• Title/Summary/Keyword: 경화수축

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Study on the Improvement of Film Shrinkage in UV-curing Process (자외선 경화 과정에서의 필름 수축현상 개선에 관한 연구)

  • Kwon, Youn-Joong;Cho, Ur-Ryong
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.320-324
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    • 2011
  • Two functional urethane acrylates were synthesized by using polycarprolactonediol (PCLD) and diisocyanate. The synthesized fuctional urethane acrylate was mixed with butyl acrylate(BA) or adhesion promoters, and their properties were investigated. To synthesize an excellent transparent urethane acrylate, isophorone diisocyanate(IPDI) was used. In addition, the effect of adding butyl acrylate for the improvement of shrinkage of urethane acrylate was studied. The results showed that the addition of butyl acrylate improved the shrinkage, and the optimum butyl acrylate content was 15 wt%. Both 2-ethyl hexyl acrylate (2-EHA) and ethyl acrylate(EA) were polymerized at $85^{\circ}C$ for 4 hrs to use as adhesion promoters, and the polymerized adhesion promoters were mixed to the UV-curing resin. The results showed that the adhesion properties increased with the increase of adhesion promoters content up to 15 wt%.

Effects of Intaking of Red Ginseng Products on Correlationship between Obesity and Blood Lipids (홍삼류의 섭취가 비만과 혈중 지질의 상호관계에 미치는 영향)

  • 박화진;이정희;이소진;함혜선;조현정;임창률;유영빈;박기현
    • Biomedical Science Letters
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    • v.6 no.4
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    • pp.253-260
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    • 2000
  • Obesity is the risk factor of atherosclerosis and not only increases triglyceride concentration in blood but also decreases relatively the ratio of TG to HDL-Cholesterol in blood. In case of obesity, systolic blood pressure is also increased in responding the increase of TG in blood. Index of obesity in red ginseng-taking group (ginseng group) was lower as compared with non-red ginseng-taking group (control group). The TG concentration, the ratio of triglyceride to HDL-cholesterol in blood and systolic blood pressure were decreased in the subjects of ginseng group compared with that in control group. It is inferred that long-term intake of ginseng products may help to prevent the risk of atherosclerosis and obesity.

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Evaluating Early Age Shrinkage Behavior of Ultra High Performance Cementitious Composites (UHPCC) with CSA Expansive Admixture and Shrinkage Reducing Agent (CSA계 팽창재 및 수축 저감제의 혼입에 따른 UHPCC의 초기 수축 거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.4
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    • pp.441-448
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    • 2011
  • In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

Durability and Crack Control of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 균열제어 및 내구성)

  • Yun, Hyun-Do;Yang, Il-Seung;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.57-64
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    • 2006
  • The crack presented in concrete structures causes a structural defect, the durability decrease, and external damages etc. Therefore, it is necessary to improve durability through the effort to control the crack. Fluosilicic acid($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicates prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.0{\sim}2.0%$ of adding ratio of fluosilicate salt based inorganic compound. To evaluate correlation of concrete strength and adding ratio of fluosilicate salt based inorganic compound, the tests were performed about design strength(21, 24, 27 MPa) with 0.5% of adding ratio of fluosilicate salt based inorganic compound. Applications of fluosilicate salt based inorganic compound to reduce cracks resulted from plastic and drying shrinkage, to improve durability are presented in this paper. Durability was evaluated as neutralization, chloride ion penetration depth, freezing thawing resistant tests and weight loss according reinforcement corrosion. It is ascertained that the concrete added fluosilicate salt based inorganic compound showed m ability to reduce the total area and maximum crack width significantly as compared non-added concrete. In addition, the durability of concrete improved because of resistance to crack and watertightness by packing role of fluosilicate salt based inorganic compound obtained and pozzolanic reaction of soluble $SiO_2$ than non-added concrete.

Studies on Thermal and Mechanical Properties of Siloxane-modified Epoxy Resins (실록산 변성 에폭시 수지의 열적.기계적 특성 연구)

  • 박수진;김현철;박병기
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.451-454
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    • 2002
  • 최근 우주 항공 및 자동차 산업 등에서 기존의 금속재료를 대체하기 위하여 고강도 경량 구조 재료인 선진 복합재료 (advanced composite materials)의 개발에 관심이 모아지고 있다[1]. 선진 복합재료의 매트릭스 수지로서 가장 많이 사용되고 있는 에폭시는 수지 및 경화제의 종류에 따라 여러 가지 물성을 나타낼 수 있다. 에폭시 수지는 기계적 물성 및 내화학성이 우수하고 경화시 수축변형이 적은 장점이 있으나 높은 가교밀도 때문에 순간적인 충격에 취약하다는 단점을 지니고 있다. (중략)

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The Experimental study on setting shrinkage of polymer concrete with recycled PET (재활용 PET를 이용한 폴리머 콘크리트의 경화수축에 관한 실험적 연구)

  • 조병완;태기호;윤영한;박재욱
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.816-821
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    • 2003
  • This paper deals with a reduction in the setting shrikage of polymer concrete using bentonite as shrinkage reducing agent. This study with polymer concrete using unsaturated polyester(UP) based on recycled PET waste was performed to verify the effect of various shrinkage reducing agent contents and the types of filler which are fly ash and $CaCo_3$. Setting stress induced by setting shrinkage was investigated in temrs of mechanical and chemical combination.

