• Title/Summary/Keyword: 계수극성

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Nano-dispersion of the Organics in the Organic/Inorganic Sol-Gel Hybrid Matrices (유/무기 졸-겔 재료에 광기능성 유기물의 나노 분산)

  • 백인찬;석상일;진문영;이창진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.218-218
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    • 2003
  • 21세기 정보기반사회에서는 정보처리량의 증가로 인한 대용량 정보 교환을 위하여 신호처리의 고속화/광대역화가 요구되어진다. 완전 광통신망의 구축에 의한 대용량의 광통신을 위해서는 고속이며, 집적화가 가능한 저가의 광전자 소자 개발이 필요하다. 광전자 소자 중 전기-광학 변조 효과를 이용한 광소자의 구현을 위한 소재로서 극성 배향된 비선형 광학 유기고분자 소재는 가공성이 뛰어나 원하는 형태의 광도파로로 제조할 수 있다는 장점에 많은 연구가 진행되고 있다. 그러나 아직 전기광학계수의 향상과 더불어 유기고분자가 가지고 있는 열 및 광화학적 안정성이 낮은 기본적인 문제점과 폴링(poling)에 의해 배향된 극성이 시간에 따라 완화되는 문제의 해결이 요구되고 있다. 이러한 문제점 해결을 위한 기초 연구로 유기물을 졸-겔 매트릭스에 나노 사이즈로 분산하는 방법으로 유기물의 내화학적 안정성을 향상하고자 시도하였다. 잘 알려져 있는 바와 같이 유/무기 하이브리드 졸-겔 재료는 광 투광성이 우수하고 저온에서의 재료 합성과 저가 공정이 가능하여 광기능성 유기물의 호스트(host) 재료로 많이 연구되고 있다. 본 연구에서는 MTMS(methyltrimethoxysilane)과 TEOS (tetra-ethoxyorthosilicate)를 0-100 mol%로 혼합하고 가수분해하는 방법으로 친수성/친유성 특성을 제어하여, 분산되는 유기물의 사이즈를 조정하였다. 각 실험 조건에 따른 유기물 분산체의 크기를 SEM 및 TEM으로 관찰하였으며, 나노 사이즈로 분산된 유/무기 졸-겔 코팅막의 광학적 특성을 프리즘 커플러를 이용하여 조사하였다.

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Enhanced Migration of Gasohol Fuels in Clay Soils and Sediments (Gasoline-ethanol(Gasohol)혼합액의 점토층 내 이동에 대한 연구)

  • Hee-Chul Choi;W.M. Stallard;Kwang-Soo Kim;In-Soo Kim
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.67-79
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    • 1996
  • Clay soils typically have low hydraulic conductivities in the presence of high polarity pore fluid, such as water. Low polarity fluids, such as hydrocarbon fuels and halogenated organic solvents, typically cannot migrate into clay pores because they cannot displace the pore water. Oxygenated additives in gasoline, such as alcohols and methyl-tert-butyl ether, are increasingly used to control air pollution emissions. These relatively polar and highly water-soluble compounds may facilitate displacement of pore water and enhance migration of fuels and solvents through clay-rich soil strata. In the reported research, the migration of gasoline-alcohol fuel mixtures (gasohol) through consolidated clay was examined. Prepared kaolinite clay samples were consolidated from slurry, and various combinations of gasoline, alcohol, and water were applied to the clays under 152 Pa gauge pressure. Movement of the fluids into the clay samples was monitored by measur ing displaced pore fluid and by magnetic resonance imaging of the samples. The structures of selected samples were examined using environmental scanning electron microscopy. Results of the research suggest that alcohol added to hydrocarbon fuels can enhance migration through some clays significantly. Gasoline did not migrate appreciably into water saturated clay, even after 14 days under pressure. The gasohol mixture migrated readily into the clay in only 20 minutes. Increased hydraulic conductivity of the clay in the presence of gasohol is hypothesized to be due to the collapse of the clays pore structure when ethanol is present, creating larger pores. Increasing pore diameter decreases the capillary pressure needed for the gasohol to replace water and allows gasohol to migrate through the clay.

