• Title/Summary/Keyword: 계면활성제 무첨가

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Gelatinization and Retrogradation Properties of Surfactant Added Sweet Potato Starches (계면활성제 첨가 고구마 전분의 호화와 노화특성)

  • Lee, Shin-Kyung;Shin, Mal-Shick
    • Applied Biological Chemistry
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    • v.37 no.6
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    • pp.463-471
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    • 1994
  • Physicochemical properties, gelatinization and retrogradation characteristics of surfactant added sweet potato starches were investigated. Three different surfactants, SSL (sodium stearoyl-2-lactylate), Dimodan (mono/diglyceride) and SE1670 (sucrose fatty acid ester 1670) were used. Shapes and crystallinities of starch granules were not changed by the addition of surfactants. Total lipid contents increased and the amylose content decreased by the addition of surfactants and the order was as follows: SE1670>SSL>Dimodan. The swelling power and solubility at $80^{\circ}C$ decreased in the surfactant added starches. By amylograph, initial gelatinization temperature of untreated sweet potato starch was $72.5^{\circ}C$, and did not change by the addition of surfactants, but SE1670 or Dimodan added starch showed the peak viscosity. The peak temperature of gelatinization and enthalpy of untreated starch by DSC were $53.9^{\circ}C$ and 1.3cal/g, respectively. The peak temperature increased by the addition of surfactants, while the enthalpy decreased. In gelatinization by alkali, the viscosity was lower in surfactant added starches than in untreated starch at concentration. The degree of retrogradation by ${\alpha}-amylase-iodine$ method was a lower in SSL and SE1670 added starches than untreated starch and the enthalpy by DSC also decreased in surfactant added and retrograded starches.

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Effect of Surfactants on the Characteristics of Cooked Rice During Storage (계면활성제가 저장 중의 밥의 특성에 미치는 영향)

  • 김수경;이신경;신말식
    • Korean journal of food and cookery science
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    • v.13 no.3
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    • pp.278-285
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    • 1997
  • The effects of three surfactants (SSL, Dimodan, and SE1670) on the properties of cooked nonwaxy and waxy rice during storage were investigated by sensory evaluation, instrumental test, and measurement of retrogradation degree. The results of sensory evaluation revealed that the overall quality of cooked rice was affected by textural characteristics. The addition of surfactant decreased the roughness and hardness of cooked rice, however, increased the stickiness and moistness during the storage in the order of SE, SSL, and Dimodan. In instron test, the hardness of surfactant-added cooked rice was significant lower than that of control. The addition of surfactant decreased the degree of retrogradation both in cooked nonwaxy and waxy rices.

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Application Methods for Enhancing Phytotoxicity of Glyphosate I. Effects of Surfactants and Spray Volumes on Leaf Retention of Various Plant Species (Glyphosate의 살초효과(殺草效果) 증진(增進)을 위한 살포방법(撒布方法)에 관(關)한 연구(硏究) I. 계면활성제(界面活性劑)와 살포량(撒布量)에 따른 초종별(草種別) Glyphosate 엽면부착량(葉面附着量)의 차이(差異))

  • Lee, J.J.;Pyon, J.Y.
    • Korean Journal of Weed Science
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    • v.7 no.1
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    • pp.58-63
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    • 1987
  • Laboratory and greenhouse studies were conducted to evaluate effects of spray volumes and surfactants, L-77 and Triton CS-7 on leaf retention of glyphosate in Zea mays, Hordeum vulgare, Artemisia princeps, Trifolium repens and Equisetum arvense. Leaf retention was increased when glyphosate with L-77 or Triton CS-7 was applied in a spray volumes of 10-20 l/10a in Zea mays and 40 l/10a in Artemisia princeps but decreased when spray volumes were higher than above volumes and 40-80 l/10a in Trifolium repens. Hordeum vulgare leaves retained more spray when glyphosate with L-77 or Triton CS-7 was applied in all spray volumes tested. Equisetum arvense retained higher amount of spray by application of glyphosate with L-77 compared with Triton CS-7 and no surfactant treatments.

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The Roles of Lipid Supplements in Ethanol Production Using a Continuous Immobilized and Suspended Cell Bioreactor (연속식 고정화 및 현탁 세포 생물 반응기에 의한 에탄을 생성중 지질 첨가 영향)

  • Gil, Gwang-Hoon
    • Applied Biological Chemistry
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    • v.39 no.1
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    • pp.1-8
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    • 1996
  • A one-stage, continuous-flow bioreactor with both immobilized and suspended cells was used to investigate the roles of lipid supplements in ethanol production by Saccharomyces cerevisiae. The reactor performance and the level of alcohol dehydrogenase(ADH) activities of the suspended cells, grown under various conditions, were measured. When ergosterol and/or oleic acid were added with surfactants to the yeast culture grown under non-aerated conditions, remarkable increases in ethanol production and cell growth was achieved, but specific ADH activities were not affected. Especially, no difference of specific ADH activities of the suspended cells grown under aerated and non-aerated condition was observed. The addition of the surfactant as a supplement also resulted in significant increases in ethanol production, cell growth, and specific ADH activity. When ergosterol and oleic acid were added to the yeast culture exposed to higher ethanol concentration($>40\;g/{\ell}$) level, ethanol production, cell growth, and specific ADH activity were increased, but the addition of surfactant was as effective as at lower ethanol concentration level. The results indicated that lipid supplements were more effective at higher ethanol concentration level than at lower ethanol concentration level during ethanol production. ADH isozyme patterns of the yeast cultures grown under various conditions on starch gel electrophoresis showed only one major band, probably ADH I. The migrating distance of the major isozyme, however, varied slightly according to the culture conditions of the cells. No apparent correlation was found between specific ADH activity and amount of ethanol produced. Cell mass was more important factor for ethanol production than specific ADH activity of the cells.

