• Title/Summary/Keyword: 계면물성

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The Effects of the Coplymerization Conditions in Synthesis of Polycarboxylic Type Superplasticizer on Interfacial Properties and on Cement Mortar Fluidity (Polycarboxylate계 콘크리트 유동화제의 합성에 있어서 공중합 조건에 따른 계면물성 변화 및 이의 시멘트 몰탈의 물성에 미치는 영향)

  • Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.463-468
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    • 2010
  • The polycarboxylic (PC) type concrete superplasticizer was synthesized. The effects of ethylene oxide group number and its molecular weight on the properties of the polycarboxylic type concrete superplasticizer and the concrete motar properties were studied. To investigated of the interfacial properties of the premixed-concrete with the superplasticizer, the type and the amount of polyethylene glycol, meta acrylate added, and type of the initialization agent were studied. Also the interfacial properties of the superplasticizer aqueous phase, the wettability on the cement particle, the fluidity of the cement mortar, and the strength properties of the concrete were measured. For a high fluidity of the cement mortar and a high strength of concrete, a low value of the surface tension and contact angle were required for PC. To have a good performance for PC, the reaction condition of 1.3 mol ratio of MA against to MPEG was suitable with KSP initiator.

Microfailure Degradation Mechanisms and Interfacial Properties of Bioabsorbable Composites for Implant Materials using Micromechanical Technique and Acoustic Emission (Micromechanical 시험법과 음향방출을 이용한 Implant용 Bioabsorbable 복합재료의 미세파괴 분해메커니즘과 계면물성)

  • 박종만;김대식
    • Composites Research
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    • v.14 no.4
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    • pp.15-26
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    • 2001
  • Interfacial properties and microfailure degradation mechanisms of the bioabsorbable composites fur implant materials were investigated using micromechanical technique and nondestructive acoustic emission (AE). As hydrolysis time increased, the tensile strength, the modulus and the elongation of poly(ester-amide) (PEA) and bioactive glass fibers decreased, whereas these of chitosan fiber almost did not change. Interfacial shear strength (IFSS) between bioactive glass fiber and poly-L-lactide (PLLA) was much higher than PEA or chitosan fiber/PLLA systems using dual matrix composite (DMC) specimen. The decreasing rate of IFSS was the fastest in bioactive glass fiber/PLLA composites whereas that of chitosan fiber/PLLA composites was the slowest. AE amplitude and AE energy of PEA fiber decreased gradually, and their distributions became narrower than those in the initial state with hydrolysis time. In case of bioactive glass fiber, AE amplitude and AE energy in tensile failure were much higher than in compression. In addition, AE parameters at the initial state were much higher than those after degradation under both tensile and compressive tests. In this work, interfacial properties and microfailure degradation mechanisms can be important factors to control bioabsorbable composite performance.

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Studies on Surface Free Energy and Tear Properties of Surface-Modified Silicas/LDPE Composites (표면처리된 실리카/LDPE 복합재료의 표면 자유에너지 변화 및 인열물성에 관한 연구)

  • 정우영;박병기;박수진
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.330-333
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    • 2001
  • 일반적으로 하나 또는 그 이상의 입자상 충전재 흑은 섬유상 강화재와 연속상인 고분자 기재로 이루어진 고분자 복합재료는 물성이나 기능이 더욱 더 우수한 고성능/고기능성 고분자 재료에 대한 수요가 급격히 증대됨에 따라 이에 대한 많은 연구가 행해지고 있다[1,2]. 그러나 고분자 복합재료의 응력전달은 강화재와 고분자 기재의 계면을 통하여 일어나게 되므로 복합재료의 기계적 물성 등은 충전재의 양, 입자의 크기, 표면성질 뿐만 아니라 강화재와 고분자 기재 사이의 계면 접착력 또는 계면 성질에 크게 좌우된다. (중략)

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Effect of Interfacial Properties on the Detergency in Dishwashing Agent Composition (식기용 세정제 조성에 있어서 계면물성이 세정력에 미치는 영향)

  • Oh, Hyun-Joo;Lim, Hyo-Seon;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.193-199
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    • 2020
  • The effects of the composition of the dishwashing detergent on interfaces of the oil (O) and the aqueous (W) solution in addition to the cleaning effects of interfacial properties were investigated. Also, the cleaning power of the oil contaminated on the surface of the dish according to each composition and the residuals of the contaminants and the cleaning agent after the washing rinses were evaluated. The removal of contaminated oil on the solid (S) surface in the composition of the cleaning agents used in this study was strongly related to the interfacial properties between the W/O/S, and was particularly dependent on the forward and backward dynamic contact angles. When both contact angles were low at the same time, the permeability of the cleaning solution was so high that the contaminated oil showed a high removal effect. The smaller the interfacial tension of O/W was, the better emulsification of the contaminated oil, the higher the interfacial tension, and the poorer emulsification were achieved. However, the emulsification effect did not significantly affect the cleaning power. In particular, in the case of the cleaner having low interfacial tension, the cleaning material remained on the surface of the solid after washing.