• Title/Summary/Keyword: 고리화

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Electrically Controllable Asymmetric Split-Loop Terahertz Resonator with Outer Square Loop (전기적 제어 가능한 외곽 사각 고리 추가형 테라헤르츠 비대칭 분리고리공진기)

  • Park, Dae-Jun;Ryu, Han-Cheol
    • Korean Journal of Optics and Photonics
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    • v.28 no.2
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    • pp.59-67
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    • 2017
  • This paper proposes an asymmetric split-loop resonator with an outer square loop (ASLR-OSL), which can actively control terahertz wave transmission properties while maintaining a high-Q-factor of the asymmetric split-loop resonator (ASLR). An added outer square loop is designed to play the roles of both a metamaterial and a micro-heater, which can control the temperature through a directly applied bias voltage. A vanadium dioxide ($VO_2$) thin film, which exhibits an insulator-metal phase transition with temperature change, is used to control the transmission properties. The proposed ASLR-OSL shows transmission properties similar to those of the ASLR, and they can be successfully controlled by directly applying bias voltage to the outer square loop. Based on these results, an electrically controllable terahertz high-Q metamaterial could be achieved simply by adding a square loop to the outside of a well-known high-Q metamaterial.

LES analysis of mixing enhancement in Gas Generator with Turbulence Ring (난류 고리가 장착된 가스발생기의 혼합 증진에 관한 대 와동 모사)

  • Yu, Jung-Min;Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.110-113
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    • 2007
  • LES code was developed and verified to investigate the turbulence evolution in the gas generator equipped with turbulence ring. We compared mixing enhancement of various turbulence rings having different shape and size. To qualify the mixedness, we used two perturbation values of energy and enstrophy.

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Study on the isomerization of the saturated-poly-cyclic-compound over zeolite catalyst (제올라이트 촉매를 이용한 포화다중고리화합물의 이성화반응 연구)

  • Cho Deug-Hee;Han Jeong-Sik;Choi Myong-Jae;Cho Joon-Hyun;Lee Ho-Jin;Kim Young-Youn
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.193-196
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    • 2006
  • This paper presents the results of catalytic endo- to exo- isomerization of saturated poly cyclic compound. Several zeolites were tested and influences of, Si/Al ratio and Structures of the zeolites on the reaction were investigated. The results showed that Y zeolites were more active than other zeolites, because of its large pore size and relative strong acidity. In all Y zeolites with different Si/Al, Y-5.4 is best. In all the zeolites tested, Y calcined at $450^{\circ}C$ was favorable. Still now the aluminium chloride catalyst is more active than zeolites. However, considering of environmental problems, corrosion, and treatment can make the zeolite catalyst substitute the aluminium chloride catalyst.

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Study on Properties of High Energetic and High Dense Cyclic Hydrocarbons by the Structure (고에너지 고밀도 고리탄화수소 화합물의 구조에 따른 물성 연구)

  • Cho, Joon-Hyun;Kwon, Tae-Soo;Jeong, Deok-Jin;Oh, Chang-Ho;Park, Dae-In;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.463-466
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    • 2008
  • The weapon systems with a liquid propulsion engine have been used for various purposes and demands of the liquid fuel with variety of properties for its operational purposes and environment. The cyclic hydrocarbons including norbornane or dicyclopentane structures have many applications to the guided weapon systems due to the high density and high energy characteristics, also efforts have been given in many fields. In this study, the cyclic hydrocarbons that we designed and fabricated were investigated to obtain tendency on the structures.

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Statistical Convergence Properties of an Adaptive Normalized LMS Algorithm with Gaussian Signals (가우시안 신호를 갖는 적응 정규화 LMS 앨고리듬의 통계학적 수렴 성질)

  • Sung Ho CHO;Iickho SONG;Kwang Ho PARK
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.16 no.12
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    • pp.1274-1285
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    • 1991
  • This paper presents a statistical convergence analysis of the normalized least mean square(NLMS)algorithm that employs a single-pole lowpass filter, In this algorithm the lowpass filter is used to adjust its output towards the estimated value of the input signal power recursively. The estimated input signal power so obtained at each time is then used to normalize the convergence parameter. Under the assumption that the primary and reference inputs to the adaptive filter are zero mean wide sense stationary, and Gaussian random processes, and further making use of the independence assumption. we derive expressions that characterize the mean and maen squared behavior of the filter coefficients as well as the mean squared estimation error. Conditions for the mean and mean squared convergence are explored. Comparisons are also made between the performance of the NLMS algorithm and that of the popular least mean square(LMS) algorithm Finally, experimental results that show very good agreement between the analytical and emprincal results are presented.