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Photovoltaic Effect of Adsorbed Metallophthalocyanine on Zinc Oxide (프탈로시아닌이 흡착된 산화아연의 광기전력효과에 관한 연구)

  • Soun-Ok Heur;Young-Soon Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.4
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    • pp.416-422
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    • 1993
  • As a result of adsorbing phthalocyanine (metal free, ${\alpha}\;and\;{\beta}$-Cu) on zinc oxide in aqueous solution using nonionic surfactant, all of the added dye was adsorbed and Na salt of sulfonated phthalocyanine showed the Langmuir monolayer adsorption. To analyze the effect of adsorption on zinc oxide, photovoltage was measured using surface photovoltmeter. The high photovoltaic effect was observed at intrinsic wavelength of zinc oxide and wavelength of adsorbed phthalocyanine dye. Metal free phthalocyanine, ${\alpha}$-copper phthalocyanine and ${\beta}$-copper phthalocyanine showed the highest photovoltaic effect when the percentage of coverage (${\theta}_{BET}$) for zinc oxide is about 80, while sulfonated phthalocyanine showed the highest photovoltaic effect when the percentage of coverage for zinc oxide is about 30.

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Removal of Oil from Soil Using Nonionic Surfactant : The Effects of Middle Phase Formation and Dynamic Interfacial Tension (비이온 계면활성제를 사용한 토양으로부터 오일의 제거에 관한 연구 : 중간상생성 및 동적 계면장력의 영향)

  • Lee, Kee-Suh;Kim, Young-Ho;Kim, Chul-Ung;Lee, Jung-Min;Koo, Kee-Kahb
    • Clean Technology
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    • v.6 no.1
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    • pp.51-60
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    • 2000
  • The soil remediation by non-ionic surfactant solutions ($C_{12}H_{25}O(CH_2CH_2O)_5H$ and Triton X-100) was studied. Depending on the amounts and use of co-surfactants, MPT(phase inversion temperature), dynamic interfacial tension, and the detergency efficiency of the surfactant solutions in soil were investigated. The oils used were kerosene, n-hexadecane, and paraffin oil. With respect to a higher detergency efficiency, a lower interfacial tension and the MPT was very important. The $C_{12}H_{25}O(CH_2CH_2O)_5H$ was better than Triton X-100 on the oil removal from the soil and the effect of oil kinds was kerosene>paraffin $oil{\geq}n-hexadecane$. The co-surfactant, n-dodecanol, reduced the MPT compared to no addition of this, whereas it did not enhance the detergent efficiency.

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Effects of Non-ionic or Zwitterionic Surfactant on in vitro Digestibility of Rice Straw and Growth of Rumen Mixed Microorganisms. (비이온성 및 양쪽 이온성 계면활성제 첨가가 반추위 혼합 미생물의 성장과 볏짚의 in vitro 소화에 미치는 영향)

  • Lee, Shin-Ja;Kim, Wan-Young;Moon, Yea-Hwang;Kim, Hyeon-Shup;Kim, Kyoung-Hoon;Ha, Jong-Kyu;Lee, Sung-Sill
    • Journal of Life Science
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    • v.18 no.4
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    • pp.515-521
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    • 2008
  • This experiment was conducted to investigate effects of non-ionic or zwitterionic (+/-) surfactants on digestibility of rice straw, and changes of growth of rumen mixed microbes, pH, and gas production during in vitro fermentation. Also, during in vitro ruminal fermentation, microbial attachment on rice straw was investigated using scanning electron microscopy (SEM). Tween 80 or SOLFA-850 for non-ionic surfactant (NIS), and 3-(Dodecyldimethylammonio) propanesulfanate (DDAP) for zwitterionic surfactant (ZIS) was supplemented by 0.05% and 0.1% in Dehority's artificial medium containing Holtein rumen fluid, respectively, and the substrate for fermentation was rice straw passed through 1 mm screen. The experiment was composed of 7 treatments (two levels of two NISs, two levels of a ZIS) including the control, and 6, 12, 24, 48 and 72 hr of fermentation time with 3 replications per treatment. Treatment of Tween 80 increased in vitro DM digestibilities during 48 hr and 72 h post fermentations compared to the other treatments, whereas treatment of DDAP as a ZIS resulted in decreased DM digestibility than that of the control from 24 hr post fermentation (P<0.05). Gas production in vitro was greater (P<0.05) with addition of NIS than the control or ZIS, and increased as fermentation time elapsed. Rumen mixed microbial growth was greatest with addition of Tween 80 as NIS, and lowest when DDAP as ZIS was supplemented to the fermentation tube (P<0.05). In SEM observation, rumen microbial population attached on rice straw particle was greater with addition of NIS, but was less with addition ZIS compared with the control. In conclusion we could not found any positive effects of ZIS surfactants on rumunal fermentation characteristics and rumen microbial growth rates.

