• Polymer(Korea)
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• v.27 no.2
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• pp.120-128
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• 2003

The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

• Analytical Science and Technology
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• v.9 no.2
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• pp.179-191
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• 1996

In order to understand the high temperature deformation behavior of superalloy 718, a rotating grade 718 alloy has been compression tested to about 0.7 upset ratio at $927{\sim}1066^{\circ}C$ temperature range and $5{\times}10^{-4}{\sim}5{\times}10^0sec^{-1}$ strain rate. The maximum flow stress was increased with increasing strain rate, and similar behavior was observed with decreasing temperature. At low temperature and high strain rates other than $5{\times}10^{-1}sec^{-1}$, strain softening was occurred mainly by dynamic recovery and deformation twinning processes, while at high temperature and low strain rates strain softening was offseted by dynamic recrystallization. At $5{\times}10^{-1}sec^{-1}$, strain hardening was occurred due to work hardening of the dynamic recrystallized grains. Strain rate sensitivity, m, was varied with strain rates. In the case of lower strain rate tests, m was measured as 0.3 and it was observed that the deformation was mainly controlled by dynamic recrystallization. At higher strain rate, m was lowered to 0.1 and the deformation was controlled by the dynamic recovery and the deformation twinning processes.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2000.04a
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• pp.32-32
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• 2000

잠입노즐은 로케트 추진기관의 길이 및 중량을 감소시켜 체계설계의 관점에서 볼 때 많은 이점을 제공한다. 본 연구에서는 3단형 과학로케트 원지점 차넣기 모타(apogee kick motor)에 적용하기위한 잠입노즐의 기초기술 개발에 주안점을 두었다. 고고도에서 저속으로 회전하며 비행하는 원지점 차넣기 모타를 제작하기위해서 체계 요구성능에 의해 예상된 실물형의 50% 크기에 해당하는 축소형 잠입노즐을 제작하였다. 잠입노즐은 잠입부의 내외부가 고온의 추진제 연소가스에 노출된 상태에서 노즐 내부 압력 외에 연소실압에 의한 외부압력이 작용하므로 이를 고려한 열 및 구조설계가 중요하다. 본 연구에서는 노즐 수렴부와 목부에 일체형 그라파이트 소재를 적용하고 확장부 내열재 및 잠입부 배면내열재에 탄소/페놀 복합재를 노즐 내열재로 사용하였다. 그리고 이들의 구조적 지지를 위해 스틸구조물을 적용하였다. 적용된 스틸구조물에는 K형 열전쌍을 이용해 내열재와 구조물 온도를 측정할 수 있는 관통구멍 및 나사부를 구조물 외변에 가공하였다. 열전쌍은 노즐 목직경의 2, 4배 되는 확장부 내열재 단면위치의 2mm와 4mm 깊이와 구조물 내면 및 외면의 4개소에 열전쌍을 부착하여 지상연소시험시 노즐 내열재와 구조물의 온도분포를 관찰한다. 그리고 노즐 조립시 확장부 내열재와 구조물에 각 각 반원형 홈을 내어 여분의 접착제가 원형 홈에 밀려들어가 경화되어 노즐 기밀유지와 체결력을 향상시킬 수 있는 원형공간 접착제 충전 공법을 적용하여 실제모타에 대한 적용가능성을 지상연소시험을 통해 확인한다.

• Journal of the Korean Wood Science and Technology
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• v.42 no.3
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• pp.339-345
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• 2014

For enhancing productivity of glulam, high frequency (HF) curing technique was researched in this study. Heat energy is generated by electromagnetic energy dissipation when HF wave is applied to a dielectric material. Because both lamina and adhesives have dielectric property, internal heat generation would be occurred when HF wave is applied to glulam. Most room temperature setting adhesives such as phenol-resorcinol-formaldehyde (PRF) resin, which is popularly used for manufacturing glulam, can be cured more quickly as temperature of adhesives increases. In this study, dielectric properties of larch wood and PRF adhesives were experimentally evaluated, and the mechanism of HF heating, which induced the fast curing of glue layer in glulam, was theoretically analyzed. Result of our experiments showed relative loss factor of PRF resin, which leads temperature increase, was higher than that of larch wood. Also, it showed density and specific heat of PRF, which are resistance factors of temperature increase, were higher than those of wood. It was expected that the heat generation in PRF resin by HF heating would occur greater than in larch wood, because the ratio of relative loss factor to density and specific heat of PRF resin was greater than that of larch wood. Through theoretical approach with the experimental results, the relative strengths of ISM band HF electric fields to achieve a target heating rate were estimated.

• Korean Journal of Food Science and Technology
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• v.49 no.1
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• pp.85-89
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• 2017

This study was conducted to prevent hardened texture in retorted frozen seafoods such as small octopus, squid, and top shell by adding sorbitol; the strength of mechanical hardness and other qualities were measured. The hardness of the 3 kinds of seafood pretreated with 2-4% (w/w) sorbitol solution decreased by 9-36% compared to the control. The hardness of retorted frozen octopus, squid, and top shell treated with sorbitol solution upon freezing significantly decreased to 1670, 1015, and $521g_f/cm^2$ compared to levels in untreated food of 1841, 1291, and $815g_f/cm^2$ (p<0.05), respectively. Yields based on weight in retorted seafood treated with sorbitol were increased by 2-5% compared to untreated samples. Additionally, the overall preference of texture was 0.4 points higher than that of control samples in descriptive sensory evaluation (p<0.05). The tissue softening of pretreated seafood was based on decreased dewatering due to the formation of small ice crystals during freezing as a result of sorbitol treatment.