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Investigations of Reactive Intermediate formed in the oxidation of 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,2] octane 1-sulfide (4Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,2]octanel-sulfide의 산화반응 중 생성되는 반응성 중간체에 대한 연구)

  • Kim, Jeong-Han
    • Applied Biological Chemistry
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    • v.39 no.3
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    • pp.227-234
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    • 1996
  • 4-Methyl-2,6,7-trioxa-1-phosphabicyclo [2,2,2] octane 1-sulfide (BPS), 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,2] octane 1-oxide (BPO) and related monocyclic methylphosphates were prepared and the oxidation of BPS with MCPBA in chlorofrom or methanol was carried out to investigate the formation of reactive intermediates and reaction mechanism. BPO was the only product in chloroform while in methanol isomeric monocyclic methylphosphates were formed through opening of bicylic structure with subsequent phosphorylation of methanol by reactive intermediate formed in reaction. Formation of little amount of BPO was also observed. The structure of phosphorylating intermediate was probed with various spectroscopic methods and monocyclic methyl sulfenyl ester was suggested as a possible structure.

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Tautomerism and Alkylation of 5-Amino-2H-1,2,4-thiadiazoline-3-one (5-Amino-2H-1,2,4-thiadiazoline-3-one의 토토머화 현상과 알킬화 반응)

  • Cho, Nam Sook;Park, Young Cheol;Ra, Do Young;Kang, Sungkwon
    • Journal of the Korean Chemical Society
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    • v.39 no.7
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    • pp.564-571
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    • 1995
  • 5-Amino-2H-1,2,4-thiadiazoline-3-one has been prepared from 2-thiobiuret through a oxidative cyclization under basic hydrogen peroxide condition. Lactam-lactim tautomerism of 5-amino-2H-1,2,4-thiadiazoline-3-one has been examined by spectroscopic methods and ab initio molecular orbital calculation. These results were shown that 5-amino-2H-1,2,4-thiadiazoline-3-one exists as lactam form. Reaction conditions for alkylating 5-amino-2H-1,2,4-thiadiazoline-3-one with alkyl halides in the presence of various bases were studied in DMF and $H_2O$-THF two phase system. $Li_2CO_3$ base in DMF method gave best result in this investigation. The alkylation has been taken place at N-2 position. The identification of the product is confirmed by spectral data of IR, $^1H$ NMR and $^13C$ NMR and the comparison of authentic sample, 5-amino-2-methyl-1,2,4-thiadiazolidine-3-one, obtained from the oxidative cyclization of 5-methyl-2-thiobiuret.

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Hydrogenation of Polycyclic Aromatic Hydrocarbons Over Pt/Kieselguhr Catalysts in a Trickle Bed Reactor (Trickle Bed Reactor에서 Pt/Kieselguhr 촉매를 이용한 다환방향족 탄화수소 수소화 반응)

  • Seung Kyo, Oh;Seohyeon, Oh;Gi Bo, Han;Byunghun, Jeong;Jong-Ki, Jeon
    • Clean Technology
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    • v.28 no.4
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    • pp.331-338
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    • 2022
  • The objective of this study is to prepare bead-type and pellet-type Pt (1 wt%)/Kieselguhr catalysts as hydrogenation catalysts for the polycyclic aromatic hydrocarbons (PAHs) included in pyrolysis fuel oil (PFO). The optimal reaction temperature to maximize the yield of saturated cyclic hydrocarbons during the PFO-cut hydrogenation reaction in a trickle bed reactor was determined to be 250 ℃. A hydrogen/PFO-cut flow rate ratio of 1800 was found to maximize 1-ring saturated cyclic compounds. The yield of saturated cyclic compound increased as the space velocity (LHSV) of PFO-cut decreased. The difference in hydrogenation reaction performance between the pellet catalyst and the bead catalyst was negligible. However, the catalyst impregnated by Pt after molding the Kieselguhr support (AI catalyst) showed higher hydrogenation activity than the catalyst molded after Pt impregnation on the Kieselguhr powder (BI catalyst), which was a common phenomenon in both the pellet catalysts and bead catalysts. This may be due to a higher number of active sites over the AI catalyst compared to the BI catalyst. It was confirmed that the pellet catalyst prepared by the AI method had the best reaction activity of the prepared catalysts in this study. The majority of the PFO-cut hydrogenation products were cyclic hydrocarbons ranging from C8 to C15, and C11 cyclic hydrocarbons had the highest distribution. It was confirmed that both a cracking reaction and hydrogenation occurred, which shifted the carbon number distribution towards light hydrocarbons.