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The Material Characteristics of Steel Fiber Reinforced Polymer Concrete (강섬유 보강 폴리머 콘크리트의 재료적 특성)

  • 김기락
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.3
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    • pp.73-80
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    • 1999
  • The objective of this study were to investigate the properties and to improve the disadvantages of the polymer concrete such as brittle fracture, large hardening shrinkage . In this paper, steel fiber reinforced polymer concrete is prepared with various steel fiber aspect ratios(ι/d), contents(vol.%), and their material characteristics were investigated experimentally . The aspect ration (ι/d) of the steel fiber was reversly proportional to slump value, and slump value tended to decrease as increase of steel fiber content . And harding shrinkage and impact resistance tended to be improved as the steel fiber content and aspect ration were increased.

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A Study on the Physical Characteristics of Acryl Concretes for Thin Bridge Deck Pavements (박층 교면포장용 아크릴 콘크리트의 물리적 특성 연구)

  • Kim, Tae-Woo;Kim, Dae-Young;Nguyen, Manh Tuan;Lee, Hyun-Jong
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.1-11
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    • 2009
  • This study focuses on evaluating the applicability of an acryl based polymer concrete to the thin bridge deck pavements. The acryl concrete developed in this study is composed of Methyl Methacrylate(MMA) resin, benzol peroxide and fillers. To study the effects of the types and amounts of the components on the physical characteristics of the acryl concrete, viscosity, compressive strength and bending tests were conducted. The optimum mixture design was then determined based on the testing results. Several different types of laboratory tests, such as water and chlorine ion penetration tests, shrinkage and thermal coefficients tests, and tensile bonding strength tests were performed for the optimum acryl concrete and conventional cement concrete. The testing results show that water and chroline ion resistance, bonding strength between acryl and cement concrete and crack resistance of the acryl concrete is better than those of the conventional cement concrete. There are shortcomings that the conventional acryl concrete has a higher shrinkage and thermal coefficients. However, it was confirmed that to use newly developed rubberized MMA resin in this study reduces the crack resistance with substantially increased ductility.

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An Experimental Research on the Material Properties of Super Flowing Concrete (초유동 콘크리트의 재료특성에 관한 실험적 연구)

  • 김진근;한상훈;박연동;노재호
    • Magazine of the Korea Concrete Institute
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    • v.8 no.3
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    • pp.135-146
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    • 1996
  • In this study, the properties of super flowing concrete containing fly ash were experimentally investigated and compared with those of ordinary concrete. Tests were carried out on five types of super flowing concrete mixes containing fly ash and three types of ordinary concrete mixes without fly ash. Flow test, 0-funnel test, box test, L type test and slump test were carried out to obtain the properties for flowability and workability of fresh concrete. The mechanical properties of hardened concrete were also investigated in terms of compressive strength, splitting tensile strength, modulus of elasticity, creep and drying shrinkage. In fresh concrete, it was found that super flowing concrete had excellent workability and flowability compared with ordinary concrete, and had self-compactable performance. Super flowing concrete *also had good mechanical properties at both early and late ages with compressive strength reaching as high as 40 MPa at 28 days. The creep deformation of super flowing concrete investigated was relatively lower than that of ordinary concrete, but drying shrinkage was much higher.

Influence of Cardiac Contraction and its Phase Angle with Coronary Blood flow on Atherosclerosis of Coronary Artery (심장의 수축운동과 관상동맥 혈류와의 위상차가 관상동맥 혈관의 동맥경화 민감성에 미치는 영향)

  • 김민철;이종선;김찬중;권혁문
    • Journal of Biomedical Engineering Research
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    • v.23 no.6
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    • pp.437-449
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    • 2002
  • Coronary arteries are subjected to very different flow conditions compared to other arteries in systemic blood circulation. We Performed a computational fluid dynamic research to investigate influence of such flow conditions in coronary arteries on development and progress of atherosclerosis in the same. The results showed big differences in the flow field of the coronary artery compared to the abdominal and femoral arteries. The coronary artery showed higher wall shear stresses due to the small vessel diameter. On the other hand, it showed only one vortex distal to the stenosis throat during a whole pulse cycle. However. several vortices were observed in the abdominal and femoral arteries in both proximal and distal sides of the stenosis throat The wall shear stresses and extent of recirculation area were increased with impedance phase angle increasing toward more negative values. Therefore, cardiac contraction and the negative impedance phase angle as large as -110。 may induce a flow field that accelerates atherosclerosis.