• Title/Summary/Keyword: 고온전이

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Effects of barrier film on optical properties of quantum dot film (베리어 필름이 양자점 필름의 광특성에 미치는 영향)

  • Lee, Jung-Il;Kim, Young-Ju;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.78-81
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    • 2020
  • Quantum dot efficiency was increased to evaluate reliability and optical characteristics using incidental materials. Quantum dot was manufactured by wrapping a sandwich type quantum layer using a product with a barrier property to prevent water and oxygen because it is vulnerable to oxygen and moisture. We used the three quantum dot films consisting of quantum dot only and quantum dot products consisting of film and barrier film combined with PET in the quantum dot product to evaluate the change over 650 hours under high temperature and high humidity conditions at 60℃ and 90 % humidity. As a result, the quantum dot product with Barrier Film has lowered luminance by 8 %, CIE x by 2 % and CIE y by 8 %. Quantum dot products exposed to moisture and oxygen were oxidized and measured low before measurement.

Pretreatment Characteristics of Ammonia Soaking Method for Cellulosic Biomass (암모니아 Soaking 방법을 이용한 섬유소계 바이오매스의 전처리 특성)

  • Park, Yong-Cheol;Kim, Jin-Woo;Kim, Jun-Seok
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.292-296
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    • 2011
  • Liberation of fermentable sugars from lignocellulosic biomass is one of the key challenges in production of cellulosic ethanol. Aqueous ammonia cleaves ether and ester bonds in lignin carbohydrate complexes. It is an effective swelling reagent for lignocellulosic biomass. The aqueous ammonia pretreatment selectively reduces the lignin content of biomass. However, at high temperatures, this process solubilizes more than 50% of the hemicellulose in the biomass. Here we conducted a SAA(Soaking in Aqueous Ammonia) process by moderate reaction temperatures at atmospheric pressure using various lignocellulosicbiomass. The optimum condition of this process was 15 wt% of aqueous ammonia at 50 of reaction time during 72 hr. The delignification was up to 60% basis on initial biomass and the enzymatic digestibility was 60-90% for agricultural biomass, respectively.

Characteristics of Temperature in Reformer Tube and Chemical Reaction for Steam Methane Ratio (수증기-메탄 혼합비에 따른 개질 튜브 내 온도 및 화학반응 특성)

  • Han, Jun Hee;Kim, Ji Yoon;Lee, Seong Hyuk
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.27-33
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    • 2016
  • The aim of numerical study is the investigation of the solid and fluid temperatures in a reformer tube and chemical reaction characteristics of different steam-carbon ratio. We considered conjugate heat transfer contain radiation, convection and conductive heat transfers. This is because steam reforming reaction of hydrocarbon occurred high temperature conditions up to 800 K- 1000 K by using commercial computational fluid dynamics (CFD) code (Fluent ver. 13.0). For numerical simulation, the Reynolds-Averaged Navier-Stokes, momentum and energy equation were employed. In addition, inside of reformer tube is assumed as the porous medium to consider the Nichrome-based catalyst. To analysis characteristics of tube temperature in chemical reaction, we changed steam-methane ratio(SCR) from 1 to 6. As increased SCR, the higher tube temperature and methane conversion were observed. It was obtained that the highest hydrogen production held in SCR of 5.

