• 기계와재료
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• v.21 no.4
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• pp.48-55
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• 2010

극저온에서 고분자 복합재료는 열전도도가 낮아 단열 특성이 탁월하고 전기절연성이 뛰어나 에너지 산업, 전기 및 전자산업, 생물공학, 의료분야, 수송산업, 우주 항공 산업 등 응용 범위가 매우 광범위하고, 산업 규모 또한 지속적으로 성장하고 있다. 향후 신재생 에너지의 저장 및 수송용으로 열전도도가 낮은 고분자 복합재에 대한 수요가 크게 증가할 것으로 예상된다. 따라서 본 고에서는 고분자 복합재료의 극저온 응용에 관한 국내외 기술동향과 수지 및 복합재 물성, 극저온에서의 특성 평가 기술 등에 대하여 소개하였다.

• Elastomers and Composites
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• v.48 no.2
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• pp.133-140
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• 2013

Carbon fiber reinforced polymer (CFRP) composites consist of carbon fibers in a polymer matrix. Recently, CFRP composites having high thermal stability and low outgassing are finding their use in high performance materials for aerospace and electronics applications under high temperature and high vacuum conditions. Cyanate ester resin is one of the most suitable matrix resins for this purpose. In this study, proper combination of cyanate ester and catalyst, curing behavior, and cure cycle were determined by chemorheology. Optimum condition was found to be catalyst content of 100 ppm and curing temperature of $150^{\circ}C$. Thermal stability and outgassing of cured resin composition were analyzed and the results showed thermal decomposition temperature of $385^{\circ}C$ and total mass loss of 0.29%. The CFRP prepregs and subsequent composites were fabricated by predetermined resin composition and the cure condition. Tensile moduli of the composites were compared with theoretical models and the results were very consistent.

• Polymer(Korea)
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• v.24 no.4
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• pp.556-563
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• 2000

In general, the development of thermoplastic composites has been confronted with difficult problems such as the weak bonding strength between fibers and matrix. However, now, such problems are being surmounted by the development of resins, the improvement of processes, and introduction of interphase. Especially, the introduction of interphase between fiber and matrix can help a dissipation of the impact energy and provide a good adhesion between fibers and matrix. In this study, polymeric interphase was introduced by electrodeposition, modified polypropylene was added to improve the weak bonding strength between interphase and polypropylene matrix. By evaluation of interlaminar shear strength and impact strength of the composites, it was found that composites with introduced composites showed higher mechanical properties than those of composites without interphase. Reactive polymers which have either anhydride or free acid functional group were used as interphase materials, and these polymers also behave as charge carrier in aqueous solution during the electrodeposition process. Weight gain on the carbon fibers was evaluated by changing process parameters such as concentration of solution, current density, and electrodeposition time.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.422-425
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• 1998

섬유강화 복합재료는 고성능 섬유와 고분자 수지를 조합하여 재료의 물성 향상 및 고기능화를 목적으로 만들어지는 재료이며, 사용되는 고분자 매트릭스의 종류에 따라 열가소성 복합재료와 열경화성 복합재료로 나뉘어진다. 이 중 열경화성 복합재료에 관한 연구 및 그의 실용화는 오래 전부터 활발히 진행되어 산업재료 및 군사, 우주용 재료로 각광을 받아 왔으나 최근 지구 환경문제가 심각해지면서 사용 후 분해 및 재활용이 가능한 열가소성 복합재료에 관한 연구에 관심을 가지게 되었다. (중략)

• Composites Research
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• v.20 no.6
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• pp.1-7
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• 2007