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Analysis of Polar Maps of Dipyridamole Stress/Rest $^{99m}Tc$-MIBI Myocardial SPECT in 14 Healthy Young Men (건강한 청년 남자 14 례에서 Dipyridamole 부하 $^{99m}Tc$-MIBI 심근 SPECT 극성지도의 분석)

  • Cho, Ihn-Ho;Sin, Dong-Gu;Lee, Hyoung-Woo;Kim, Young-Jo;Shim, Bong-Sup;Lee, Hyun-Woo
    • Journal of Yeungnam Medical Science
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    • v.11 no.1
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    • pp.146-152
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    • 1994
  • We performed the same day dipyridamole stress/rest myocardial SPECT in 14 healthy young men, reconstructed the polar maps according to Cedars-Sinai method and quantitated the radioactivity of myocardial wall. We divided the whole myocardium to 9 sectors. The latero-anterior wall contains the highest count. The infero-septal wall contains the lowest count. There isn't any significant differences of radioactivity in each segment between stress and rest polar map. The hemodynamic parameters after dipyridamole injection in the subjects were significantly changed except systolic blood pressure : the heart rate was increased and diastolic blood pressure was decreased. Adverse effects were reported in 85.7%. We suggest that these data can be used to dectect perfusion defect in the coromary artery disease.

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Measurement of Peltier Heat at the Solid/Liquid Interface and Its Application to Crystal Growth I : Theoretical Approach (고/액 계면에서의 Peltier 열 측정 및 결정성장에의 응용 I : 이론적 접근)

  • Kim, Il-Ho;Jang, Gyeong-Uk;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1108-1111
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    • 1999
  • The Peltier heat absorbed or evolved at the solidiliquid interface in the unidirectional solidification process could contribute to the increase of temperature gradient in liquid and growth velocity, and the enhancement of crystal orientation. In this study, in order to measure the Peltier heat generated at the solidiliquid interface as a way of application to crystal growth, the thermoelectric effects were investigated on the temperature changes at the solid- and liquid-phase of the same material and its interface. Through the theoretical consideration, it was possible to separate sole Peltier. Thomson or Joule heat from the temperature changes due to current density, polarity, and temperature gradient. Thomson coefficient of solid- and liquid-phase as well as Peltier coefficient at the solid/liquid interface could be obtained.

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Simple Neutral Point Potential Control with Wide Modulation Indices Using Unified Voltage Modulation for Three-Level Diode-Clamped Inverter (3레벨 NPC 인버터의 전원전압변조 방식을 이용한 넓은 변조 지수에서 제어 가능한 간단한 중성점 제어 기법)

  • Moon, Seok-Hwan;Park, Byoung-Gun;Kim, Ji-won;Kim, Jong-Mu;Lee, Ki-chang;Ha, Hyung-Uk;Lee, Jung-Uk;Park, Byeong-Woo
    • Proceedings of the KIPE Conference
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    • 2014.07a
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    • pp.221-222
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    • 2014
  • 본 논문에서는 3레벨 NPC 인버터의 전원전압변조 방식을 이용하여 넓은 변조 지수에서 제어 가능한 간단한 중성점 제어 방법을 제안하였다. 제안한 제어 방법은 전원 전압 변조방법을 이용한 중성점 균형 계수와 정확한 옵셋 전압의 제한치를 이용하여 계산된다. 중성점 균형 계수는 전류의 극성과 상하 커패시터의 전압에 의해서 정의되어 진다. 제안된 제어 방법은 중성점 제어를 위해 공간전압 PWM과 불연속 PWM까지 동작범위를 확장하여 동작되어 진다. 제안된 방법은 넓은 변조지수에서 전원전압변조를 이용하여 공간전압 PWM방법을 쉽게 구현할 수 있다. 제안된 중성점 제어 방법의 타당성은 시뮬레이션을 통하여 검증하였다.

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The Permeation Properties of $O_{2}\;and\;N_{2}$ for BPSf/TMSPSf Blend Membrane (BPSf/TMSSf 블렌드막을 통한 산소와 질소의 투과특성)

  • Kim Hyunjoon;Hong Suk-In
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.29-36
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    • 2001
  • The permeation properties of $O_2\;and\;N_2$ were measured for bromobisphenol A polysulfone(BPSf), bisphenol A trimethylsilylated polysulfone(TMSPSf) and their blend membrane to investigate the structure-properties relationships. BPSf shows relatively high permselectivity. It can be explained that the strong polarity of bromine in BPSf increases chain packing ability. In this case the distance of polymer chains is reduced by increasing of interchain interaction by induced dipole. TMSPSf shows relatively high permeability. The higher value of permeability coefficients for TMSPSf is due to the substitution of very bulky trimethylsilyl groups. The replacement of phenyl hydrogens of bisphenol A polysulfone(PSf) with trimethylsilyl groups results in higher fractional free volume(FFV). In this work, taking into account the complimentary features of BPSf and TMSPSf, BPSf/TMSPSf blend was prepared and the compatibility in mixing are examined. The BPSf/TMSPSf blend shows higher permeability than commercial PSf, with minimum loss of selectivity. The miscibility of the BPSf/TMSPSf blend is confirmed by the single glass transition temperature.