투명 면상 발열체 응용을 위한 하이브리드 스퍼터 GZO/Ag/GZO 박막의 물성평가

  • Kim, Jae-Yeon;Song, Pung-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.182.2-182.2
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    • 2015
  • 최근 학계나 산업계에서 투명 전자 소자에 대하여 활발한 연구가 진행되면서, 투명 전 도성 산화물(TCO: transparent conductive oxide)에 대한 관심이 높아지고 있다. 대표적인 TCO 물질인 Indium Tin Oxide (ITO)는 가시 광 영역에서의 높은 투과 및 높은 도전성을 가져 전압을 인가하면 발열이 가능하므로 이를 투명 면상 발열체에 적용시키는 연구가 활발히 진행되고 있다. 하지만, ITO는 발열 테스트 결과 온도가 상승함에 따라 발열이 일부분에 집중되는 현상이 있으며, 전도성을 높이기 위하여 추가공정이 필요하다. 또한, 글라스의 곡면 부분에서 ITO를 사용하면 유연성이 부족하므로 크랙이 발생한다는 단점이 있다. 따라서, 최근 Silver nanowire (AgNW), Single-walled Carbon nanotube (SWCNT), ITO를 기반으로 한 AgNW에 ITO를 증착 하거나 SWCNT를 코팅하여 우수한 전기적, 광학적 특성을 지닌 하이브리드 전극이 투명 면상 발열체 재료로서 사용되고 있다. 하지만 대체된 재료들도 다양한 문제점을 가지고 있다. 예를 들어 고온에서 발열을 유지하지 못하고 끊어지거나 가시광영역의 투과율이 낮은 점 등이 있다. 이런 다양한 문제점들을 보완 할 수 있는 새로운 투명 면상 발열체에 적용한 연구가 요구되고 있다. 본 연구에서는 GZO/Ag/GZO 하이브리드 구조의 투명 면상 발열체를 제작하여 전기적, 광학적 특성을 비교하고 발열량, 온도 균일 성, 발열 유지 안정도를 확인하였다. 본 연구에서는 $50{\times}50mm$ 크기의 Non-alkali glass (삼성코닝 E2000) 기판 상에 DC마그네트론 스퍼터링 공정을 이용하여 상온에서 GZO, Ag, GZO 박막을 연속적으로 증착 하여 다층구조의 하이브리드형 투명 면상 발열체를 제조하였다. 박막 증착 파워는 DC (Ag) power 50 W, RF (GZO) power 200 W로 하였으며 GZO박막두께는 45 nm로 고정 시키고 Ag박막 두께는 5~20 nm로 변화를 주었다. 증착원은 3인치 GZO 세라믹 타깃 (2.27 wt. % Ga2O3) 과 Ag 금속 타깃 (순도 99.99%)을 사용하였으며, Ar을 40 sccm 주입 후 Working pressure는 고 순도 Ar을 사용하여 1.0 Pa로 고정하며 10분간 Pre-sputtering을하고 증착을 진행하였다. 앞선 실험을 통해 증착한 박막의 전기적, 광학적 특성은 각각 Hall-effect measurements system (ECOPIA, HMS3000), UV-Vis spectrophotometer (UV-1800, Shimadzu)를 사용해 측정 되었으며, 하이브리드 표면의 구조 및 형상은 FESEM으로 관찰하였다. 또한 표면온도 측정기infrared camera (IR camera)를 이용하여 4~12 V/cm의 전압을 인가 시 시간에 따른 투명 면상 발열체의 표면 온도변화를 관찰하였다.

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Growth and Green Pod Yield by Sowing and Acclimation Dates in Autumn Green Pea (추파 풋완두 파종과 순화시기에 따른 생육 및 수량)

  • 김동관;이정양;윤창용;이야성;국용인;천상욱;박인진
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.447-451
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    • 2003
  • When sowing green peas in the autumn, proper seedling stands and growth quantity should be secured before winter begins. Also, for proper acclimatization, injuries caused by low temperatures, frost or high temperatures in the P.E. film during mulching, should be avoided during the regeneration period; that being early spring. The days required for growth in each stage in Yeosu are shorter than those in Naju because Yeosu has high temperatures during the growth period. Furthermore, in Yoesu, it was observed that there were more effective branches as well as effective and attached node positions on the branches. The first pods on the main stems and effective branches were observed to be higher than those in Naju. The number of pods per plant and the number of seeds per pod in Yoesu was greater than for those in Naju and the pod length was longer as well. Considering the missing plant rate, growth, and green pod yield, the optimum sowing date for the green pea was mid-November in both location. The stable acclimatizing date for the green pea was early March when the highest yield can be acquired due to a lot of effective branches and pods per plant and with the lowest missing plant rate and rate of injury in acclimatization.

Antioxidation mechanism of Al metal powders on $Al_2O_3-C$ refractory ($Al_2O_3-C$계 내화물에서 알루미늄 금속분말의 산화억제 메카니즘)

  • 류정호;임창성;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.97-105
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    • 1998
  • Antioxidation mechanism of Al metal powders on $Al_2O_3-C$ refractory was investigated in temperature range from 800 to $1400^{\circ}C$. The addition of 5 wt% Al metal powders suppressed the oxidation of carbon in $Al_2O_3$-C sample. The carbons were distributed uniformly on the surface and the interface of the $Al_2O_3$-C-Al. Reaction products of $Al_4C_3$ and AIN were found with a composition of Al-C at temperatures between 800 and $1200^{\circ}C$ and transformed to $Al_2O_3$ above $1400^{\circ}C$. Cavity structures related to the to the formation of $Al_4C_3$ were observed for the AI-C after heating at $1000^{\circ}C$ ofr 1 hour. Thermodynamic mechanism was considered to discuss the formation $Al_4C_3$, AlN and their transformation to $Al_2O_3$, which leads to the effect of oxidation resistance.