A Study on Formulation of Surfactant-free Aqueous Cleaning agents and Evaluation of Their Physical Properties and Cleaning Ability (계면활성제 무첨가 세정제의 배합 및 물성/세정성 평가 연구)

  • Lee, Jae Ryoung;Yoon, Hee Keun;Lee, Min Jae;Bae, Jae Heum;Bae, Soo Jeong;Lee, Ho Yeoul;Kim, Jong Hee
    • Clean Technology
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    • v.19 no.3
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    • pp.219-225
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    • 2013
  • Environment-friendly and surfactant-free aqueous cleaning agents have been developed in order to solve various problems generated by surfactants in the aqueous cleaning agents. Aqueous surfactant-free cleaning agents, S-1 and S-2 have been formulated with water-soluble solvents such as propylene glycol and propylene glycol ether on their main components and with some additives. These solvents were chosen because of their good solubility in water and excellent solubility of fluxes which are major contaminants of printed circuit board in the electronic industry. Physical properties of the formulated and the imported cleaning agents were measured to predict their cleaning performance, and their cleaning abilities of flux and solder contaminants were evaluated under the various ultrasonic frequencies by a gravimetric method. The measurement results show that the physical properties of cleaning agent V are generally similar with those of formulated cleaning agents S-1 and S-2. Both the cleaning agent V and the formulated cleaning agents S-1 and S-2 showed similar trends that their pH decrease in the beginning and then increases later on with the increase of their dilution in water. It is considered that the wetting indices of the cleaning agents calculated with experimental values do not not have any influence on their cleaning ability. In ultrasonic cleaning tests under three ultrasonic frequencies of 28, 45, and 100 kHz, their best performances of cleaning solder and flux were obtained at 45 kHz and 28 kHz, respectively, and the cleaning performance of the formulated cleaning agents S-1 and S-2 was better than that of the cleaning agent V. However, in the case of the recommended diluted concentration of 25 wt% cleaning solution, the cleaning performance of the cleaner V for solder and flux was better in the initial stage of cleaning compared to the formulated cleaners. And it may be concluded that the formulated cleaning agents S-1 and S-2 can be applied to cleaning of solder and flux in the industry, based on the experimental results in this study.

Effect of Some Swelling Agents on Soaking Treatment of Raw Silk (생사의 침지처리에서 팽화약제처리 효과)

  • 김영대;김남정
    • Journal of Sericultural and Entomological Science
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    • v.37 no.2
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    • pp.132-136
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    • 1995
  • This study was carried out to elucidate the effective of some swelling agents on the soaking treatment of raw silk. The swelling of raw silk is commonly practiced by soaking in warm water, However, it is not enough to weaving of raw silk. Therefore, the combination of some chemical agents were tested to improve the swelling ratio of raw silk. The pretreatment of raw silk in 0.4N sodium carbonate aqueous solution before soaking in the mixed solution of Emulon 1 g/l, Emanol 0.5 g/l and 0.04N sodium silicate increased the swelling ratio by 57%, compared to the nontreatment. In SEM observation, the surface of raw silk soaked in swelling agents was swollen and smoothed.

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Microbiological Cleaning Effect of Electrolyzed Acid Water by Containing Polysorbates (Polysorbates를 첨가한 전해산화수의 미생물학적 세정효과)

  • Jeong, Jin-Woong;Park, Kee-Jai;Jung, Sung-Won
    • Korean Journal of Food Science and Technology
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    • v.31 no.4
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    • pp.1029-1034
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    • 1999
  • To enhance the cleaning and sterilization effect of cooled electrolyzed acid water on lettuce, several kinds of polysorbates were used at various concentrations in immersion washing process. In case of the treatment containing polysorbate 20, coliform count of lettuce was reduced to about 1/40 level of that in non-treated lettuce. The treatment containing polysorbate 60 did not show a significant sterilization effect. Otherwise, the total and coliform counts of lettuce during immersion in electrolyzed acid water containing 1 ppm of polysorbate 80 was reduced to about 1/300 and 1/1,700 level of those in non-treated one. And, the changes of ORP(oxidation-reduction potential), pH and color value of lettuce in electrolyzed acid water containing 1 ppm of polysorbate 80 were not quite different during 60 min. immersion, but HCIO content decreased from 10.28 ppm to 8.51 ppm after 20 min. immersion. Also, total and coliform count of lettuce immersed in electrolyzed acid water containing 1 ppm of polysorbate 80 was lower to about 1/1,800 after 20 min. and 1/5,550 after 30 min, compared with non-treated lettuce.

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