• Proceedings of the Materials Research Society of Korea Conference
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• 2009.05a
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• pp.57.1-57.1
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• 2009

나노이산화티타늄은 인체에는 화장품, 의약, 식품분야 등에 쓰이고 외부 환경 재료에는 광촉매로서 유독가스 정화제, 옥내 외 항균, 수소발생 가시광 응답형 촉매 및 멤브레인 필터 등과 전자소재용 유전재료, 발광 재료 등 용도가 다양하다. 나노 산화티타늄 화합물의 제조법은 수열합성법, 기상법 등 여러 방법이 있다. 이들에 대한 리뷰의 목적은 2009년도 정부의 투자 계획 중에서 본제목에 관련되는 핵심 산업 재원 원천기술 개발, 태양광, 풍력 등의 신재생 에너지 개발, 록색 기술 개발을 통한 에너지절약형 LED 개발, 차세대 핵심환경 기술 개발, 핵심나노기반기술개발 등의 개발을 위하여 4,363억 원의 예산을 편성하고 연구자와 기술자들이 참여하여 유익한 실적이 창출되기를 원하고 있으므로 본 발표자들은 이 분야에서 연구하는 연구자와 기술자들에게 이 분야에 관련되는 자료를 참고로 제시하는데 있다. 페로브스카이트형 산화물인 유전재료($BaTiO_3$), 발광재료(CaTiO3:Pr3+적색), 박막형 반응기재료($Ca0.8Sr0.2TiO_3$), 등의 여러 가지 산화물은 류통식 급속 승온 수열 합성법, 겔 졸 법, 수열 합성법 등 여러 방법에 의하여 페로브스카이트형 산화물 입자 직경이 약 20nm~100nm 범위까지 합성된다. 태양광을 조사하여 물을분해 해서 수소를 생산하는 산화티타늄계 가시광 응답형 Vis-$TiO_2$ 박막은 기상법으로 제조하는데 한 예로써 RF 스퍼터링법으로 박막을 제조하여 수소와 산소를 회수하였으며, 황도프산화티타늄, 질소 도프 산화티타늄은 유기물 분해에 의한 공해제거, $NO_x$ 제거 등 환경정화에 사용되고, 고온 고압수법/산화티타늄 복합기술에 의해서는 바이오매스 분해 하고, 일종의 수열법인 개량형 HyCOM 법은 가시광 응답성 산화티타늄을 합성하여 NO가스 제거에 사용한다. 이들 여러 방법에 관한 것을 소개하고저 한다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.3
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• pp.223-229
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• 1994

$KTP(KTiOPO_4)$ single crystals have been hydrothermally grown in KOH solutions. Properties and Raman spectra of grown crystal were investigated. The most effective solvents for the crystal growth of KTP were KOH and KF solutions. In this study, the properties of KTP single crystals grown hydrothermally at $500^{\circ}C$ in 9 m KOH solution were measured. The following results were obtained : lattice parameters ; a=1.281 nm and c=1.058 nm, density ; $2.94 g/cm^3$, Vickers hardness ; $562kg/cm^2$, refractive indices ; $n_e=1.740$ and $n_e= 1.747.$ And Raman spectra of hydrothermal growth KTP single crystal have been investigated at room temperature under atmospheric pressure. As a result, the $A_1$ modes agree very well with KTP single crystal of high temperatures solution growth but the behavior of $B_2$ modes were slightly different.

• Magazine of the Korea Concrete Institute
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• v.14 no.2
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• pp.17-23
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• 2002

화재로 인한 건물의 화해 정도는 건축구조불의 안전성에 크게 영향을 미치게 된다. 특히, 철근 콘크리트 구조물이 화재로 인하여 고열을 받게되면, 그 구조적인 내력이 저하되므로, 이에 대한 안전성 검토는 매우 중요하다. 콘크리트의 고온성상은 시멘트의 종류, 골재의 석질. 배합, 함수율, 재령에 따라 달라진다. 또한, 화해를 입은 콘크리트조 건물은 수열조건에 따라 매우 복잡한 양상을 띄게된다. 일반적으로 화재 건물의 콘크리트 부재에서 나타나는 화해는 각 부재의 폭열 또는 콘크리트의 박리에 의한 주근의 노출 등 직접적인 손상과 보의 변형 기둥의 좌굴, 열팽창에 의한 전단균열 등의 2차 적인 피해가 있다. 그 화해 정도는 지진피해의 파괴현상과 유사한 경우도 있다. 이와 같이 콘크리트 부재의 화재 정도를 검토하기 위해서는 콘크리트의 고온성상 파악이 중요하다.(중략)

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.176-177
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• 2017

IN order to use it for high-temperature fire, Fireproof boards mainly composed of Ca and Mg used. Korea does not have a fireproof board for explosive high temperatuer fire in tunnel, and it is applying existing fireproof coating. However, when a high-temperature fire(1350℃)with explosion occurs, it can not sustain its strength and can not be destroyed to have fire resistance. Each year, more than 100,100tons of wastes are produced by using Ca as an oyster shell. In this study, we try to determine whether or not to reuse the heat-heated fireproof board.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.75-76
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• 2022

