• Polymer(Korea)
• /
• v.25 no.4
• /
• pp.568-574
• /
• 2001

PEO-like solid polymer electrolytes based on bisphenol A ethoxylate acrylate were synthesized and their electrochemical properties and mechanical stability were studied. Low molecular weight poly(ethylene glycol) dimethyl ether (PEGDMe) was added to increase the conductivity of the electrolyte. The maximum conductivity of the resulting polymer electrolyte was found to be 1.0 ${\times}$ 10$^{-3}$ S/cm [Bisphenol A ethoxylate diacrylate ([EO]/[phenol]= 15), PEGDMe250 80 wt%, LiCF$_3SO_3$] at 30$^{\circ}$C. Tensile strength of the free standing polymer electrolyte films was measured to be in the range of 0.4 ~ 5 MPa and these polymer electrolyte films did not show a crack even in 90$^{\circ}$ and 180$^{\circ}$ bending against ${\phi}$=3 mm bar. These electrolytes showed oxidation stability up to 4.5 V vs. lithium reference electrode.

• International Journal of Highway Engineering
• /
• v.11 no.4
• /
• pp.127-132
• /
• 2009

This study presents the test results on the compaction characteristics of warm mix asphalt mixtures that include the additive in 3 different mixtures(hot mix asphalt, SBS and SMA). The tests were conducted to find out the compaction characteristics on the compactability with varying compaction time, different amount of the warm mix additive and lowering the compaction temperature. The Superpave gyratory compactor was used to find out the variation of the density when the number of the gyration is varied. A dense mixture and 3 different warm mix additives were employed to find the relationship between compactability and compaction time. The comparison of the compactability with lowering the temperature was conducted using dense mixture, SBS polymer modified mixture and stone matrix asphalt mixture(SMA). The difference of the density of warm mix asphalt mixtures was not found due to the lowering of compaction temperature when it was compared with the standard mixture and the warm mix showed the stable condition in density. In the mean time, depending upon the different warm mix additive and mixture, the difference of density and the variation trend of compaction is found to be existed and shows the relationship between these two variables.

• Polymer(Korea)
• /
• v.31 no.4
• /
• pp.297-301
• /
• 2007

In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt ($LiClO_4$), and sodium montmorillonite ($Na^+-MMT$) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of $Na^+-MMT$, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

• Korean Chemical Engineering Research
• /
• v.43 no.1
• /
• pp.21-26
• /
• 2005

Experimental researches on the preparation of porous polymeric monoliths in supercritical carbon dioxide have been performed and the effects of monomer and polymerization parameters on the physical properties of the monolith prepared were examined. Polymerizations were carried out in the high pressure stainless steel reactor with sapphire window to show the phase change during the polymerization reaction, and continuous and dry porous monolithic polymer could be obtained. The specific surface area of monolithic polymer increased with monomer contents in reaction mixture and reaction pressure. The Rockwell hardness could be enhanced by the addition of co-monomer MMA in reaction mixtures.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.15 no.3
• /
• pp.71-79
• /
• 2007

The effects of synthetic bulking agent (SBA) on the composting reaction were investigated with a lab-scale composting reactor. The positive effects of SBA addition were observed in composting reactions where relatively tough composting conditions like high water content and no addition of seed compost were provided. Such effects were assumed to be caused by the enhanced free air space in compost mixture. It was additional benefits of using SBA, a bulking agent, that the amount of saw dust, another bulking agent, could be reduced to 50% compared to composting without SBA. Although SBA would be used as a bulking agent, two options are thought to be very important to ensure composting reaction well. One is that optimal water content should be maintained around 60%. The other is that saw dust is inevitable bulking agent to prevent food waste from lumping, so combination use of two ones are necessary.

• Proceedings of the Korean Fiber Society Conference
• /
• 1998.04a
• /
• pp.36-39
• /
• 1998

플루란은 글루코스 삼량체인 말토트리오스(maltotiose)를 반복단위로 하고, 그 삼량체와는 다른 결합인 $\alpha$-1,6결합에 의해 반복결합한 고분자 선상 중합체이다(Fig. 1) 플루란은 검정색 효모인 aureobasidium pullulans에 의해 배양 생산된 천연 다당류의 일종이다. 플루란은 원료가 저렴하기도 하지만 플루란으로 만들어진 막, 필름(1), 섬유(2) 등의 일반적인 성형물은 투명성, 강인성, 산소 불투과성이 있으며 땅속 수중에서 자연 분해되며 소각에 의해 유독가스와 고엽이 발생하지 않으므로 공해를 동반하지 않는다.(중략)

