• Journal of the Korea Institute of Building Construction
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• v.14 no.2
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• pp.156-162
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• 2014

This study aims to develop a rapidly hardening type of concrete to achieve the removal of form intensity (more than 10MPa) using the method of curing at room temperature in order to solve some economic environmental problems by omitting the steam curing process involved in producing PC (Precast Concrete). Therefore, this study evaluated a rapidly hardening cement containing a high amunt of C3S, which is very responsive in expressing early intensity, and a rapidly hardening type of concrete which uses some hardening accelerator to increase thehydration reaction of $C_3S$. The results of the experiment on concrete using some hardening accelerator are asfollows. In the slump flow experiment for identifying the liquidity and the air test, the desired values were met. The compression strength showed rapid expression response by 12 hours, and met the desired value within 6~9 hours. Its drying shrinkage value and Autogenous shrinkage value were measured as below ($-754.5{\times}10^{-6}$),and satisfied the requirements. In addition, in the Semi-Adiabatic Temperature Test, it was found that the concrete rose to its peak temperature within 24 hours and then its temperature dropped.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.11a
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• pp.470-473
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• 2011

본 연구에서는 산업현장에서 에폭시 강화촉진제, 도로용 첨가제 등으로 많이 사용되고 있는 경화제(M.E.K)의 혼합비에 따른 자연발화 위험성을 알아보고 산업 현장의 화재 예방을 위한 기초자료로 제공하고자 하였다. M.E.K와 에포비아 수지를 각기 다른 비율로 혼합한 상태에서 시간경과에 따른 시료의 온도변화 와 유증기 발생 및 자연발화 여부를 관찰한 결과 합성수지와 경화제의 혼합시 경화제가 5% 이상으로 혼합될 경우 혼합 수지의 내부온도가 약 $40^{\circ}C$ 이상으로 상승하면서 발포 현상과 함께 다량의 유증기가 발생하였고, 유증기가 발생된 모든 조건에 대하여 자연발화 여부는 확인할 수 없었다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.221-222
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• 2012

This study is to high early concrete development which reveals 14 MPa within 12 hours in order to reduce the mold time of dismantlement and not do the steam curing of the precast concrete product. About (40~50) min could shorten the final setting time if the coagulation test result cement amount 100 kg/m3 was increased. In the case of the compressive strength, it was exposed to be satisfied the target value with the cement amount 500 kg/m3 combination according to the hardening accelerator addition.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.4
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• pp.592-601
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• 2001

Fiber reinforced metal laminates(FRMLs) are new types of hybrid materials. FRMLs consists of high strength metal(Al 5052-H34) and laminated fiber with structural adhesive bond. The mixture ratio effect of epoxy resin$.$curing agent$.$accelerator on the fatigue behavior of FRMLs was investigated in this study. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured by methylene dianiline(MDA) with or without an accelerator(K-54). Eight different kinds of resin mixture ratios were selected for the test ; five kinds of FRMLs(1) and three others of FRMLs(2). The relationship between da/dN and ΔK with variation of resin mixture ratio was studied. FRMLs(1) and FRMLs(2) indicated approximately 2 times and 2.2 times more improved maximum bending strengths in comparison with those of Al 5052-H34. The resin mixture ratio <1:1> in case of FRMLs(1) indicated the maximum fatigue life, while the resin mixture ratio <1:1:0.2> in case of FRMLs(2) indicated the maximum fatigue life. As results, FRMLs(2) turned out to have more effective characteristics on the fatigue properties and the bending strength than those of FRMLs(1).

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.963-969
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• 1996

Cure characteristics of DGEBA(diglycidyl ether of bisphenol A)/dicy(dicyandiamide) system containing diuron(3-(3,4-dichloro phenyl) -1,1-dimethylurea) as an accelerator was investigated. The system has shelf life of six months because dicy is insoluble in liquid/solid resins at room temperature. It is generally known that dicy is an adequate curing agent for one component adhesive due to its highly latent property. With increasing the amount of added dicy, reaction heat of DGEBA/dicy system increased and degree of conversion was not varied. For DGEBA/dicy/diuron system, cure temperature decreased about $40^{\circ}C$ and cure reaction became fast by the addition of diuron which activates dicy. $T_g$ of the mixed resin decreased with the amount of accelerator. which was interpreated with molecular structure forming loose chain. Cure kinetics of DGEBA/dicy and DGEBA/dicy/diuron system were explained using Kamal's autocatalytic reaction model. The effect of acceleration was confirmed with that reaction model.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.929-932
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• 2008

The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.445-448
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• 2008

The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) and UP in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS and UP contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.05a
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• pp.56-58
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• 2013

In order to develop concrete generating compressive strength of 15MPa~30MPa aging for 6~12 hours in the room temperature curing, Hardening accelerator containing Ca²⁺ mixed with rapid hardening portland cement containing C₃S in quantity. The result was that the more addictive contents of Hardening accelerator is, the more greatly early compressive strength was improved. That s because the composition of Ca(OH)₂ was mass-produced at early-ages.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.58-65
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• 1998

Substituted dicyandiamide(Sub-DICY), Accelerated dicyandiamide(Acc-DICY), Trimellitic anhydride(TMA), Pyromellitic dianhydride(PMDA) and Phenolic curing agent(Ph.C.A.) are mainly used for epoxy powder coating curing agent. Various characteristics of epoxy films fully cured by optimum condition such as mechanical properties like $T_g$, tensile strength, elongation at break hardness, abrasion resistance and chemical properties like water absorption, acid resistance, alkali resistance and electrical properties, corrosion resistance are determined by various measuring devices and analyses devices. In conclusion, phenolic curing agent was shown excellent thoughness but severe color change as temperature increased. Acid anhydride has excellent insulation properties and color stability at elevated temperature but lower thoughness and adhesion to substrate. DICY curing agent was shown high water absorption and severe color chance as temperature increased.

• Polymer(Korea)
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• v.38 no.2
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• pp.171-179
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• 2014

Low temperature cure prepregs are being developed for use in the preparation of large-structured fiber-reinforced polymer (FRP) composites with good performance. Cure behavior and chemorheology of low temperature cure epoxy resin system, based on epoxy resin, curing agent, and accelerators, were investigated to provide a matrix resin suitable for the prepreg preparation. Characteristics of cure reaction were studied in both dynamic and isothermal conditions by means of differential scanning calorimetry and rheometry. The low temperature cure epoxy resin system suggested in this study as a matrix resin was curable at $80^{\circ}C$ for 3 h, and showed the gel times of 120 and 20 min at 80 and $90^{\circ}C$, respectively. Thermal and mechanical properties of the cured sample were almost the same as high temperature cure counterparts.