• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.05a
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• pp.302-308
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• 2004

• Journal of Power System Engineering
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• v.14 no.2
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• pp.5-11
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• 2010

분사연료의 혼합기형성과정 최적화를 통한 연소제어 기술은 디젤기관의 기관운전 및 배기특성을 향상시키기 위하여 매우 중요하다. 또한 분무의 혼합기형성 최적화를 위해서는 분사된 연료와 주위기체와의 혼합과정에 영향을 미치는 분무내부의 유동특성에 대한 연구는 필수 불가결하다. 따라서 본 연구에서는 고온 고압의 증발장에서 분무의 액상 거동에 주목하고, 그 거동특성을 통하여 증발디젤분무의 혼합기형성을 해석한다. 비정상 증발분무의 중심축에 레이저 시트광을 입사한 후, 액상분무 액적의 Mie 산란광에 의한 2차원 화상을 획득하여 증발분무 액상의 속도분포 및 와도(vorticity) 등을 구하였다. 분무의 속도분포 및 와도는 2차원 화상에 PIV법을 적용하여 계산하였다. 그림 1에 본 연구에서 구한 속도분포의 일례를 보인다. 본 연구의 결과로 상변화를 동반하는 비정상 증발장에서 구한 분무액상의 거동 특성은 상변화가 일어나지 않는 비증발장에 있어서의 분무거동특성과 유사함을 확인하였다.

• Clean Technology
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• v.19 no.1
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• pp.8-12
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• 2013

Phase behavior of carbon dioxide + surfactant binary system and carbon dioxide + surfactant + water ternary system was investigated at the temperatures from 318 K to 348 K by using high pressure vapor liquid equilibrium apparatus containing variable-volume view cell. Sorbitan monopalmitate was used as the surfactant. The cloud point pressures for the binary mixture of carbon dioxide + sorbitan monopalmitate increased with an increasing of system temperatures and the maximum cloud point pressure was observed at the composition of 0.226 wt% of sorbitan monopalmitate. On the other hand, as the temperatures and compositions of water increased, the cloud point pressures for ternary system containing 0.1 wt% of sorbitan monopalmitate increased significantly. For the ternary system of constant 0.2 wt% of water, the cloud point pressure curves show relatively flat according to the change of compositions of surfactant. The cloud point pressures increased when the temperatures and compositions of water increased.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.424-429
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• 1998

Cloud-point data at $230^{\circ}C$ and 1,800 bar are presented for two poly(ethylene-co-vinyl alcohol)(PEVA) copolymers[9.9mol% and 17.8mol% vinyl alcohol(VA)] in ethylene, propane, propylene, n-butane, 1-butene, dimethyl ether(DME), and chlorodifluromethane(CDFM). The static type experimental apparatus with a view cell has been used for the experiment at the high pressure and temperature. The pressure-temperature (P-T) loops of PEVA(9.9mol% VA) copolymer-DME mixtures are presented at copolymer concentrations of 1.4wt% to 20.0wt%. Also, we presented the phase behavior of PEVA(17.8mol% VA) copolymer-DME system at copolymer concentration of 1.9wt% to 6.8wt%. The cloud-point curves for the PEVA copolymers in dimethyl ether showed single phase above 480 bar as a result of the hydrogen bonding between the vinyl alcohol unit and dimethyl ether. The pressure-concentration(P-x) isotherm loops of PEVA(9.9mol% and 17.8mol% VA)-DME system are obtained. The cloud-point curves for PEVA(9.9mol% and 17.8 mol% VA) copolymers andthe ethylene, propane, propylene, n-butane, 1-butene, and CDFM all show negative slopes of phase behavior and are located at pressures below 1,800 bar. For PEVA copolymer-DME system(9.9mol% VA), cloud-point curves show positive slopes that decrease in pressures with decrease in temperature in the temperature range of $80^{\circ}C$ to $160^{\circ}C$.

