activities and it is necessary to consider this relationship as well explicitly in an analysis of the employment performance through technological innovation. Based on this critical mind, this study would analyze the structural relationships among enterprises' innovative activities, the performance of technological innovation, a compensation system and the creation of employment, reflecting the correlation of the process of the actual technology management performed simultaneously, utilizing the seemingly unrelated regression(SUR) model to estimate a simultaneous equation in addition to analyzing the relationship between technological innovation and the effect on employment with the ordered logit model to estimate a single equation as in the preceding studies. As a result of the analysis, a structural relationship could be found out, in which the execution of the compensation system would increase the performances of technical development and technology commercialization, which in turn, accelerates enterprises' employment. Especially, it is judged that enterprises' employment performance increases when technological innovation is managed from a process perspective in that the commercialization performance, as well as technical development, acts as a kind of hurdle in the effect on employment.

• Journal of Service Research and Studies
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• v.6 no.3
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• pp.15-27
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• 2016

The current research suggests a new industry and employment structure accelerated by the 4th industrial revolution. An in-depth analysis on relevant researches and a macro analysis on industry and employment structure change have been performed. Past and present industrial revolutions have been reviewed based on the nature of employment and industry structure. With technological advances and increase in productivity, the services industry has developed during the 1st and 2nd industrial revolutions. Moreover, in the 4th industrial revolution era, more changes are expected within the services industry. A new U-model has been derived and a service economy acceleration model has been suggested. This research can be used for deriving desirable industry and economic policy. Future research is needed to develop a detailed solution for human resource management strategy for service economy in the 4th industrial revolution era.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.166-166
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• 2003

경제적 효율의 발전을 원칙으로 하는 종래의 틀을 넘어서서 환경공생형의 새로운 에너지 시스템의 개발에 대한 요구가 증대되어 지고 있다. 이러한 시대적 흐름에 부응하는 여러 가지 신재료의 개발에 관한 연구가 이루어지고 있다. 그 중에서 전기를 열로 열을 전기로 변환 시킬 수 있어서 폐열의 이용 및 전자냉각기술 등에 이용 가능한 열전변환재료가 커다란 기대를 모으고 있다. 열전재료는 사용온도 영역에 따라 여러 가지 재료가 개발되어 지고 있으며, 현재 상온부근 및 저온영역에서 응용 가능한 재료로써 Bi$_2$Te$_3$계 고용체에 관한 연구가 활발하게 진행되고 있다. 예를 들어, Bi$_2$Te$_3$ 고용체에서 Bi를 Sb으로 치환한 p-type의 (Bi,Sb)$_2$Te$_3$ 고용체와 Te을 Se으로 치환한 n-type의 Bi$_2$(Te,Se)$_3$ 고용체에 관한 연구가 이루어지고 있다. 최근 들어 Kutasov등은 종래에 P-type의 열전재료로써 높은 특성을 나타내는 것으로 알려진(Bi,Sb)$_2$Te$_3$ 고용체가 Sb의 치환량과 Te의 도핑량을 잘 조절하면 n-type의 높은 열전 특성을 나타낸다고 보고하였다. 본 연구에서는 과잉으로 첨가된 Te이 n-type (Bi,Sb)$_2$Te$_3$ 고용체에 미치는 영향을 보다 체계적으로 조사하기 위한 기초단계의 연구로써 Te을 0-0.9at.%로 과잉 첨가하여 제조한 고용체 및 소결체의 미세구조에 관하여 조사하였다.