• Journal of the Society of Cosmetic Scientists of Korea
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• v.25 no.3
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• pp.1-21
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• 1999

화장품, 의료용, 가정용품 및 공업용제품에까지 광범위한 용도로 사용량이 많은 중요한 비이온 계면활성제의 종류 중에서 polyoxyethylene(POE) 부가형 계면활성제의 경우 그 부가몰수에 따라 특성이 달라지고 용도가 다르게 사용된다. 이때 부가된 분자들의 분자량이 크고 분포를 이루는 혼합물이기 때문에 분석이 매우 어렵다. 따라서 MALDI-TOF/MS 방법을 이용하여 이들의 분자량과 그 분포를 측정함으로써 쉽고 빠르게 측정할 수 있는 새로운 방법을 개발하고자 하였다. 이 논문에서는 화장품에 주로 사용되는 비이온 계면활성제를 선택하여 MALDI-TOF/AfS를 측정하여 스펙트럼으로부터 분자량 분포와 POE부가정도를 측정할 수 있었다. 그리고 이 조건을 적용하여 시중에 판매되는 제품에서 추출된 비이온 계면활성제의 MALDI-TOF/MS 스펙트럼으로부터 분자량 분포와 POE 부가 정도를 확인 할 수 있었다.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.1
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• pp.70-73
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• 2013

Solubility of oil contaminants in surfactant solutions plays an important role in selecting a suitable surfactant type for soil remediation. Solubility measurement procedures consist of making an equilibrium between surfactant solution and oil, solvent extraction using dichloromethane, and condensation for gas chromatography analysis. Solubility measurement requires time consumption and lots of materials. Interfacial tension is the contracting force between two immiscible liquids, surfactant solution and oil, and also closely related to solubility of oil. This study established a relationship between the interfacial tension and solubility of diesel fuel in surfactant solution and suggested a quick method to estimate solubility of oil in a surfactant solution by measuring its interfacial tension. The results of this study showed that the solubility of diesel fuel in surfactant solution was exponentially increased by decreasing the interfacial tension between two immiscible liquids. The solubility of diesel fuel was significantly increased under the interfacial tension conditions below 1 dyne/cm, while the solubility change was not apparent under the interfacial tension conditions beyond 5 dyne/cm. Interfacial tension measurements may allow us to quickly select an efficient surfactant and its concentration for soil remediation.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.291-298
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• 2016

In this study, zwitterionic surfactants were added to liposome systems at different pH conditions to understand the effect of surfactants on liposome characteristics. For this purpose, amine oxide surfactants having different hydrocarbon chain lengths were synthesized and the structure of the resulting product was elucidated by using $^1H$ NMR, $^{13}C$ NMR, and FT-IR. In addition, the physical properties of newly synthesized surfactants such as critical micelle concentration (CMC), surface tension and isoelectric point were measured. The stability characteristics of liposome systems including average particle sizes and zeta potentials were measured by varying pH and hydrocarbon chain lengths of an amine oxide surfactant. Effects of the pH and hydrocarbon chain length of an amine oxide surfactant on fluidity of a liposome membrane were also examined by measuring the deformability and the binding degree between the surfactant and liposome.

• Clean Technology
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• v.19 no.4
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• pp.481-486
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• 2013

Alkali-surfactant-polymer (ASP) solution was manufactured by using the domestic surfactants for enhanced oil recovery. Domestic surfactants such as linear alkylbenzene sulfonic acid (LAS) and dioctyl sulfosiuccinate (DOSS) were used. This surfactants were purchased from AK chemtech Co., Ltd. (Korea). LAS and DOSS were blended and the ratio of LAS to DOSS are 1:1 and 2:1. Decane was used as a model compound of the crude oil. Surfactant solution and decane were blended to analyze microemulsion. Brine-oil-surfactant are mixed at varying concentration of brine from 0.8 to 3.6 wt.%. Increasing salinity causes the phase transition of microemulsion from water to middle to oil. Also, by measuring the surface tension and interfacial tension using pendent drop tensiometer and Huh's equation optimal ratio of the ASP solution was determined.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.394-396
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• 2008

기존의 PECVD에서 문제시 되고 있는 플라즈마에 의한 박막손상과 $300^{\circ}C$ 이상의 증착온도 등의 단점을 보완한 증착 기술로 중성입자 빔 (Hyper-thermal neutral beam ; HNB)을 이용한 저온 증착방법에 대한 연구를 진행하였다. 중성빔을 이용하여 HNB sputtering 방법과 $SiH_4$와 Ar, $H_2$ 가스를 이용한 HNB CVD 방법으로 a-Si 박막 제작에 대한 연구를 진행하였고, HIT(heterojunction with Intrinsic Thin layer) cell 태양전지를 만들고자 기본적인 박막 증착과 박막 특성 및 계면특성 등의 분석을 실시하였다. 유리기판과 p-type Si 기판 위에 a-Si 및 nc-Si 박막을 증착하였으며, TEM, FTIR, Raman, IV 측정 등을 통해 그 특성을 분석하여 HNB의 특성 및 효과를 규명하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.493-496
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• 1999