• Polymer(Korea)
• /
• v.36 no.4
• /
• pp.500-506
• /
• 2012

In this study, we developed and optimized hydrophilic polymer based solid dispersion formulations (SDs) for enhancing the aqueous solubility of eprosartan, one of poorly soluble drugs, that has been broadly used for the treatment of high blood pressure. Poly(ethylene glycol) (PEG) and poly(vinyl pyrrolidone) (PVP) based SDs were prepared by hot melting and solvent evaporation methods and the drug/polymer composition varied in the range of 1:1~1:5 with or without poloxamer 407 (P407) as a polymeric surfactant. The SDs prepared by solvent evaporation showed more reduced crystallinity than ones by hot melting, and PVP based SDs showed more enhanced solubility and lower crystallinity than PEG based SDs. Furthermore, it was observed from DSC and PXRD analysis that the SDs with P407 (drug:polymer: P407 = 1:5:1) demonstrated no crystallinity and the most enhanced solubility (more than 3~4 times).

• Membrane Journal
• /
• v.16 no.4
• /
• pp.294-302
• /
• 2006

Silver polymer electrolytes are very promising membrane materials for the separation of olefin/paraffn mixtures. Olefin molecules are known to be transported through reversible complex formation with silver ions entrapped iii polymer matrix. However, they have poor long-term stability, which is very important fur the industrial application; the selectivity through the membrane decreases gradually with time mostly due to the reduction of silver ions ($Ag^+$) into silver nanoparticles ($Ag^0$). In this study, the stability of silver polymer electrolyte was investigated for poly(vinyl pyrrolidone) (PVP) and $AgBF_4$ system containing a surfactant, i.e. $C_{18}H_{35}(OCH_2CH_2)_{20}OH$ (Brij98) as a stabilizer. The reduction behavior of silver ions to silver nanoparticles in PVP was also investigated by atomic force microscopy (AFM) and UV-visible spectroscopy. It was found that the growth of silver nanoparticles was slower and selectivity of polymer electrolyte for propylene in propylene/propane was maintained longer time when Brij98 was added as a stabilizer.

• Journal of Korean Ophthalmic Optics Society
• /
• v.19 no.3
• /
• pp.315-322
• /
• 2014

Purpose: The physical and optical characteristics of hydrophilic tinted contact lens containing titanium silicon oxide nanoparticles and the basic hydrogel contact lens material containing 4-iodoaniline were examined. In this study, the utility of titanium silicon oxide nanoparticles as a UV-blocking material for ophthalmologic devices were investigated by measuring the UV transmittance of the produced polymer. Also, titanium silicon oxide nanoparticles only without the addition of 4-iodoaniline in primary contact lens materials by copolymerizing two groups were compared. Methods: For manufacturing hydrogel lens, HEMA, MA, MMA, 4-iodoaniline and a cross-linker EGDMA were copolymerized in the presence of AIBN as an initiator. Also, the titanium silicon oxide nanoparticles was used as additive. After polymerization the physical properties such as water content, refractive index, contact angle and spectral transmittance of produced contact lenses were measured. Results: Measurement of the physical properties of the copolymerized material showed that the water content, refractive index, UV-B transmittance and contact angle were in the range of 35.01~38.60%, 1.4350~1.4418, $34.15{\sim}57.25^{\circ}$ and 1.0~10.0%, respectively. Titanium silicon oxide nanoparticles is not used as an additive in the experimental group, the results of the measurement showed that the water content, refractive index, contan angle and UV-B transmittance of the hydrogel lens polymer was 34.00~36.80%, 1.4378~1.4420, $40.15{\sim}60.16^{\circ}$ and 1.8~25.0%, respectively. Conclusions: Also, the transmittance for UV light was reduced significantly in combinations containing titanium oxide nanoparticles.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1991.10a
• /
• pp.36-36
• /
• 1991

본 연구에서는 Poly(etherimide)를 이용하여 한외여과용막의 최적 제막조건에 관하여 조사 검토하였다. 제막 조건은 폴리머의 농도, 첨가제 등을 변화시켜, 상전환법에 의한 비대칭막을 제조하여 제막조건에 따른 막의 성능에 미치는 영향에 대하여 조사하였다.