In the event of a fire in the lower space, a high temperature of 1000℃ or more and an explosive fire may occur due to the closed structural features and combustible materials. On the other hand, more than 90% of oyster shells are made of CaCO₃, and when heated to about 700℃ or higher, CaO and CO₂ is generated due to decarboxylation reaction. In this study, we try to infer the amount generated by CO₂ changing the weight of mortar using oyster shells as fine aggregates after heating. in conclusion It is considered that the smaller the particle, the greater the decarboxylation reaction and the greater the weight change.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.588-594
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• 2020

This study proposes non-destructive rebound-hardness and ultrasonic testing methods to more accurately evaluate the residual structural performance of reinforced concrete structures in a fire. Techniques are also proposed to assess the stiffness used in the deflection calculation with natural frequencies obtained by vibration tests. In the compressive strength evaluation using rebound hardness, the residual compressive strength of thick specimens and a larger water/cement (W/C) ratio were shown to be large. The homogeneity of concrete at high temperature compared to ambient temperature conditions was assessed by the velocity of ultrasonic waves that penetrate the concrete, and it followed W/C or thickness of slab makes little different results. To assess the stiffness of fire-damaged slabs and increase in deflection, the natural frequency was measured by vibration tests and incorporated into the equation of the stiffness. The application of this technique to the slab experiment showed that it can be a very reasonable evaluation technique. In addition, to evaluate the residual strength of a member after fire, a test of the strength of a component was carried out during and after heating.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.12 no.1
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• pp.17-22
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• 2016

It is very important to obtain a out-of season production in horticultural greenhouses corresponding with higher crop prices. A ground source heat pump system has been highly spotlighed as an energy efficient heating system for the greenhouse. This paper investigated the operating cost of the ground source heat pump system with the variation of generating temperature and designing methods for heating system of the greenhouse. Even though the COP of the ground source heat pump system decreased with an increment of generating temperature in heating mode, the operating cost could be reduced. By adopting the high temperature heat pump system and heat storage tank, it could be achieved to save energy and reduce the operating time of auxiliary oil heating system for producing good plant-growth in the greenhouse.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.12 no.4
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• pp.27-32
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• 2016

It is estimated that only heating and cooling take about one third of the total energy consumption worldwide. However, the conventional heating and cooling systems have low efficiencies. Also, boilers and electric heaters that are mostly used to generate both domestic and industrial hot water are inefficient and high energy consumers. For this reason, cascade heat pumps which are known to be very energy efficient and have less environmental impact are being promoted to replace conventional heating, cooling and hot water systems. In this study, a newly designed cascade heat pump by two-stage water heating method has been experimentally investigated. By adopting the auxiliary heat exchanger, the performance of the system was increased. The performance enhancement rate of the system could be maximized by adjusting the low stage compressor speed rather than the high stage compressor speed. The performance of the system with the auxiliary heat exchanger was enhanced by 16.5%.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.313-313
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• 2011

최근, 산화물 반도체를 통한 나노선 연구가 활발히 진행되고 있다. 1차원 나노선은 넓은 표면적을 가지며 다양한 특성을 지녀 미래 nanodevice로의 중요한 building block 소자로의 활용이 가능하다. 본 연구에서는 이종의 나노선을 합성하여 hierarchical nanojunction structure를 제작, 특성을 확인하였다. 이러한 구조는 나노선이 가지는 넓은 표면적의 특성과 동시에, multi-component fuctional nanodevice를 구현하는데에 적합한 구조이다. 본 연구는 텅스텐 기판 위에 고온의 열증착 방식을 이용하여 텅스텐 산화물 나노선을 제작시켜 그 위에 저온의 수열합성을 통한 산화아연 나노선을 제작한 후 향상된 field emission emitter로서의 특성을 살펴보았다. 합성된 텅스텐 산화물 나노선은 quasi-allign된 구조를 가지며, 이러한 구조 위에 ZnO를 스퍼터링하여 seed layer를 형성시키고, 암모니아수와 아연염을 이용한 수열합성법을 통하여 합성된 나노선 위에 nanobranch의 산화아연 나노선을 형성하였다. 이러한 성장특성은 SEM, TEM을 통하여 확인하였고 각각의 특성과 계면을 살펴보았다. 또한 이러한 구조를 이용하여 전계방출특성을 확인하였는데, 약 5.7 eV의 일함수를 갖는 텅스텐 산화물 나노선 위에 더 작은 값의 일함수를 갖는 산화아연 나노선을 합성하여 전계방출특성을 보았으며, 더 향상된 결과를 얻을 수 있었다. 또한 산화아연의 합성방법에 따른 전계방출 특성의 차이도 비교하였다.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.361-372
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• 1994

Vanadium containing MFI type zeolites have been prepared hydrothermally or by the impregnation method with $NH_4VO_3$ solution after dealumination of HZSM-5. Incorporation of vanadium into the framework of zeolite has been demonstrated by XRD, DTA, FT-IR and ESR analyses. Upon $NH_4VO_3$ impregnation and calcination of dealuminated zeolite, vanadium substitution into the framework could be performed like a hydrothermally synthesized zeolite. Vanadium in zeolite is able to pass redox cycles at high temperatures, and it is shown that vanadium is probably fixed and atomically dispersed in the structure of zeolite. The catalytic benzene hydroxylation, hexanes and alcohols oxidation were used for evaluating the properties of vanadium incorporated MFI zeolite.