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Production of Hydrogen-Rich Gas from Methane by a Thermal Plasma Reforming (고온 플라즈마 개질에 의한 메탄으로부터 고농도 수소생산)

  • Kim, Seong-Cheon;Lim, Mun-Sup;Chun, Young-Nam
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.362-370
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    • 2006
  • The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

Hydrogen Production by the High Temperature Steam Electrolysis of NiO/YSZ/Pt Cell (NiO/YSZ/Pt 전해셀의 고온 수증기 전해에 의한 수소제조 특성)

  • Yu, Ji-Haeng;Kim, Young-Woon;Lee, Shi-Woo;Seo, Doo-Won;Hong, Ki-Suk;Han, In-Sub;Woo, Sang-Kuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.62-68
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    • 2006
  • High temperature electrolysis is a promising technology to produce massively hydrogen using renewable and nuclear energy. Solid oxide fuel cell materials are candidates as the components of steam electrolysers. However, the polarization characteristics of the typical electrode materials during the electrolysis have not been intensively investigated. In this study, NiO electrode was deposited on YSZ electrolyte by spin coat process and firing at $1300^{\circ}C$. Pt electrode was applied on the other side of the electrolyte to compare the polarization characteristics with those by NiO during electrolysis. The $H_2$ evolution rate was also monitored by measuring the electromotive force of Lambda probe and calculated by thermodynamic consideration. At low current density, Pt showed lower cathodic polarization and thus higher current efficiency than Ni, but the oxidation of Ni into NiO caused the increase of anodic resistance with increasing current density. High overpotential induced high power consumption to produce hydrogen by electrolysis.

Characterization of a new variety "Backryeon" developed by crossing in Tricholoma giganteum (왕송이(Tricholoma giganteum) 신품종 '백련'의 특성)

  • Jang, Kab-Yeul;Kong, Won-Sik;Yoo, Young-Bok;Lee, Kang-Hyo;Jhune, Chang-Sung;Lee, Jung-Hoon;Sung, Jae-Mo
    • Journal of Mushroom
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    • v.7 no.4
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    • pp.187-192
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    • 2009
  • Tricholoma giganteum, belongs to Tricholomataceae of Tricholoma, is also well-known as the medicinal mushroom in Taiwan. "Backryon" was the first variety developed by intra-specific crossing in Korea. It was improved with hybridization between monokaryotic strain derived from MKACC50852 and MKACC 50853. The optimum temperature of mycelial growth and fruiting body development were $25{\sim}30^{\circ}C$ and $20{\sim}25^{\circ}C$, respectively. The color of fruitingbody was pure white and cap type was umbrella. It suggested that 'Backryon' was new commercial variety for small-sized cultivator during the summer season.

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Preparation of Flexible and Light Thermal Insulating Ceramic Composites Using Foaming Technology (발포공정을 이용한 경량의 연질 세라믹 보온단열재의 제조)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.59-66
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    • 2015
  • A new concept of an inorganic foaming process at low temperature was demonstrated for the production of inorganic thermal insulating materials with the properties of flexible light-weight, the advantages of organic-based thermal insulation material. The foaming process was proceeded by establishing a skeleton of the foam body by using inorganic fibrous sepiolite and aluminum silicate. A cavity was formed by the expansion of fibrous skeleton body, by the gas which was generated from foaming agent at low temperature. Then the multi-vesicular expanded perlite with low thermal conductivity was filled into the cavity in a skeleton of the foam body. Finally through these overall process, a new inorganic foamed body could be obtained at low temperature without the hot melting of inorganic materials. In order to achieve this object, various preparations such as fibrous sepiolite fibrillation process, heat treatment process of the fibrous slurry were needed, and the optimal compositional condition of slurry was required. The foam body produced showed the properties of flexible light-weight thermal insulation materials such as bulk density, yield strength, flexural strength, and high heat resistance.