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Studies on the Estimation of Theoretical cmc and Micellization Range by Computer Programming (컴퓨터 프로그래밍에 의한 이론적 임계미셀 농도 및 미셀화 영역의 산정에 관한 연구)

  • Kim, Tae-Young;Cho, Gyung-Heung;Choi, Seung-Ok;Jeong, No-Hee;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.63-69
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    • 1997
  • Micellization range and cmc for the dilute aqueous solution of sucrose monoesters, that is, sucrose monolaurate, sucrose monomyristate, sucrose monopalmitate, sucrose monostearate and sucrose monooleate were investigated by computer programming. The extreme of the curvature of ${\sigma}$(C) as a new suggested method to determine the cmc and the micellization range was accomplished with computer programming. The values of cmc and micellization range can be obtained by the extreme of the curve by direct processing of only a few experimental data. The values of cmc particulary was in good agreement with those deduced intuitively from the shape of experimental curves of ${\sigma}$(C).

Characterization of Opuntia humifusa Extract Solution Obtained under Low Temperature and Reduced Pressure and Its Application to Cosmetics (천년초 저온 감압 추출액의 특성 분석 및 화장품 적용)

  • Lee, Seo Young;Yoo, Byeongseong;Jin, Byung Suk
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.4
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    • pp.381-388
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    • 2018
  • Various characteristics of Opuntia humifusa (O. humifusa) extract solution obtained under low temperature and reduced pressure were examined and cosmetic essences using the extract solution as a humectant were prepared. The O. humifusa extract solution represented very small surface tension (25 mN/m) and contact angle ($8^{\circ}$), compared with other humectants such as glycerine and 1% hyaluronic acid solution. Also, the viscosity and stickiness of the extract solution were very low. The O. humifusa extract solution made it possible for a small amount of oil to be dispersed stably in water without any surfactant. Unlike other humectants, the viscosity and stickiness of cosmetic essences were reduced as the extract solution content in formulation increased. These results show that the O. humifusa extract solution obtained under low temperature and reduced pressure can be used as a natural humectant that provides moisturizing property and less sticky feeling.

A Numerical Analysis of the Behavior of Liquid Film Around a Rotating Cylinder (회전하는 실린더 주변 액막의 거동에 대한 수치해석적 연구)

  • Lee, Sang-Hyuk;Lee, Jung-Hee;Hur, Nahm-Keon;Seo, Young-Jin;Kim, In-Cheol;Lee, Sung-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.5
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    • pp.481-486
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    • 2011
  • It is important to predict the behavior of a liquid film around a rotating cylinder in the film coating process of the steel industry. When the cylinder rotates, the behavior of the liquid film on the rotating cylinder surface is influenced by the cylinder diameter, the rotation speed, the gravitational force, and the fluid properties. These parameters determine the liquid film thickness and the rise of the film on the cylinder surface. In the present study, the two-phase interfacial flow of the liquid film on the rotating cylinder were numerically investigated by using a VOF method. For various rotation speeds, cylinder diameters and fluid viscosities, the behavior of liquid film on the rotating cylinder were predicted. Thicker film around the rotating cylinder was observed with an increase in the rotation speed, cylinder diameter, and fluid viscosity. The present results for the film thickness agreed well with available experimental and analytical results.

Basic Study of Spray-Behavior Characteristics of Emulsified Fuel (에멀젼연료의 분무거동특성에 관한 기초연구)

  • Yeom, Jeong Kuk;Yoon, Jeong Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.9
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    • pp.763-771
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    • 2014
  • As a preliminary study on the spray behavior characteristics of emulsified fuel, the fuel properties (viscosity, surface tension, and density) and evaporation characteristics of a fuel droplet were investigated. The emulsified fuel was made by mixing diesel and $H_2O_2$. In addition, the macroscopic spray behavior characteristics such as the spray penetrations and spray angles of the emulsified and diesel fuels were compared. The stirring condition of the emulsified fuel was a 9:1 mixture of the diesel fuel and the surfactant span 80. The mixing ratios for the hydrogen peroxide were set at EF2, EF12, EF22, EF32, EF42, EF52, EF62, EF72, EF82, and EF92. The injection pressures were set at 400, 600, 800, and 1000 bar. We found that as the mixing ratio of the hydrogen peroxide was increased from EF2 to EF52, the viscosity of the emulsified fuel increased. However, afterward, the viscosity of the emulsified fuel gradually decreased and approached the viscosity value of the diesel fuel. Therefore, generally oil-in-water emulsions were used for the hydrogen peroxide mixing ratios up to 52 (EF52), and water-in-oil emulsions were used for the hydrogen peroxide mixing ratios above 52. Finally, the spray behavior characteristics (spray penetration and spray angle) of the emulsified fuel were found to be almost independent of the mixing ratio.