Expanded graphite/carbon fiber hybrid conductive polymer composites were fabricated by the preform molding technique. The conductive fillers were mechanically mixed with a phenol resin to provide an electrical property to composites. The conductive filler loading was fixed at 60wt.% to accomplish a high electrical conductivity. Expanded graphites were excellent in forming a conductive networking by direct contacts between them while it was hard to get the high flexural strength over 40MPa with using only expanded graphite and phenol resin. In this study, carbon fibers were added in composites to compensate the weakened flexural strength. The effect of carbon fibers on the mechanical and electrical properties was examined according to the weight ratio of carbon fiber. As the carbon fiber ratio increased, the flexural strength increased until the carbon fiber ratio of 24wt.%, and then decreased afterward. The electrical conductivity gradually decreased as the increase of the carbon fiber ratio. This was attributed to the non-conducting regions generated among the carbon fibers and the reduction of the direct contact areas between expanded graphites.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2000.11a
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• pp.307-312
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• 2000

최근 고분자 화학의 급속한 발전에 따라 우수한 특성을 가진 다양한 절연재료가 개발되어 왔으며, 이러한 유기고분자 재료의 용도와 수요가 매년 급증하고 있다. 이들 고분자 재료 중 유리섬유 강화 복합재료(FRP; fiber reinforced plastics)는 전기$\cdot$화학적으로 우수한 특성을 갖는 에폭시 수지에 기계적 강도를 보강하기 위해 유리섬유를 복합시틴 hybrid 재료로서 애자, PCB 기판 및 우주항공 산업분야에 이르기까지 그 응용분야를 확대시키고 있다.(중략)

• Polymer Science and Technology
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• v.6 no.5
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• pp.451-458
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• 1995

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.227-230
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• 2003

열방성 액정고분자 (Thermotropic liquid crystal polymer, TLCP)는 초고강도 섬유로의 응용가능성을 갖고 있어 많은 관심이 집중되고 있으며, 액정고분자의 고강도와 고탄성, 우수한 내열성과 내화학성, 가공시 성형수축률 및 선팽창계수가 작기 때문에 고성능 섬유 및 엔지니어링 플라스틱, 그리고 고분자 복합재료 등 다양한 분야에 응용되고 있다 [1]. 또한 범용성 열가소성 수지와 TLCP와의 용융블렌드는 고분자 복합재료의 강도 및 탄성의 향상뿐만 아니라 우수한 가공성 및 고성능 발현이 가능하기 때문에 현재 많은 연구가 진행되고 있다 [2]. (중략)

• Composites Research
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• v.32 no.6
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• pp.319-326
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• 2019

To address tremendous needs for developing efficiently heat dissipating material with lightweights, a new class of polymer possessing recyclable and malleable characteristics was synthesized for incorporating model functional hexagonal boron nitride (h-BN) filler. A good interfacial affinity between the polymer matrix and the filler along with shear force generated upon manufacturing the composite yielded the final product bearing highly aligned filler via simple hot pressing method. For this reason, the composite exhibited a high thermal conductivity of 13.8 W/mK. Moreover, it was possible to recover the h-BN from the composite without physical/chemical denaturation of the filler by chemically depolymerizing the matrix, thus the recovered filler can be re-used in the future. We believe this polymer could be beneficial as matrix for incorporating many other functional fillers, thus they may find applications in various polymeric composite related fields.

• Polymer(Korea)
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• v.27 no.6
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• pp.576-582
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• 2003

When the halogenated flame retardant, decabromodiphenyl oxide, was added to the polypropylene/nylon blend, and was compounded with montmorillonite and compatibilizer, maleic anhydride polypropylene, the improvement of flame retardancy and mechanical properties was investigated. The degree of dispersion between polymer resin and inorganic nanoparticles was investigated, and the flame retardancy and mechanical properties was measured quantitatively. XRD results showed that the montrnorillonite was com-pletely exfoliated after polypropylen/nylon nanocomposites was mixed above twice. By compounding with montmorillonite, polypropylene/nylon blend system was overcome the deterioration of flame retardancy. The tensile strength and impact strength were slightly increased, and by compounding with montmorillonite, the additional increase in mechanical properties was obtained. Therefore, the flame retardancy of polypropylene / nylon blend was decreased by adding nylon, but by compounding with inorganic nanoparticle, improvement of the flame retardancy and mechanical properties was obtained.