• Title/Summary/Keyword: 고분자복합재

Search Result 199, Processing Time 0.026 seconds

Molecular Dynamics and Micromechanics Study on Mechanical Behavior and Interfacial Properties of BNNT/Polymer Nanocomposites (분자동역학 전산모사와 미시역학 모델을 이용한 질화붕소 나노튜브/고분자 복합재의 역학적 물성 및 계면특성 예측)

  • Choi, Seoyeon;Yang, Seunghwa
    • Composites Research
    • /
    • v.30 no.4
    • /
    • pp.247-253
    • /
    • 2017
  • In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

Synthesis and Characterization of Allyl Ester Resin-Layered Silicate Nanocomposite (알릴 에스터 수지-층상 실리케이트 나노복합재료의 합성과 특성)

  • 팽세웅;김장엽;허완수;조길원;이상원
    • Polymer(Korea)
    • /
    • v.28 no.2
    • /
    • pp.177-184
    • /
    • 2004
  • Polymer-clay nanocomposite containing the low amounts of clay shows improved physical, mechanical properties. In this study, allyl ester prepolymer was synthesised by reactions of the diallyl terephthalate monomers and the 1,3-butanediol monomers. Nanocomposites of allyl ester prepolymer and the two kinds of the organically layered silicate were prepared by using the intercalation method as well as the in-situ polymerization method using. By varying the amount of clay content, curing conditions, and feeding conditions. the nanocomposite was studied using X-ray diffraction. From XRD results, allyl ester-Cloisite 30 B nanocomposite made by the in-situ polymerization method shows better exfoliation behavior compared with the intercalation method. It can be said that the transesterification reaction between functional groups (-OH) of intercalant and monomers results in the increased gallery distance. Also mechanical and thermal properties indicate that the dispersity of clay is an important factor for improving physical properties of the nanocomposite.

Characteristic of organic/inorganic composite formed grounding resistance lowering agents (유/무기 복합재료형 접지저감제의 특성)

  • Kim, Jang-Wook;Chung, Chul-Hee;Cho, Dae-Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
    • /
    • 2004.05a
    • /
    • pp.74-80
    • /
    • 2004
  • Among inorganic materials, it is grounding resistance lower agent of new form that use being strata style clay and makes using water soluble polymer by main material to organic substance. Water soluble polymer chains are dispertion in water because water soluble polymer reacts with water if is done and these discrete polymer chains are inserted to floor of being strata style clay with water. This material that moisture content is very excellent and rate of expansion, electrical conductivity that measure after supplies water of 300wt % as well as is excellent. Can prevent corrosion or electrolytic corrosion of grounding bar securing very environmentally, chemically and pollution of soil. When applied to general grounding rod worker $7{\sim}8$ times ground resistance reduction effect of not application.

  • PDF

Evaluation of Yield Surfaces of Epoxy Polymers Considering the Influence of Crosslinking Ratio: A Molecular Dynamics Study (분자동역학 해석 기반 가교율에 따른 에폭시 폴리머의 항복 표면 형상 평가)

  • Jinyoung Kim;Hyungbum Park
    • Composites Research
    • /
    • v.36 no.5
    • /
    • pp.369-376
    • /
    • 2023
  • This study focuses on investigating the influence of epoxy polymer crosslinking density, a crucial aspect in composite material matrices, on the yield surface using molecular dynamics simulations. Our approach involved generating epoxy models with diverse crosslinking densities and subjecting them to both uniaxial and multiaxial deformation simulations, accounting for the elasto-plastic deformation behaviors. Through this, we obtained key mechanical parameters including elastic modulus, yield point, and strain hardening coefficient, all correlated with crosslinking conversion ratios. A particularly noteworthy finding is the rapid expansion of the yield surface in the biaxial compression region with increasing crosslinking ratios, compared to the uniaxial tensile region. This unique behavior led to observable yield surface variations, indicating a significant pressure-dependent relationship of the yield surface considering plastic strain and crosslinking conversion ratio. These results contribute to a deeper understanding of the complex interplay between crosslinking density and plastic mechanical response, especially in the aspect of multiaxial deformation behaviors.

Recent Developments in Natural Fiber Reinforced Composites (천연섬유보강 복합재료의 최근 연구 개발)

  • Mirza, Foisal Ahmed;Afsar, Ali Md.;Kim, Byung-Sun;Song, Jong-Il
    • Composites Research
    • /
    • v.22 no.4
    • /
    • pp.41-49
    • /
    • 2009
  • Natural fiber reinforced composites are emerging as low-cost, lightweight, recyclable, and eco-friendly materials. These are biodegradable and non-abrasive. Due to eco-friendly and biodegradable characteristics of natural fibers, they are being considered as potential candidates to replace the conventional fibers. The chemical, mechanical, and physical properties of natural fibers have distinct features depending upon the cellulose content of the fibers which varies from fiber to fiber. The mechanical properties of composites are influenced mainly by the adhesion between matrix and fibers. Several chemical and physical modification methods of fiber surface were incorporated to improve the tiber-matrix adhesion resulting in the enhancement of mechanical properties of the composites. This paper outlines the works reported on natural tiber reinforced composites with special reference to the type of fibers, polymer matrix, processing techniques, treatment of fibers, and fiber-matrix interface.

Physical Properties and Preparation of HDPE Filled with Microencapsulated Glass Beads (마이크로 캡슐화된 Glass bead 충전 HDPE 복합재의 제조와 물리적 성질)

  • Kim, Dong-Kook;Kim, Kwang-Ho;Im, Seung-Soon;Noh, Si-Tae
    • Applied Chemistry for Engineering
    • /
    • v.3 no.3
    • /
    • pp.430-439
    • /
    • 1992
  • To improve the adhesion of interface and dispersion of glass beads in the composite, HDPE filled with glass brads, we encapsulated the g1ass beads with polymer by phase separation method using complex coacervation in organic solvent. EMAA and EAA were used as the polymeric wall materials. The microencapsulation efficiency and morphology were observed by thermogravimetric analysis and SEM, respectively. And also we investigated the physical and dynamic mechanical properties of the composite as the function of the beads contents and microencapsulation efficiency. Compared with the composite containing non-treated glass beads, the decrease in tensile strengthe of the composites containing the encapsulated glass beads become markedly small, and about 30~40% Increase in tensile modulus was observed. From the results of the dynamic mechanical analysis, it was found that the adhesion of interface and dispersion could be improved upon encapsulation.

  • PDF