• Journal of Korean Society of Forest Science
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• v.60 no.1
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• pp.51-57
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• 1983

Properties and glue shear strength of each water soluble rues-phenol copolymer adhesive and phenolic resin adhesive were examined as a high temperature curing binder through the manufacture of plywood made of Kapur veneer. The former has different molar ratio and the latter was made from different catalyst method. The results are summarized as follows: 1) Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.67 to 0.82 and their moisture contents met the K.S. standard 2) In dry and wet shear strength, adhesives with 60 percent of non volatile content showed higher values than those with 50 percent except phenolic resin. Urea-phenol copolymer resin with 20 percent of phenol content exhibited the highest, and that with 70 percent the lowest. Filling effect of wood flour on the bonding strength is great in urea-phenol copolymer resin with more than 50 percent of phenol content, especially significant in 50 percent of non volatile content including alkali catalyst phenolic resin. Alkali and acid catalyst methods were the highest among the adhesive manufacture methods. In wet strength, urea resin belongs to the lowest group. 3) In glue shear strength after boiling and drying test, no method for manufacturing phenolic formaldehyde resin adhesive was stronger than alkali and acid catalyst methods. Phenolic resin made from alkali catalyst method needs a wood flour filler to improve the bonding quality. Urea-phenol copolymer resin with 10 percent of phenol content showed the reasonable water resistance.

• Composites Research
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• v.27 no.4
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• pp.174-181
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• 2014

This study describes viscoelasticity analysis of carbon-fiber reinforced polymer matrix composite material. One of the most important problem during high temperature molding process is residual stress. Residual stress can cause warpage and cracks which can lead to serious defects of the final product. For the difference in thermal expansion coefficient and change of resin property during curing, it is difficult to predict the final deformed shape of carbon-fiber reinforced polymer matrix composite. The consideration of chemical shrinkage can reduce the prediction errors. For this reason, this study includes the viscoelasticity and chemical shrinkage effects in FE analysis by creating subroutines in ABAQUS. Analysis results are compared with other researches to verify the validity of the subroutine developed, and several stacking sequences are introduced to compare tested results.

• Journal of the Korean Vacuum Society
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• v.14 no.4
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• pp.222-228
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• 2005

Undoped GaN epitaxial layer was grown on c-plane sapphire substrate by a two-step growth with metalorganic chemical vapor deposition(MOCVD). We have investigated the effects of the variation of final growth temperature on surface morphology, roughness, crystal quality, optical property, and electrical property In a horizontal MOCVD reactor, the film was grown at 300 Tow low-pressure with a fixed nucleation temperature of $500^{\circ}C$, varing the final growth temperature from $850\~1050^{\circ}C$ . The undoped GaN epilayers were characterized by atomic force microscopy, high-resolution x-ray diffractometer, photoluminescence, and Hall effect measurement.

• Journal of the Korean Society for Heat Treatment
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• v.5 no.4
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• pp.201-208
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• 1992

An experimental study of the constitutive response of precipitation-strengthened Al-0.55wt% Zr alloy, which consists of an Al matrix precipitation-strengthened by coherent particles, ${\beta}^{\prime}(Al_3Zr)$ with $L1_2$ structure has been performed. The deformation response of the materials has been examined by stress relaxation test at 573K, 623K and 673K. It was found that there exist the threshold stress during stress relaxation and threshold stress results from the presense of ${\beta}^{\prime}(Al_3Zr)$ particles. The ratio of threshold stress and Orowan stress decreased gradually with increasing temperature. The resistance to climb-pass of particles was independent of particles size for a fixed volume fraction although the threshold for bowing and particles cutting are sensitive to the particles dimensions. The smaller particles cutted by dislocations. This behavior of dislocations in this alloy was explained in terms of the small value antiphase boundary energy. The dislocation networks wrere more extensive in spesimens subjected to stress relaxation and there were numerous areas that have a high denstiy of jogged dislocation. This experiment results indicate that the rate controlling stress relaxation process is the climb of edge dislocation over particles.

• Proceedings of the KAIS Fall Conference
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• 2010.05b
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• pp.689-692
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• 2010

일반형 자동차 내장부품은 외부가 플라스틱 사출 성형한 형태로 사용되지만, 고급 차종은 내장재의 미감이나 질감을 위하여 사출물 표면에 엠보싱 무늬가 형성된 표피재가 수지에 추가로 부착되어 제작된다. 부착하는 방법은 한 장비에서 저압 사출 후 플라스틱이 완전 응고 전에 표피재를 넣고 압입하는 저압 사출법과 표피재 수지를 기 사출된 제품위에 놓고 압착시키는 압착법이 있으나 이 두 방법 모두 엠보싱 무늬가 형성된 표피재를 넣고 작업하기 때문에 고온 압착시 기존 무늬가 찌그러지고 코너 부위가 경화되어 기존의 질감을 얻지 못하며, 치수 공차가 변형되어 불량률이 증가하므로 이를 시급히 개선할 새로운 제조 기술의 필요성이 대두된다. 본 연구는 가열 압착기로 지그 및 금형을 새로 개발하여 도어 트림 제조시, 기 사출물을 금형 쪽으로 기 조직을 삽입한 후 엠보싱 무늬가 없는 원소재 표피재로 상부 금형 쪽으로 소재조직을 진공으로 흡입하여 무늬를 성형한 후 하강시켜, 기 사출물에 압착시키는 가열 압착으로 엠보싱무늬의 손상을 방지하는 금형을 제안하였으며 그에 대한 해석, 설계, 실험을 통하여 성능을 평가 분석 하였다.