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Thermal and temporal stabilities of a electro-optic coefficient $\gamma_{33}$ in a PI-SOT nonlinear polymer thin film (고분자 박막인 PI-SOT의 전기광학계수 $\gamma_{33}$의 열적 . 시간적 안정성)

  • Jeong, Youn-Hong;Jo, Jae-Heung;Chang, Soo;Kim, Tae;lee, Kwang-Sup
    • Korean Journal of Optics and Photonics
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    • v.10 no.3
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    • pp.188-194
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    • 1999
  • We synthesized the nonlinear optical (NLO) PI-SOT(polyimide system, 4-[N,N-bis(hydroxyethyl)amino-4,-($\beta$-cyano-$\beta$-methylsulfonyl)vinyl]azobenzene) polymer with high electro-optic coefficients as well as good thermal and temporal stabilities of the elector-optic coefficient ${\gamma}_33$ by the simple Mitsunobu reaction. By using the simple reflection method of C. C. Teng, we measured the thermal and temporal stabilities of the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer at the wavelength of 632.8 nm and 852 nm, respectively. At the temperature of $20^{\circ}C$, the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer were 25.12 pm/V at the wavelength of 632.8 nm and 5.40 pm/V at the wavelength of 852 nm. These values were highly stabilized for more than 60 days at 2$0^{\circ}C$ and stabilized within 6% for more than 10 hours at $100^{\circ}C$.

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Analysis of Impedance of Multilayer Structure using Cepstrum Technique (켑스트럼 기법을 이용한 다층구조물의 임피던스 해석)

  • Shin, Jin-Seob;Jun, Kye-Suk
    • The Journal of the Acoustical Society of Korea
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    • v.16 no.4
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    • pp.85-89
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    • 1997
  • In this paper, the imdedance for each layer using triple cepstrum signal processing for reflected ultrasonic signal from the multilayer structure has been analyzed. The reflection coefficient can be obtained from the amplitude and the polarity of the peaks in the triple cepstrum, and then the impedance of each layer has been reconstructed by the reflection coefficient. In this experiment, four types of multilayers consisting of different metal layers were manufactured. The reflected signals from the multilayer structure have been detected by pulse-echo method. The impedances have been reconstructed by triple cepstrum technique. The experimental results have been in good agreement with the theoretical results.

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Effects of Vortex Viscosity Variation on the Flowfields in a Micro-slot between Rotating Surfaces of Revolution (와점성 변화가 회전곡면으로 이루어진 마이크로 슬롯 유동장에 미치는 영향)

  • Choi, G.W.;Kim, Youn-J.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.591-596
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    • 2001
  • Micron-size mechanical devices are becoming more prevalent, both in commercial applications and in scientific inquiry. Within the last decade, a dramatic increase in research activities has taken place, mostly due to the rapidly expanding growth of applications in areas of MEMS(Micro-Electro-Mechanical Systems), bioengineering, chemical systems, and advanced energy systems. In this study, we have described the effects of vortex viscosity variation on the flowfields in a micro-slot between rotating surfaces of revolution using a micropolar fluid theory. In order to solve this problem, we have used boundary layer equations and applied non-zero values of the microrotation vector on the wall. The results are compared with the corresponding flow problems for Newtonian fluid. Results show that the coefficient $\delta$ controls the main part of velocity ${\upsilon}_x$ and the coefficient M controls the main part of microrotation component ${\Omega}_{\theta}$.

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Poly(vinyl alcohol) Membranes Containing Sulfonic Acid Groups for Direct Methanol Fuel Cell Application (설폰산기를 함유한 PVA막의 직접 메탄올 연료전지 응용)

  • Lee Young Moo;Lee Sun Yong
    • Membrane Journal
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    • v.14 no.3
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    • pp.240-249
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    • 2004
  • Crosslinked PVA membranes were achieved by esterification between the hydroxyl groups of PVA and carboxyl group of sulfosuccinic acid (SSA). SSA containing sulfonic group was used as a chemical crosslinking agent as well as a donor of fixed anionic group ($-SO_3$H). The crosslinking density of membranes was controlled by SSA content and calculated using polar and non-polar solvent. The crosslinking density measured by using non-polar solvent such as xylene and benzene increases with SSA content. However, using the polar solvent such as water and methanol, the crosslinking density increases up to SSA content of 20 wt% and above the content decrease due to sulfonic acid groups. The crosslinked PVA membranes were studied in relation with water diffusion coefficient and mechanical property as well as proton conductivity and methanol permeability as a function of crosslinking density. These properties were all dependent on the effect of SSA content.