• Journal of Power System Engineering
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• v.15 no.3
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• pp.5-11
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• 2011

디젤기관의 경우는 종래부터 직분식이 주류를 이루었고, 근래에는 분사압력의 고압화가 진행중이다. 분사압력의 고압화에 의해 연소효율의 향상 및 배출가스중의 입자상물질(PM:Particulate Matter)의 저감을 유도하고 있으나, 연소가스의 고온화로 인해 질소산화물(NOx:Nitrogen Oxides)은 증가한다. 따라서, 분사기간의 지연(Retard)이나 파일럿분사(Pilot injection)등의 혼합기제어에 의해 질소산화물의 저감을 꾀하고 있다. 이와 같이 디젤기관에 있어서도 혼합기 형성의 최적화에 의한 연소제어를 시도하는 수법이 중시되고 있고, 이를 위해서는 디젤분무 구조에 기초한 혼합기의 형성기구에 대한 규명이 매우 중요하다. 그러므로 본 연구에서는 보다 고도의 혼합기형성 제어를 위한 기초연구로서 고온 고압장에서의 증발디젤자유분무구조를 해석하였으며, 계측영역은 연료와 주위기체와의 혼합이 활발히 진행되는 분무의 하류영역으로 설정하고, 입자화상속도측정법(particle Image Velocimetry:PIV)을 이용한 분무의 유동해석을 기초로 증발 디젤분무의 구조 해석을 행하였다. 실험조건으로서 분사압력을 72MPa, 112MPa로 각각 변화시켰다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.11
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• pp.1377-1382
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• 2011

Recently, alternative and novel energy resources have been developed for use in the future because of the current environmental problems and exhaustion of fossil energy resources. Hydrogen energy has many merits, such as its environmental friendliness, easy storage, and easy production, but it also has disadvantages, in that it is highly combustible and explosive. In this study, a test procedure using a simple SP test under highly pressurized hydrogen gas conditions was established. In order to evaluate its applicability, SP tests were carried out using a stainless steel (SUS316L) sample under atmospheric, pressurized helium, and pressurized hydrogen gas conditions. The results under the pressurized hydrogen gas condition showed fissuring and produced a reduction of the elongation in the plastic instability region due to hydrogen embrittlement, showing the effectiveness of the current in-situ SP test.

• Korean Journal of Crystallography
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• v.12 no.2
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• pp.102-112
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• 2001

The mechanical properties of silicon crystals are important from the viewpoint of wafer and device fabrication processes. It is now widely recognized that silicon undergoes a series of phase transformations when subjected to high pressures, using conventional high pressure devices, such as diamond anvils or indenters. Diamond tip scratching on a silicon surface in the various conditions introduces various kinds of mechanical damage and stressed states. Micro Raman spectroscopy was used to observe the phase transition of single crystal silicon. As results, different morphologies were observed as functions of scratching speed and loading condition and various phases were observed as functions of scratching speed and loading condition.

• Journal of the Mineralogical Society of Korea
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• v.31 no.4
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• pp.277-285
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• 2018

Azurite ($Cu_3(CO_3)_2(OH)_2$) was compressed up to 21.52 GPa for its behaviors at ambient temperature. High pressure experiment was performed using the symmetrical diamond anvil cell employed in the angle dispersive X-ray diffraction method. Pressure was determined by ruby fluorescence calibration method. No phase transitions were observed within the present pressure limit and bulk modulus was determined to be 54.4 GPa when ${K_0}^{\prime}$ is fixed to be 4. Applying the normalized pressure-strain analysis, reliability of the azurite compression pattern was checked.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.761-766
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• 1999

In this paper, high pressure phase behavior in the binary polyethylene/butane and polyethylene/dimethyl ether has been studied. The pressure-temperature diagrams in polyethylene/butane were shown by increasing concentration for molecular weight standards, that is, $M_w=700,\;1000$ and 2000. It is found that the temperature and the pressures go up with increasing in concentrations for each molecular weight, but the latter lower in concentrations over 16 wt % polyethylene. In addition, the phase behaviors for each molecular weights with about 5 wt % polyethylene are shown in pressure-temperature, and pressures increase with increasing in molecular weight($M_w=700,\;1000$, and 2000). The phase behaviors in polyethylene/dimethyl ether are determined according to its molecular weight, and are shown for a range of pressures of 40~280 bar and temperatures of about $120{\sim}220^{\circ}C$. It is shown that in pressure-temperature of polyethylene/dimethyl ether the pressure increases with increasing in polyethylene molecular weight, and the difference in pressure for each molecular weight shows by about 60 bar. The gap in pressure between polyethylene/butane and polyethylene/dimethyl ether system with 5 wt % polyethylene for each molecular weight standards indicates about 25(700), 90(1000), and 100 bar(2000), respectively.

• Clean Technology
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• v.13 no.1 s.36
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• pp.34-45
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• 2007

Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.