Ni/3C-SiC 옴믹 접합에 대한 미세구조적-접합 특성과의 상관관계를 규명하였다. 3C-SiC 웨이퍼 위에 저저항 전면 옴믹 적합층을 형성하기 위하여 Ni(t=300$\AA$)을 thermal evaporator를 사용하여 증착하고, 50$0^{\circ}C$, 80$0^{\circ}C$, 103$0^{\circ}C$ 온도에서 30분간(Ar 분위기) 열처리 한 후, scratch test를 실행하여 Ni/3C-SiC의 접착력 특성을 조사하였다. 여러 다른 온도에 따른 Ni/3C-SiC 층의 표면과 계면의 미세구조는 X-ray scattering 법을 사용하였다. 50$0^{\circ}C$ 에서 열처리된 Ni/3C-SiC 층은 가장 낮은 계면 평활도와 가장 높은 표면 평활도를 나타내었다. Ni/3C-SiC 접착력 분석에서 500 $^{\circ}C$ 열처리된 시편의 측정된 임계하중 값은 As-deposited 시편(12 N~ 13 N)보다 훨씬 낮은 2 N~3 N 범위의 값을 보였으나, 열처리 온도가 증가함에 따라 다시 높아지는 경향을 보였다. 미세구조 특성에서는 열처리 온도가 500 $^{\circ}C$ 이상에서는 NiSi$_2$silicides의 domain size는 결정성의 향상에 따라 증가되었다. 결정성 향상이 3C-SiC와 silicides 사이의 격자상수의 낮은 불일치를 완화시키는데 기여 하였 다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.219-220
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• 2005

본 논문은 산소 플라즈마 처리에 따른 반도전성 실리콘 고무의 표면특성 변화를 조사하였다. 실리콘 고무는 각종 초고압 전력기기에서 절연부품으로 많이 사용되어 지고 있다. 하지만, 실리콘 고무가 가지고 있는 고유의 특성 때문에 반도전성 부품과 절연성 부품간의 계면이 접착이 잘 되지 않는 문제점이 나타난다. 이를 위해서 접착제를 사용하거나 표면 거칠기를 변화시키는 개질을 하기도 하지만, 이는 새로운 계면을 형성하거나 약점을 만드는 문제가 있다. 이를 위해 반도전성 실리콘 고무 표면을 산소 플라즈마 개질시켜, 표면을 활성화 시키는 역할과 표면을 균일하게 에칭시켜 기계적 interlocking 메커니즘으로 접착력을 향상시킬 수 있다. 본 실험에서는 산소 플라즈마 처리에 따른 반도전성 실리콘 고무의 표면을 표면에너지. XPS로 기본적인 표면특성을 조사하였다. 실험 결과, 단시간의 산소플라즈마 처리로 표면에 다수의 관능기가 관찰되었다. 이러한 산화층은 실록산 결합쇄가 산화된 실리카 유사층으로 밝혀졌다. 이로써 절연부와 접착 용이성이 기대되었으며, 벌크적인 실리콘 고무의 특성변화 없이 표면개질 만으로 우수한 계면특성을 얻을 수 있다.

• Composites Research
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• v.30 no.4
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• pp.235-240
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• 2017

Animal glue, a water-soluble adhesive, has been used historically for high-performance traditional furniture despite the disadvantage of weakness against moisture. Many scientists studied the ways to improve water resistance of animal glue. Improvements on the interfacial, thermal, and water resistance properties of wood sandwich composites (WSC) was studied with carbon nanotube (CNT) wt% in animal glue. Real-time temperature of WSC was measured after WSC was heated with increasing CNT wt%. Lap shear test was performed to determine the interfacial properties of wood and animal glue with CNTs. Water resistance properties of animal glue were determined by lap shear test using specimens dipped in water and the results were compared with the dry case. Hydrophobicity of animal glue by static contact angle was correlated with the variation of lap shear test. Interfacial, thermal, and water resistance properties for animal glue were improved with properly added CNTs.

• Journal of Adhesion and Interface
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• v.1 no.1
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• pp.47-55
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• 2000

In this article, the characterization of the interface of hybrid composites was discussed. Interfacial interaction in organic/inorganic hybrid composites, especially silica-containing hybrids can be characterized by fluorescence spectroscopy, small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), atomic force microscopy (AFM), and $^{29}Si$ NMR spectroscopy measurements.

• Applied Microscopy
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• v.29 no.2
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• pp.255-263
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• 1999

We have investigated the interfacial reactions in Co/Ti multilayer thin films prepared by DC Magnetron sputtering system. We observed that the amorphous Co-Ti phase formed by SSAR (Solid State Amorphization Reaction) upon annealing at $200^{\circ}C$. Upon annealing treatments at $300^{\circ}C\;and\;400^{\circ}C$, a crystalline phase of CoTi formed at the Co/Ti interface. The sheet resistance of Co/Ti multilayer thin film increased by the formation of the amorphous phase at the Co/Ti interface, which decreased by the formation of new crystalline compound CoTi.