Fate and Activity of Microorganism introduced into the Soil (토양에 투입된 미생물의 거동 및 활성)

  • Chung, Jae-Chun;Ju, Seul;Lee, Jae-Woong;Lee, Jung-Jae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.100-116
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    • 2002
  • There are several purpose to introduce microorganism into the Soil. The major purpose is to promote plant growth and inhibit plant pathogens. The model example is to put in nitrogen fixing symbiotic bacteria, Pythium and Rhizobium. In order to achieve the intended goal, the introduced microorganism should survive and colonize with sufficient density. The survival of introduced microorganism depend upon biotic and abiotic factors. Predation and competition are important among biotic factor. Water tension, organic carbon, inorganic nutrients(N, P), pH are important factor among abiootic factor. Soil texture and distribution of soil pore are also important in the survival and colonization of introduced microorganism. Selection by soil ecosystem for inoculant is a crucial factor for colonization. Good example are control of autochtonous microorganism and the introduction of surfactant biodegrading Pseudomonas. Sometimes, carriers such as peat and montmorillonite can be added to help colonization. Carriers can protect introduced microorganism by supplying protective microhabitat. Organic polymer is also used as a carrier to immobilize bacteria or industrial enzymes. Examples of these carrier are calcium alginate, agarose and k-carrageenan. The function of these carrier is to provide microhabitat and help colonization for introduced microorganism.

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Physico-chemical Properties and Antibacterial Activities of Lactonic Sophorolipid (락톤형 소포로리피드의 물리화학적 특성 및 항균효과)

  • Cho, Soo A;Eom, Gyeong Tae;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.303-307
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    • 2019
  • Sophorolipid is a biological surfactant of the glycolipid structure produced by Candida bombicola, which generally exists as a mixture of acidic and lactonic forms. In this study, we investigated physico-chemical properties, antibacterial activities, and cytotoxicity of the sophorolipid containing more than 96% of the lactonic form, produced by the gene regulation of production strains and application of a metabolic engineering technique. The lactonic sophorolipid showed a weak acidity in the range of pH 3.2~4.6 when diluted in water at the concentrations from 1 to 0.001 wt%. The $pK_a$ value of the lactonic sophorolipid was estimated to be around 4.3 from the acid-base titration curve. The critical micelle concentration (CMC) of the lactonic sophorolipid was $10^{-2}wt%$, at which the surface tension of aqueous solution was reduced to 36 mN/m. The lactonic sophorolipid showed the minimum inhibitory concentrations (MIC) of $1{\times}10^{-3}$ and $5{\times}10^{-3}g/mL$ against Propionibacterium acnes and Corynebacterium xerosis, respectively. The MTT (3-(4,5-Dimethylthiazol-2-yl)-2,5-Diphenyltetrazolium Bromide] assay showed that cytotoxicity of the lactonic sophorolipid was ten times lower than that of triclosan.

Processing of Oleoresin Onion (양파 Oleoresin의 가공)

  • 최옥수;배태진
    • The Korean Journal of Food And Nutrition
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    • v.10 no.3
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    • pp.302-308
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    • 1997
  • The purpose of this study was to investigate the extraction yield and quality stability as to the oleoresin process with large amount of onion at one time. The first mixed-product is raw onion juice which was reduced the compression and concentrated by Brix 70% mixed together wit the residue which was extracted and concentrated by ethanol, the second product manufactured by the same method above after the autoclaving with onion, and the other product is made by grinding by 50mesh to freeze-dried onion. Each of yields were 7.3, 9.1 and 0.8% and each of total sugar content was 616.4, 712.3 and 150.3mg/g. Therefore the product extracted by ethanol from freeze-dried onion was very low in yield and total sugar content. By the index of the overall odor intensity, contents of total pyruvate were 1,733.7, 520.6, and 2,716.5$\mu\textrm{g}$/g for each product. As a result, oleoresin onion processing that desired to use raw onion was remarkable for odor recovery. For the homogenous mixture with concentrate of onion juice and ethanol extract were emulsified by the addition of 2% of PGDR(polyglycerol condensed ricinoleate) and agitation(10,000rpm, 30 minutes). At this time, interfacial tension was 1.9 dyne/cm and the formation of emulsion was for 96.2% when left over 24hours in 6$0^{\circ}C$. When it was to be centrifuged(2,000$\times$G, 80 minutes) after emulsification, the volume of emulsion level without seperation was 92.6%, and very high in emulsification stability. The induced heating-oxidize with soy bean oil and sesame oil added to 1% of onion oleoresin, induction-time extension effect appeared with antioxidant activity that was applicable for 80.8~82.2% as to the effect of addition of 0.02% BHA.

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